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1. 发明授权

US5496918A Process for improving the properties of polymers 失效
标题翻译：提高聚合物性能的方法
公开(公告)号：US5496918A
公开(公告)日：1996-03-05
申请号：US322976
申请日：1994-10-13
申请人： Yash P. Khanna , Kevin R. Slusarz , Mina K. Gabriel , Annemarie C. Reimschuessel , John P. Sibilia
发明人： Yash P. Khanna , Kevin R. Slusarz , Mina K. Gabriel , Annemarie C. Reimschuessel , John P. Sibilia
IPC分类号： C08G69/28 , C08G69/46 , C08K3/00
CPC分类号： C08G69/46 , C08G69/28 , C08K3/0033
摘要： This invention relates to a process of forming a polyamide composition having increased crystallization rate which comprises the steps of reducing the oligomeric polyamide content of said composition to less than 8% by weight of the composition, preferably with prior melt shearing, use of 1-2% nucleating filler e.g. talc and a mold release agent.
摘要翻译：本发明涉及形成具有增加的结晶速率的聚酰胺组合物的方法，该方法包括以下步骤：将所述组合物的低聚聚酰胺含量降低至组合物重量的小于8％，优选使用现有的熔融剪切，使用1-2 ％成核填料例如滑石和脱模剂。

2. 发明授权

US4566991A Process for preparing conducting polymeric compositions 失效
标题翻译：制备导电聚合物组合物的方法
公开(公告)号：US4566991A
公开(公告)日：1986-01-28
申请号：US394752
申请日：1982-07-02
申请人： John P. Sibilia , Hyo-gun Kim , Arthur R. Paterson
发明人： John P. Sibilia , Hyo-gun Kim , Arthur R. Paterson
IPC分类号： C08J7/00 , C08K3/00 , H01B1/12 , H01B1/02
CPC分类号： H01B1/122 , C08K3/0033 , Y10S524/914
摘要： Process for reducing the resistivity of polymers, by forming a composition comprised of such polymers and one or more metal salts, and treating such a composition with a reagent to form the corresponding carbonate, sulfide and/or oxide salts of such metal salts on and in the surfaces of the polymer.
摘要翻译：通过形成由这种聚合物和一种或多种金属盐组成的组合物，并用试剂处理这种组合物以在其上形成相应的碳酸盐，硫化物和/或氧化物盐，从而降低聚合物电阻率的方法聚合物的表面。

3. 发明授权

US4876127A Method of blow molding polyamides 失效
标题翻译：聚酰胺吹塑方法
公开(公告)号：US4876127A
公开(公告)日：1989-10-24
申请号：US269030
申请日：1988-11-09
申请人： Yash P. Khanna , Himangshu R. Bhattacharjee , Rakesh Kumar , Jon I. Williams , John P. Sibilia
发明人： Yash P. Khanna , Himangshu R. Bhattacharjee , Rakesh Kumar , Jon I. Williams , John P. Sibilia
IPC分类号： B29C49/00 , B29C49/64 , B29K77/00 , B29L22/00 , C08K5/5399 , C08L77/00
CPC分类号： B29C49/0005 , C08K5/5399 , B29K2077/00 , Y10T428/1352
摘要： This invention relates to a process for blow molding polyamide compositions where the molten polyamide includes an effective amount of one or more aryl phosphoryl azide compounds.
摘要翻译：本发明涉及一种吹塑聚酰胺组合物的方法，其中熔融聚酰胺包括有效量的一种或多种芳基磷酰基叠氮化合物。

4. 发明授权

US5173556A Fluorinated copolymer and barrier films 失效
标题翻译：氟化共聚物和阻隔膜
公开(公告)号：US5173556A
公开(公告)日：1992-12-22
申请号：US696414
申请日：1991-05-06
申请人： Frank Mares , Bryce C. Oxenrider , David J. Long , John P. Sibilia
发明人： Frank Mares , Bryce C. Oxenrider , David J. Long , John P. Sibilia
IPC分类号： C08F8/12 , C08F214/18 , C08F218/04
CPC分类号： C08F214/186 , C08F218/04 , C08F8/12 , C08J5/18 , C08F2810/50
摘要： The present invention is directed to a copolymer of a fluoromonomer having the formula R.sub.1 R.sub.2 C.dbd.CR.sub.3 F wherein R.sub.1, R.sub.2 and R.sub.3 are selected from H and F, and R.sub.3 may be Cl when R.sub.1 and R.sub.2 are F; and a vinyl monomer having the formula H.sub.2 C.dbd.CHR.sub.x, wherein R.sub.x is a radical having the formula --O.sub.2 CR.sub.y, wherein R.sub.y is a radical selected from CH.sub.3 and C.sub.2 H.sub.5.The resulting copolymer comprises fluorinated units having the formula (R.sub.1 R.sub.2 C--CR.sub.3 F) wherein R.sub.1, R.sub.2 and R.sub.3 are selected from H and F, and R.sub.3 may be Cl when R.sub.1 and R.sub.2 are F, and corresponding amounts of vinyl units having the formula (H.sub.2 C--CHR.sub.x), wherein R.sub.x is selected from --CH.sub.3 and C.sub.2 H.sub.5. In an alternate and preferred embodiment the copolymer is hydrolyzed so that R.sub.x becomes --OH.
摘要翻译：本发明涉及式R1R2C = CR3F的含氟单体的共聚物，其中R 1，R 2和R 3选自H和F，当R 1和R 2为F时，R 3可以为Cl; 和具有式H2C = CHRx的乙烯基单体，其中Rx是具有式-O2CRy的基团，其中Ry是选自CH3和C2H5的基团。所得共聚物包括具有式（R 1 R 2 C-CR 3 F）的氟化单元，其中R 1，R 2和R 3选自H和F，当R 1和R 2为F时，R 3可为Cl，并且相应量的具有式 -CHRx），其中Rx选自-CH 3和C 2 H 5。在替代和优选的实施方案中，共聚物被水解，使得Rx变成-OH。

5. 发明授权

US4618528A Polymer films containing platelet particles 失效
标题翻译：含有血小板颗粒的聚合物膜
公开(公告)号：US4618528A
公开(公告)日：1986-10-21
申请号：US709264
申请日：1985-04-15
申请人： William Sacks , John P. Sibilia , Abraham M. Kotliar , Harold D. Oltmann , Shu P. Chen
发明人： William Sacks , John P. Sibilia , Abraham M. Kotliar , Harold D. Oltmann , Shu P. Chen
IPC分类号： B32B27/20 , B32B27/32 , C08J5/18 , C08K3/34 , B32B7/02 , B32B5/16 , B32B27/34
CPC分类号： C08J5/18 , B32B27/20 , B32B27/322 , C08K3/34 , Y10T428/24975 , Y10T428/259 , Y10T428/31725
摘要： Thin polymer films containing small sized platelet type filler. The polymer has a melt index of from 0.01 to 10 grams per 10 minutes at 190.degree. C. to 250.degree. C. as measured on ASTM Test No. D-1238 at a load of 1000 to 2160 grams. The preferred polymer is polycaprolactam or high density polyethylene. There is from 10 to 50 percent of a platelet filler having an average equivalent diameter of from 1 to 8 micrometers, a maximum equivalent diameter of about 25 micrometers, and an average thickness of less than 0.5 micrometers. The preferred filler is talc. The film is from 10 to 100 micrometers thick and can be a single ply or a laminate.
摘要翻译：含有小尺寸血小板型填料的薄聚合物膜。聚合物在190℃至250℃下的熔体指数为0.01至10克/ 10分钟，如ASTM测试号D-1238在1000至2160克的载荷下测量。优选的聚合物是聚己内酰胺或高密度聚乙烯。具有10至50％的平均当量直径为1至8微米，最大当量直径为约25微米，平均厚度小于0.5微米的血小板填充剂。优选的填料是滑石。该膜的厚度为10至100微米，可以是单层或层压板。

6. 发明授权

US4558019A Periclase refractory brick with oxyhydrocarbon component 失效
$Periclase refractory brick with oxyhydrocarbon component$
标题翻译：百日咳耐火砖与羟基烃成分
公开(公告)号：US4558019A
公开(公告)日：1985-12-10
申请号：US572727
申请日：1984-01-20
申请人： Abraham M. Kotliar , John P. Sibilia , Ronald H. Hughes , Richard A. Landy
发明人： Abraham M. Kotliar , John P. Sibilia , Ronald H. Hughes , Richard A. Landy
IPC分类号： C04B35/01 , C04B35/52
CPC分类号： C04B35/013
摘要： A periclase refractory composition comprising magnesium oxide granules, carbon granules and a carbonaceous binding material capable of undergoing pyrolytic decomposition. Added to the periclase refractory composition is at least one oxyhydrocarbon compound selected from the group consisting of (a) acyclic carboxylic acids, (b) oxidized polyolefin waxes, (c) poly(alkylene oxides) and ethers thereof, (d) olefin copolymers, (e) polyvinyl alcohol, and (f) furan polymers.
摘要翻译：包含镁氧化物颗粒，碳颗粒和能够进行热解分解的碳质结合材料的玻璃纤维素耐火材料组合物。添加到所述百格斯耐火材料组合物中的是至少一种选自（a）无环羧酸，（b）氧化聚烯烃蜡，（c）聚（环氧烷烃）及其醚），（d）烯烃共聚物，（e）聚乙烯醇，和（f）呋喃聚合物。

7. 发明授权

US4427825A Blends of polyamide and ethylene vinyl alcohol copolymers 失效
公开(公告)号：US4427825A
公开(公告)日：1984-01-24
申请号：US319165
申请日：1981-11-09
申请人： Alfieri Degrassi , William Sacks , John P. Sibilia , Abraham M. Kotliar , Charles D. Mason
发明人： Alfieri Degrassi , William Sacks , John P. Sibilia , Abraham M. Kotliar , Charles D. Mason
IPC分类号： C08L23/08 , C08L29/04 , C08L77/00 , C08L77/02 , C08L29/02 , C08F16/06
CPC分类号： C08L23/0861 , C08L29/04 , C08L77/00 , C08L77/02
摘要： A composition of matter comprising a polyamide, preferably polyepsiloncaprolactam, and from 1 to 65 percent of an ethylene vinyl alcohol copolymer. The composition is useful for making moldings, films, and fibers.

8. 发明授权

US4886689A Matrix-matrix polyblend adhesives and method of bonding incompatible polymers 失效
标题翻译：基质矩阵聚合胶粘剂和粘合不相容聚合物的方法
公开(公告)号：US4886689A
公开(公告)日：1989-12-12
申请号：US196819
申请日：1988-05-19
申请人： Abraham M. Kotliar , William Sacks , John P. Sibilia , Rakesh Kumar
发明人： Abraham M. Kotliar , William Sacks , John P. Sibilia , Rakesh Kumar
IPC分类号： B29C47/06 , B32B7/12 , C09J123/02
CPC分类号： B32B7/12 , B29C47/06 , C09J123/02 , B29C47/0023 , Y10S525/903 , Y10S525/931 , Y10T428/1352 , Y10T428/31544
摘要： A novel adhesive is described, consisting of a matrix-matrix polyblend of polymer components useful in an adhesive tie layer to bond incompatible polymer layers. The adhesives are a blend of the components making up the incompatible polymer layers themselves, or polymers substantially similar to these, and are melt processed to produce a matrix-matrix morphology with mechanical interlocking of the polymer components that is maintained upon cooling. Additives may be provided in one or both adhesive components to improve the cohesive strength of the adhesive formed by the mechanical interlocking.
摘要翻译：描述了一种新型粘合剂，其由用于粘合不相容的聚合物层的粘合剂粘合层中的聚合物组分的基质 - 基质聚合物组成。粘合剂是构成不相容的聚合物层本身的组分或基本上与其相似的聚合物的共混物，并且被熔融加工以产生基体 - 基体形态，其中冷凝时保持的聚合物组分具有机械互锁。可以在一个或两个粘合剂组分中提供添加剂，以改善通过机械互锁形成的粘合剂的内聚强度。

9. 发明授权

US4728478A Polymer films containing platelet particles 失效
标题翻译：含有血小板颗粒的聚合物膜
公开(公告)号：US4728478A
公开(公告)日：1988-03-01
申请号：US912726
申请日：1986-09-29
申请人： William Sacks , John P. Sibilia , Abraham M. Kotliar , Harold D. Oltman , Shu P. Chen
发明人： William Sacks , John P. Sibilia , Abraham M. Kotliar , Harold D. Oltman , Shu P. Chen
IPC分类号： B32B27/20 , B32B27/32 , C08J5/18 , C08K3/34 , B29C47/06
CPC分类号： C08J5/18 , B32B27/20 , B32B27/322 , C08K3/34
摘要： Thin polymer films containing small sized platelet type filler. The polymer has a melt index of from 0.01 to 10 grams per 10 minutes at 190.degree. C. to 250.degree. C.as measured on ASTM Test No. D-1238 at a load of 1000 to 2160 grams. The preferred polymer is polycaprolactam or high density polyethylene. There is from 10 to 50 percent of a platelet filler having an average equivalent diameter of from 1 to 8 micrometers, a maximum equivalent diameter of about 25 micrometers, and an average thickness of less than 0.5 micrometers. The preferred filler is talc. The film is from 10 to 100 micrometers thick and can be a single ply or a laminate.
摘要翻译：含有小尺寸血小板型填料的薄聚合物膜。该聚合物在190℃至250℃下的熔体指数为0.01至10克/ 10分钟。在ASTM试验编号D-1238中，以1000至2160克的载荷测量。优选的聚合物是聚己内酰胺或高密度聚乙烯。具有10至50％的平均当量直径为1至8微米，最大当量直径为约25微米，平均厚度小于0.5微米的血小板填充剂。优选的填料是滑石。该膜的厚度为10至100微米，可以是单层或层压板。

10. 发明授权

US4696857A Annealed thin walled polymer articles and method to anneal 失效
标题翻译：退火的薄壁聚合物制品和退火方法
公开(公告)号：US4696857A
公开(公告)日：1987-09-29
申请号：US808807
申请日：1985-12-13
申请人： John P. Sibilia , Abraham M. Kotliar , Narasimhaiah S. Murthy , William Sacks
发明人： John P. Sibilia , Abraham M. Kotliar , Narasimhaiah S. Murthy , William Sacks
IPC分类号： B29C71/02 , B32B27/34 , C08J5/18 , B32B5/16 , B29B17/00
CPC分类号： C08J5/18 , B29C71/02 , B32B27/34 , B29C2071/022 , B29K2023/065 , B29K2077/00 , B29K2105/16 , C08J2323/06 , C08J2377/00 , Y10T428/25 , Y10T428/259 , Y10T428/31725
摘要： The permeation resistance to gases and vapors of polymeric articles including thin walled articles such as films and bottles can be increased by annealing the film. A preferred embodiment is one where the preferred polymer is polycaprolactam or high density polyethylene. There is from 1 to 50 percent of a platelet filler having an average equivalent diameter of from 1 to 8 micrometers, a maximum equivalent diameter of about 25 micrometers, and an average thickness of less than 0.5 micrometers.
摘要翻译：包括薄壁制品如薄膜和瓶子在内的聚合制品对气体和蒸气的耐渗透性可以通过退火薄膜来提高。优选的实施方案是优选的聚合物是聚己内酰胺或高密度聚乙烯。具有1至50％的平均当量直径为1至8微米，最大当量直径为约25微米，平均厚度小于0.5微米的血小板填充剂。

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