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1. 发明授权

US5173343A Narrow molecular weight distribution ethylene-acrylate cling layer in stretch/cling films 失效
标题翻译：拉伸/粘贴膜中窄分子量分布乙烯 - 丙烯酸酯粘合层
公开(公告)号：US5173343A
公开(公告)日：1992-12-22
申请号：US633509
申请日：1990-12-28
申请人： Marsha M. Arvedson , Patrick Brant , Joseph D. Domine , Paul M. German
发明人： Marsha M. Arvedson , Patrick Brant , Joseph D. Domine , Paul M. German
IPC分类号： B32B27/08 , B32B27/32
CPC分类号： B32B27/08 , B32B27/32 , Y10S428/91 , Y10T428/1328 , Y10T428/31913 , Y10T428/31928
摘要： A thermoplastic film is provided which is especially suited for use in stretch/cling applications such as, for example, the bundling, packaging and unitizing of foods and other goods. The film comprises a cling layer comprising a polymer of at least ethylene and 2-40 wt % acrylate having a ratio of M.sub.w /M.sub.n less than about 3.5, a ratio of M.sub.z /M.sub.w less than about 3, a melt index of about 0.1-30 dg/min, and a melt index swell ratio less than about 1.6, preferably without a tackifying additive. The film may further comprise a non-cling layer comprising a thermoplastic preferably essentially free of anticling (slip and/or antiblock) additive. Preferred thermoplastic materials include polyethylene and polypropylene.
摘要翻译：提供了一种热塑性薄膜，其特别适用于拉伸/粘贴应用，例如食品和其他物品的捆扎，包装和组合。该薄膜包括一层粘合层，该粘结层包含至少为乙烯和2-40wt％丙烯酸酯的聚合物，其Mw / Mn比小于约3.5，Mz / Mw小于约3，熔体指数为约0.1 30dg / min，熔体指数溶胀比小于约1.6，优选不含增粘剂。膜可以进一步包括非粘附层，其包含优选基本上不含抗皱（滑动和/或抗粘连）添加剂的热塑性塑料。优选的热塑性材料包括聚乙烯和聚丙烯。

2. 发明授权

US5141809A Low comonomer content ethylene-acrylate polymers in stretch/cling films 失效
标题翻译：低共聚单体含量在拉伸/粘贴膜中的乙烯 - 丙烯酸酯聚合物
公开(公告)号：US5141809A
公开(公告)日：1992-08-25
申请号：US633488
申请日：1990-12-28
申请人： Marsha M. Arvedson , Joseph D. Domine , Paul M. German
发明人： Marsha M. Arvedson , Joseph D. Domine , Paul M. German
IPC分类号： B32B27/08 , B32B27/32
CPC分类号： B32B27/32 , B32B27/08 , Y10T428/2826 , Y10T428/31913 , Y10T428/31928 , Y10T428/31935
摘要： A thermoplastic film is provided which is especially suited for use in stretch/cling applications such as, for example, the bundling, packaging and unitizing of foods and other goods. The film comprises a cling layer comprising (i) a non-cling polymer of at least ethylene and acrylate or vinyl acetate, blended with (ii) a compatible, non-migratory tackifier. The film may further comprise a non-cling layer comprising a polyolefin essentially free of tackifier, with or without an anticling (slip and/or antiblock) additive. Preferred polyolefins include linear low density polyethylene and polypropylene.
摘要翻译：提供了一种热塑性薄膜，其特别适用于拉伸/粘贴应用，例如食品和其他物品的捆扎，包装和组合。所述膜包括粘附层，所述粘附层包含（i）至少乙烯和丙烯酸酯或乙酸乙烯酯的非粘着聚合物，与（ii）相容的非迁移性增粘剂共混。膜可以进一步包含含有基本上不含增粘剂的聚烯烃的非粘附层，具有或不具有抗皱（滑移和/或抗粘连）添加剂。优选的聚烯烃包括线性低密度聚乙烯和聚丙烯。

3. 发明授权

US07405008B2 Ionomer laminates and articles formed from ionomer laminates 失效
标题翻译：离子聚合物层压材料和由离聚物层压体形成的制品
公开(公告)号：US07405008B2
公开(公告)日：2008-07-29
申请号：US11141445
申请日：2005-05-31
申请人： Joseph D. Domine , Jeffrey Valentage , Prasadarao Meka
发明人： Joseph D. Domine , Jeffrey Valentage , Prasadarao Meka
IPC分类号： B32B27/08
CPC分类号： B32B27/08 , B29C45/14811 , B29K2715/006 , B29L2031/3044 , B32B7/10 , B32B27/20 , B32B27/32 , B32B38/12 , B32B2270/00 , B32B2307/4026 , B32B2307/584 , B32B2605/003 , C08L23/04 , C08L23/0815 , C08L23/0869 , C08L23/0876 , C08L23/142 , C08L2205/03 , Y10T428/31855 , Y10T428/31909 , Y10T428/31913 , Y10T428/31928 , Y10T428/31931 , Y10T428/31935 , Y10T428/31938 , C08L2666/06
摘要： The present invention includes a laminate and formation of a laminate having at least one layer of an ionomer and at least one layer of an acid polymer or blend of acid polymer and a thermoplastic polyolefin that can be thermoformed to form a shaped laminate. The shaped laminate can then be contacted with a plastic substrate such as a thermoplastic polyolefin to form a composite article by such means as, for example, injection molding. The laminate can be pigmented to eliminate the need to paint the surface of the plastic substrate. Impact and scratch resistant articles can be formed from the laminated substrate such as automotive parts, appliance body parts and sporting equipment.
摘要翻译：本发明包括层压体和层压体的形成，其具有至少一层离聚物和至少一层酸聚合物或酸聚合物的共混物和热塑性聚烯烃的混合物，其可热成型以形成成型层压体。然后可以将成形的层压体与诸如热塑性聚烯烃的塑料基材接触，以通过例如注射成型的方式形成复合制品。层压材料可以着色以消除对塑料基材表面的涂漆的需要。冲击和防刮擦制品可以由诸如汽车部件，器具主体部件和运动设备的层压基板形成。

4. 发明授权

US06946528B2 Hot melt adhesives 失效
标题翻译：热熔胶
公开(公告)号：US06946528B2
公开(公告)日：2005-09-20
申请号：US10466454
申请日：2002-01-18
申请人： Joseph D. Domine , Jean M. Tancrede , Sally Q. Pugh
发明人： Joseph D. Domine , Jean M. Tancrede , Sally Q. Pugh
IPC分类号： C09J123/08 , C08F210/02 , C08F220/12 , C08J5/00 , C08L23/08 , C08L33/08 , C08L91/06 , C08L93/04 , C09J11/02 , C09J11/08 , C09J191/06 , C08F2/00 , C08G85/00
CPC分类号： C08F210/02 , C08F220/12 , C08L23/0853 , C08L23/0869 , C08L91/06 , C08L93/04 , C08L2666/26 , C09J123/0869 , Y10T428/1397 , Y10T428/2822 , C08F220/18 , C08F218/08 , C08F2500/12 , C08F2500/20 , C08F2500/17
摘要： The invention provides a hot melt adhesive composition including a tubular reactor copolymer of ethylene and 5 to 20 mol % of comonomer units derived from an alkyl acrylate or alkyl methacrylate, wherein the copolymer has a melt index of at least 300 g/10 min. The alkyl group of the alkyl acrylate or alkyl methacrylate can be a linear or branched C1 to C12 group, particularly n-butyl. If desired, the hot melt adhesive can further include tackifiers, waxes, antioxidants and other desired additives. The hot melt adhesive composition shows improved heat resistance and favorable properties, such as has a shear adhesion fail temperature of at least 80° C., without the need to use high melting waxes. The invention further provides articles such as cartons, cases, trays, bookbindings or disposables including the hot melt adhesive compositions.
摘要翻译：本发明提供一种热熔粘合剂组合物，其包括乙烯的管式反应器共聚物和衍生自丙烯酸烷基酯或甲基丙烯酸烷基酯的5至20摩尔％的共聚单体单元，其中该共聚物的熔体指数为至少300克/ 10分钟。丙烯酸烷基酯或甲基丙烯酸烷基酯的烷基可以是直链或支链C 1至C 12 - 基团，特别是正丁基。如果需要，热熔粘合剂还可以包括增粘剂，蜡，抗氧化剂和其它所需的添加剂。热熔粘合剂组合物显示出改进的耐热性和良好的性能，如剪切粘附失效温度至少为80℃，而不需要使用高熔点蜡。本发明还提供诸如纸箱，箱子，托盘，书本或包括热熔粘合剂组合物的一次性用品的物品。

5. 发明授权

US4888391A Paintable thermoplastic polyolefin compositions having improved flexural properties 失效
标题翻译：具有改进的弯曲性能的可涂覆热塑性聚烯烃组合物
公开(公告)号：US4888391A
公开(公告)日：1989-12-19
申请号：US231569
申请日：1988-08-12
申请人： Joseph D. Domine , Anton J. Buchner
发明人： Joseph D. Domine , Anton J. Buchner
IPC分类号： C08L23/10 , C08L23/06 , C08L23/08 , C08L23/12 , C08L23/16
CPC分类号： C08L23/10 , C08L2205/02 , C08L2205/035 , C08L23/06 , C08L23/0869 , C08L23/16
摘要： A polyolefin composition of ethylene, propylene, or copolymers thereof having good paint retention and improved flexural modulus is described. The properties result from incorporation into said polyolefin of a discontinuous phase made up of an ethylene/lower alkyl (meth)acrylate/(meth)acrylic acid terpolymer. This composition is particularly useful for molding paintable auto parts.

6. 发明授权

US07335424B2 Ionomer laminates and articles formed from ionomer laminates 失效
标题翻译：离子聚合物层压材料和由离聚物层压体形成的制品
公开(公告)号：US07335424B2
公开(公告)日：2008-02-26
申请号：US11141306
申请日：2005-05-31
申请人： Joseph D. Domine , Jeffrey Valentage , Prasadarao Meka
发明人： Joseph D. Domine , Jeffrey Valentage , Prasadarao Meka
IPC分类号： B32B27/08
CPC分类号： B32B7/10 , B29C45/14811 , B29K2715/006 , B29L2031/3044 , B32B27/08 , B32B27/32 , B32B37/153 , B32B38/12 , B32B2270/00 , B32B2307/4026 , B32B2307/558 , B32B2307/584 , B32B2323/043 , B32B2323/046 , B32B2323/10 , B32B2605/08 , C08L23/04 , C08L23/0815 , C08L23/0869 , C08L23/0876 , C08L23/142 , C08L2205/03 , Y10T428/25 , Y10T428/31855 , Y10T428/31909 , Y10T428/31913 , Y10T428/31928 , Y10T428/31935 , Y10T428/31938 , C08L2666/06
摘要： A co-extruded laminate of at least one layer of an ionomer and at least one layer of an acid polymer that can be thermoformed with a plastic substrate such as a polyolefin. The laminate can be pigmented to eliminate the need to paint the surface of the plastic substrate. Articles can be formed from the laminated substrate such as automotive parts and sporting equipment.
摘要翻译：至少一层离子交联聚合物和至少一层酸聚合物的共挤出层压材料，其可以用诸如聚烯烃的塑料基材进行热成型。层压材料可以着色以消除对塑料基材表面的涂漆的需要。制品可以由诸如汽车部件和运动器材的层压基底形成。

7. 发明授权

US07112624B2 Ethylene alkyl acrylate copolymers with improved heat resistance 失效
标题翻译：乙烯丙烯酸烷基酯共聚物具有改善的耐热性
公开(公告)号：US07112624B2
公开(公告)日：2006-09-26
申请号：US10466450
申请日：2002-01-18
申请人： Joseph D. Domine
发明人： Joseph D. Domine
IPC分类号： C08K5/01
CPC分类号： C08F220/12 , C08F210/02 , C08F4/34 , C08F220/18 , C08F218/08 , C08F2500/12 , C08F2500/20 , C08F2500/17
摘要： The invention provides a copolymer of ethylene and at least 5 mol % of comonomer units derived from an alkyl acrylate or alkyl methacrylate, wherein the copolymer has a melt index of from 1 to 10,000 g/10 min, and a maximum peak melting temperature of at least 100° C. The alkyl group of the alkyl acrylate or alkyl methacrylate can be a linear or branched C1 to C12 group, particularly n-butyl. The copolymer shows increased heat resistance as characterized by a temperature required to melt 50% of the copolymer of at least 80° C., a temperature required to melt 80% of the copolymer of at least 100° C., a temperature required to melt 100% of the copolymer of at least 110° C. The invention further provides a process for copolymerizing ethylene and an alkyl acrylate or alkyl methacrylate comonomer.
摘要翻译：本发明提供乙烯与至少5mol％衍生自丙烯酸烷基酯或甲基丙烯酸烷基酯的共聚单体共聚物的共聚物，其中共聚物的熔体指数为1至10,000g / 10min，最大熔融温度为at 至少100℃。丙烯酸烷基酯或甲基丙烯酸烷基酯的烷基可以是直链或支链C 1至C 12 - 基团，特别是正丁基。共聚物显示出增加的耐热性，其特征在于将50％的共聚物熔融至少80℃所需的温度，熔融80％共聚物至少100℃所需的温度，熔融所需的温度 100％的共聚物为至少110℃。本发明还提供了一种使乙烯和丙烯酸烷基酯或甲基丙烯酸烷基酯共聚单体共聚的方法。

8. 发明授权

US5648438A Process for producing polymers with multimodal molecular weight distributions 失效
标题翻译：制备具有多峰分子量分布的聚合物的方法
公开(公告)号：US5648438A
公开(公告)日：1997-07-15
申请号：US221915
申请日：1994-04-01
申请人： David T. Henry , Doulgas J. McLain , Joseph D. Domine , Aspy Keki Mehta , William Joseph Zafian , Norbert Baron , Bernard J. Folie
发明人： David T. Henry , Doulgas J. McLain , Joseph D. Domine , Aspy Keki Mehta , William Joseph Zafian , Norbert Baron , Bernard J. Folie
IPC分类号： C08F4/64 , C08F2/00 , C08F2/14 , C08F2/34 , C08F10/00 , C08F210/16
CPC分类号： C08F210/16
摘要： The invention provides a continuous process for catalytically polymerizing a monomer feed of ethylene and at least one comonomer which comprises introducing a catalyst including a bulky ancillary ligand transition metal compound and monomer feed in an upstream reaction zone for polymerization, introducing further catalyst in a downstream reaction zone for further polymerization, the peak temperature in the downstream reaction zone being at least 50.degree. C. higher than in the upstream zone and being above 150.degree. C. The process economically produces polymer of good properties which is melt processable.
摘要翻译：本发明提供了用于催化聚合乙烯和至少一种共聚单体的单体进料的连续方法，其包括在上游反应区中引入包含大体积辅助配体过渡金属化合物和单体进料的催化剂进行聚合，在下游反应中引入另外的催化剂用于进一步聚合的区域，下游反应区域中的峰值温度比上游区域高至少50℃且高于150℃。该方法经济地生产可熔融加工的具有良好性能的聚合物。

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