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    • 2. 发明授权
    • Aqueous surfactant solution method for stripping metal plasma etch
deposited oxidized metal impregnated polymer residue layers from
patterned metal layers
    • 用于从图案化金属层剥离金属等离子体蚀刻沉积的氧化金属浸渍的聚合物残余物层的水性表面活性剂溶液方法
    • US06057240A
    • 2000-05-02
    • US55437
    • 1998-04-06
    • Mei-Sheng ZhouJian-Hui YeSimon ChooiYoung-Tong Tsai
    • Mei-Sheng ZhouJian-Hui YeSimon ChooiYoung-Tong Tsai
    • C11D1/04C11D1/68C11D1/70C11D3/30C11D11/00H01L21/02H01L21/311H01L21/3213H05K3/06H01R13/502C11D9/00
    • H01L21/02071B82Y10/00B82Y30/00C11D11/0047C11D3/30H01L21/31138H01L21/32136H05K3/064C11D1/04H05K2203/0793H05K2203/095
    • A method for forming a patterned metal layer within a microelectronics fabrication. There is first provided a substrate employed within a microelectronics fabrication. There is then formed over the substrate a blanket metal layer. There is then formed over the blanket metal layer a patterned photoresist layer. There is then etched through use of a plasma etch method while employing the patterned photoresist layer as a photoresist etch mask layer the blanket metal layer to form a patterned metal layer. The patterned metal layer so formed has a metal impregnated carbonaceous polymer residue layer formed upon a sidewall of the patterned metal layer. There is then stripped from the patterned metal layer the patterned photoresist layer through use of an oxygen containing plasma while simultaneously oxidizing the metal impregnated carbonaceous polymer residue layer to form an oxidized metal impregnated polymer residue layer upon the sidewall of the patterned metal layer. There is then stripped from the sidewall of the patterned metal layer the oxidized metal impregnated polymer residue layer while employing an aqueous alkyl ammonium hydroxide based solution. The aqueous alkyl ammonium hydroxide based solution has incorporated therein a surfactant capable of forming a monolayer adsorbed upon the sidewall of the patterned metal layer.
    • 一种用于在微电子制造中形成图案化金属层的方法。 首先提供了在微电子制造中使用的衬底。 然后在衬底上形成覆盖金属层。 然后在覆盖金属层上形成图案化的光致抗蚀剂层。 然后通过使用等离子体蚀刻方法蚀刻,同时使用图案化的光致抗蚀剂层作为光刻胶蚀刻掩模层,覆盖金属层以形成图案化的金属层。 如此形成的图案化金属层具有形成在图案化金属层的侧壁上的金属浸渍碳质聚合物残余层。 然后通过使用含氧等离子体从图案化的金属层剥离图案化的光刻胶层,同时对金属浸渍的碳质聚合物残余层进行氧化,以在图案化金属层的侧壁上形成氧化金属浸渍的聚合物残余物层。 然后从图案化金属层的侧壁剥离氧化金属浸渍的聚合物残余物层,同时使用基于烷基氢氧化铵的水溶液。 基于烷基氢氧化铵的水溶液溶液中加入了能够形成单层吸附在图案化金属层的侧壁上的表面活性剂。
    • 3. 发明授权
    • Photoresist and polymer removal by UV laser aqueous oxidant
    • UV激光水性氧化剂除去光致抗蚀剂和聚合物
    • US6009888A
    • 2000-01-04
    • US73946
    • 1998-05-07
    • Jian-Hui YeYuan-Ping LeeMei-Sheng ZhouYong-Feng Lu
    • Jian-Hui YeYuan-Ping LeeMei-Sheng ZhouYong-Feng Lu
    • B08B7/00G03F7/42H01L21/311B08B7/04
    • H01L21/31127B08B7/0042G03F7/423H01L21/31133
    • A method of stripping photoresist and polymer from a wafer after a dry etch of a nitrade or a polysilicon layer that immerses the wafer in a peroxydisulfate (S.sub.2 O.sub.8.sup.2-)/HCl wet bath and while the wafer is still immersed, irradiates the wafer with a UV laser. The method comprises: (a) forming an silicon nitride layer 24 and a photoresist pattern 28 over a semi conductor structure 10; (b) dry etching the silicon nitride layer 24 thus forming a polymer 30 over the photoresist pattern, and the silicon nitride layer, (c) Immersing the substrate, the photoresist pattern, the polymer 30 in a liquid bath 34 comprising (1) peroxydisulfate (S.sub.2 O.sub.8.sup.2-), (2) HCl, and (3) water; and irradiating the photoresist pattern 28 and polymer layer 30 with a UV laser thereby removing the photoresist 28 and polymer 30.
    • 在将晶片浸入过氧二硫酸盐(S2O82-)/ HCl湿浴中并在晶片仍然浸没之后的氮化或多晶硅层的干蚀刻之后,从晶片剥离光致抗蚀剂和聚合物的方法, 激光。 该方法包括:(a)在半导体结构10上形成氮化硅层24和光致抗蚀剂图案28; (b)干蚀刻氮化硅层24,从而在光致抗蚀剂图案和氮化硅层上形成聚合物30,(c)将基底,光致抗蚀剂图案,聚合物30浸入液浴34中,该液槽34包括(1)过氧化二硫酸 (S2O82-),(2)HCl和(3)水; 并用UV激光照射光致抗蚀剂图案28和聚合物层30,从而除去光致抗蚀剂28和聚合物30。
    • 4. 发明授权
    • Hydrolytically stable organic polymer material for organic polymer
anti-reflective (ARC) layer
    • 用于有机聚合物抗反射(ARC)层的水解稳定的有机聚合物材料
    • US6004722A
    • 1999-12-21
    • US55440
    • 1998-04-06
    • Ai-Qiang ZhangJian-Hui Ye
    • Ai-Qiang ZhangJian-Hui Ye
    • G03F7/09G03C1/492
    • G03F7/091
    • A method for forming an anti-reflective coating (ARC) layer within a fabrication and a fabrication having the anti-reflective coating (ARC) layer formed therein. To practice the method, there is first provided a substrate. There is then formed over the substrate a reflective layer. There is then formed upon the reflective layer an organic polymer anti-reflective coating (ARC) layer, where the organic polymer anti-reflective coating (ARC) layer is formed from an organic polymer anti-reflective coating (ARC) material which is not susceptible to a hydrolysis reaction. There may then be formed upon the organic polymer anti-reflective coating (ARC) layer a photoresist layer which is photoexposed and developed to form a patterned photoresist layer which may be employed as an etch mask for forming a patterned reflective layer from the reflective layer. The patterned reflective layer so formed is formed with uniform and reproducible linewidth dimension.
    • 在其中形成有抗反射涂层(ARC)层的制造和制造中形成抗反射涂层(ARC)层的方法。 为了实践该方法,首先提供了一种衬底。 然后在衬底上形成反射层。 然后在反射层上形成有机聚合物抗反射涂层(ARC)层,其中有机聚合物抗反射涂层(ARC)层由不敏感的有机聚合物抗反射涂层(ARC)材料形成 进行水解反应。 然后可以在有机聚合物抗反射涂层(ARC)层上形成光致抗蚀剂层,光致抗蚀剂层被光曝光和显影以形成图案化的光致抗蚀剂层,其可以用作用于从反射层形成图案化反射层的蚀刻掩模。 如此形成的图案化反射层形成均匀且可再现的线宽尺寸。