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1. 发明授权

US07202315B2 Process for the preparation of ethylene polymers 失效
标题翻译：制备乙烯聚合物的方法
公开(公告)号：US07202315B2
公开(公告)日：2007-04-10
申请号：US10381401
申请日：2001-09-24
申请人： Tiziano Dall'Occo , Andrew D. Horton , Bart J. Ruisch , Klaas L. von Hebel , Arie van Zon , Henri H. Deuling , Eric J. M. de Boer
发明人： Tiziano Dall'Occo , Andrew D. Horton , Bart J. Ruisch , Klaas L. von Hebel , Arie van Zon , Henri H. Deuling , Eric J. M. de Boer
IPC分类号： C08F4/76 , C08F4/52 , C08F110/02
CPC分类号： C08F10/00 , C08F4/65908 , C08F4/65912 , C08F10/02 , C08F110/02 , C08F210/02 , C08F210/16 , C08F2410/03 , C08F4/027 , C08F4/64072 , C08F4/659 , C08F2500/17 , C08F2500/20 , C08F2500/09 , C08F2500/03 , C08F2500/12 , C08F2500/07 , C08F232/00 , C08F2500/25 , C08F210/06 , C08F210/14
摘要： A process for polymerizing ethylene comprising contacting under polymerization condition ethylene and optionally one or more olefins with a catalyst system obtainable by contacting: a bis amido compound of formula (I) wherein Y is Si, Ge and Sn; X is hydrogen, halogen or an hydrocarbon radical; R1, R2, R3, R4, R5 and R6, are hydrocarbon radical; Q is a neutral Lewis base; and m is 0–2; one or more boron activating cocatalysts and one or more aluminum alkyls or alumoxanes.
摘要翻译：一种用于聚合乙烯的方法，包括在聚合条件下乙烯和任选的一种或多种烯烃与可通过以下方法获得的催化剂体系接触：其中Y为Si，Ge和Sn的式（I）的双酰胺基化合物; X是氢，卤素或烃基; R 1，R 2，R 3，R 4，R 5和R 5， R 6是烃基; Q是中性路易斯碱; m为0-2; 一种或多种硼活化助催化剂和一种或多种烷基铝或铝氧烷。

2. 发明授权

US06559252B1 Catalysts and processes for the polymerization of olefins 失效
标题翻译：催化剂和烯烃聚合方法
公开(公告)号：US06559252B1
公开(公告)日：2003-05-06
申请号：US09331917
申请日：1999-06-29
申请人： Andrew D. Horton , Jan F. van Baar , Peter A. Schut , Gerard M. M. van Kessel , Klaas L. von Hebel
发明人： Andrew D. Horton , Jan F. van Baar , Peter A. Schut , Gerard M. M. van Kessel , Klaas L. von Hebel
IPC分类号： C08F4642
CPC分类号： C08F10/00 , C08F4/65927 , C08F110/02 , C08F4/65912
摘要： Catalysts for the polymerization of olefins are disclosed, which comprise the product obtained by contacting: (A) a bridged and/or substituted cyclopentadienyl compound of titanium, zirconium or hafnium; (B) an organometallic aluminium compound of the formula: Al(CH2—CR4R5—CR6R7R8)wR9qHz wherein R4 is a C1-C10 alkyl, alkenyl, or arylalkyl group; R5 is hydrogen or a C1-C10 alkyl, alkenyl, or arylalkyl group; R6 and R7 are C1-C10 alkyl, alkenyl, aryl, arylalkyl or alkylaryl groups; R8 is hydrogen or a C1-C10 alkyl, alkenyl, aryl, arylalkyl or alkylaryl group; R9 is a C1-C10 alkyl, alkenyl, or arylalkyl group, a carbon atom in the compound of formula (II) being optionally replaced by a Si or Ge atom; w is 1-3, z is 0 or 1, q=3−w−z, and (C) water; the molar ratio (B)/(C) being comprised between 1:1 and 100:1. These catalysts show an improved activity with respect to known catalysts, wherein different aluminium compounds are used.
摘要翻译：公开了用于烯烃聚合的催化剂，其包括通过使（A）钛，锆或铪的桥连和/或取代的环戊二烯基化合物接触而获得的产物; （B）下式的有机金属铝化合物：Al（CH2-CR4R5-CR6R7R8）wR9qHz其中R4是C1-C10烷基，烯基或芳基烷基; R5是氢或C1-C10烷基，烯基或芳基烷基; R6和R7是C1-C10烷基，烯基，芳基，芳基烷基或烷基芳基; R8是氢或C1-C10烷基，烯基，芳基，芳基烷基或烷基芳基; R9是C1-C10烷基，烯基或芳基烷基，式（II）化合物中的碳原子任选被Si或Ge原子取代; w为1-3，z为0或1，q = 3-w-z，（C）水; 摩尔比（B）/（C）为1:1至100:1。这些催化剂相对于已知的催化剂显示出改进的活性，其中使用不同的铝化合物。

3. 发明授权

US06372684B1 Catalyst system for &agr;-olefin oligomerization 失效
标题翻译：用于α-烯烃低聚的催化剂体系
公开(公告)号：US06372684B1
公开(公告)日：2002-04-16
申请号：US09292139
申请日：1999-04-15
申请人： Andrew D. Horton , Bart Johan Ruisch , Klaas L. von Hebel , Henderikus Hyacinthus Deuling
发明人： Andrew D. Horton , Bart Johan Ruisch , Klaas L. von Hebel , Henderikus Hyacinthus Deuling
IPC分类号： B01J3118
CPC分类号： C07C2/32 , B01J31/0239 , B01J31/0252 , B01J31/128 , B01J31/14 , B01J31/143 , B01J31/1608 , B01J31/1805 , B01J2231/20 , B01J2531/46 , B01J2531/48 , B01J2531/49 , C07C2531/14 , C07C2531/22 , Y10S526/943
摘要： It is disclosed a new catalyst system, having high catalytic activity in the oligomerization of &agr;-olefins, comprising a bridged bis-amido Group 4 metal compound of formula (I): wherein M is Ti, Zr or Hf; Y is Si, Ge or Sn; X is a hydrogen, halogen or an hydrocarbon radical; R1, R2, R3, R4, R5 and R6 are hydrocarbon radicals, optionally containing Si, Ge, O, S, P, B or N atoms; Q is a neutral Lewis base; and m is 0-2; in association with a boron activating compound, and with one or more branched alkylaluminiums and/or alumoxanes of branched alkylaluminiums; said catalyst system allows oligomers to be obtained in high yields, with a high selectivity towards &agr;-oligomers.
摘要翻译：公开了一种在α-烯烃的低聚反应中具有高催化活性的新型催化剂体系，其包含式（I）的桥连双酰胺基4族金属化合物：其中M为Ti，Zr或Hf; Y是Si，Ge或Sn; X是氢，卤素或烃基; R 1，R 2，R 3，R 4，R 5和R 6是任选含有Si，Ge，O，S，P，B或N原子的烃基; Q是中性路易斯碱; m为0-2; 与硼活化化合物和支链烷基铝的一种或多种支化烷基铝和/或铝氧烷结合; 所述催化剂体系允许以高产率获得低聚物，对α-低聚物具有高选择性。

4. 发明授权

US06476163B2 Catalysts for the polymerization of olefins and process for the preparation thereof 失效
标题翻译：用于烯烃聚合的催化剂及其制备方法
公开(公告)号：US06476163B2
公开(公告)日：2002-11-05
申请号：US09331928
申请日：1999-06-29
申请人： Jan F. Van Baar , Maurizio Galimberti , Klaas L. Von Hebel , Andrew D. Horton , Gerard M. M. Van Kessel , Peter A. Schut , Tiziano Dall'occo
发明人： Jan F. Van Baar , Maurizio Galimberti , Klaas L. Von Hebel , Andrew D. Horton , Gerard M. M. Van Kessel , Peter A. Schut , Tiziano Dall'occo
IPC分类号： C08F4642
CPC分类号： C08F10/00 , C08F4/65927 , C08F110/06 , C08F210/16 , Y10S526/943 , C08F4/65912 , C08F210/06
摘要： Catalysts for the polymerization of olefins are disclosed, comprising the product obtainable by contacting: (A) a bridged and/or substituted cyclopentadienyl compound of Ti, Zr or Hf; (B) one or more organometallic aluminium compounds of formula (II): AlR43−zHz wherein the substituents R4, same or different from each other, are linear or branched, saturated or unsaturated C1-C20 alkyl or alkylaryl radicals, optionally containing Si or Ge atoms, wherein at least one of the substituents R4 is different from a straight alkyl group; z is 0 or 1; and (C) water, the molar ratio between the organometallic aluminium compound and water being comprised between 1:1 and 100:1; said catalyst being obtainable by a process comprising the following steps: (i) contacting component (A) with part of component (B) in the absence of component (C); (ii) contacting part of component (B) with component (C) in the absence of component (A) and successively (iii) contacting the products obtained in steps (i) and (ii).
摘要翻译：公开了用于烯烃聚合的催化剂，其包含通过使（A）Ti，Zr或Hf的桥连和/或取代的环戊二烯基化合物接触而获得的产物; （B）一种或多种式（II）的有机金属铝化合物：AlR43-zHz其中相同或不同的取代基R4是直链或支链的，饱和或不饱和的C 1 -C 20烷基或烷基芳基，任选地含有Si或 Ge原子，其中至少一个取代基R4不同于直链烷基; z为0或1; 和（C）水，有机金属铝化合物与水的摩尔比为1:1至100:1; 所述催化剂可通过包括以下步骤的方法获得：（i）在不存在组分（C）的情况下使组分（A）与组分（B）的一部分接触; （ii）在不存在组分（A）的情况下将组分（B）的一部分与组分（C）接触，并且连续地（iii）使步骤（i）和（ii）中获得的产物接触。

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