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1. 发明授权

US09249025B2 Method for producing carbonaceous film and method for producing graphite film 有权
标题翻译：碳质膜的制造方法和石墨膜的制造方法
公开(公告)号：US09249025B2
公开(公告)日：2016-02-02
申请号：US14343639
申请日：2012-07-25
申请人： Makoto Mishiro , Yusuke Ohta , Takashi Inada , Yasushi Nishikawa
发明人： Makoto Mishiro , Yusuke Ohta , Takashi Inada , Yasushi Nishikawa
IPC分类号： C01B31/02 , C01B31/04
CPC分类号： C01B31/04 , C01B32/20
摘要： Disclosed herein is a method for producing a roll-shaped carbonaceous film by polymer pyrolyzis while suppressing the occurrence of fusion bonding in the roll-shaped carbonaceous film. The carbonaceous film production method includes the step of heat-treating a polymer film wound into a roll, wherein, at a temperature equal to or higher than the pyrolyzis onset temperature of the polymer film but equal to or lower than a temperature at which the weight of the polymer film is reduced by 40% as compared to that before heat treatment, the roll-shaped polymer film has (2-1) a gap between layers of the polymer film so that a value determined for the whole roll-shaped polymer film by dividing the thickness of the gap between adjacent layers of the polymer film (Ts) by the thickness of the polymer film (Tf) (Ts/Tf) satisfies a relationship of 0.33≦Ts/Tf≦1.50 and/or (2-2) a space inside a 50% cross-sectional circle of the roll-shaped polymer film so that the area of the space inside the 50% cross-sectional circle is 25% or more of the cross-sectional area of the 50% cross-sectional circle.
摘要翻译：本文公开了一种通过聚合物热解产生辊状碳质膜的方法，同时抑制在辊状碳质膜中的熔融粘合的发生。含碳膜的制造方法包括对卷绕成卷的聚合物膜进行热处理的步骤，其中，在等于或高于聚合物膜的热解起始温度的温度下，但等于或低于重量的聚合物膜与热处理相比降低了40％，所以辊状聚合物膜具有（2-1）聚合物膜之间的间隙，使得对于整个辊状聚合物膜确定的值通过将聚合物膜（Ts）的相邻层之间的间隙的厚度除以聚合物膜的厚度（Tf）（Ts / Tf）之间的间隔的厚度满足0.33≤n1E; Ts / Tf＆lt; lE; 1.50和/或（2- 2）辊状聚合物膜的50％横截面圆内的空间，使得50％横截面圆内的空间面积为50％横截面的横截面积的25％以上截面圆。

2. 发明授权

US09249024B2 Method for producing graphite film, method for rewinding same, and method for producing graphite composite film and graphite die-cutting product 有权
标题翻译：生产石墨膜的方法，其重绕方法，以及生产石墨复合膜和石墨模切产品的方法
公开(公告)号：US09249024B2
公开(公告)日：2016-02-02
申请号：US13579961
申请日：2011-02-14
申请人： Yusuke Ohta , Takashi Inada , Makoto Mishiro , Yasushi Nishikawa , Takashi Inada
发明人： Yusuke Ohta , Takashi Inada , Makoto Mishiro , Yasushi Nishikawa , Takashi Inada
IPC分类号： C01B31/00 , B65H18/08 , B65H35/02 , B65H35/04 , C01B31/04 , C04B35/52 , C04B35/524 , C04B35/622 , C04B35/626 , C04B35/634
CPC分类号： B32B37/20 , B32B7/12 , B32B9/007 , B32B37/0053 , B32B37/12 , B32B38/10 , B32B38/18 , B32B2250/02 , B32B2313/04 , C01B32/20 , C04B35/522 , C04B35/524 , C04B35/62218 , C04B35/6269 , C04B35/63468 , C04B2235/604 , C04B2235/6581 , C04B2235/96 , C04B2235/9638
摘要： A graphite film showing an extremely low average tearing force is more likely to suffer from various kinds of defects, such as splitting, winding deviation, wrinkling, and poor dimensional accuracy, in a step of producing the graphite film and in a step of processing the graphite film. However, these defects can be prevented by using a graphite film that satisfies the following requirements: 1) having an average tearing force of not more than 0.08 N as determined by Trouser tear method in accordance with JIS K7128; and 2) having sag of not less than 5 mm and not greater than 80 mm as determined by a method of film windability evaluation in accordance with JIS C2151.
摘要翻译：在制造石墨膜的步骤中，显示平均撕裂力极低的石墨膜在制造石墨膜的步骤中更可能遭受各种各样的缺陷，例如分裂，卷绕偏差，起皱和尺寸精度差，石墨膜。然而，通过使用满足以下要求的石墨膜可以防止这些缺陷：1）通过根据JIS K7128的裤子撕裂法测定的平均撕裂力不大于0.08N; 和2）根据JIS C2151通过膜卷取性评价方法确定的凹陷不小于5mm且不大于80mm。

3. 发明授权

US08999286B2 Method for producing graphite film and method for producing carbonized film 有权
标题翻译：石墨膜的制造方法和碳化膜的制造方法
公开(公告)号：US08999286B2
公开(公告)日：2015-04-07
申请号：US14005423
申请日：2012-03-15
申请人： Yusuke Ohta , Takashi Inada , Makoto Mishiro , Yasushi Nishikawa
发明人： Yusuke Ohta , Takashi Inada , Makoto Mishiro , Yasushi Nishikawa
IPC分类号： C01B31/02 , C01B31/04 , H01L23/373 , C04B35/52 , C04B35/524 , C04B35/622
CPC分类号： C01B31/04 , C04B35/522 , C04B35/524 , C04B35/62218 , H01L23/373 , H01L2924/0002 , H01L2924/00
摘要： A graphite film with fewer wrinkles and/or undulations is obtained providing two or more stages of heating space and carrying out continuous baking. Especially when a cooling space is provided between each of the heating spaces and another, a graphite film can be obtained which is excellent in flatness and has a high thermal diffusivity.
摘要翻译：获得具有较少皱纹和/或起伏的石墨膜，其提供两个或多个加热空间阶段并进行连续烘烤。特别是当在每个加热空间和另一个加热空间之间设置冷却空间时，可以获得平坦度优异并且具有高热扩散率的石墨膜。

4. 发明授权

US08992876B2 Method for producing carbonaceous film, method for producing graphite film, roll of polymer film, and roll of carbonaceous film 有权
标题翻译：碳质膜的制造方法，石墨膜的制造方法，聚合物膜的辊和碳质膜的卷
公开(公告)号：US08992876B2
公开(公告)日：2015-03-31
申请号：US14008390
申请日：2012-03-26
申请人： Makoto Mishiro , Yusuke Ohta , Takashi Inada , Yasushi Nishikawa
发明人： Makoto Mishiro , Yusuke Ohta , Takashi Inada , Yasushi Nishikawa
IPC分类号： C01B31/02 , C08G73/10 , C01B31/04 , B32B18/00 , C04B35/52 , C04B35/524
CPC分类号： C01B31/02 , B32B18/00 , C01B32/05 , C01B32/20 , C04B35/522 , C04B35/524 , C04B2237/363 , C04B2237/704 , C04B2237/84 , C08G73/10
摘要： Disclosed herein is a method for producing an elongated (rolled) carbonaceous film by polymer pyrolysis while suppressing the fusion bonding and the rippling of the carbonaceous film. The method for producing a carbonaceous film includes the step of heat-treating a polymer film wound into a roll, wherein the heat treatment is performed after the polymer film is wound into a roll at a temperature lower than a pyrolysis onset temperature of the polymer film so that the roll of polymer film has a center and has a space inside its cross-sectional circle (50% cross-sectional circle) (space within 50% cross-sectional circle) whose center is at the center and whose circumference passes through a point at which a length of the polymer film from an inner end thereof is 50% of a total length of the polymer film and that an area of the space within 50% cross-sectional circle is 25% or more of an area of the 50% cross-sectional circle. Particularly, providing a space between a core and an innermost layer of the roll of polymer film is more effective at solving the above problem.
摘要翻译：本发明公开了一种通过聚合物热解生产细长（卷）碳质膜的方法，同时抑制碳质膜的熔融粘结和起皱。碳质膜的制造方法包括对卷绕成卷的聚合物膜进行热处理的工序，其中在聚合物膜在低于聚合物膜的热解开始温度的温度下卷绕成辊之后进行热处理使得该聚合物膜卷具有中心并且在其中心处于其中心并且其圆周通过一个中心的横截面圆（50％横截面圆）（50％横截面圆内的空间）内具有空间其内端的聚合物膜的长度为聚合物膜的总长度的50％，50％横截面圆内的空间面积为50％以上的面积的25％以上％横截面圆。特别地，在解决上述问题时，在聚合物膜卷的芯和最内层之间提供空间更为有效。

5. 发明授权

US08883068B2 Method for improving the flatness of graphite film, graphite film, and method for producing same 有权
标题翻译：改善石墨膜，石墨膜的平坦度的方法及其制造方法
公开(公告)号：US08883068B2
公开(公告)日：2014-11-11
申请号：US13700580
申请日：2011-05-12
申请人： Yusuke Ohta , Takashi Inada , Makoto Mishiro , Takashi Inada , Yasushi Nishikawa
发明人： Yusuke Ohta , Takashi Inada , Makoto Mishiro , Takashi Inada , Yasushi Nishikawa
IPC分类号： C01B31/04
CPC分类号： C01B31/04 , C01B32/20
摘要： When a raw material graphite film bad in flatness is laminated onto another material, creases and other defects may be caused. In particular, when a graphite film having a large area is laminated, defects such as creases may be often caused. In order to solve such defects, a flatness correction treatment step is performed wherein a raw material graphite film is subjected to heat treatment up to 2000° C. or higher while a pressure is applied thereto. This flatness correction treatment gives a graphite film good in flatness. Furthermore, when the flatness of the raw material graphite film is corrected by use of a thermal expansion of a core, a graphite film small in sagging can be obtained.
摘要翻译：当将平坦度不好的原料石墨膜层压到另一种材料上时，可能引起折痕和其它缺陷。特别地，当层压有大面积的石墨膜时，可能经常引起折痕等缺陷。为了解决这种缺陷，进行平面度校正处理步骤，其中在施加压力的同时对原料石墨膜进行高达2000℃或更高的热处理。该平坦度校正处理使得平坦度好的石墨膜。此外，当通过使用芯的热膨胀来校正原料石墨膜的平坦度时，可以获得小的下垂的石墨膜。

6. 发明授权

US08858847B2 Method for producing carbonaceous film, and graphite film obtained by the same 有权
标题翻译：制造碳质膜的方法和由其获得的石墨膜
公开(公告)号：US08858847B2
公开(公告)日：2014-10-14
申请号：US13063419
申请日：2009-09-11
申请人： Takashi Inada , Yasushi Nishikawa , Makoto Mishiro
发明人： Takashi Inada , Yasushi Nishikawa , Makoto Mishiro
IPC分类号： C01B31/00 , C01B31/04
CPC分类号： C01B31/02 , C01B32/05 , C01B32/20
摘要： In a method for producing a carbonaceous film in which a polymer film is wrapped around a core and is subjected to a heat treatment, material film surfaces during the carbonization step are prevented from fusion, whereby a long carbonaceous having a large area film is obtained.Fusion can be prevented by subjecting a polymer film to a heat treatment under a reduced pressure, and under a reduced pressure while allowing an inert gas to flow. The range of the pressure reduction is preferably −0.08 MPa to −0.01 kPa. It is preferred to carry out carbonization with the pressure reduced in the range of from −0.08 MPa to −0.01 kPa while allowing an inert gas to flow. In addition, the polymer film wrapped around the core is placed in an outer casing, and provided that a value derived by dividing (internal diameter of the outer casing−diameter of the core) by 2 is designated as “a” (mm), and a thickness of wrapping of the polymer film is designated as “b” (mm), a value (b/a) derived by dividing the “b” by the “a” is set to fall within the range of from 0.2 to 0.9.
摘要翻译：在将聚合物膜缠绕在芯上并进行热处理的碳质膜的制造方法中，防止碳化工序中的材料膜表面熔融，得到面积大的膜的长碳素。可以通过使聚合物膜在减压下进行热处理，并在减压下同时允许惰性气体流动来防止熔融。减压的范围优选为-0.08MPa〜-0.01kPa。优选在惰性气体流动的同时，将压力降低至-0.08MPa至-0.01kPa的压力进行碳化。此外，包裹在芯体上的聚合物膜被放置在外壳中，并且将通过将芯部的外壳直径的内径除以2得到的值被指定为“a”（mm）将聚合物膜的包裹厚度设为“b”（mm），将“b”除以“a”得到的值（b / a）设定为0.2〜0.9的范围。

7. 发明申请

US20130240128A1 METHOD FOR PRODUCING CARBONIZED FILM AND METHOD FOR PRODUCING GRAPHITE FILM 有权
标题翻译：生产碳膜的方法和生产石墨膜的方法
公开(公告)号：US20130240128A1
公开(公告)日：2013-09-19
申请号：US13583572
申请日：2011-03-09
申请人： Makoto Mishiro , Yasushi Nishikawa , yusuke Ohta , Takashi Inada
发明人： Makoto Mishiro , Yasushi Nishikawa , yusuke Ohta , Takashi Inada
IPC分类号： B32B38/00
CPC分类号： B32B38/0036 , C01B32/20
摘要： Disclosed herein is a production method capable of efficiently producing a carbonized film wound into a roll without the occurrence of fusion bonding between the layers of the film. The method includes a carbonization step in which a polymer film wound around a core is placed in a heating furnace and carbonized by heat treatment to obtain a carbonized film wound around the core. The carbonization step is performed by increasing a temperature of the heat treatment from an initial temperature through a pyrolysis onset temperature to a pyrolysis end temperature. In the carbonization step, the heating furnace is decompressed when the temperature of the heat treatment is lower than the pyrolysis onset temperature, and after the temperature of the heat treatment reaches the pyrolysis onset temperature, the heating furnace is not decompressed or the heating furnace is decompressed so that an absolute pressure in the heating furnace is in a range of 21.3 kPa to 101.29 kPa.
摘要翻译：本发明公开了一种能够有效地制造卷绕在辊中的碳化膜而不发生膜层之间的熔合的制造方法。该方法包括碳化步骤，其中缠绕在芯上的聚合物膜放置在加热炉中并通过热处理碳化，以获得卷绕在芯上的碳化膜。通过将热处理的温度从初始温度升高到裂解开始温度到热解结束温度来进行碳化步骤。在碳化步骤中，当热处理温度低于热解开始温度时，加热炉减压，在热处理温度达到热解开始温度后，加热炉不减压或加热炉减压，使得加热炉中的绝对压力在21.3kPa至101.29kPa的范围内。

8. 发明授权

US09266736B2 Graphite film and method for producing graphite film 有权
标题翻译：石墨膜和石墨膜生产方法
公开(公告)号：US09266736B2
公开(公告)日：2016-02-23
申请号：US13380373
申请日：2009-06-22
申请人： Yusuke Ohta , Makoto Mishiro , Takashi Inada , Yasushi Nishikawa
发明人： Yusuke Ohta , Makoto Mishiro , Takashi Inada , Yasushi Nishikawa
IPC分类号： B32B9/00 , C01B31/04
CPC分类号： C04B35/524 , C01B32/19 , C01B32/20 , C01B32/205 , C01B32/225 , Y10T428/30
摘要： Provided is a long and large-area graphite film having improved thermal diffusivity and flex resistance, and accompanied by ameliorated ruffling. According to a method for producing a graphite film, in which graphitization of a heat-treated film consisting of a carbonized polymer film is carried out in a state being wrapped around an internal core, the method being characterized in that a heat treatment is executed by controlling distance(s) between the internal core and the film, and/or between the layers of the film, a graphite film accompanied by significantly ameliorated ruffling can be obtained.
摘要翻译：提供了具有改善的热扩散率和抗弯曲性的长且大面积的石墨膜，并伴随着改善的褶皱。根据石墨膜的制造方法，其特征在于，在由碳化聚合物膜构成的热处理膜的石墨化被包裹在内部芯部的状态下进行，其特征在于，通过以下方式进行热处理：可以获得控制内芯和薄膜之间和/或薄膜之间的距离，可以获得伴随显着改善的褶皱的石墨薄膜。

9. 发明授权

US09187331B2 Method for producing carbonaceous film, method for producing graphite film, roll of polymer film, and roll of carbonaceous film 有权
标题翻译：碳质膜的制造方法，石墨膜的制造方法，聚合物膜的辊和碳质膜的卷
公开(公告)号：US09187331B2
公开(公告)日：2015-11-17
申请号：US14008227
申请日：2012-03-26
申请人： Makoto Mishiro , Yusuke Ohta , Takashi Inada , Yasushi Nishikawa
发明人： Makoto Mishiro , Yusuke Ohta , Takashi Inada , Yasushi Nishikawa
IPC分类号： C01B31/02 , C01B31/04 , B29C35/00
CPC分类号： B65D85/671 , C01B32/00 , C01B32/05 , C01B32/20 , C08G73/10 , Y10T428/24744
摘要： Disclosed herein is a method for producing an elongated (rolled) carbonaceous film by polymer pyrolysis while suppressing the fusion bonding of the carbonaceous film. The method for producing a carbonaceous film includes the step of heat-treating a polymer film wound into a roll, wherein the heat treatment is performed after the polymer film is wound into a roll to have a gap between adjacent layers of the polymer film at a temperature lower than a pyrolysis onset temperature of the polymer film so that the roll of polymer film as a whole satisfies a relationship that a value obtained by dividing a thickness of a gap between adjacent layers of the polymer film (Ts) by a thickness of the polymer film (Tf) (Ts/Tf) is 0.16 or higher but 1.50 or lower. As a method for forming gaps between the layers of the polymer film, a method in which the polymer film is wound into a roll together with a slip sheet and then the slip sheet is removed can be used, which is effective at suppressing the fusion bonding of a carbonaceous film.
摘要翻译：本文公开了一种通过聚合物热分解制备细长（滚动）碳质膜的方法，同时抑制碳质膜的熔融粘合。碳质膜的制造方法包括对卷绕成卷的聚合物膜进行热处理的步骤，其中在将聚合物膜卷绕成辊之后进行热处理，以在聚合物膜的相邻层之间具有间隙温度低于聚合物膜的热解开始温度，使得聚合物膜的整体整体满足通过将聚合物膜（Ts）的相邻层之间的间隙的厚度除以通过将聚合物膜聚合物膜（Tf）（Ts / Tf）为0.16以上且1.50以下。作为在聚合物膜之间形成间隙的方法，可以使用其中将聚合物膜与滑动片一起卷绕成卷并且然后除去滑动片的方法，其有效地抑制熔融粘合的碳质膜。

10. 发明授权

US09067185B2 Process for producing graphite film 有权
标题翻译：生产石墨膜的工艺
公开(公告)号：US09067185B2
公开(公告)日：2015-06-30
申请号：US14007786
申请日：2012-03-26
申请人： Yusuke Ohta , Takashi Inada , Makoto Mishiro , Yasushi Nishikawa
发明人： Yusuke Ohta , Takashi Inada , Makoto Mishiro , Yasushi Nishikawa
IPC分类号： B01J6/00 , C01B31/04
CPC分类号： B01J6/008 , C01B32/20 , C01P2006/60
摘要： The present invention performs special heat treatment on a polymer film in a temperature range from (i) a lower limit to temperature rise being equal to or higher than a starting temperature of thermal decomposition of the polymer film, i.e., which is a temperature observed at an early stage of the thermal decomposition of the polymer film, to (ii) an upper limit to temperature rise being equal to or lower than an intermediate temperature of thermal decomposition of the polymer film. This reduces foaming in the film during graphitization treatment following the special heat treatment. Thus, even with a higher heating rate for graphitization, it is possible to produce a graphite film having good quality.
摘要翻译：本发明在从（i）下限到升温等于或高于聚合物膜的热分解起始温度的温度范围内对聚合物膜进行特殊热处理，即，在聚合物膜的热分解的早期阶段，（ii）升温的上限等于或低于聚合物膜的热分解中间温度。这在特殊热处理之后的石墨化处理期间减少了膜中的起泡。因此，即使用于石墨化的较高加热速率，也可以制造质量好的石墨膜。

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