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    • 7. 发明授权
    • Stable polymeric dispersion and methods for making
    • 稳定的聚合物分散体和制备方法
    • US4524199A
    • 1985-06-18
    • US549933
    • 1983-11-09
    • Kar P. LokChristopher K. Ober
    • Kar P. LokChristopher K. Ober
    • C08F2/24C08F251/02C08F2/22
    • C08F251/02
    • Dry monodispersed polymeric particles, a stabilized dispersion of such and a method for making are described. The dispersion comprises a polar dispersion medium having dispersed therein monodispersed particles comprising a thermoplastic resin core substantially insoluble in the dispersion medium formed from a styrene or butylmethacrylate containing monomer or mixtures thereof and having irreversibly anchored thereto, a nonionic amphipathic steric stabilizer comprising a graft copolymer having a portion formed from a styrene or butylmethacrylate containing monomer or mixture thereof and a portion formed from hydroxyethyl cellulose, hydroxypropyl cellulose, hydroxybutyl methyl cellulose, hydroxypropyl methyl cellulose, ethyl cellulose or cellulose propionate. The stable dispersion is made by dissolving the nonionic cellulose ether in the polar dispersion medium and in the presence of a free radical initiator adding styrene or butylmethacrylate containing monomer a mixture thereof thereto, and permitting polymerization to take place.
    • 描述干燥的单分散聚合物颗粒,稳定的分散体和制备方法。 分散体包括分散有单分散颗粒的极性分散介质,其包含基本上不溶于由苯乙烯或甲基丙烯酸丁酯单体或其混合物形成并且不可逆地锚定在其上的分散介质中的热塑性树脂芯,包含接枝共聚物的非离子两亲空间稳定剂, 由苯乙烯或甲基丙烯酸丁酯含有单体或其混合物形成的部分和由羟乙基纤维素,羟丙基纤维素,羟丁基甲基纤维素,羟丙基甲基纤维素,乙基纤维素或丙酸纤维素形成的部分。 通过将非离子纤维素醚溶解在极性分散介质中并在自由基引发剂的存在下,将苯乙烯或甲基丙烯酸丁酯的单体与其混合物加入,并使聚合发生,从而制得稳定的分散体。
    • 8. 发明授权
    • Dyed stabilized liquid developer and method for making
    • 染色稳定液体显影剂及其制造方法
    • US4476210A
    • 1984-10-09
    • US499054
    • 1983-05-27
    • Melvin D. CroucherJames M. DuffMichael L. HairKar P. LokRaymond W. Wong
    • Melvin D. CroucherJames M. DuffMichael L. HairKar P. LokRaymond W. Wong
    • G03G9/12G03G9/13
    • G03G9/122G03G9/131G03G9/133
    • A stable colored liquid developer and method for making such are described wherein an improved optical density resulting from a colored dye being imbibed into a thermoplastic resin core occurs. In particular, the liquid developer comprises a marking particle dispersed in an aliphatic dispersion medium, the marking particle comprises a thermoplastic resin core having an amphipathic block or graft copolymeric steric stabilizer irreversibly chemically or physically anchored to the thermoplastic resin core with the dye being imbibed in the resin core and being soluble therein and insoluble in the dispersion medium. The stable colored liquid developer is preferably made by first preparing a graft or block copolymer amphipathic steric stabilizer, anchoring said stabilizer to a thermoplastic resin core, and to the aliphatic disperion of said particle adding a solution of a dye dissolved in a polar solvent, preferrably methanol, the dye being soluble in the thermoplastic resin core to enable it to be imbibed therein and substantially insoluble in the dispersion medium.
    • 描述稳定的着色液体显影剂及其制备方法,其中出现由着色染料吸收到热塑性树脂芯中得到的改善的光密度。 特别地,液体显影剂包括分散在脂族分散介质中的标记颗粒,标记颗粒包括具有两亲性嵌段或接枝共聚空间稳定剂的热塑性树脂芯,其不可逆地化学或物理锚定到热塑性树脂芯上,染料被吸入 树脂芯并且可溶于其中并且不溶于分散介质中。 稳定着色的液体显影剂优选通过首先制备接枝或嵌段共聚物两亲空间稳定剂,将所述稳定剂锚定到热塑性树脂核心,以及添加溶解在极性溶剂中的染料溶液的所述颗粒的脂肪族分散体,优选地 甲醇,染料可溶于热塑性树脂核心,使其能够吸收在其中并且基本上不溶于分散介质中。