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    • 1. 发明授权
    • Method for making polarizing glasses by extrusion
    • 通过挤出制造偏光眼镜的方法
    • US4304584A
    • 1981-12-08
    • US144451
    • 1980-04-28
    • Nicholas F. BorrelliKuang-hsin K. Lo
    • Nicholas F. BorrelliKuang-hsin K. Lo
    • C03B32/00C03C3/11C03C4/06C03C23/00G02B5/30C03B17/00C03B19/00
    • C03C23/007C03C4/06
    • The instant invention is directed to the production of highly polarizing glasses, i.e., the glasses exhibit dichroic ratios up to 40 and higher, from silver-containing glasses that are characterized as being phase separable or, more preferably, as being photochromic because of the presence of silver halide particles therein, i.e., particles selected from the group of AgCl, AgBr, and AgI. The inventive method contemplates two general steps:(a) the glasses are elongated under stress such that the glass phases and/or silver halide particles are elongated and aligned in the direction of the stress; and(b) the elongated glasses are heat treated in a reducing environment at temperatures below the annealing point of the glass but above about 300.degree. C. to reduce a portion of the silver ions in the glass to metallic silver which is deposited in at least one of the glass phases and/or along the phase boundaries of the glass phases and/or deposited upon the silver halide particles.
    • 本发明涉及高偏振度玻璃的生产,即玻璃表现出高达40以上的分色比例,其含银玻璃的特征在于可相分离,或更优选由于存在着光致变色 的卤化银颗粒,即选自AgCl,AgBr和AgI的颗粒。 本发明的方法考虑了两个一般步骤:(a)玻璃在应力下伸长,使得玻璃相和/或卤化银颗粒在应力方向上伸长并排列; 和(b)细长玻璃在低于玻璃退火温度但高于约300℃的温度的还原环境中进行热处理,以将玻璃中的一部分银离子还原为至少沉积在金属中的银 一个玻璃相和/或沿着玻璃相的相边界和/或沉积在卤化银颗粒上。
    • 2. 发明授权
    • Method for making polarizing glasses through extrusion
    • 通过挤出制造偏光眼镜的方法
    • US4282022A
    • 1981-08-04
    • US144537
    • 1980-04-28
    • Kuang-Hsin K. LoDaniel A. Nolan
    • Kuang-Hsin K. LoDaniel A. Nolan
    • C03B32/00C03B17/00C03B17/06C03C3/11C03C4/00C03C4/06G02B5/30C03C3/26
    • C03C4/06C03B17/06
    • The present invention relates to the preparation of polarizing glasses from silver-containing glasses characterized by the presence of metallic silver particles therein and/or by being photochromic through the inclusion of silver halide particles therein selected from the group of AgCl, AgBr, and AgI. The method contemplates extruding the glass at a temperature between the annealing and softening points of the glass at a sufficiently high applied pressure to elongate the metallic silver and/or silver halide particles to an aspect ratio of at least 2:1 and up to 30:1 and greater. The extrudate is cooled in a manner to prevent the elongated particles from resuming their original shape. Dichroic ratios of up to 5.0 are achievable where the elongated particles exhibit an oblate configuration.
    • 本发明涉及由含银玻璃制备偏光玻璃,其特征在于其中存在金属银颗粒和/或通过在其中选择AgCl,AgBr和AgI中包含其中的卤化银颗粒进行光致变色。 该方法考虑在足够高的施加压力下在玻璃的退火和软化点之间的温度下挤出玻璃以将金属银和/或卤化银颗粒细长至至少2:1至高达30:1的纵横比。 1及以上。 挤出物被冷却以防止细长颗粒恢复其原始形状。 可以实现高达5.0的二向色比,其中细长颗粒呈现扁圆形结构。