专利快速检索-快速检索全球专利，免费商用专利数据库-IPRDB

1. 发明授权

US06583203B2 Branched polyacetal resin composition 失效
标题翻译：支化聚缩醛树脂组合物
公开(公告)号：US06583203B2
公开(公告)日：2003-06-24
申请号：US09869805
申请日：2001-07-05
申请人： Kuniaki Kawaguchi , Hidetoshi Okawa , Yoshihisa Tajima
发明人： Kuniaki Kawaguchi , Hidetoshi Okawa , Yoshihisa Tajima
IPC分类号： C08K534
CPC分类号： C08G2/18 , C08L59/00 , C08L59/04
摘要： To offer a resin material in which various properties such as excellent appearance and rigidity inherent to a polyacetal resin are maintained and a weather (light) resistance is improved. That is, a branched polyacetal resin composition comprising 100 parts by weight of a branched polyacetal copolymer (A) having an oxymethylene group as the main repeating unit and having a branching unit represented by the following formula (I), 0.01 to 5 parts by weight of a weather (light) resistant stabilizer (B) and 0.01 to 5 parts by weight of a hindered amine substance (C): wherein m and n each is an integer of 0 to 5; the sum of m+n is 1 to 5; and R is a monovalent organic group having a molecular weight of 40 to 1000.
摘要翻译：提供一种树脂材料，其中保持聚缩醛树脂固有的优异的外观和刚性等各种性能，并提高耐候性（耐光性）。即，含有100重量份作为主要重复单元的具有甲醛基的支链聚缩醛共聚物（A）和由下式（I）表示的支化单元的支链聚缩醛树脂组合物，其为0.01〜5重量份耐光稳定剂（B）和0.01〜5重量份的受阻胺物质（C）：其中m和n各自为0至5的整数; m + n的和为1〜5; R为分子量为40〜1000的一价有机基团。

2. 发明授权

US5300332A Melt-stable copolyester resins and molded articles thereof 失效
标题翻译：熔融稳定的共聚酯树脂及其模塑制品
公开(公告)号：US5300332A
公开(公告)日：1994-04-05
申请号：US15181
申请日：1993-02-11
申请人： Kuniaki Kawaguchi , Toshio Nakane , Kenji Hijikata
发明人： Kuniaki Kawaguchi , Toshio Nakane , Kenji Hijikata
IPC分类号： C08G63/672 , C08G63/20 , C08G63/66 , C08G63/688 , B32B1/00
CPC分类号： C08G63/6884 , C08G63/20 , Y10T428/13 , Y10T428/2913
摘要： A modified polyester resin is the reaction product of:(A) an acid component mainly comprised of terephthalic acid, 2,6-naphthalene dicarboxylic acid or a lower alcohol ester thereof,(B) a diol component mainly comprising an alkylene glycol having 2 to 8 carbon atoms, and(C) an aromatic sulfonic acid compound of the following general formula (1):HO(RO).sub.n --Ar--SO.sub.3 M (1) where Ar represents a benzene or naphthale ring, n represents an integer from 1 to 10, R represents a group selected from among alkylenes having 2 or 3 carbon atoms and when n is 2 or more, R may be the same as or different from one another, and M represents an alkali metal selected from lithium, sodium and potassium. The modified polyester resin also satisfies the following formulas (2) and (3):0.25.ltoreq.x.ltoreq.100 (meq/kg) (2)2.ltoreq.(x/CEG).times.100.ltoreq.150 (%) (3) where x represents the amount of the aromatic sulfonic acid compound represented by the above general formula (1) introduced thereinto and CEG represents the amount of the carboxy end groups, and x and CEG are each expressed in millequivalent per kilogram (meq/kg) of the polymer.
摘要翻译：改性聚酯树脂是以下物质的反应产物：（A）主要由对苯二甲酸，2,6-萘二甲酸或其低级醇酯组成的酸组分，（B）主要包含亚烷基二醇的二醇组分， 8个碳原子，和（C）以下通式（1）的芳香族磺酸化合物：HO（RO）n -Ar-SO 3 M（1）其中Ar表示苯或萘环，n表示1〜 10，R表示选自具有2或3个碳原子的亚烷基，当n为2以上时，R可以相同或不同，M表示选自锂，钠，钾的碱金属。改性聚酯树脂也满足下式（2）和（3）：0.25 <= x <= 100（meq / kg）（2）2 <=（x / CEG）* 100 <= 150（％））其中x表示引入其中的上述通式（1）表示的芳族磺酸化合物的量，CEG表示羧基端基的量，x和CEG各自以千克当量每千克表示（meq / kg）的聚合物。

3. 发明授权

US5213754A Thermoforming process for forming a sheet of polybutylene terephthalate into a transparent container 失效
标题翻译：将聚苯乙烯聚苯乙烯薄片制成透明容器的热成型工艺
公开(公告)号：US5213754A
公开(公告)日：1993-05-25
申请号：US675266
申请日：1991-03-26
申请人： Kuniaki Kawaguchi , Toshio Nakane , Hiroaki Konuma , Yukihiko Kageyama , Kenji Hijikata
发明人： Kuniaki Kawaguchi , Toshio Nakane , Hiroaki Konuma , Yukihiko Kageyama , Kenji Hijikata
IPC分类号： B29B11/10 , B29B11/14 , B29C51/00 , B29C51/02 , B29C51/42 , B29D22/00 , B29K67/00 , B29K105/32 , B29L22/00 , B65D1/00 , C08G63/12 , C08G63/18 , C08G63/672
CPC分类号： B29C51/002 , B29C51/426 , C08G63/672 , B29K2067/00 , B29K2995/0026
摘要： A transparent polyester container is produced by melt-molding a copolyester resin containing 75 to 98 molar % of repeating units of an ester of terephthalic acid with 1,4-butanediol with the balance mainly containing repeating units of an ester of terephthalic acid with an alkylene oxide adduct of a bisphenol compound, rapidly cooling the molding to prepare a sheet having a low crystallinity, maturing the sheet at a temperature selected so as to meet a requirement represented by the following formula (1) to prepare a sheet satisfying a requirement represented by the following formula (2) and subjecting the sheet to thermoforming through the use of a cavity mold at a temperature falling within a range represented by the following formula (3):______________________________________ Ta .ltoreq. Tcc (.degree.C.) (1) (.DELTA.Hcc).sub.a .gtoreq. 5 (J/g) (2) Tcc + 2 .ltoreq. Tb .ltoreq. Tm - 2 (.degree.C.) (3) ______________________________________ whereinTa is the maturing temperature (.degree.C.),Tb is the cavity mold temperature (.degree.C.),Tcc is the cold crystallization temperature (.degree.C.),Tm is the melting point (.degree.C.) of the resin, and(.DELTA.Hcc).sub.a is the quantity of heat (J/g) of cold crystallization of the sheet after maturing.

4. 发明申请

US20100093901A1 POLYACETAL RESIN COMPOSITION AND MOLDED ARTICLE THEREOF 审中-公开
标题翻译：聚酯树脂组合物及其成型品
公开(公告)号：US20100093901A1
公开(公告)日：2010-04-15
申请号：US12520913
申请日：2007-12-07
申请人： Kuniaki Kawaguchi , Hiroyuki Hase , Hayato Kurita , Hiraku Iketani
发明人： Kuniaki Kawaguchi , Hiroyuki Hase , Hayato Kurita , Hiraku Iketani
IPC分类号： C08K5/24
CPC分类号： C08L59/04 , C08K5/13 , C08K5/25 , C08K5/29
摘要： The present invention provides a polyacetal resin composition having excellent processability and stability, significantly suppressing the amount of formaldehyde generated from the molded article thereof, and preventing the bleeding of blending components. Specifically, to 100 parts by weight of (A) a polyacetal copolymer in which the amount of hemiformal terminal group is 1.0 mmol/kg or less, the amount of formyl terminal group is 0.5 mmol/kg or less, and the amount of unstable terminal group is 0.5% by weight or less, there are added: 0.01 to 3 parts by weight of (B) a hindered phenol-based antioxidant; 0.01 to 1 part by weight of (C) a hydrazide compound; and 0.01 to 1 part by weight of a compound selected from (D) an isocyanate compound, an isothiocyanate compound, and a modified compound thereof.
摘要翻译：本发明提供一种加工性和稳定性优异的聚缩醛树脂组合物，显着抑制由其成型体产生的甲醛的量，并防止混合成分的渗出。具体而言，向（A）半缩氨基末端基的量为1.0mmol / kg以下的聚缩醛共聚物（甲醛）为100重量份时，甲酰基末端的量为0.5mmol / kg以下，不稳定末端的量基团为0.5重量％以下，添加：（B）受阻酚系抗氧化剂0.01〜3重量份， 0.01〜1重量份的（C）酰肼化合物; 和0.01〜1重量份选自（D）异氰酸酯化合物，异硫氰酸酯化合物及其改性化合物的化合物。

5. 发明授权

US07030207B2 Polyacetal (co)polymers 失效
标题翻译：聚缩醛（共）聚合物
公开(公告)号：US07030207B2
公开(公告)日：2006-04-18
申请号：US10476075
申请日：2002-07-23
申请人： Yoshihisa Tajima , Hiroaki Nakao , Kuniaki Kawaguchi
发明人： Yoshihisa Tajima , Hiroaki Nakao , Kuniaki Kawaguchi
IPC分类号： C08G2/22
CPC分类号： C08G2/18 , C08L59/02 , C08L59/04
摘要： The invention is to provide a polymer, having a high affinity to water, is liquid in spite of being a polymer, simultaneously possesses also a thermal stability and is suitably used as a heating medium or a lubricant. It is the polyacetal (co)polymer, being liquid at room temperature, prepared by copolymerizing (A) 75 to 100 mol % of 1,3-dioxolane and (B) 25 to 0 mol % of trioxane and having the total amount of terminal groups of 15 to 300 mmol/kg and an amount of a hemiformal terminal group of 80 mmol/kg or less.
摘要翻译：本发明提供一种对水具有高亲和性的聚合物，尽管是聚合物，但是是液体，同时具有热稳定性，并且适合用作加热介质或润滑剂。（A）75〜100摩尔％的1,3-二氧戊环和（B）25〜0摩尔％的三恶烷并具有末端总量的聚缩醛（共）聚合物，在室温下为液体 15〜300mmol / kg的组，半缩甲基端基的量为80mmol / kg以下。

6. 发明申请

US20050182200A1 Polyacetal resin composition 审中-公开
标题翻译：聚缩醛树脂组合物
公开(公告)号：US20050182200A1
公开(公告)日：2005-08-18
申请号：US10510337
申请日：2003-05-29
申请人： Kuniaki Kawaguchi , Hidetoshi Okawa , Yoshihisa Tajima
发明人： Kuniaki Kawaguchi , Hidetoshi Okawa , Yoshihisa Tajima
IPC分类号： C08L59/04 , C08G2/12 , C08G2/18 , C08L59/00
CPC分类号： C08G2/12 , C08L59/00 , C08L2205/02 , C08L2666/16
摘要： A polyacetal resin composition having high rigidity and also excellent in dimensional stability and creep characteristics is provided. A polyacetal resin composition prepared by blending (A) 99.9 to 90 parts by weight of a linear polyacetal resin having a melt index of 1 to 50 g/min obtained by copolymerizing (a) 99.5 to 97.5% by weight of trioxane and (b) 0.5 to 2.5% by weight of a compound selected from a mono-functional cyclic ether compound and a mono-functional cyclic formal compound, with (B) from 0.1 to 10 parts by weight of a branched or crosslinked polyacetal resin having a melt index of 0.1 to 10 g/min obtained by copolymerizing (a) 99.49 to 95.0% by weight of trioxane, (b) 0.5 to 4.0% by weight of a compound selected from a mono-functional cyclic ether compound and mono-functional cyclic formal compound and (c) 0.01 to 1.0% by weight of a poly-functional glycidyl ether compound with the number of functional groups of 3 to 4, in which (A) and (B) are selected so that the ratio between the melt index of (A) and the melt index of (B) can satisfy the relation of the following formula: 0.02≦MIB/MIA≦1.5 (1) (where MIA is a melt index of (A) and MIB is a melt index of (B))
摘要翻译：提供了具有高刚性并且尺寸稳定性和蠕变特性优异的聚缩醛树脂组合物。通过共混（A）99重量份至90重量份熔融指数为1〜50克/分的线性聚缩醛树脂（a）99.5〜97.5重量％的三恶烷和（b）共聚合得到的聚缩醛树脂组合物， 0.5〜2.5重量％的选自单官能环状醚化合物和单官能环状缩甲醛化合物的化合物，（B）0.1〜10重量份的熔融指数为通过共聚合（a）99.49〜95.0重量％的三恶烷，（b）0.5〜4.0重量％的选自单官能环醚化合物和单官能环状缩甲醛化合物的化合物，得到0.1〜10g / min，以及（c）0.01〜1.0重量％的官能团数为3〜4的多官能缩水甘油醚化合物，其中选择（A）和（B），使得（A ）和（B）的熔融指数可以满足下列公式的关系：<？在线公式描述 =“线上公式”end =“lead”？> 0.02 <= MI / MI <= 1.5（1）<？in-line-formula 描述=“在线公式”end =“tail”？>（其中MI A A是熔融指数（A）和MI B B是熔体指数（ B））

7. 发明授权

US06737475B1 Branched polyacetal resin composition 失效
标题翻译：支化聚缩醛树脂组合物
公开(公告)号：US06737475B1
公开(公告)日：2004-05-18
申请号：US09869806
申请日：2001-07-05
申请人： Yoshihisa Tajima , Hidetoshi Okawa , Kuniaki Kawaguchi
发明人： Yoshihisa Tajima , Hidetoshi Okawa , Kuniaki Kawaguchi
IPC分类号： C08L5900
CPC分类号： C08G2/18 , C08L59/04 , C08L2666/06
摘要： To provide a polyacetal resin material in which an excellent sliding property is given and the appearance, dimensional precision, mechanical properties, etc. of the molded article thereof are improved as well. That is, a branched polyacetal resin composition, comprising 100 parts by weight of a branched polyacetal copolymer (A) having an oxymethylene group as the main repeating unit and having a specific branching unit, and 0.5 to 40 parts by weight of at least one polymer (B) selected from the group consisting of the following polymer (B-1) and (B-2), i.e. polymer (B-1): a graft or block copolymer prepared from an olefin polymer (b-1) and at least one vinyl polymer (b-2); and polymer (B-2): a modified olefin polymer in which an olefin polymer (b-3) is modified with at least one compound selected from the group consisting of an unsaturated carboxylic acid, an unsaturated carboxylic acid anhydride and derivatives thereof and/or 0.1 to 5 parts by weight of a lubricant (C).
摘要翻译：为了提供具有优异滑动性的聚缩醛树脂材料，并且其成型制品的外观，尺寸精度，机械性能也得到改善。也就是说，支链聚缩醛树脂组合物包含100重量份具有甲醛基作为主要重复单元并具有特定分支单元的支链聚缩醛共聚物（A）和0.5至40重量份的至少一种选自以下聚合物（B-1）和（B-2），聚合物（B-1）的聚合物（B）：由烯烃聚合物（b-1）制备的接枝或嵌段共聚物至少一种乙烯基聚合物（b-2）; 和聚合物（B-2）：烯烃聚合物（b-3）用至少一种选自不饱和羧酸，不饱和羧酸酐及其衍生物和/或0.1的化合物改性的改性烯烃聚合物至5重量份的润滑剂（C）。

8. 发明授权

US5929195A Process for producing branched or crosslinked polyacetal resin 失效
标题翻译：制备支链或交联聚缩醛树脂的方法
公开(公告)号：US5929195A
公开(公告)日：1999-07-27
申请号：US115625
申请日：1998-07-14
申请人： Kuniaki Kawaguchi , Kaoru Yamamoto , Hajime Serizawa
发明人： Kuniaki Kawaguchi , Kaoru Yamamoto , Hajime Serizawa
IPC分类号： C08G65/10 , C08G2/10 , C08G2/22 , C08G4/00 , C08G6/00 , C08G65/26 , C08G10/02
CPC分类号： C08G6/00 , C08G2/22 , C08G4/00
摘要： A branched or crosslinked polyacetal resin is excellent in blow moldability, has impact resistances such as plane impact resistance, and the smoothness of the inner surfaces of moldings produced therefrom, and is suitable for molding, particularly blow molding. It can be produced by the bulk polymerization of (A) trioxane with (B) a cyclic ether and/or cyclic formal and (C) a polyfunctional glycidyl ether compound in the presence of (D) a cationic polymerization catalyst, a mixture prepared by mixing the cyclic ether and/or cyclic formal (B) with the polyfunctional glycidyl ether compound (C) and the cationic polymerization catalyst (D) is added to trioxane (A) to conduct the polymerization.
摘要翻译：支化或交联的聚缩醛树脂具有优异的吹塑成型性，耐冲击性如平面抗冲击性，以及由其制成的模制品的内表面的平滑度，并且适于成型，特别是吹塑。在（D）阳离子聚合催化剂存在下，通过（A）三恶烷与（B）环醚和/或环状缩甲醛和（C）多官能缩水甘油醚化合物的本体聚合可以制备，将环醚和/或环状缩甲醛（B）与多官能缩水甘油醚化合物（C）和阳离子聚合催化剂（D）混合，加入到三恶烷（A）中进行聚合。

9. 发明授权

US5302690A Process for preparing polyester resin and the polyester resin thereby prepared 失效
标题翻译：由此制备聚酯树脂和聚酯树脂的方法
公开(公告)号：US5302690A
公开(公告)日：1994-04-12
申请号：US892898
申请日：1992-06-03
申请人： Kuniaki Kawaguchi , Kenji Hijikata , Toshio Nakane
发明人： Kuniaki Kawaguchi , Kenji Hijikata , Toshio Nakane
IPC分类号： C08G63/20 , C08G63/688 , C08G63/85 , C08L67/02
CPC分类号： C08G63/85 , C08G63/20 , C08G63/6886 , C08L67/02
摘要： Polyester resins are prepared by reacting a lower alkyl ester of an aromatic dicarboxylic acid with an aliphatic diol to form an aromatic polyester, and which includes (i) subjecting to transesterification reaction conditions in the presence of a titanium compound catalyst a transesterification reaction system having the lower alkyl ester of the aromatic dicarboxylic acid, the aliphatic and between 0.02 to 5.0 mole percent, based on the amount of the lower alkyl ester of the aromatic dicarboxylic acid, of an aromatic sulfonic acid compound represented by the following general formula (I):OH--R--O--Ar--SO.sub.3 M (I)wherein Ar is a p-substituted benzene group or a 2,6-substituted naphthalene group, R is a divalent group selected from among --CH.sub.2 CH(CH.sub.3)--, --CH(CH.sub.3)CH.sub.2 --, --CH.sub.2 CH(CH.sub.3)-- and --CH.sub.2 CH.sub.2 OCH.sub.2 CH.sub.2 --, and M is an alkali metal selected from the group consisting of lithium, sodium and potassium. The resulting transesterification reaction product is thereafter subjected to polycondensation to obtain the polyester resin. The polyester resin may be blended with an aromatic polyester base resin to yield a moldable polyester resin composition having exceptional crystallization rates.
摘要翻译：聚酯树脂通过使芳族二羧酸的低级烷基酯与脂肪族二醇反应形成芳族聚酯来制备，其包括（i）在钛化合物催化剂的存在下进行酯交换反应条件，所述酯交换反应体系具有芳族二羧酸的低级烷基酯，脂肪族和基于芳族二羧酸的低级烷基酯的量为0.02-5.0摩尔％的由以下通式（I）表示的芳族磺酸化合物： OH-RO-Ar-SO 3 M（I）其中Ar是对取代的苯基或2,6-取代的萘基，R是选自-CH 2 CH（CH 3） - ， - CH（CH 3）CH 2 - ，-CH 2 CH（CH 3） - 和-CH 2 CH 2 OCH 2 CH 2 - ，M是选自锂，钠和钾的碱金属。然后将所得的酯交换反应产物进行缩聚，得到聚酯树脂。可以将聚酯树脂与芳族聚酯基础树脂混合，得到具有异常结晶速率的可成型聚酯树脂组合物。

10. 发明申请

US20060058457A1 Polyacetal resin composition 审中-公开
标题翻译：聚缩醛树脂组合物
公开(公告)号：US20060058457A1
公开(公告)日：2006-03-16
申请号：US10540142
申请日：2004-06-03
申请人： Kuniaki Kawaguchi
发明人： Kuniaki Kawaguchi
IPC分类号： C08L59/02 , C08L59/04
CPC分类号： C08K3/40 , C08L59/00
摘要： It is a purpose of the present invention to provide a polyacetal resin composition that contains a glass inorganic filler, improves adhesiveness between the glass inorganic filler and the polyacetal resin, and attains excellent mechanical strength. A polyacetal resin composition comprises 100 parts by weight of a polyacetal resin component (A) and 3-200 parts by weight of a glass in organic filler (B), wherein said polyacetal resin component (A) consists of 99.9-80 parts by weight of a polyacetal resin (A1) having hydroxyl groups at 0-20 mmol/kg in the molecule and 0.1-20 parts by weight of a modified polyacetal resin (A2) having hydroxyl groups at 50-2,000 mmol/kg in the molecule.
摘要翻译：本发明的目的是提供含有玻璃无机填料的聚缩醛树脂组合物，提高玻璃无机填料与聚缩醛树脂之间的粘合性，并且获得优异的机械强度。聚缩醛树脂组合物包含100重量份聚缩醛树脂组分（A）和3-200重量份有机填料（B）中的玻璃，其中所述聚缩醛树脂组分（A）由99.9-80重量份的分子中具有0〜20mmol / kg的羟基的聚缩醛树脂（A1）和0.1〜20重量份的在分子中具有50-2,000mmol / kg羟基的改性聚缩醛树脂（A2）。

你已经成功收藏专利！

检索式保存成功!

IPRDB

热门服务

关于我们

友情链接

联系方式