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    • 3. 发明授权
    • Production of high capacity inorganic crystalline base exchange materials
    • 生产高能无机晶体基质交换材料
    • US4041135A
    • 1977-08-09
    • US599232
    • 1975-07-25
    • Lloyd E. WilliamsRobert K. MaysJoseph E. Wagner, III
    • Lloyd E. WilliamsRobert K. MaysJoseph E. Wagner, III
    • B01J39/14B01D20060101B01D15/00B01J20060101C01B20060101C01B33/26C01B39/02C01B39/16C11D9/18C01B33/28
    • C01B33/2823C01B33/2807
    • A method is disclosed for producing inorganic crystalline base exchange materials having high total exchange capacities and specific initial exchange rates which yield well-defined residual concentrations for the elements of Group II of the Periodic Table. The method of the invention includes the concept of controlling the rate of the addition of the reactants and other reaction variables to prevent gel structure formation and to provide a precipitate of discrete particles with a preoriented array of the elements that is predisposed to the final crystalline structure. Recycle of the mother liquor to provide a totally closed system is further disclosed. By preventing the formation of the gel structure it is possible to eliminate cumbersome and costly processing steps and equipment. By varying the precipitation and crystallation conditions, it is possible to control the ultimate crystal size. Recycle allows recovery of the chemical values of the mother liquor and reduces manufacturing cost. Throughput is also significantly increased. Specific and significant process steps include: make-up of the reactants, purification purge of the reactants, precipitation, crystallization, decanting and quench, solids separation and recycle of the mother liquor to provide the closed system. Recycling includes concentration and desalination. The method of the invention further includes particularly unique processing steps comprising solids separation and countercurrent washing.
    • 公开了一种用于生产具有高总交换容量和特定初始交换率的无机结晶基交换材料的方法,其产生周期表第II组元素的明确的残留浓度。 本发明的方法包括控制反应物的加入速率和其它反应变量的概念,以防止凝胶结构形成并提供离散颗粒的沉淀物,该沉淀物具有倾向于最终结晶结构的元素的预取向阵列 。 进一步公开母液的再循环以提供完全封闭的系统。 通过防止凝胶结构的形成,可以消除麻烦和昂贵的处理步骤和设备。 通过改变沉淀和结晶条件,可以控制最终的晶体尺寸。 回收可以回收母液的化学成分,降低制造成本。 吞吐量也显着增加。 具体和重要的方法步骤包括:反应物的组成,反应物的纯化吹扫,沉淀,结晶,倾析​​和骤冷,固体分离和母液的再循环以提供封闭系统。 回收包括集中和淡化。 本发明的方法还包括特别独特的包括固体分离和逆流洗涤的加工步骤。
    • 8. 发明授权
    • Synthetic amorphous sodium aluminosilicate base exchange materials
    • 合成无定形硅铝酸钠基质交换材料
    • US4213874A
    • 1980-07-22
    • US872968
    • 1978-01-27
    • Lloyd E. WilliamsRobert K. Mays
    • Lloyd E. WilliamsRobert K. Mays
    • C11D3/12C01B33/28C02B1/44C11D3/14
    • C01B33/28C11D3/128
    • A method for producing certain novel finely divided amorphous, precipitated alkali metal alumino silicates having a increased ion exchange properties is disclosed. The products of the invention are produced by commingling and precipitating, under certain controlled conditions, dilute aqueous solutions of an alkali metal silicate and alkali metal aluminate. Significant process variables include the chemical composition and concentration of the reactants, the precipitating temperatures and pH, the sequence and rate of the addition of the reactants and the mixing intensity during the precipitation. The amorphous products of the invention have base or ion exchange capacities equal and/or superior to known crystalline zeolitic base exchangers or absorbents and such may be used for water softening. Their use in detergents is also disclosed.
    • 公开了一种用于生产具有增加的离子交换特性的某些新颖的细碎无定形,沉淀的碱金属铝硅酸盐的方法。 本发明的产品通过在某些受控条件下混合和沉淀碱金属硅酸盐和碱金属铝酸盐的稀水溶液来制备。 显着的过程变量包括反应物的化学成分和浓度,沉淀温度和pH,反应物的添加顺序和速率以及沉淀过程中的混合强度。 本发明的无定形产物的碱或离子交换容量等于和/或优于已知的结晶沸石基础交换剂或吸收剂,并且可以用于水软化。 还公开了它们在洗涤剂中的用途。