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1. 发明授权

US5756053A System and method for abatement of food cooking fumes 失效
公开(公告)号：US5756053A
公开(公告)日：1998-05-26
申请号：US646180
申请日：1996-05-07
申请人： Jeffrey B. Hoke , Matthew P. Larkin , Robert J. Farrauto , Kenneth E. Voss , Robert E. Whiteley , Leonard M. Quick
发明人： Jeffrey B. Hoke , Matthew P. Larkin , Robert J. Farrauto , Kenneth E. Voss , Robert E. Whiteley , Leonard M. Quick
IPC分类号： B01D53/86 , B01D53/94 , B01J23/10 , B01J23/40 , B01J23/63 , B01J29/72 , B01J35/10 , B01J37/02 , F02B3/06 , F24C15/20 , B01D53/34
CPC分类号： B01D53/944 , B01D53/864 , B01D53/8668 , B01D53/9481 , B01J23/10 , B01J23/63 , B01J35/10 , B01J37/0215 , B01J37/0244 , F24C15/205 , B01J29/7215 , B01J35/1014 , B01J35/1019 , B01J35/1047 , B01J35/1061 , F02B3/06
摘要： A method for treating cooking fumes to oxidize oxidizeable particulate and gaseous components thereof includes contacting the fumes with a catalytic material containing ceria and alumina each having a BET surface of at least about 10 m.sup.2 /g, for example, ceria and activated alumina in a weight ratio of from about 1.5:1 and 1:1.5 and a BET surface area of from about 25 m.sup.2 /g to 200 m.sup.2 /g. Optionally, a catalytic metal component such as platinum or palladium may be included in the catalytic material. The foodstuffs cooking fumes are contacted with the catalyst composition (22 or 40) at a temperature of 200.degree. C. to 600.degree. C. to promote the oxidation of both particulate (atomized) animal and/or vegetable oils and fats and oxidizeable gas phase components of the fumes. Optionally, a separate, supplemental gas phase oxidation catalyst (42) may be used in conjunction with and downstream of the above-described catalyst (40) to provide a two-catalyst system for treating cooking fumes.

2. 发明授权

US5509798A Stabilized catalyst carrier and improved carrier configuration for catalytic combustion system 失效
公开(公告)号：US5509798A
公开(公告)日：1996-04-23
申请号：US318020
申请日：1994-10-04
申请人： Jennifer S. Feeley , Dianne O. Simone , Leonard M. Quick , Martha M. Hamil
发明人： Jennifer S. Feeley , Dianne O. Simone , Leonard M. Quick , Martha M. Hamil
IPC分类号： F23C99/00 , B01J21/14 , B01J23/44 , B01J35/00 , B01J37/02 , B01J37/10 , C10L3/00 , F23C13/00 , F23D3/40
CPC分类号： F23C13/08 , B01J35/0006 , B01J37/0217 , B01J37/10
摘要： A catalyst member for use in processes for the catalytic combustion of gaseous carbonaceous fuels is made from a stabilized carrier having a plurality of gas flow passages extending therethrough defined by channel walls and a catalyst material disposed on the channel walls, wherein the carrier is stabilized against interaction with the catalyst material. The stabilized carrier may be prepared from a monolith comprising silica, magnesia and alumina that has a coating of alumina on the channel walls and by subjecting the coated monolith to stabilizing conditions. The stabilizing conditions may include exposure to high temperature steam.

3. 发明授权

US4549957A Hydrotreating catalyst and process 失效
标题翻译：加氢处理催化剂和工艺
公开(公告)号：US4549957A
公开(公告)日：1985-10-29
申请号：US506293
申请日：1983-06-21
申请人： Albert L. Hensley, Jr. , Leonard M. Quick
发明人： Albert L. Hensley, Jr. , Leonard M. Quick
IPC分类号： B01J23/28 , B01J23/88 , B01J27/16 , B01J35/10 , B01J37/10 , C10G45/04 , C10G49/04 , C10G45/08 , C10G45/20
CPC分类号： B01J35/108 , B01J23/28 , B01J23/88 , B01J27/16 , B01J35/10 , B01J37/10 , C10G49/04 , B01J21/12 , C10G2300/107
摘要： Hydrotreating catalysts comprise a hydrogenating component and a support comprising at least one porous refractory inorganic oxide, said catalyst having BET surface area of 150 to about 190 m.sup.2 /g, nitrogen desorption pore volume of 0.8 to about 1.2 cc/g in micropores with radii up to 600 .ANG., with at least 0.7 cc/g of such micropore volume in pores having radii ranging from 50 to 600 .ANG., mercury penetration pore volume of 0.1 to about 0.5 cc/g in macropores with radii of 600 to 25,000 .ANG. and bulk density of about 0.3 to about 0.5 g/cc. Hydrotreating process comprises contacting a hydrocarbon feed susceptible to upgrading with hydrogen in the presence of the aforesaid catalysts under hydrotreating conditions. The catalyt and process are particularly useful in hydrotreating feeds comprising high metals or high metals and sulfur content materials.
摘要翻译：加氢处理催化剂包括氢化组分和包含至少一种多孔耐火无机氧化物的载体，所述催化剂具有150至约190m 2 / g的BET表面积，具有半径的微孔中的氮解吸孔体积为0.8至约1.2cc / g 至600，在孔中具有至少0.7cc / g这样的微孔体积，半径范围为50至600，大孔中的汞渗透孔体积为0.1至约0.5cc / g，半径为600至25,000，体积密度为约0.3至约0.5g / cc。加氢处理方法包括在加氢处理条件下在上述催化剂存在下使容易升级的烃进料接触。催化剂和方法在加氢处理包含高金属或高金属和硫含量材料的进料中特别有用。

4. 发明授权

US4297242A Process for demetallation and desulfurization of heavy hydrocarbons 失效
标题翻译：重质烃脱金属脱硫工艺
公开(公告)号：US4297242A
公开(公告)日：1981-10-27
申请号：US168297
申请日：1980-07-14
申请人： Albert L. Hensley, Jr. , Leonard M. Quick
发明人： Albert L. Hensley, Jr. , Leonard M. Quick
IPC分类号： B01J21/04 , B01J23/24 , B01J23/28 , B01J35/10 , C10G45/04 , C10G45/08 , C10G65/04 , B01J27/02 , B01J23/16
CPC分类号： B01J35/10 , B01J23/24 , B01J23/28 , B01J21/04 , B01J35/1019 , B01J35/1042 , B01J35/1061 , B01J35/108 , C10G2300/107
摘要： Disclosed is a two-stage catalytic process for hydrodemetallation and hydrodesulfurization of heavy hydrocarbon streams containing asphaltenes and a substantial amount of metals. The first stage of this process comprises contacting the feedstock in a first reaction zone with hydrogen and a demetallation catalyst comprising hydrogenation metal selected from Group VIB and/or Group VIII deposed on a large-pore, high surface area inorganic oxide support; the second stage of the process comprises contacting the effluent from the first reaction zone with a catalyst consisting essentially of hydrogenation metal selected from Group VIB deposed on a smaller-pore, catalytically active support comprising alumina, said second-stage catalyst having a surface area within the range of about 150 m.sup.2 /gm to about 300 m.sup.2 /gm, having a majority of its pore volume in pore diameters within the range of about 80 A to about 130 A, and the catalyst has a pore volume within the range of about 0.4 cc/gm to about 0.9 cc/gm.
摘要翻译：公开了用于含有沥青质和大量金属的重质烃流的加氢脱金属和加氢脱硫的两阶段催化方法。该方法的第一阶段包括使第一反应区中的原料与氢气和脱金属催化剂接触，所述脱金属催化剂包含选自分布在大孔，高表面积无机氧化物载体上的VIB族和/或VIII族的氢化金属; 该方法的第二阶段包括将来自第一反应区的流出物与基本上由选自组分VIB的氢化金属组成的催化剂接触，所述组VIB位于包含氧化铝的较小孔催化活性载体上，所述第二级催化剂的表面积在约150m 2 / gm至约300m 2 / gm的范围，其孔径的大部分孔径在约80至约130的范围内，并且催化剂的孔体积在约0.4的范围内 cc / gm至约0.9cc / gm。

5. 发明授权

US4225421A Process for hydrotreating heavy hydrocarbons 失效
标题翻译：加氢处理重质烃的方法
公开(公告)号：US4225421A
公开(公告)日：1980-09-30
申请号：US20072
申请日：1979-03-13
申请人： Albert L. Hensley, Jr. , Leonard M. Quick
发明人： Albert L. Hensley, Jr. , Leonard M. Quick
IPC分类号： B01J23/28 , B01J35/10 , C10G45/04 , C10G45/08 , C10G65/10 , C10G49/04
CPC分类号： B01J35/10 , B01J23/28 , B01J35/1019 , B01J35/1042 , B01J35/1061 , B01J35/1066 , B01J35/109 , C10G2300/107
摘要： A process for hydrodemetallation and hydrodesulfurization of hydrocarbon feedstock containing asphaltenes and metals by contacting said feedstock with hydrogen and a bimodal catalyst consisting essentially of at least one active original hydrogenation metal selected from Group VIB deposited on a support comprising alumina wherein said catalyst has a surface area within the range of about 140 to about 300 m.sup.2 /gm, a total pore volume based upon measurement by mercury penetration within the range of about 0.4 cc/gm to about 1.0 cc/gm, and comprising about 60% to about 95% of its micropore volume in micropores having diameters within the range of about 50 A to about 200 A, 0% to about 15% of its micropore volume in pores having diameters within the range of about 200 A to about 600 A and about 3% to about 30% of said total pore volume based upon measurements by mercury penetration in macropores having diameters of 600 A or greater.
摘要翻译：通过使所述原料与氢和双键催化剂接触，该催化剂主要由选自沉积在包含氧化铝的载体上的至少一种活性原始氢化金属组成的双峰催化剂进行加氢脱金属和加氢脱硫的方法，其中所述催化剂具有表面积在约140至约300m 2 / gm的范围内，基于通过汞渗透测量在约0.4cc / gm至约1.0cc / gm范围内的总孔体积，并且包含其约60％至约95％直径在约50A至约200A范围内的微孔中的微孔体积，其孔径中的微孔体积的0％至约15％，其直径在约200至约600的范围内，并且约3％至约30 基于直径为600A或更大的大孔中汞渗透测量的所述总孔体积的百分比。

6. 发明授权

US4224144A Hydrotreating a hydrocarbon stream to remove nitrogen and sulfur 失效
标题翻译：加氢处理烃流以除去氮和硫
公开(公告)号：US4224144A
公开(公告)日：1980-09-23
申请号：US21575
申请日：1979-03-19
申请人： Albert L. Hensley, Jr. , Leonard M. Quick , P. Donald Hopkins
发明人： Albert L. Hensley, Jr. , Leonard M. Quick , P. Donald Hopkins
IPC分类号： B01J21/12 , B01J35/10 , C10G45/08 , C10G23/02
CPC分类号： B01J35/10 , C10G45/08 , B01J21/12 , B01J35/1019 , B01J35/1038 , B01J35/1042 , B01J35/1061
摘要： A process for hydrotreating a hydrocarbon stream such as petroleum distillate and similar hydrocarbon materials by contacting said stream with hydrogen and a catalyst comprising a porous refractory inorganic oxide support and deposited thereon hydrogenation components comprising chromium, molybdenum and at least one Group VIII metal. This process enables improved removal of nitrogen and sulfur, particularly from gas oils.
摘要翻译：通过使所述物流与氢和包含多孔耐火无机氧化物载体的催化剂接触并在其上沉积有包含铬，钼和至少一种VIII族金属的氢化组分的催化剂来加氢处理烃流如石油馏出物和类似烃物质的方法。该方法能够改善氮和硫的去除，特别是瓦斯油的去除。

7. 发明授权

US3960706A Process for upgrading a hydrocarbon fraction 失效
$Process for upgrading a hydrocarbon fraction$
标题翻译：烃馏分升级方法
公开(公告)号：US3960706A
公开(公告)日：1976-06-01
申请号：US474927
申请日：1974-05-31
申请人： John D. McCollum , Leonard M. Quick
发明人： John D. McCollum , Leonard M. Quick
IPC分类号： C10G1/00 , C10G1/04 , C10G1/08 , C10G13/06 , C10G17/00 , C10G23/00
CPC分类号： C10G1/04 , C10G1/00 , C10G1/083
摘要： A process for upgrading a hydrocarbon fraction and for generating hydrogen in situ by contacting the hydrocarbon fraction with a dense-water-containing fluid at a temperature in the range of from about 600.degree. to about 900.degree.F. in the absence of externally supplied hydrogen and of pretreatment of the hydrocarbon fraction and in the presence of a catalyst system containing a sulfur- and nitrogen-resistant catalyst.
摘要翻译：在不存在外部供应的氢气的情况下，在约600℃至约900℃的温度范围内使烃馏分与含稠密水的流体接触，从而使烃馏分升级并原位产生氢气的方法以及在含有耐硫和耐氮催化剂的催化剂体系存在下，对烃馏分进行预处理。

8. 发明授权

US5580535A System and method for abatement of food cooking fumes 失效
标题翻译：减少食物烹饪烟雾的系统和方法
公开(公告)号：US5580535A
公开(公告)日：1996-12-03
申请号：US271709
申请日：1994-07-07
申请人： Jeffrey B. Hoke , Matthew P. Larkin , Robert J. Farrauto , Kenneth E. Voss , Robert E. Whiteley , Leonard M. Quick
发明人： Jeffrey B. Hoke , Matthew P. Larkin , Robert J. Farrauto , Kenneth E. Voss , Robert E. Whiteley , Leonard M. Quick
IPC分类号： B01D53/86 , B01D53/94 , B01J23/10 , B01J23/40 , B01J23/63 , B01J29/72 , B01J35/10 , B01J37/02 , F02B3/06 , F24C15/20 , B01J8/00 , B01J23/00 , B01J23/56
CPC分类号： B01D53/944 , B01D53/864 , B01D53/8668 , B01D53/9481 , B01J23/10 , B01J23/63 , B01J35/10 , B01J37/0215 , B01J37/0244 , F24C15/205 , B01J29/7215 , B01J35/1014 , B01J35/1019 , B01J35/1047 , B01J35/1061 , F02B3/06
摘要： A method for treating cooking fumes to oxidize oxidizeable particulate and gaseous components thereof includes contacting the fumes with a catalytic material containing ceria and alumina each having a BET surface of at least about 10 m.sup.2 /g, for example, ceria and activated alumina in a weight ratio of from about 1.5:1 and 1:1.5 and a BET surface area of from about 25 m.sup.2 /g to 200 m.sup.2 /g. Optionally, a catalytic metal component such as platinum or palladium may be included in the catalytic material. The foodstuffs cooking fumes are contacted with the catalyst composition (22 or 40) at a temperature of 200.degree. C. to 600.degree. C. to promote the oxidation of both particulate (atomized) animal and/or vegetable oils and fats and oxidizeable gas phase components of the fumes. Optionally, a separate, supplemental gas phase oxidation catalyst (42) may be used in conjunction with and downstream of the above-described catalyst (40) to provide a two-catalyst system for treating cooking fumes.
摘要翻译：用于处理烹饪烟雾以氧化可氧化颗粒和气体组分的方法包括使烟雾与含有至少约10m 2 / g的BET表面的二氧化铈和氧化铝的催化材料接触，例如二氧化铈和活性氧化铝，其重量比例为约1.5:1和1:1.5，BET表面积为约25m 2 / g至200m 2 / g。任选地，催化金属组分如铂或钯可以包括在催化材料中。烹饪烟雾的食物在200℃至600℃的温度下与催化剂组合物（22或40）接触以促进颗粒（雾化）动物和/或植物油和脂肪和可氧化气相的氧化烟雾成分。任选地，单独的补充气相氧化催化剂（42）可以与上述催化剂（40）结合使用和下游使用，以提供用于处理烹饪烟雾的双催化剂体系。

9. 发明授权

US4456699A Catalyst and support, and their methods of preparation 失效
标题翻译：催化剂和配方及其制备方法
公开(公告)号：US4456699A
公开(公告)日：1984-06-26
申请号：US485308
申请日：1983-04-15
申请人： Albert L. Hensley, Jr. , Leonard M. Quick
发明人： Albert L. Hensley, Jr. , Leonard M. Quick
IPC分类号： B01J21/02 , B01J21/12 , B01J27/16 , B01J35/10 , B01J37/10 , C10G45/04 , B01J27/14
CPC分类号： B01J37/10 , B01J21/02 , B01J21/12 , B01J27/16 , B01J35/10 , B01J35/1019 , B01J35/1047 , B01J35/1061 , C10G2300/107
摘要： A catalyst support is prepared from a composite comprising alumina and one or more oxides of phosphorus by forming the composite into a shaped support material having at least 0.8 cc/gm of its pore volume in pores having diameters of 0 nm (0 .ANG.) to 120 nm (1,200 .ANG.) and at least 0.1 cc/gm of its pore volume in pores having diameters of 120 nm (1,200 .ANG.) to 5,000 nm (50,000 .ANG.) and heating said shaped support material in the presence of steam at sufficient elevated temperature, steam pressure, and time period to increase the average pore diameter of said shaped support in the absence of any appreciable reduction in pore volume.A catalyst is prepared by impregnating the steam-treated support with at least one hydrogenating metal.The catalyst can be used suitably in hydrocarbon conversion processes, such as a process for the hydrodemetallization of a hydrocarbon stream containing asphaltenes and a substantial amount of metals.
摘要翻译：催化剂载体由包含氧化铝和一种或多种磷的氧化物的复合材料制成，通过将复合材料形成为直径为0nm（0安格姆）至120的孔中至少具有0.8cc / gm孔体积的成形载体材料 nm（1200 ANGSTROM），并且在直径为120nm（1,200）至5,000nm（50,000）的孔中，其孔体积至少为0.1cc / gm，并且在足够高的温度下在蒸汽存在下加热所述成形载体材料，蒸汽压力和时间段，以在没有任何明显的孔体积减小的情况下增加所述成形支撑件的平均孔径。通过用至少一种氢化金属浸渍蒸汽处理的载体来制备催化剂。催化剂可以适用于烃转化方法，例如含有沥青质的烃物流和大量金属的加氢脱金属的方法。

10. 发明授权

US4191635A Process for the cracking of heavy hydrocarbon streams 失效
标题翻译：重烃流裂解过程
公开(公告)号：US4191635A
公开(公告)日：1980-03-04
申请号：US967416
申请日：1978-12-07
申请人： Leonard M. Quick , Albert L. Hensley, Jr.
发明人： Leonard M. Quick , Albert L. Hensley, Jr.
IPC分类号： B01J23/28 , B01J23/88 , B01J23/887 , B01J35/10 , C10G45/04 , C10G69/04 , C10G23/02
CPC分类号： B01J23/8878 , B01J23/28 , B01J35/10 , C10G69/04 , B01J35/1019 , B01J35/1042 , B01J35/1061 , B01J35/1085 , C10G2300/107
摘要： A heavy hydrocarbon stream containing metals, asphaltenes, nitrogen compounds, and sulfur compounds is (a) contacted with hydrogen and a hydrotreating catalyst containing molybdenum and chromium, either as metals, as oxides, as sulfides, or mixtures thereof, deposed on a large-pore, catalytically active alumina to reduce the metals content in said stream, to convert the asphaltenes, nitrogen compounds, and sulphur compounds in said stream, the catalyst has a pore volume within the range of about 0.4 cc/gm to about 0.8 cc/gm, a surface area within the range of about 150 m.sup.2 /gm to about 300 m.sup.2 /gm, and an average pore diameter within the range of about 100 A (10 nm) to about 200 A (20 nm); and (b) at least a portion of the hydrotreated stream is cracked with a cracking catalyst to produce gasoline and distillates in improved yields. The catalyst in step (a) may also contain cobalt.
摘要翻译：含有金属，沥青质，氮化合物和硫化合物的重质烃流是（a）与氢气和含有钼和铬的加氢处理催化剂接触，所述催化剂含有钼和铬，作为氧化物，作为硫化物或其混合物，孔，催化活性氧化铝以降低所述料流中的金属含量，以转化所述料流中的沥青质，氮化合物和硫化合物，催化剂的孔体积在约0.4cc / g至约0.8cc / g的范围内，约150m 2 / gm至约300m 2 / gm范围内的表面积和在约100A（10nm）至约200A（20nm）范围内的平均孔径; 和（b）加氢处理物流的至少一部分用裂解催化剂裂化，以提高产率生产汽油和馏出物。步骤（a）中的催化剂也可以含有钴。

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