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1. 发明申请

US20120142847A1 AQUEOUS CROSS-LINKING COMPOSITIONS AND METHODS 有权
标题翻译：水质交联组合物和方法
公开(公告)号：US20120142847A1
公开(公告)日：2012-06-07
申请号：US13152856
申请日：2011-06-03
申请人： Yong Yang , Yue Chen , Robert J. Sheerin , Jean Fredrick Mauck , Navin Tilara , Johanna Garcia de Visicaro
发明人： Yong Yang , Yue Chen , Robert J. Sheerin , Jean Fredrick Mauck , Navin Tilara , Johanna Garcia de Visicaro
IPC分类号： C09D167/00 , C08F220/06 , C09J133/08 , C09D11/00
CPC分类号： C09D5/024 , C08G59/4014 , C08L2201/56 , C09D133/02 , C09D133/068 , C09D163/00 , C08K5/30
摘要： Water-borne cross-linking polymeric compositions and related embodiments, such as methods of making and using the compositions, as well as products formed with said compositions are described. For example, the water-borne composition may comprise polymers incorporating cross-linking functionality such as, but not limited to, carbonyl or epoxy functionality, and a blocked cross-linking agent, for example, a hydrazone. The cross-linking functionality does not react with the blocked cross-linking agent; however, the blocked cross-linking agent is capable of reacting with the alternative form cross-linking agent such as, but not limited to, a hydrazide, to yield a cross-linked polymer. The alternative form cross-linking agent may be formed in an equilibrium reaction including the blocked cross-linking agent.
摘要翻译：描述了水性交联聚合物组合物和相关实施方案，例如制备和使用组合物的方法，以及与所述组合物形成的产品。例如，水性组合物可以包含掺入交联官能团的聚合物，例如但不限于羰基或环氧官能团，以及封端的交联剂，例如腙。交联官能团不与阻断的交联剂反应; 然而，封端交联剂能够与替代形式的交联剂反应，例如但不限于酰肼，以产生交联聚合物。交替形成的交联剂可以在包括封端交联剂的平衡反应中形成。

2. 发明授权

US08815981B2 Hybrid organic-inorganic nanocomposites 有权
标题翻译：混合有机 - 无机纳米复合材料
公开(公告)号：US08815981B2
公开(公告)日：2014-08-26
申请号：US13583694
申请日：2011-02-11
申请人： Yong Yang , Johanna Garcia de Visicaro , Robert Sheerin
发明人： Yong Yang , Johanna Garcia de Visicaro , Robert Sheerin
IPC分类号： C08K13/02 , C08K3/36 , B60C1/00
CPC分类号： C08K13/02 , B60C1/00 , C09D133/04
摘要： The present invention relates to a dispersion of hybrid organic-inorganic nanocomposite molecules comprising discrete inorganic silica nanoparticles that are covalently bonded to organic polymers, wherein the dispersion has a high solid content (>30% wt.) and high silica content (>35% wt.) with low coagulum (about 100-400 ppm or about 0.05% wt or less). The hybrid organic-inorganic nanocomposite is prepared by (1) hydrolyzing silane monomers at acidic conditions; (2) surface treating inorganic silica nanoparticles with silane monomers; (3) stabilizing the surface-treated inorganic silica nanoparticles with an amine stabilizer; and (4) reacting organic monomers with surface-treated inorganic silica nanoparticles.
摘要翻译：本发明涉及共价键合到有机聚合物上的离散无机二氧化硅纳米粒子的杂化有机 - 无机纳米复合材料分散体，其中分散体具有高固含量（> 30％重量）和高二氧化硅含量（> 35％（约100-400ppm或约0.05wt％或更少）。通过（1）在酸性条件下水解硅烷单体制备杂化有机 - 无机纳米复合材料; （2）用硅烷单体表面处理无机二氧化硅纳米粒子; （3）用胺稳定剂稳定表面处理的无机二氧化硅纳米粒子; 和（4）使有机单体与表面处理的无机二氧化硅纳米颗粒反应。

3. 发明授权

US09790374B2 Aqueous cross-linking compositions and methods 有权
公开(公告)号：US09790374B2
公开(公告)日：2017-10-17
申请号：US13152856
申请日：2011-06-03
申请人： Yue Chen , Yong Yang , Robert J. Sheerin , Jean Fredrick Mauck , Navin Tilara , Johanna Garcia de Visicaro
发明人： Yue Chen , Yong Yang , Robert J. Sheerin , Jean Fredrick Mauck , Navin Tilara , Johanna Garcia de Visicaro
IPC分类号： C08K5/24 , C08K5/25 , C09D133/08 , C09D133/06 , C09D133/26 , C09D5/02 , C08G59/40 , C09D133/02 , C09D163/00
CPC分类号： C09D5/024 , C08G59/4014 , C08L2201/56 , C09D133/02 , C09D133/068 , C09D163/00 , C08K5/30
摘要： Water-borne cross-linking polymeric compositions and related embodiments, such as methods of making and using the compositions, as well as products formed with said compositions are described. For example, the water-borne composition may comprise polymers incorporating cross-linking functionality such as, but not limited to, carbonyl or epoxy functionality, and a blocked cross-linking agent, for example, a hydrazone. The cross-linking functionality does not react with the blocked cross-linking agent; however, the blocked cross-linking agent is capable of reacting with the alternative form cross-linking agent such as, but not limited to, a hydrazide, to yield a cross-linked polymer. The alternative form cross-linking agent may be formed in an equilibrium reaction including the blocked cross-linking agent.

4. 发明申请

US20130005881A1 Hybrid Organic-Inorganic Nanocomposites 有权
标题翻译：混合有机无机纳米复合材料
公开(公告)号：US20130005881A1
公开(公告)日：2013-01-03
申请号：US13583694
申请日：2011-02-11
申请人： Yong Yang , Johanna Garcia De Visicaro , Robert Sheerin
发明人： Yong Yang , Johanna Garcia De Visicaro , Robert Sheerin
IPC分类号： C08L33/12 , C09D133/12 , C08K13/02 , C07F7/08 , C08K3/36 , C08F230/08 , B82Y30/00
CPC分类号： C08K13/02 , B60C1/00 , C09D133/04
摘要： The present invention relates to a dispersion of hybrid organic-inorganic nanocomposite molecules comprising discrete inorganic silica nanoparticles that are covalently bonded to organic polymers, wherein the dispersion has a high solid content (>30% wt.) and high silica content (>35% wt.) with low coagulum (about 100-400 ppm or about 0.05% wt or less). The hybrid organic-inorganic nanocomposite is prepared by (1) hydrolyzing silane monomers at acidic conditions; (2) surface treating inorganic silica nanoparticles with silane monomers; (3) stabilizing the surface-treated inorganic silica nanoparticles with an amine stabilizer; and (4) reacting organic monomers with surface-treated inorganic silica nanoparticles.
摘要翻译：本发明涉及共价键合到有机聚合物上的离散无机二氧化硅纳米粒子的杂化有机 - 无机纳米复合材料分散体，其中分散体具有高固含量（> 30％重量）和高二氧化硅含量（> 35％（约100-400ppm或约0.05wt％或更少）。通过（1）在酸性条件下水解硅烷单体制备杂化有机 - 无机纳米复合材料; （2）用硅烷单体表面处理无机二氧化硅纳米粒子; （3）用胺稳定剂稳定表面处理的无机二氧化硅纳米粒子; 和（4）使有机单体与表面处理的无机二氧化硅纳米颗粒反应。

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