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1. 发明申请

US20070253825A1 Airfoil having improved impact and erosion resistance and method for preparing same 失效
标题翻译：具有改进的耐冲击和耐腐蚀性的翼型及其制备方法
公开(公告)号：US20070253825A1
公开(公告)日：2007-11-01
申请号：US11656974
申请日：2007-01-24
申请人： Robert Bruce , Jerry Schell , Mark Gorman
发明人： Robert Bruce , Jerry Schell , Mark Gorman
IPC分类号： F03B3/00
CPC分类号： F01D5/288 , C23C28/321 , C23C28/322 , C23C28/34 , C23C28/341 , C23C28/42 , C23C30/00 , F01D25/007 , F04D29/023 , F04D29/324 , F05D2230/90 , F05D2240/303 , F05D2260/95 , Y02T50/672 , Y10T428/12458
摘要： A turbine airfoil having an improved impact and erosion resistance. The airfoil comprises: (a) a base segment having an impact resistant leading edge section proximate to the leading edge comprising a material having having a yield strength of least about 250 ksi and an elongation percentage of about 12% or less; and (b) an erosion resistant coating overlaying the base segment at least in the leading and trailing edge portions of the pressure side, the erosion resistant coating comprising at least one ceramic layer having at least one of the following properties: (1) an erosion value of at least about 200 g. of erodent to cause a thickness loss of about 15-20 microns; (2) an erosion volume loss value (V) of about 1.9 or less as defined by the equation V=H−0.18×E0.75×F−1.65 where H is hardness, E is elastic modulus and F is fracture toughness; and (3) an F value of at least about 1.5 MPa*m1/2. The erosion resistant coating can comprise alternating ceramic and metallic layers and is typically formed by a method involving the step of forming on the pressure side of the base segment of the airfoil in alternating fashion at least one ceramic layer and at least one metallic layer.
摘要翻译：具有改善的冲击和耐冲蚀性的涡轮机翼型。翼型件包括：（a）具有靠近前缘的抗冲击前缘部分的基部段，包括具有至少约250ksi的屈服强度和约12％或更小的伸长率的材料; 至少在所述压力侧的前缘部和后缘部分覆盖所述基部段的抗侵蚀涂层，所述耐侵蚀涂层包括至少一个具有以下特性中的至少一个的陶瓷层：（1）侵蚀值至少约为200g。的腐蚀导致约15-20微米的厚度损失; （2）如等式V = H -0.18的限定的约1.9或更小的侵蚀体积损失值（V）x = 0.75×F -1.65 < SUP>其中H是硬度，E是弹性模量，F是断裂韧度; 和（3）F值至少约1.5MPa * m 1/2。抗侵蚀涂层可以包括交替的陶瓷和金属层，并且通常通过以下方法形成，该方法包括以至少一个陶瓷层和至少一个金属层交替形成在翼型的基部段的压力侧上的步骤。

2. 发明申请

US20070128360A1 Bond coat with low deposited aluminum level and method therefore 失效
标题翻译：具有低沉积铝含量的粘结涂层和方法
公开(公告)号：US20070128360A1
公开(公告)日：2007-06-07
申请号：US11295278
申请日：2005-12-05
申请人： Mark Gorman , Brett Boutwell , Robert Zimmerman
发明人： Mark Gorman , Brett Boutwell , Robert Zimmerman
IPC分类号： B05D7/22 , C23C16/00
CPC分类号： C23C14/16 , C23C10/02 , C23C10/08 , C23C14/5806 , C23C14/5846 , C23C30/00 , Y10T428/12764 , Y10T428/12944
摘要： A method for applying a NiAl based bond coat and a diffusion aluminide coating to a metal substrate comprises, in part, coating a portion of the external surface of the superalloy substrate, by physical vapor deposition with a layer of a NiAl based metal alloy, wherein the deposited NiAl based metal alloy includes a controlled amount of about 6 to 25 weight percent aluminum, wherein the deposited aluminum level of the NiAl based metal alloy is controlled to be about 50-100% of its final level after aluminizing to form a coated external portion; and subsequently, simultaneously aluminizing the coated external portion and a different surface of the superalloy substrate.
摘要翻译：将NiAl基键合涂层和扩散铝化物涂层施加到金属基底上的方法包括部分地通过物理气相沉积用NiAl基金属合金层涂覆超级合金基底的外表面的一部分，其中沉积的NiAl基金属合金包括约6至25重量％的铝的受控量，其中将NiAl基金属合金的沉积铝含量控制在铝化后的最终水平的约50-100％以形成涂覆的外部一部分; 并且随后对涂覆的外部部分和超合金基底的不同表面进行同时镀铝。

3. 发明申请

US20060121304A1 Article protected by a diffusion-barrier layer and a plantium-group protective layer 审中-公开
标题翻译：由扩散阻挡层和植物群保护层保护的物品
公开(公告)号：US20060121304A1
公开(公告)日：2006-06-08
申请号：US11003244
申请日：2004-12-03
申请人： Mark Gorman , Ramgopal Darolia , Michael Gigliotti
发明人： Mark Gorman , Ramgopal Darolia , Michael Gigliotti
IPC分类号： C25D11/02 , B32B15/00 , B32B15/01
CPC分类号： C23C28/021 , C23C28/321 , C23C28/3455 , Y02T50/67 , Y02T50/6765 , Y10T428/12535 , Y10T428/1259 , Y10T428/12771 , Y10T428/12861 , Y10T428/12875
摘要： A protected article includes a substrate, and a protective structure overlying the substrate. The protective structure has a diffusion-barrier layer overlying the substrate, wherein the diffusion-barrier layer comprises at least about 70 percent by weight iridium, and a protective layer overlying the diffusion-barrier layer so that the diffusion-barrier layer is between the substrate and the protective layer. The protective layer is at least about 70 percent by weight of a platinum-group element. A ceramic thermal barrier coating may overlie the protective layer.
摘要翻译：受保护的制品包括衬底和覆盖衬底的保护结构。保护结构具有覆盖衬底的扩散阻挡层，其中扩散阻挡层包含至少约70重量％的铱，以及覆盖扩散阻挡层的保护层，使得扩散阻挡层位于衬底之间和保护层。保护层为铂族元素的至少约70重量％。陶瓷热障涂层可以覆盖保护层。

4. 发明申请

US20050118334A1 PROCESS FOR INHIBITING SRZ FORMATION AND COATING SYSTEM THEREFOR 审中-公开
标题翻译：抑制SRZ形成和涂层体系的方法
公开(公告)号：US20050118334A1
公开(公告)日：2005-06-02
申请号：US10711240
申请日：2004-09-03
申请人： Mark Gorman , Ramgopal Darolia , Robert Bruce
发明人： Mark Gorman , Ramgopal Darolia , Robert Bruce
IPC分类号： C23C10/60 , C23C16/00 , C23C22/74 , C23C28/00 , C23F1/20 , C23F1/44 , F01D5/28
CPC分类号： C23C10/60 , C23C22/74 , C23C28/321 , C23C28/3215 , C23C28/34 , C23C28/341 , C23C28/345 , C23C28/3455 , C23C28/36 , C23F1/20 , C23F1/44 , F01D5/288 , F05D2230/90 , F05D2300/611
摘要： A process for reducing the incidence of a secondary reaction zone (SRZ) in alloys prone to SRZ formation, particularly superalloys that have a high refractory element content. The process finds use with articles having a wall region that defines external and internal surfaces on the exterior and within the article, respectively. Diffusion coatings are formed on the internal and external surfaces of the article, with at least the diffusion coating on the external surface comprising an additive layer and a diffusion zone that is beneath the additive layer and extends into the wall region. The additive layer and at least a portion of the diffusion zone of the external diffusion coating is then removed to define an exposed surface region on the exterior of the article. An overlay coating is then deposited on the exposed surface region.
摘要翻译：一种降低易发生SRZ合金的合金中次级反应区（SRZ）的发生率的方法，特别是具有高难熔元素含量的超级合金。该方法与具有分别在外部和内部定义外部和内部表面的壁区域的制品一起使用。在制品的内表面和外表面上形成扩散涂层，至少外表面上的扩散涂层包含一添加层和位于该添加层之下并延伸到该壁区域内的扩散区。然后去除外部扩散涂层的添加剂层和扩散区域的至少一部分，以限定制品外部的暴露表面区域。然后将覆盖涂层沉积在暴露的表面区域上。

5. 发明申请

US20050064228A1 Protective coating for turbine engine component 失效
标题翻译：涡轮发动机部件的保护涂层
公开(公告)号：US20050064228A1
公开(公告)日：2005-03-24
申请号：US10668087
申请日：2003-09-22
申请人： Ramgopal Darolia , Mark Gorman , Melvin Jackson , Ji-Cheng Zhao
发明人： Ramgopal Darolia , Mark Gorman , Melvin Jackson , Ji-Cheng Zhao
IPC分类号： B32B15/00 , B32B15/04 , C23C28/00 , C25D3/50 , C25D3/56 , C25D5/10 , C25D5/50 , C25D7/00 , C25D15/02 , F01D5/28
CPC分类号： C23C28/321 , C23C28/325 , C23C28/3455 , C25D3/50 , C25D3/56 , C25D5/10 , C25D5/50 , C25D15/02 , F01D5/288 , F05D2230/90 , Y02T50/67 , Y10S428/926 , Y10S428/935 , Y10T428/12014 , Y10T428/12535 , Y10T428/12611 , Y10T428/12875 , Y10T428/12931 , Y10T428/12944
摘要： A turbine engine component comprising a substrate made of a nickel-base or cobalt-base superalloy and a protective coating overlying the substrate, the coating formed by electroplating at least two platinum group metals selected from the group consisting of platinum, palladium, rhodium, ruthenium and iridium. The protective coating is typically heat treated to increase homogeneity of the coating and adherence with the substrate. The component typically further comprises a ceramic thermal barrier coating overlying the protective coating. Also disclosed are methods for forming the protective coating on the turbine engine component by electroplating the platinum group metals.
摘要翻译：一种涡轮发动机部件，包括由镍基或钴基超级合金制成的基板和覆盖在基板上的保护涂层，所述涂层通过电镀由铂，钯，铑，钌中的至少两种铂族金属和铱。保护涂层通常被热处理以增加涂层的均匀性和与基材的粘附性。该组件通常还包括覆盖保护涂层的陶瓷热障涂层。还公开了通过电镀铂族金属在涡轮发动机部件上形成保护涂层的方法。

6. 发明申请

US20100068556A1 Diffusion barrier layer and methods of forming 审中-公开
标题翻译：扩散阻挡层及其形成方法
公开(公告)号：US20100068556A1
公开(公告)日：2010-03-18
申请号：US11298811
申请日：2005-12-09
申请人： John Lemmon , Don Lipkin , Liang Jiang , Melvin Jackson , Ji-Cheng Zhao , Ann Ritter , Ramgopal Darolia , Daniel Lewis , Mark Gorman
发明人： John Lemmon , Don Lipkin , Liang Jiang , Melvin Jackson , Ji-Cheng Zhao , Ann Ritter , Ramgopal Darolia , Daniel Lewis , Mark Gorman
IPC分类号： B05D5/00 , C09D1/00 , B32B15/00 , B05D7/00
CPC分类号： C23C28/321 , C23C28/322 , C23C28/324 , C23C28/325 , C23C28/345 , C23C28/3455 , Y10T428/12611
摘要： A diffusion barrier coating includes, in an exemplary embodiment, a composition selected from the group consisting of a solid-solution alloy comprising rhenium and ruthenium wherein the ruthenium comprises about 50 atom % or less of the composition and where a total amount of rhenium and ruthenium is greater than 70 atom %; an intermetallic compound including at least one of Ru(TaAl) and Ru2TaAl, where Ru(TaAl) has a B2 structure and Ru2TaAl has a Heusler structure; and an oxide dispersed in a metallic matrix wherein greater than about 50 volume percent of the matrix comprises the oxide.
摘要翻译：在示例性实施方案中，扩散阻挡涂层包括选自包含铼和钌的固溶体合金的组合物，其中钌包含组合物的约50原子％或更少，并且其中铼和钌的总量大于70原子％; 包含Ru（TaAl）和Ru2TaAl中的至少一种的金属间化合物，其中Ru（TaAl）具有B2结构，Ru2TaAl具有Heusler结构; 和分散在金属基体中的氧化物，其中大于约50体积％的基质包含氧化物。

7. 发明申请

US20090169914A1 Thermal Barrier Coating Systems Including a Rare Earth Aluminate Layer for Improved Resistance to CMAS Infiltration and Coated Articles 有权
标题翻译：包含稀土铝酸盐层的热障涂层系统，以提高对CMAS渗透和涂层制品的抵抗力
公开(公告)号：US20090169914A1
公开(公告)日：2009-07-02
申请号：US11964953
申请日：2007-12-27
申请人： Ming Fu , Ramgopal Darolia , Mark Gorman , Bangalore Aswatha Nagaraj
发明人： Ming Fu , Ramgopal Darolia , Mark Gorman , Bangalore Aswatha Nagaraj
IPC分类号： B32B15/20 , B32B15/00
CPC分类号： C23C28/321 , C23C28/3215 , C23C28/325 , C23C28/345 , C23C28/3455 , C23C28/36 , Y02T50/67 , Y10T428/12458 , Y10T428/12667
摘要： Thermal barrier coating systems for use with hot section components of a gas turbine engine include an inner layer overlying a bond coated substrate and a top layer overlying at least a portion of the inner layer. The inner layer includes a thermal barrier material such as yttria-stabilized zirconia. The top layer includes a rare earth aluminate. The thicknesses and microstructures of the layers may be varied depending on the type of component to be coated. Articles incorporating the thermal barrier coating system exhibit improved resistance to CMAS infiltration
摘要翻译：用于燃气涡轮发动机的热段部件的热障涂层系统包括覆盖粘合涂覆的基底的内层和覆盖至少一部分内层的顶层。内层包括热阻材料，例如氧化钇稳定的氧化锆。顶层包括稀土铝酸盐。层的厚度和微观结构可以根据待涂覆的组分的类型而变化。结合热障涂层系统的制品具有改善的抗CMAS浸润性能

8. 发明申请

US20060121293A1 Thermal barrier coating/environmental barrier coating system for a ceramic-matrix composite (CMC) article to improve high temperature capability 有权
标题翻译：陶瓷基复合材料（CMC）制品的隔热涂层/环境屏障涂层系统，以提高高温能力
公开(公告)号：US20060121293A1
公开(公告)日：2006-06-08
申请号：US11006292
申请日：2004-12-06
申请人： Brett Boutwell , Irene Spitsberg , Christine Govern , Bangalore Nagaraj , Brian Hazel , Ramgopal Darolia , Curtis Johnson , Yan Gao , Mark Gorman
发明人： Brett Boutwell , Irene Spitsberg , Christine Govern , Bangalore Nagaraj , Brian Hazel , Ramgopal Darolia , Curtis Johnson , Yan Gao , Mark Gorman
IPC分类号： B32B15/04 , B32B9/00
CPC分类号： C04B41/009 , C04B41/52 , C04B41/89 , C04B2111/0025 , C23C28/042 , C23C28/322 , C23C28/345 , C23C28/3455 , F01D5/288 , F05D2230/90 , F05D2300/2118 , F05D2300/50211 , F05D2300/611 , C04B41/4527 , C04B41/5096 , C04B41/5035 , C04B41/522 , C04B41/5024 , C04B41/5037 , C04B41/5031 , C04B41/5042 , C04B41/5044 , C04B41/4529 , C04B35/565 , C04B35/584 , C04B35/806
摘要： In accordance with an embodiment of the invention, an article is provided. The article comprises a substrate comprised of silicon containing material, an environmental barrier coating (EBC) overlying the substrate and a thermal barrier coating (TBC) on the environmental barrier coating. The thermal barrier coating comprising a compound having a rhombohedral phase.
摘要翻译：根据本发明的实施例，提供了一种制品。该制品包括由含硅材料构成的衬底，覆盖衬底的环境阻挡涂层（EBC）和环境屏障涂层上的热障涂层（TBC）。该热障涂层包含具有菱面体相的化合物。

9. 发明申请

US20060040129A1 Article protected by a strong local coating 审中-公开
标题翻译：受到强烈的局部涂层保护的物品
公开(公告)号：US20060040129A1
公开(公告)日：2006-02-23
申请号：US10922527
申请日：2004-08-20
申请人： Ramgopal Darolia , Mark Gorman , Joseph Rigney
发明人： Ramgopal Darolia , Mark Gorman , Joseph Rigney
IPC分类号： B32B15/01
CPC分类号： C23C30/00 , C23C28/321 , C23C28/3215 , C23C28/322 , C23C28/345 , C23C28/3455 , Y02T50/67 , Y02T50/6765 , Y10T428/12736 , Y10T428/12875
摘要： A protected article includes a substrate having a surface and a substrate aluminum content. A first protective layer overlies a first region of the surface of the substrate, wherein the first protective layer has a composition having a first-protective-layer aluminum content at least 3 atomic percent greater than the substrate aluminum content. A second protective layer overlies a second region of the surface of the substrate different from the first region, wherein the second protective layer has a composition with at least about 60 percent by weight of platinum, rhodium, or palladium, and combinations thereof.
摘要翻译：受保护的制品包括具有表面和基底铝含量的基底。第一保护层覆盖在基板的表面的第一区域上，其中第一保护层具有比基板铝含量大至少3原子％的第一保护层铝含量的组合物。第二保护层覆盖不同于第一区域的衬底表面的第二区域，其中第二保护层具有至少约60重量％的铂，铑或钯及其组合的组成。

10. 发明申请

US20050142393A1 Ceramic compositions for thermal barrier coatings stabilized in the cubic crystalline phase 审中-公开
标题翻译：用于隔热涂层的陶瓷组合物稳定在立方晶相
公开(公告)号：US20050142393A1
公开(公告)日：2005-06-30
申请号：US10748517
申请日：2003-12-30
申请人： Brett Boutwell , Mark Gorman , Irene Spitsberg , Ramgopal Darolia , Robert Bruce , Venkat Venkataramani
发明人： Brett Boutwell , Mark Gorman , Irene Spitsberg , Ramgopal Darolia , Robert Bruce , Venkat Venkataramani
IPC分类号： C04B35/486 , C04B37/02 , C23C14/08 , C23C28/00 , C23C30/00 , F01D5/28 , B32B9/00 , C23C16/00
CPC分类号： F01D5/288 , B82Y30/00 , C04B35/486 , C04B2235/3206 , C04B2235/3208 , C04B2235/3224 , C04B2235/3225 , C04B2235/3227 , C04B2235/3229 , C04B2235/3251 , C04B2235/3286 , C04B2235/781 , C04B2235/9607 , C23C14/08 , C23C14/083 , C23C28/321 , C23C28/3215 , C23C28/3455 , C23C30/00 , F05D2230/90 , F05D2300/2118 , F05D2300/611 , Y10T428/12611 , Y10T428/26
摘要： Zirconia-containing ceramic compositions that are capable of providing thermal barrier coatings wherein the zirconia is stabilized in the cubic crystalline phase. These compositions comprise at least about 50 mole % zirconia and a stabilizing amount up to about 49 mole % of a stabilizer component comprising: (1) a first metal oxide selected from the group consisting of ytterbia, neodymia, mixtures of ytterbia and neodymia, mixtures of ytterbia and lanthana, mixtures of neodymia and lanthana, and mixtures of ytterbia, neodymia and lanthana in an amount of from about 5 to about 49 mole % of the composition; and (2) a second metal oxide selected from the group consisting of yttria, calcia, ceria, scandia, magnesia, india and mixtures thereof in an amount of about 4 mole % or less of the composition. The ceramic composition further comprises one or more of a third metal oxide selected from the group consisting of: (a) hafnia in an amount from about 0.5 to about 40 mole % of the composition; and (b) tantala in an amount of from about 0.5 to about 10 mole % of the composition. These compositions are useful in preparing thermal barrier coatings for an underlying substrate of articles that operate at, or are exposed to, high temperatures.
摘要翻译：能够提供热障涂层的含氧化锆的陶瓷组合物，其中氧化锆稳定在立方晶体相中。这些组合物包含至少约50摩尔％的氧化锆和至多约49摩尔％的稳定剂组分的稳定剂组分，其包含：（1）选自下列组的第一金属氧化物：镱，钕，镱和钕的混合物，混合物镱和镧的混合物，钕和镧的混合物，以及组合物的约5至约49摩尔％的镱，钕和镧的混合物; 和（2）选自组合物的约4摩尔％以下的量的氧化钇，氧化钙，二氧化铈，钪，氧化镁，印度及其混合物的第二金属氧化物。所述陶瓷组合物还包含选自以下的一种或多种第三金属氧化物：（a）组合物的约0.5至约40摩尔％的量的铪; 和（b）所述组合物的约0.5至约10摩尔％的量的黄铁矿。这些组合物可用于制备在高温下操作或暴露于其中的制品的下层基材的热障涂层。

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