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1. 发明授权

US5198573A Diesters of hexene-1,6-dioic acids produced from 1,2-dialkoxy-3-butenes/co 失效
标题翻译：从1,2-二烷氧基-3-丁烯生产的己烷-1,6-二氧化物的二氧化碳
公开(公告)号：US5198573A
公开(公告)日：1993-03-30
申请号：US762402
申请日：1991-09-19
申请人： Helene Deweerdt , Jean Jenck , Philippe Kalck , Sylvain Mutez , Robert Perron
发明人： Helene Deweerdt , Jean Jenck , Philippe Kalck , Sylvain Mutez , Robert Perron
IPC分类号： B01J27/10 , B01J27/13 , B01J31/04 , C07B61/00 , C07C67/37 , C07C69/593
CPC分类号： C07C67/37
摘要： Diesters of hexene-1,6-dioic acids are prepared by reacting at least one 1,2-dialkoxy-3-butene with carbon monoxide in the presence of a catalytically effective amount of a palladium-based catalyst and a halogen compound, in liquid phase, at elevated temperature and at superatmospheric pressure.
摘要翻译：己烯-1,6-二酸的二酯通过在催化有效量的钯基催化剂和卤素化合物的存在下在液体中使至少一种1,2-二烷氧基-3-丁烯与一氧化碳反应来制备在高温和超大气压下进行。

2. 发明授权

US5041642A Preparation of .beta., .gamma.-unsaturated carboxylic acids 失效
标题翻译：制备β，γ-不饱和羧酸
公开(公告)号：US5041642A
公开(公告)日：1991-08-20
申请号：US814807
申请日：1985-12-30
申请人： Jean Jenck
发明人： Jean Jenck
IPC分类号： C07C57/03 , B01J23/00 , B01J23/44 , B01J31/00 , B01J31/28 , C07B61/00 , C07C51/00 , C07C51/14 , C07C67/00
CPC分类号： C07C51/14
摘要： .beta.,.gamma.-Unsaturated carboxylic acids are facilely prepared by carbonylating a conjugated diene with carbon monoxide in the presence of (i) water, (ii) a halogenated hydracid, (iii) a palladium catalyst comprising palladium metal or supported palladium metal, a palladium oxide, or a complex salt of palladium, the anion coordinated to the palladium cation of which comprising a hard or borderline base, and (iv) a quaternary onium salt of nitrogen, phosphorus or arsenic, said N, P or As being tetra-coordinated to a carbon atom, the anion of which comprising a hard or borderline base.
摘要翻译： β，γ-不饱和羧酸通过在（i）水，（ⅱ）卤化氢化物，（ⅲ）包含钯金属或负载钯金属的钯催化剂，钯氧化物或钯的络合盐，所述阴离子与其包含硬或边界碱的钯阳离子配位，和（iv）氮，磷或砷的季铵盐，所述N，P或As是四配位的碳原子，其阴离子包含硬或边界碱。

3. 发明授权

US4654176A Sulphonated chiral phosphines, their preparation and their use 失效
标题翻译：磺化手性膦，其制备及其用途
公开(公告)号：US4654176A
公开(公告)日：1987-03-31
申请号：US635185
申请日：1984-07-27
申请人： Tuan-Phat Dang , Jean Jenck , Didier Morel
发明人： Tuan-Phat Dang , Jean Jenck , Didier Morel
IPC分类号： C07B53/00 , B01J31/24 , C07B31/00 , C07C45/50 , C07C67/00 , C07F9/50 , C07C143/24 , C07C143/42
CPC分类号： B01J31/2404 , B01J31/2409 , B01J31/2414 , C07C45/505 , C07F9/5022 , C07F9/5027 , B01J2231/645 , B01J2531/822 , B01J2531/96
摘要： The invention provides novel sulphonated chiral phosphines of the formula: ##STR1## in which R represents an alkyl radical, a cycloalkyl radical optionally substituted with an alkyl radical, a cycloalkylalkyl radical optionally substituted with an alkyl radical, a phenyl, phenylalkyl, binaphthyl or binaphthylalkyl radical, in which the alkyl, cycloalkyl, phenyl and binaphthyl radicals, and the alkyl portions of the other radicals, can be substituted by a radical of general formula: ##STR2## R.sub.1 represents an alkyl, cycloalkyl, phenyl, or phenylalkyl radical, Ar represents a phenyl or naphthyl radical, m.sup.+ represents a proton or alkali metal ion or alkaline earth metal ion, m=1 or 2, n=0, 1 or 2, p=1 or 2, (p+m) .ltoreq.3, and R and R.sub.1 can be chiral or achiral. These chiral phosphines form water-soluble metal complexes useful as catalysts in asymmetric organic synthesis.
摘要翻译：本发明提供下式的新型磺化手性膦：其中R表示烷基，任选被烷基取代的环烷基，任选被烷基取代的环烷基烷基，苯基，苯基烷基，联萘或联萘基其中烷基，环烷基，苯基和联萘基以及其它基团的烷基部分可以被下列基团取代：R 1表示烷基，环烷基，苯基或苯基烷基，Ar 表示苯基或萘基，m +表示质子或碱金属离子或碱土金属离子，m = 1或2，n = 0,1或2，p = 1或2，（p + m），R和R 1可以是手性或非手性的。这些手性膦形成水溶性金属络合物，可用作不对称有机合成中的催化剂。

4. 发明授权

US5670701A Preparation of alkyl adipates 失效
标题翻译：己二酸烷基酯的制备
公开(公告)号：US5670701A
公开(公告)日：1997-09-23
申请号：US199544
申请日：1994-02-18
申请人： Philippe Denis , Jean-Michel Grosselin , Jean Jenck , Francois Metz , Paul Rouyer
发明人： Philippe Denis , Jean-Michel Grosselin , Jean Jenck , Francois Metz , Paul Rouyer
IPC分类号： B01J31/12 , C07B61/00 , C07C67/38 , C07C69/44 , C07C67/36
CPC分类号： C07C67/38
摘要： The alkyl adipates are prepared by reacting admixture consisting essentially of alkyl 3-pentenoate and alkyl 2-pentenoate with carbon monoxide and an alcohol, at elevated temperature, under superatmospheric pressure and in the presence of a catalytically effective amount of cobalt or a cobalt compound and a nitrogenous heterocyclic base.
摘要翻译：烷基己二酸酯通过基本上由3-戊烯酸烷基酯和2-戊烯酸烷基酯与一氧化碳和醇组成的混合物在升高的温度下在超大气压下和在催化有效量的钴或钴化合物的存在下反应制备，含氮杂环基。

5. 发明授权

US4925973A Preparation of diesters of hexenedioic acid 失效
标题翻译：己烯二酸二酯的制备
公开(公告)号：US4925973A
公开(公告)日：1990-05-15
申请号：US365768
申请日：1989-06-13
申请人： Helene Deweerdt , Jean Jenck , Philippe Kalck
发明人： Helene Deweerdt , Jean Jenck , Philippe Kalck
IPC分类号： B01J27/13 , B01J31/28 , B01J31/30 , C07B61/00 , C07C67/36 , C07C69/593
CPC分类号： C07C67/36 , C07C69/593
摘要： Diesters of hexene-1,6-dioic acid are efficiently and selectively prepared by reacting carbon monoxide and an alcohol with at least one diacyloxylated butene compound, in the presence of (a) a catalytically effective amount of a palladium-based catalyst and (b) a quaternary onium chloride or bromide of nitrogen or phosphorus.
摘要翻译：在（a）催化有效量的钯基催化剂和（b）的存在下，通过使一氧化碳和醇与至少一种二酰氧基化的丁烯化合物反应来有效地和选择性地制备己烯-1,6-二酸的二酯）氮或磷的季铵氯化物或溴化物。

6. 发明授权

US4485255A Carbonylation of .alpha.,.beta.-unsaturated esters to linear saturated diesters 失效
标题翻译： α，β-不饱和酯羰基化成线性饱和二酯
公开(公告)号：US4485255A
公开(公告)日：1984-11-27
申请号：US444886
申请日：1982-11-29
申请人： Jean Jenck
发明人： Jean Jenck
IPC分类号： C07C67/36 , B01J23/00 , B01J27/00 , B01J31/00 , B01J31/02 , B01J31/28 , C07B61/00 , C07C67/38 , C07C69/34 , C07C69/44 , C07C69/63 , C07C69/67 , C07C69/708 , C07C69/78
CPC分类号： C07C67/38
摘要： Linear saturated diesters, e.g., dialkyl adipates, are prepared by carbonylating an .alpha.,.beta.-unsaturated ester, e.g., an alkyl pent-2-enoate, with carbon monoxide and an alcohol, in the presence of a cobalt catalyst and a tertiary nitrogen-containing base.
摘要翻译：线性饱和二酯，例如己二酸二烷基酯，是通过在钴催化剂和叔氮气存在下将α，β-不饱和酯，例如戊-2-烯酸烷基酯与一氧化碳和醇羰基化制备的，含有碱。

7. 发明授权

US5081292A Preparation of .beta., .gamma.-unsaturated carboxylic acids 失效
标题翻译：（BETA），（氨基） - 脲基羧酸的制备
公开(公告)号：US5081292A
公开(公告)日：1992-01-14
申请号：US516737
申请日：1990-04-30
申请人： Philippe Denis , Jean Jenck , Robert Perron
发明人： Philippe Denis , Jean Jenck , Robert Perron
IPC分类号： B01J27/13 , B01J31/04 , B01J31/24 , C07B61/00 , C07C51/12 , C07C57/02 , C07C57/13 , C07C57/30 , C07C61/08
CPC分类号： C07C51/12
摘要： .beta., .gamma.-Unsaturated carboxylic acids, e.g., 3-hexene-1,6-dioic acid, are selectively prepared by carbonylating (with carbon monoxide) an allyl alcohol, e.g., a butenediol, at an elevated temperature and under superatmospheric pressure, in the presence of a catalytically effective amount of a palladium-based catalyst and at least one quaternary onium chloride of one of the Group VB elements nitrogen or phosphorus, such element being tetracoordinated via carbon atoms and with the proviso that such nitrogen atom may be coordinated to two pentavalent phosphorus atoms.
摘要翻译： β，γ-不饱和羧酸，例如3-己烯-1,6-二酸，通过在升高的温度和超大气压下羰基化（用一氧化碳）烯丙醇，例如丁烯二醇来选择性地制备，存在催化有效量的钯基催化剂和至少一种VB族元素氮或磷之一的季铵氯化物，该元素通过碳原子四配位，条件是这样的氮原子可以配位到两个五价磷原子。

8. 发明授权

US5077433A Preparation of hexene-1,6-dioic acids 失效
标题翻译： HEXENE-1,6-DIOIC酸的制备
公开(公告)号：US5077433A
公开(公告)日：1991-12-31
申请号：US516743
申请日：1990-04-30
申请人： Jean Jenck , Philippe Denis , Philippe Kalck , Helene Deweerdt
发明人： Jean Jenck , Philippe Denis , Philippe Kalck , Helene Deweerdt
IPC分类号： B01J23/44 , B01J27/13 , B01J31/04 , B01J31/12 , C07B61/00 , C07C51/12 , C07C51/14 , C07C57/13
CPC分类号： C07C51/12
摘要： The hexene-1,6-dioic acids, e.g., hex-3-ene-1,6-dioic acid, are prepared by reacting carbon monoxide and water with at least one diacyloxylated butene, in the presence of a catalytically effective amount of palladium and at least one quaternary onium chloride of one of the Group VB elements nitrogen or phosphorus, such element being tetracoordinated via carbon atoms and with the proviso that such nitrogen atom may be coordinated to two pentavalent phosphorus atoms.
摘要翻译：己烯-1,6-二酸，例如己-3-烯-1,6-二酸，是通过使一氧化碳和水与至少一种二酰氧基化丁烯在催化有效量的钯和至少一种VB族元素氮或磷之一的季铵氯化物，该元素通过碳原子四配位，条件是这样的氮原子可以配位成两个五价磷原子。

9. 发明授权

US4522760A Recovery of palladium values from carbonylation reaction medium 失效
标题翻译：从羰基化反应介质中回收钯值
公开(公告)号：US4522760A
公开(公告)日：1985-06-11
申请号：US401394
申请日：1982-07-23
申请人： Jean Jenck
发明人： Jean Jenck
IPC分类号： C07C67/38 , B01J38/00 , C07C67/58 , C07C67/60 , C07C69/52 , C07C69/533 , C11C3/02
CPC分类号： C07C67/38
摘要： Palladium values are separated from the products of reaction resulting from the carbonylation of a conjugated diene with carbon monoxide in the presence of an alcohol, a halogenated hydracid and a palladium catalyst, by (i) contacting the carbonylation reaction medium with a nitrogen, phosphorus or arsenic quaternary onium salt, a polar alcohol and an apolar, aliphatic or cycloaliphatic hydrocarbon solvent, and permitting the resulting admixture to phase separate into an alcohol phase and an organic phase; (ii) decanting/separating said alcohol phase from said organic phase; (iii) recovering the palladium values and the quaternary onium salt from said alcohol phase; and (iv) recovering the products of carbonylation from said organic phase.
摘要翻译：在醇，卤代氢化物和钯催化剂存在下，将钯值与由共轭二烯与一氧化碳羰基化产生的反应产物分离，（i）使羰基化反应介质与氮，磷或砷季铵盐，极性醇和非极性脂族或脂环族烃溶剂，并允许所得混合物相分离成醇相和有机相; （ii）从所述有机相倾析/分离所述醇相; （iii）从所述醇相中回收钯值和季鎓盐; 和（iv）从所述有机相中回收羰基化产物。

10. 发明授权

US4433164A Esters of .beta.,.gamma.-unsaturated carboxylic acids by carbonylation of conjugated dienes 失效
标题翻译：通过羰基化共轭二烯的β，γ-不饱和羧酸的酯
公开(公告)号：US4433164A
公开(公告)日：1984-02-21
申请号：US341101
申请日：1982-01-20
申请人： Jean Jenck
发明人： Jean Jenck
IPC分类号： C07C69/52 , B01J31/00 , C07B61/00 , C07C67/38 , C07C69/533
CPC分类号： C07C69/533
摘要： Esters of .beta.,.gamma.-unsaturated carboxylic acids, e.g., penten-3-oates, are prepared by carbonylating a necessarily conjugated diene, e.g., butadiene, with carbon monoxide, in the presence of (i) an alcohol corresponding to the desired ester, (ii) a halogen hydracid, (iii) a palladium catalyst which comprises palladium metal, a palladium oxide, or a salt of palladium, or ionic complex thereof, the anion coordinated with the palladium cation of which being a hard or intermediate base, and (iv) a quaternary onium salt of elemental nitrogen, phosphorus or arsenic, said elemental nitrogen, phosphorus or arsenic being tetracoordinated with carbon atoms and the anion of said salt comprising a hard or intermediate base.
摘要翻译： β，γ-不饱和羧酸的酯，例如戊烯-3-酸酯，通过在（i）对应于所需酯的醇的存在下将一定的共轭二烯（例如丁二烯）与一氧化碳羰基化来制备，（ii）卤素氢化物，（iii）钯催化剂，其包含钯金属，氧化钯或钯盐或其离子络合物，所述阴离子与作为硬碱或中间碱的钯阳离子配位，以及（iv）元素氮，磷或砷的季鎓盐，所述元素氮，磷或砷与碳原子四配位，所述盐的阴离子包含硬或中间碱。

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