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1. 发明授权

US6040412A Process for preparing chain-extended organopolysiloxanes 有权
标题翻译：制备链延伸的有机聚硅氧烷的方法
公开(公告)号：US6040412A
公开(公告)日：2000-03-21
申请号：US172508
申请日：1998-10-14
申请人： Eric Damme , Jean-Marc Gilson , Patrick Leempoel , Fabrice Lebecq , Takao Takemasa
发明人： Eric Damme , Jean-Marc Gilson , Patrick Leempoel , Fabrice Lebecq , Takao Takemasa
IPC分类号： C08G77/06 , C08G77/08 , C08G77/12 , C08G77/20 , C08G77/04
CPC分类号： C08G77/06 , C08G77/08 , C08G77/12 , C08G77/20
摘要： This specification describes and claims a process for preparing chain-extended organopolysiloxanes. The process comprises the steps of: A) mixing organopolysiloxanes having at least one silicon-bonded hydroxyl group per molecule with a polymerization catalyst to form a mixture, B) allowing the mixture of step A to react so as to produce a reaction product comprising polymerized organopolysiloxanes of which some have at least one silicon-bonded hydroxyl group per molecule and C) allowing the silicon-bonded hydroxyl group containing organopolysiloxanes of the reaction product of step B to react with a nitrogen-containing silylating agent capable of chain-extending to produce a chain-extended organopolysiloxane. Preferably the silylating agent is a cyclosilazane. Organopolysiloxanes having terminal groups other than silicon-containing hydroxyl groups and which are capable of equilibrating with the mixture of step A and/or the reaction product of step B may also be introduced prior to step C. The chain-extended organopolysiloxanes are suitable for use in sealant compositions.
摘要翻译：本说明书描述并要求制备链延伸的有机聚硅氧烷的方法。该方法包括以下步骤：A）将每分子具有至少一个与硅键合的羟基的有机聚硅氧烷与聚合催化剂混合以形成混合物，B）使步骤A的混合物反应以产生包含聚合的有机聚硅氧烷，其一些每分子具有至少一个硅键合的羟基，和C）使步骤B的反应产物的与硅键合的含羟基的有机聚硅氧烷与能够扩链产生的含氮甲硅烷基化试剂反应链延伸的有机聚硅氧烷。优选地，甲硅烷基化剂是环硅氮烷。可以在步骤C之前引入具有除含硅羟基以外的端基的能够与步骤A的混合物和/或步骤B的反应产物平衡的有机聚硅氧烷。扩链的有机聚硅氧烷适用于在密封剂组合物中。

2. 发明授权

US5456888A Polymerization reactor and polymerization process 失效
标题翻译：聚合反应器和聚合过程
公开(公告)号：US5456888A
公开(公告)日：1995-10-10
申请号：US152516
申请日：1993-11-16
申请人： Jean-Marc Gilson , Denis Sbardella
发明人： Jean-Marc Gilson , Denis Sbardella
IPC分类号： C08G85/00 , B01J4/04 , B01J10/00 , B01J19/00 , B01J19/24 , C08F2/00 , C08G77/06 , C08G77/08
CPC分类号： C08G77/06 , B01J10/002 , B01J19/006 , B01J19/2415 , B01J4/04 , B01J2219/00094 , B01J2219/00103 , B01J2219/00774
摘要： A continuous static polymerization reactor for the production of liquid polymers comprises an elongated hollow reaction chamber (30) which has a porous wall (31) and a jacket means (40) spaced around the reaction chamber (30), which is provided with means (44) for introducing a fluid through the porous wall (31). The reactor is particularly useful for a process for making liquid polymers by condensing monomers and/or oligomers. It comprising the use of a pressurized gas to cause the reaction mixture to reach a foam consistency. This is beneficial in the condensation polymerization. Feeding a fluid through the porous wall into the reaction chamber avoids build up of the polymer on the wall.
摘要翻译：用于制备液体聚合物的连续静态聚合反应器包括具有多孔壁（31）和围绕反应室（30）间隔开的夹套装置（40）的细长中空反应室（30），其设有装置 44），用于通过多孔壁（31）引入流体。反应器特别可用于通过缩合单体和/或低聚物制备液体聚合物的方法。其包括使用加压气体以使反应混合物达到泡沫稠度。这在缩聚中是有益的。将流体通过多孔壁进入反应室避免聚合物在壁上积聚。

3. 发明授权

US06964753B2 Polymerization reactor and process 有权
标题翻译：聚合反应器和工艺
公开(公告)号：US06964753B2
公开(公告)日：2005-11-15
申请号：US09912635
申请日：2001-07-25
申请人： Jean Marc Gilson
发明人： Jean Marc Gilson
IPC分类号： C08G85/00 , B01J14/00 , B01J19/00 , C08F2/01 , C08G77/06 , G05D16/00 , C08F2/00
CPC分类号： B01J19/0033 , B01J14/00 , B01J2219/00033 , B01J2219/00094 , B01J2219/00162 , B01J2219/00164 , B01J2219/00168 , C08G77/06
摘要： A continuous static polymerization reactor unit for the production of liquid polymers, in particular high viscosity organopolysiloxanes, in a predetermined viscosity range comprises a reactor (1) a supply means (10,25) for supplying monomers and/or oligomers to an inlet means (2), and an outlet means (5). The inlet means (2) is adapted for the introduction of a reaction mixture into a reaction chamber (3), and a means for introducing at least one viscosity controlling agent into the supply means is provided to form a reaction mixture with monomers and/or oligomers (11,13,15,12,14,16). The unit is adapted to maintain the values of temperature and flow rate of the resulting reaction mixture/polymer in the reaction chamber (3) substantially constant. A control means (24) is used to detect any variation from a predetermined pressure drop value between the inlet means (2) and the outlet means (5), and should such a variation occur the control means (24) is also used to compute and control a compensating rate of introduction of one or more of the at least one viscosity controlling agents to cause the pressure drop between the inlet means (2) and the outlet means (5) to revert to the predetermined value. A process for making liquid polymers within a predetermined viscosity range is also disclosed.
摘要翻译：用于在预定粘度范围内生产液体聚合物，特别是高粘度有机聚硅氧烷的连续静态聚合反应器单元包括反应器（1）用于将单体和/或低聚物供应到入口装置的供应装置（10,25） 2）和出口装置（5）。入口装置（2）适于将反应混合物引入反应室（3）中，并且提供用于将至少一种粘度控制剂引入供应装置的装置以与单体和/或低聚物（11,13,15,12,14,16）。该单元适于保持所得反应混合物/聚合物在反应室（3）中的温度和流速值基本上恒定。控制装置（24）用于检测入口装置（2）和出口装置（5）之间的预定压降值的任何变化，并且如果出现这种变化，则控制装置（24）也用于计算并且控制引入所述至少一种粘度控制剂中的一种或多种的引入装置（2）和所述出口装置（5）之间的压力降低到所述预定值的补偿率。还公开了在预定粘度范围内制备液体聚合物的方法。

4. 发明授权

US5319120A Polymerization reactor and polymerization process 失效
标题翻译：聚合反应器和聚合过程
公开(公告)号：US5319120A
公开(公告)日：1994-06-07
申请号：US909859
申请日：1992-07-07
申请人： Jean-Marc Gilson , Denis Sbardella
发明人： Jean-Marc Gilson , Denis Sbardella
IPC分类号： C08G85/00 , B01J4/04 , B01J10/00 , B01J19/00 , B01J19/24 , C08F2/00 , C08G77/06 , C08G77/08 , C07F7/02 , B01D11/04
CPC分类号： C08G77/06 , B01J10/002 , B01J19/006 , B01J19/2415 , B01J4/04 , B01J2219/00094 , B01J2219/00103 , B01J2219/00774
摘要： A continuous static polymerization reactor for the production of liquid polymers comprises an elongated hollow reaction chamber (30) which has a porous wall (31) and a jacket means (40) spaced around the reaction chamber (30), which is provided with means (44) for introducing a fluid through the porous wall (31). The reactor is particularly useful for a process for making liquid polymers by condensing monomers and/or oligomers. It comprising the use of a pressurized gas to cause the reaction mixture to reach a foam-like consistency. This is beneficial in the condensation polymerization. Feeding a fluid through the porous wall into the reaction chamber avoids build up of the polymer on the wall.
摘要翻译：用于制备液体聚合物的连续静态聚合反应器包括具有多孔壁（31）和围绕反应室（30）间隔开的夹套装置（40）的细长中空反应室（30），其设有装置 44），用于通过多孔壁（31）引入流体。反应器特别可用于通过缩合单体和/或低聚物制备液体聚合物的方法。它包括使用加压气体以使反应混合物达到泡沫状稠度。这在缩聚中是有益的。将流体通过多孔壁进入反应室避免聚合物在壁上积聚。

5. 发明授权

US5504150A Method of making polysiloxane emulsions 失效
标题翻译：聚硅氧烷乳液的制备方法
公开(公告)号：US5504150A
公开(公告)日：1996-04-02
申请号：US417350
申请日：1995-04-05
申请人： Jean-Marc Gilson , Viken Kortian , Didier P. G. Vanderveken
发明人： Jean-Marc Gilson , Viken Kortian , Didier P. G. Vanderveken
IPC分类号： C08L83/04 , C08G77/06 , C08J3/03 , C08L83/00
CPC分类号： C08J3/03 , C08G77/06 , C08J2383/04
摘要： Emulsions containing liquid polymers are made by first condensing monomers in a polymerization reactor having an inlet, a reaction chamber, and an outlet. The monomers are mixed with a condensation catalyst, and a pressurized gas forms a foaming mixture. The foaming mixture is fed down the chamber to the outlet while the monomers polymerize in the chamber. Water and a surfactant are then fed to the lower end of the chamber to form a water-in-oil emulsion with the aid of the foaming action in the chamber. A shear device then inverts the water-in-oil emulsion to an oil-in-water emulsion.
摘要翻译：含有液体聚合物的乳液通过在具有入口，反应室和出口的聚合反应器中首先缩合单体制备。单体与缩合催化剂混合，加压气体形成发泡混合物。发泡混合物在室内被送入出口，而单体在室中聚合。然后将水和表面活性剂进料到室的下端，借助于室中的起泡作用形成油包水乳液。然后剪切装置将油包水乳液反转成水包油乳液。

6. 发明授权

US5210131A Method of making organopolysiloxanes 失效
标题翻译：制备有机硅氧烷的方法
公开(公告)号：US5210131A
公开(公告)日：1993-05-11
申请号：US832145
申请日：1992-02-06
申请人： Jean-Marc Gilson , Jean de la Croi Habimana
发明人： Jean-Marc Gilson , Jean de la Croi Habimana
IPC分类号： C08G77/08 , C08L83/04
CPC分类号： C08G77/08 , C08L83/04 , C08G77/12 , C08G77/14 , C08G77/16 , C08G77/18 , C08G77/70
摘要： A method of making organopolysiloxanes comprises contacting organosilicon compounds having at least one unit ##EQU1## wherein R.degree. is hydrogen, hydroxyl, a C.sub.1-18 hydrocarbon, substituted hydrocarbon or hydrocarbonoxy group and a has a value of from 0 to 4 with a phosphonitrile halide AB, wherein A is a phosphonitrile halide cation [X(PX.sub.2 .dbd.N).sub.n PX.sub.3 ].sup.+, wherein X is halide and n is from 1 to 8 and B is an anion derived from a Lewis acid not containing a P atom, e.g. [MX.sub.(v-t+1) R.sup.2 .sub.t ].sup.-. The method is particularly useful for condensation of silanol end-blocked siloxanes.
摘要翻译：制造有机聚硅氧烷的方法包括使具有至少一个单元的有机硅化合物，其中R DEG是氢，羟基，C 1-18烃，取代的烃或烃氧基，并且与磷腈卤化物的值为0-4 AB，其中A是磷腈卤化物阳离子[X（PX2 = N）nPX3] +，其中X是卤化物，n是1至8，B是源自不含P原子的路易斯酸的阴离子，例如 [MX（v-t + 1）R2 t] - 。该方法对于硅烷醇封端硅氧烷的缩合特别有用。

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