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1. 发明授权

US4060595A Process for recovering elemental sulfur from gases having a high carbon dioxide content and containing sulfur compounds 失效
标题翻译：从具有高二氧化碳含量和含硫化合物的气体中回收元素硫的方法
公开(公告)号：US4060595A
公开(公告)日：1977-11-29
申请号：US705115
申请日：1976-07-14
申请人： Karl-Heinz Eisenlohr , Karl Bratzler
发明人： Karl-Heinz Eisenlohr , Karl Bratzler
IPC分类号： C01B17/60 , C01B17/04
CPC分类号： C01B17/0456
摘要： A process for recovering elemental sulfur from gases containing inorganic and/or organic sulfur compounds together with large quantities of carbon dioxide and other possible impurities such as unsaturated hydrocarbon and hydrogen cyanide. The waste gas is combined with a combustion-promoting gas and the resulting mixture is burned with a slight excess of air and caused to contact coke at a temperature of 300.degree. to 450.degree. C. The resulting gas, from which oxygen, sulfur trioxide and nitrogen oxide have been removed, by contact with the coke, is cooled to 20.degree. to 80.degree. C and then is scrubbed with aqueous alkali salts of weak inorganic and/or organic acids or amines to remove SO.sub.2. The absorbent is stripped and the recovered SO.sub.2 is reacted with hydrogen at 200.degree. to 400.degree. C to form sulfur and/or hydrogen sulfide and, when hydrogen sulfide is produced, the latter is reacted on alumina or activated carbon at 200.degree. to 300.degree. C to produce the elemental sulfur. All or part of the gas after recovery of the elemental sulfur is recycled.
摘要翻译：一种从含有无机和/或有机硫化合物的气体中回收元素硫以及大量二氧化碳和其他可能的杂质如不饱和烃和氰化氢的方法。将废气与助燃气体结合，将得到的混合物用稍微过量的空气燃烧，并在300-450℃的温度下接触焦炭。所得的气体，氧，三氧化硫和通过与焦炭接触将氮氧化物除去，冷却至20℃至80℃，然后用弱无机和/或有机酸或胺的碱金属盐水洗涤以除去SO 2。吸收剂被汽提，回收的SO2与氢气在200-400℃下反应生成硫和/或硫化氢，当产生硫化氢时，后者在氧化铝或活性炭上200〜300℃反应以产生元素硫。回收元素硫后全部或部分气体被回收利用。

2. 发明授权

US4487687A Method of processing heavy hydrocarbon oils 失效
标题翻译：重质烃油的处理方法
公开(公告)号：US4487687A
公开(公告)日：1984-12-11
申请号：US342315
申请日：1982-01-25
申请人： Thomas Simo , Karl-Heinz Eisenlohr
发明人： Thomas Simo , Karl-Heinz Eisenlohr
IPC分类号： C10G65/12 , C10G49/20
CPC分类号： C10G65/12 , C10G2300/107
摘要： Heavy hydrocarbon oil to be processed is subjected to a treatment at elevated temperature and superatmospheric pressure in the presence of dispersed solids and molecular hydrogen and recycled hydrogen donor oil. By this treatment, a certain part of the asphaltenes absorbed on the solids may be coked. The product of that donor solvent hydrovisbreaking (DSV) is distilled. The distillate or distillates is or are catalytically hydrogenated. The visbreaking residue is used for the production of hydrogen. The hydrogenated products are separated in hydrocarbon fractions and are then processed further to fuels and/or petrochemical products and a part of the hydrogenated products is recycled as inherent donor solvent.
摘要翻译：在分散的固体和分子氢和再循环的氢供体油的存在下，待处理的重质烃油在升高的温度和超大气压下进行处理。通过这种处理，吸收在固体上的沥青质的某一部分可能被焦化。蒸馏该供体溶剂加氢裂解（DSV）的产物。馏出物或馏出物是或被催化氢化的。减粘裂化残渣用于生产氢气。氢化产物在烃馏分中分离，然后进一步加工成燃料和/或石油化学产品，一部分氢化产物作为固有的供体溶剂再循环。

3. 发明授权

US4248691A Process of producing a suspension of brown coal and oil for hydrogenation 失效
标题翻译：生产褐煤和油的氢化悬浮液的方法
公开(公告)号：US4248691A
公开(公告)日：1981-02-03
申请号：US51283
申请日：1979-06-22
申请人： Karl-Heinz Eisenlohr
发明人： Karl-Heinz Eisenlohr
IPC分类号： C10G1/00 , C10G1/06 , C10L9/00 , C10L1/32
CPC分类号： C10G1/065 , C10G1/00 , C10L9/00
摘要： A process for producing low water containing suspension of fine-grained brown coal and oil suitable for hydrogenation by hydrogen gas under pressure of 100 to 400 bars at 300.degree. to 500.degree. C. is described. The brown coal is dewatered by being disintegrated to particle sizes of below 5 mm, mixed with oil and subjected for at least about one minute in a first holding reactor to a temperature of 250.degree. to 32.degree. C. at a pressure of 25 to 120 bars. The mixture forms an oil phase and a water phase. The oil phase containing dewatered brown coal is removed from the water phase, passed to a second holding reactor and therein maintained for at least about one minute at a temperature up to 200.degree. C. under a pressure of up to 10 bars.Water-oil vapor in the second holding reactor is removed to leave behind low water-containing brown coal-oil suspension suitable for the hydrogenation.
摘要翻译：描述了在300至500℃的压力为100至400巴的压力下，适用于氢气氢化的细粒褐煤和油的低含水悬浮液的生产方法。褐煤通过分解成5mm以下的粒度而脱水，与油混合并在第一保持反应器中至少约1分钟，在25至120℃的压力下进行至250℃至32℃的温度酒吧。混合物形成油相和水相。将含有脱水褐煤的油相从水相中除去，通入第二个保持反应器，并在高达10巴的压力下在200℃的温度下保持至少约1分钟。除去第二个保持反应器中的水 - 油蒸气，留下适合于氢化的低含水棕色煤油悬浮液。

4. 发明授权

US3933979A Gas purifying method 失效
标题翻译：气体净化方法
公开(公告)号：US3933979A
公开(公告)日：1976-01-20
申请号：US390826
申请日：1973-08-23
申请人： Karl-Heinz Eisenlohr , Berthold Scholz , Ernest Kapp
发明人： Karl-Heinz Eisenlohr , Berthold Scholz , Ernest Kapp
IPC分类号： C01B3/58 , B01D53/34
CPC分类号： B01D53/8625 , C01B3/58 , B01D2251/51 , B01D2256/16 , B01D2257/404
摘要： Hydrogen containing gases are purified to remove components therein having polymerization, resinification or coking tendencies or to transform such compounds into harmless compounds. The sulfur content of the hydrogen containing gas is adjusted by adding sulfur or sulfur compounds such that the sulfur content is at least 0.05 to 8 g/Nm.sup.3. The adjusted gas is then passed through a hydrogenation catalyst at temperatures between 100.degree. and 400.degree.C. Suitable hydrogenation catalysts are one or more sulfides and/or oxides of metals of the 6th and 8th Group of the periodic system.
摘要翻译：纯化含氢气体以除去其中具有聚合，树脂化或焦化倾向的组分，或将这些化合物转化成无害化合物。通过添加硫或硫化合物来调节含氢气体的硫含量，使得硫含量为至少0.05至8g / Nm 3。然后将调整后的气体在100-400℃的温度下通过氢化催化剂。合适的氢化催化剂是周期性系统的第六和第八组的一种或多种金属的硫化物和/或氧化物。

5. 发明授权

US4515604A Process of producing a synthesis gas which has a low inert gas content 失效
标题翻译：制备惰性气体含量低的合成气的方法
公开(公告)号：US4515604A
公开(公告)日：1985-05-07
申请号：US488472
申请日：1983-04-25
申请人： Karl-Heinz Eisenlohr , Hans Gaensslen , Manfred Kriebel , Heiner Tanz
发明人： Karl-Heinz Eisenlohr , Hans Gaensslen , Manfred Kriebel , Heiner Tanz
IPC分类号： C01B3/50 , C10J3/16 , C10K1/16 , C10K3/00 , F25J3/02 , F25J3/06 , C10J3/00 , C10K1/00
CPC分类号： F25J3/0271 , C01B3/50 , C10J3/16 , C10J3/20 , C10J3/78 , C10K1/165 , C10K1/32 , C10K3/00 , F25J3/0223 , F25J3/0233 , C01B2203/0475 , C01B2203/0485 , C10J2300/093 , C10J2300/0956 , C10J2300/0959 , C10J2300/0976 , C10J2300/1665 , C10J2300/1846 , C10J2300/1884 , C10J2300/1892 , F25J2200/70 , F25J2205/04 , F25J2270/04 , Y02C10/12
摘要： In a process of producing a synthesis gas which has a low inert gas content and is intended for the synthesis of alcohols, particularly of methanol, and of hydrocarbons, and which is produced from coal or heavy hydrocarbons, by a gasification under pressure with oxygen and steam, whereafter the raw gas is cooled, the impurities are removed by a scrubbing with methanol, and the methanol is removed by means of molecular sieves from the cold pure gas. The pure gas is then cooled further and partly liquefied, the remaining gas is further cooled by a pressure relief and methane is distilled from the liquid part with simultaneous recovery of the synthesis gas, which consists of hydrogen and carbon monoxide and has a low methane content. All or part of the methane is compressed and is subsequently reacted with steam and oxygen to produce carbon monoxide and hydrogen. The produced gas is admixed to the synthesis gas or to the partly purified raw gas.
摘要翻译：在制造具有低惰性气体含量并用于合成醇，特别是甲醇和烃的合成气的合成气的过程中，由煤或重质烃生产的合成气通过在氧气下进行气化，蒸汽，然后将原料气体冷却，通过用甲醇洗涤除去杂质，并通过来自冷纯气体的分子筛除去甲醇。然后将纯气体进一步冷却并部分液化，剩余气体通过压力释放进一步冷却，并从液体部分蒸馏出甲烷，同时回收由氢气和一氧化碳组成的合成气，并且甲烷含量低。全部或部分甲烷被压缩，随后与蒸汽和氧气反应以产生一氧化碳和氢气。将生成的气体与合成气或部分纯化的原料气体混合。

6. 发明授权

US4389303A Process of converting high-boiling crude oils to equivalent petroleum products 失效
标题翻译：将高沸点原油转化为相当的石油产品的工艺
公开(公告)号：US4389303A
公开(公告)日：1983-06-21
申请号：US212393
申请日：1980-12-03
申请人： Thomas Simo , Karl-Heinz Eisenlohr
发明人： Thomas Simo , Karl-Heinz Eisenlohr
IPC分类号： C10G47/34 , C10G45/58 , C10G49/22
CPC分类号： C10G47/34 , C10G2300/107
摘要： A process for converting high-boiling crude oil having a high content of nondistillable residue which crude oil contains metals and asphaltenes by donor solvent hydrovisbreaking is disclosed wherein the process is carried out near the carbonization temperature limit in the presence of a hydrogen donor. The hydrogen donor can be one derived from the crude itself, from a similar crude oil, or from the distillate product of said donor solvent hydrovisbreaking.
摘要翻译：公开了一种通过供体溶剂加氢脱硫剂转化具有高含量的不可重复残留物的原油含有金属和沥青质的高沸点原油的方法，其中该方法在氢供体存在下在碳化温度极限附近进行。氢供体可以是衍生自原料本身的衍生物，来自类似的原油，或来自所述供体溶剂加氢脱硫剂的馏出物。

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