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1. 发明申请

US20100264015A1 METHODS FOR PRODUCING BIODIESEL 有权
标题翻译：生物体生产方法
公开(公告)号：US20100264015A1
公开(公告)日：2010-10-21
申请号：US12760087
申请日：2010-04-14
申请人： Marc A. Portnoff , David A. Purta , Margaret A. Nasta , Jingfeng Zhang , Faiz Pourarian
发明人： Marc A. Portnoff , David A. Purta , Margaret A. Nasta , Jingfeng Zhang , Faiz Pourarian
IPC分类号： C09F7/10 , C07B63/04 , C07B63/02
CPC分类号： C11C3/10 , C07C67/08 , C10L1/026 , C11C3/003 , Y02E50/13 , C07C69/24 , C07C69/52
摘要： Transesterification, esterification, and esterification-transesterification (both one-step and two-step) for producing biofuels. The process may be enhanced by one or more of the following: 1) applying microwave or RF energy; 2) passing reactants over a heterogeneous catalyst at sufficiently high velocity to achieve high shear conditions; 3) emulsifying reactants with a homogeneous catalyst; or 4) maintaining the reaction at a pressure at or above autogeneous pressure. Enhanced processes using one or more of these steps can result in higher process rates, higher conversion levels, or both.
摘要翻译：用于生产生物燃料的酯交换，酯化和酯化 - 酯交换（一步和两步）。该过程可以通过以下一个或多个来增强：1）施加微波或RF能量; 2）将反应物以非常高的速度通过非均相催化剂以达到高剪切条件; 3）用均相催化剂乳化反应物; 或4）将反应保持在等于或高于自主压力的压力。使用这些步骤中的一个或多个的增强过程可以导致更高的处理速率，更高的转换水平或两者。

2. 发明申请

US20110119992A1 OXIDATION RESISTANT INTERSTITIAL METAL HYDRIDE CATALYSTS AND ASSOCIATED PROCESSES 审中-公开
标题翻译：耐氧化间接金属氢化物催化剂及相关工艺
公开(公告)号：US20110119992A1
公开(公告)日：2011-05-26
申请号：US12948576
申请日：2010-11-17
申请人： Faiz Pourarian , Marc A. Portnoff , David A. Purta , Margaret A. Nasta , Jingfeng Zhang , Gordon F. Stuntz , Jonathan M. McConnachie , Heather A. Elsen , Patricia A. Bielenberg
发明人： Faiz Pourarian , Marc A. Portnoff , David A. Purta , Margaret A. Nasta , Jingfeng Zhang , Gordon F. Stuntz , Jonathan M. McConnachie , Heather A. Elsen , Patricia A. Bielenberg
IPC分类号： C10L1/00 , C10G47/02 , C10G45/00 , C10G45/22 , B01J21/08 , B01J21/06 , C10G73/02
CPC分类号： B01J37/14 , B01J23/755 , B01J23/86 , B01J23/8892 , B01J31/121 , B01J37/0009 , B01J37/0036 , B01J37/18 , C10G9/16 , C10G9/203 , C10G45/04 , C22C16/00
摘要： The present invention relates to novel interstitial metal hydrides and catalyst containing interstitial metal hydrides that are resistant to oxidation and resultant loss of catalytic activity. The processes of the present invention include use of these improved, oxidation resistant interstitial metal hydride compositions for improved overall hydrogenation, product conversion, as well as sulfur reduction in hydrocarbon feedstreams.
摘要翻译：本发明涉及新型间隙金属氢化物和含有间隙金属氢化物的催化剂，其具有耐氧化性和导致催化活性的损失。本发明的方法包括使用这些改进的抗氧化间隙金属氢化物组合物来改进总体氢化，产物转化以及烃进料流中的硫还原。

3. 发明申请

US20110119993A1 HIGH SEVERITY HYDROPROCESSING INTERSTITIAL METAL HYDRIDE CATALYSTS AND ASSOCIATED PROCESSES 审中-公开
标题翻译：高含量水解间接金属氢化物催化剂及相关工艺
公开(公告)号：US20110119993A1
公开(公告)日：2011-05-26
申请号：US12948595
申请日：2010-11-17
申请人： Faiz Pourarian , Marc A. Portnoff , David A. Purta , Margaret A. Nasta , Jingfeng Zhang
发明人： Faiz Pourarian , Marc A. Portnoff , David A. Purta , Margaret A. Nasta , Jingfeng Zhang
IPC分类号： C10L1/00 , B01J21/06 , B01J21/08
CPC分类号： B01J31/121 , B01J23/83 , B01J35/002 , B01J37/0009 , B01J37/0036 , B01J37/18 , C10G45/04 , C22C16/00 , C22C28/00
摘要： The present invention relates to the processing of hydrocarbon-containing feedstreams in the presence of an interstitial metal hydride containing catalyst and hydrogen at process conditions of at least 400 psig pressure and temperatures of at least 200° C. These processes use interstitial metal hydrides that possess significant hydrogen capacities and high hydrogen kinetics rate properties. The catalysts and processes of the present invention may be used with or without radio frequency or microwave energy and are preferably run under conditions of high hydrogen partial pressure above about 350 psia. The catalysts and processes of the present invention can improve overall hydrogenation, product conversion, as well as sulfur reduction in hydrocarbon feedstreams as compared to processes of the prior art operated under similar conditions.
摘要翻译：本发明涉及在至少400psig压力和至少200℃的温度的工艺条件下，在含有间隙金属氢化物的催化剂和氢气存在下，含烃进料流的加工。这些方法使用间隙金属氢化物，其具有显着的氢气容量和高氢动力学特性。本发明的催化剂和方法可以使用或不使用射频或微波能量，并且优选在高于约350psia的高氢分压的条件下运行。与在类似条件下操作的现有技术的方法相比，本发明的催化剂和方法可以改进烃类进料流中的总体氢化，产物转化以及硫的还原。

4. 发明授权

US08039652B2 Methods for producing biodiesel 有权
标题翻译：生物柴油生产方法
公开(公告)号：US08039652B2
公开(公告)日：2011-10-18
申请号：US12760087
申请日：2010-04-14
申请人： Marc A. Portnoff , David A. Purta , Margaret A. Nasta , Jingfeng Zhang , Faiz Pourarian
发明人： Marc A. Portnoff , David A. Purta , Margaret A. Nasta , Jingfeng Zhang , Faiz Pourarian
IPC分类号： C11C3/10
CPC分类号： C11C3/10 , C07C67/08 , C10L1/026 , C11C3/003 , Y02E50/13 , C07C69/24 , C07C69/52
摘要： Transesterification, esterification, and esterification-transesterification (both one-step and two-step) for producing biofuels. The process may be enhanced by one or more of the following: 1) applying microwave or RF energy; 2) passing reactants over a heterogeneous catalyst at sufficiently high velocity to achieve high shear conditions; 3) emulsifying reactants with a homogeneous catalyst; or 4) maintaining the reaction at a pressure at or above autogeneous pressure. Enhanced processes using one or more of these steps can result in higher process rates, higher conversion levels, or both.
摘要翻译：用于生产生物燃料的酯交换，酯化和酯化 - 酯交换（一步和两步）。该过程可以通过以下一个或多个来增强：1）施加微波或RF能量; 2）将反应物以非常高的速度通过非均相催化剂以达到高剪切条件; 3）用均相催化剂乳化反应物; 或4）将反应保持在等于或高于自主压力的压力。使用这些步骤中的一个或多个的增强过程可以导致更高的处理速率，更高的转换水平或两者。

5. 发明申请

US20100089741A1 PRODUCTION OF BIOFUELS 审中-公开
标题翻译：生产生物燃料
公开(公告)号：US20100089741A1
公开(公告)日：2010-04-15
申请号：US12580027
申请日：2009-10-15
申请人： Marc A. Portnoff , David A. Purta , Margaret A. Nasta , Jingfeng Zhang , Faiz Pourarian , Richard C. Jackson
发明人： Marc A. Portnoff , David A. Purta , Margaret A. Nasta , Jingfeng Zhang , Faiz Pourarian , Richard C. Jackson
IPC分类号： C07C2/00
CPC分类号： B01J19/129 , B01J19/126 , B01J2219/00108 , B01J2219/0011 , B01J2219/0884 , B01J2219/0892 , B01J2219/1275 , B01J2219/1281 , C10G3/49 , C10G3/60 , C10G15/08 , C10G32/02 , C10G47/16 , C10G2300/1014 , C10G2300/1018 , C10G2300/4018 , C10G2300/708 , C10G2400/02 , C10G2400/04 , C10G2400/08 , C10L1/02 , C10L1/04 , H05B6/806 , Y02E50/13 , Y02P30/20
摘要： A method is provided for the production of biofuels. The method includes contacting at least one of a plant oil, an animal oil and a mixture thereof with a catalyst including an acid or solid acid, thereby producing a catalyst-oil mixture. RF or microwave energy is applied to at least one of the catalyst, the plant oil, the animal oil, the mixture, and the catalyst-oil mixture to produce the biofuel. The process can be adjusted to produce gasoline, kerosene, jet fuel, or diesel range middle distillate products.
摘要翻译：提供了生产生物燃料的方法。该方法包括使植物油，动物油及其混合物中的至少一种与包含酸或固体酸的催化剂接触，从而产生催化剂 - 油混合物。将RF或微波能量施加到催化剂，植物油，动物油，混合物和催化剂 - 油混合物中的至少一种以产生生物燃料。该过程可以调整以生产汽油，煤油，喷气燃料或柴油范围的中间馏分产品。

6. 发明授权

US08618010B2 Interstitial metal hydride catalyst activity regeneration process 有权
标题翻译：间隙金属氢化物催化剂活性再生过程
公开(公告)号：US08618010B2
公开(公告)日：2013-12-31
申请号：US12948539
申请日：2010-11-17
申请人： Faiz Pourarian , Marc A. Portnoff , David A. Purta , Margaret A. Nasta , Jingfeng Zhang , Heather A. Elsen , Patricia A. Bielenberg
发明人： Faiz Pourarian , Marc A. Portnoff , David A. Purta , Margaret A. Nasta , Jingfeng Zhang , Heather A. Elsen , Patricia A. Bielenberg
IPC分类号： B01J38/04
CPC分类号： B01J31/121 , B01J21/066 , B01J23/22 , B01J23/92 , B01J31/4015 , B01J38/04 , B01J38/10 , B01J38/12 , C10G2300/1011 , Y02P30/20
摘要： The present invention relates to new processes for regenerating oxidized interstitial metal hydride containing catalysts prior to the use of such catalysts in a hydroprocessing process. Interstitial metal hydride containing catalysts are easily oxidized in the environment and once oxidized, the hydroprocessing activity of the interstitial metal hydrides is most often severely diminished and this lost activity due to oxidization of the iMeH is not susceptible to recovery under hydroprocessing conditions. As a result, these catalysts in the present art require considerable special handling in inert environments all through processes from fabrication, shipping, loading, use, and maintenance of the catalyst systems to protect the activity of the interstitial metal hydride components. The present invention embodies a process regenerating oxidized interstitial metal hydride containing catalysts prior to their use in a hydroprocessing environment, thereby eliminating the requirement for maintaining the interstitial metal hydride containing catalysts in an inert environment, and allowing the handling of such catalysts in an oxidized condition prior to use.
摘要翻译：本发明涉及在加氢处理方法中使用这种催化剂之前再生氧化间隙金属氢化物的催化剂的新方法。间歇金属氢化物的催化剂在环境中容易氧化，一旦被氧化，间隙金属氢化物的加氢处理活性最多地被严重降低，并且由于iMeH的氧化而失去的活性在加氢处理条件下不易恢复。因此，本领域的这些催化剂在惰性环境中需要相当大的特殊处理，所有这些都通过催化剂体系的制造，运输，加载，使用和维护的过程来保护间隙金属氢化物组分的活性。本发明体现了一种在加氢处理环境中使用之前再生氧化间隙金属氢化物的催化剂的方法，从而消除了在惰性环境中维持含间隙金属氢化物的催化剂的需要，并允许在氧化条件下处理这种催化剂使用前。

7. 发明申请

US20110119991A1 INTERSTITIAL METAL HYDRIDE CATALYST ACTIVITY REGENERATION AND HYDROPROCESSING PROCESSES 有权
标题翻译：间接金属氢化物催化剂活性再生和加氢处理
公开(公告)号：US20110119991A1
公开(公告)日：2011-05-26
申请号：US12948539
申请日：2010-11-17
申请人： Heather A. Elsen , Patricia A. Bielenberg , Faiz Pourarian , Marc A. Portnoff , David A. Purta , Margaret A. Nasta , Jingfeng Zhang
发明人： Heather A. Elsen , Patricia A. Bielenberg , Faiz Pourarian , Marc A. Portnoff , David A. Purta , Margaret A. Nasta , Jingfeng Zhang
IPC分类号： C10L1/00
CPC分类号： B01J31/121 , B01J21/066 , B01J23/22 , B01J23/92 , B01J31/4015 , B01J38/04 , B01J38/10 , B01J38/12 , C10G2300/1011 , Y02P30/20
摘要： The present invention relates to new processes for regenerating oxidized interstitial metal hydride containing catalysts prior to the use of such catalysts in a hydroprocessing process. Interstitial metal hydride containing catalysts are easily oxidized in the environment and once oxidized, the hydroprocessing activity of the interstitial metal hydrides is most often severely diminished and this lost activity due to oxidization of the iMeH is not susceptible to recovery under hydroprocessing conditions. As a result, these catalysts in the present art require considerable special handling in inert environments all through processes from fabrication, shipping, loading, use, and maintenance of the catalyst systems to protect the activity of the interstitial metal hydride components. The present invention embodies a process regenerating oxidized interstitial metal hydride containing catalysts prior to their use in a hydroprocessing environment, thereby eliminating the requirement for maintaining the interstitial metal hydride containing catalysts in an inert environment, and allowing the handling of such catalysts in an oxidized condition prior to use.
摘要翻译：本发明涉及在加氢处理方法中使用这种催化剂之前再生氧化间隙金属氢化物的催化剂的新方法。间歇金属氢化物的催化剂在环境中容易氧化，一旦被氧化，间隙金属氢化物的加氢处理活性最多地被严重降低，并且由于iMeH的氧化而失去的活性在加氢处理条件下不易恢复。因此，本领域的这些催化剂在惰性环境中需要相当大的特殊处理，所有这些都通过催化剂体系的制造，运输，加载，使用和维护的过程来保护间隙金属氢化物组分的活性。本发明体现了一种在加氢处理环境中使用之前再生氧化间隙金属氢化物的催化剂的方法，从而消除了在惰性环境中维持含间隙金属氢化物的催化剂的需要，并允许在氧化条件下处理这种催化剂使用前。

8. 发明授权

US07625832B2 Catalyst for the treatment of organic compounds 失效
标题翻译：用于处理有机化合物的催化剂
公开(公告)号：US07625832B2
公开(公告)日：2009-12-01
申请号：US11567047
申请日：2006-12-05
申请人： David A. Purta , Marc A. Portnoff , Faiz Pourarian , Margaret A. Nasta , Jingfeng Zhang
发明人： David A. Purta , Marc A. Portnoff , Faiz Pourarian , Margaret A. Nasta , Jingfeng Zhang
IPC分类号： B01J21/18 , B01J21/02 , B01J23/42 , B01J23/44 , B01J23/10
CPC分类号： B01J31/121 , B01J23/78 , B01J23/83 , B01J23/8892 , B01J23/894 , B01J23/8986 , B01J29/084 , B01J35/0006 , B01J35/023 , B01J37/04 , C01B3/0031 , C01B6/24 , C10G11/02 , C10G49/02 , H01M8/0612 , Y02E60/327 , Y02E60/328 , Y02P70/56
摘要： A catalyst for the hydroprocessing of organic compounds, composed of an interstitial metal hydride having a reaction surface at which monatomic hydrogen is available. The activity of the catalyst is maximized by avoiding surface oxide formation. Transition metals and lanthanide metals compose the compound from which the interstitial metal hydride is formed. The catalyst's capabilities can be further enhanced using radio frequency (RF) or microwave energy.
摘要翻译：用于加氢处理有机化合物的催化剂，由具有可得到单原子氢的反应表面的间隙金属氢化物组成。通过避免表面氧化物形成，催化剂的活性最大化。过渡金属和镧系金属组成形成间质金属氢化物的化合物。可以使用射频（RF）或微波能量进一步增强催化剂的能力。

9. 发明申请

US20080302703A1 CATALYTIC PROCESS FOR THE TREATMENT OF ORGANIC COMPOUNDS 审中-公开
标题翻译：用于处理有机化合物的催化方法
公开(公告)号：US20080302703A1
公开(公告)日：2008-12-11
申请号：US12137047
申请日：2008-06-11
申请人： David A. Purta , Marc A. Portnoff , Faiz Pourarian , Margaret A. Nasta , Jingfeng Zhang
发明人： David A. Purta , Marc A. Portnoff , Faiz Pourarian , Margaret A. Nasta , Jingfeng Zhang
IPC分类号： C10G45/00 , C07C5/02
CPC分类号： B01J23/83 , B01J23/78 , B01J23/8892 , B01J29/126 , C10G15/08 , C10G32/02 , C10G45/00 , C10G45/12 , C10G45/52 , C10G45/54
摘要： A process for the catalytic reaction of organic compounds, in which the organic compounds are contacted with a catalyst comprising an interstitial metal hydride, having a reaction surface, to produce a catalyst-organic compound mixture, energy is applied, monatomic hydrogen is produced at the reaction surface of the interstitial metal hydride, and the organic compounds are reacted with the monatomic hydrogen. Reactions accomplished by this process include petroleum hydrocracking and hydrotreating processes. The method's performance can be further enhanced using radio frequency (RF) or microwave energy.
摘要翻译：有机化合物的催化反应方法，其中使有机化合物与包含间隙金属氢化物的催化剂接触，具有反应表面，以产生催化剂 - 有机化合物混合物，能量，单原子氢在间隙金属氢化物的反应表面和有机化合物与单原子氢反应。通过该方法完成的反应包括石油加氢裂化和加氢处理。该方法的性能可以使用射频（RF）或微波能量进一步增强。

10. 发明授权

US07387712B2 Catalytic process for the treatment of organic compounds 失效
标题翻译：用于处理有机化合物的催化过程
公开(公告)号：US07387712B2
公开(公告)日：2008-06-17
申请号：US10273390
申请日：2002-10-17
申请人： David A. Purta , Marc A. Portnoff , Faiz Pourarian , Margaret A. Nasta , Jingfeng Zhang
发明人： David A. Purta , Marc A. Portnoff , Faiz Pourarian , Margaret A. Nasta , Jingfeng Zhang
IPC分类号： C07C1/00 , C07F1/00 , B01J29/70 , C10G11/00
CPC分类号： B01J23/83 , B01J23/78 , B01J23/8892 , B01J29/126 , C10G15/08 , C10G32/02 , C10G45/00 , C10G45/12 , C10G45/52 , C10G45/54
摘要： A process for the catalytic reaction of organic compounds, in which the organic compounds are contacted with a catalyst comprising an interstitial metal hydride, having a reaction surface, to produce a catalyst-organic compound mixture, energy is applied, monatomic hydrogen is produced at the reaction surface of the interstitial metal hydride, and the organic compounds are reacted with the monatomic hydrogen. Reactions accomplished by this process include petroleum hydrocracking and hydrotreating processes. The method's performance can be further enhanced using radio frequency (RF) or microwave energy.
摘要翻译：有机化合物的催化反应方法，其中使有机化合物与包含间隙金属氢化物的催化剂接触，具有反应表面，以产生催化剂 - 有机化合物混合物，能量，单原子氢在间隙金属氢化物的反应表面和有机化合物与单原子氢反应。通过该方法完成的反应包括石油加氢裂化和加氢处理。该方法的性能可以使用射频（RF）或微波能量进一步增强。

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