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1. 发明授权

US5019671A Liquid phase isomerization of alkanes 失效
标题翻译：烷烃的液相异构化
公开(公告)号：US5019671A
公开(公告)日：1991-05-28
申请号：US378334
申请日：1989-07-10
申请人： Chao-Yang Hsu , Vasant K. Patel , David H. Vahlsing , James T. Wei , Harry K. Myers, Jr.
发明人： Chao-Yang Hsu , Vasant K. Patel , David H. Vahlsing , James T. Wei , Harry K. Myers, Jr.
IPC分类号： B01J23/889 , B01J23/88 , B01J27/053 , C07B61/00 , C07C5/22 , C07C5/27 , C07C9/16
CPC分类号： C07C5/2213 , C07C5/2781 , C07C2521/06 , C07C2523/656 , C07C2523/745 , C07C2523/75 , C07C2523/889
摘要： A sulfated calcined solid catalyst which comprises (1) oxide or hydroxide of Group III or Group IV, e.g. zirconium, metal, (2) oxide or hydroxide of Group V, Group VI or Group VII, e.g. manganese or molybdenum, metal and (3) oxide or hydroxide of Group VIII, e.g. iron, or cobalt metal, is used to isomerize normal alkanes having 4 to 7 carbon atoms per molecule in the liquid phase to obtain high octane number blending components for motor fuel and/or valuable chemical and fuel intermediates.

2. 发明授权

US06355851B1 Cumene synthesis process using purified benzene and propylene feedstock streams 失效
标题翻译：使用纯化苯和丙烯原料流进行合成工艺
公开(公告)号：US06355851B1
公开(公告)日：2002-03-12
申请号：US09711285
申请日：2000-11-13
申请人： Albert H. Wu , James T. Wei
发明人： Albert H. Wu , James T. Wei
IPC分类号： C07C266
CPC分类号： C07C15/085 , C07C7/005 , C07C7/12 , C07C2529/70 , C07C15/04 , C07C11/06
摘要： A zeolite-catalyzed cumene synthesis process in which benzene and propylene feedstocks are pre-treated to remove catalyst poisons. The benzene feedstock is pre-treated under pressure by contact with a “hot” clay bed at a temperature of about 200 to 500° C., followed by distillation of the benzene feedstock to separate the benzene from the higher molecular weight materials formed from olefinic poisons during the hot clay treatment. The benzene feed is also subjected to a “cold” clay treatment wherein the benzene distillate is contacted with an ambient-temperature clay. The propylene feedstock is pre-treated by contact with an alumina to remove trace sodium compounds and moisture, a molecular sieve to remove moisture, and two modified aluminas to remove catalyst poisons. The pre-treated propylene and benzene feedstocks are then reacted in the presence of a zeolite catalyst to form cumene without causing rapid degradation of the catalyst's activity.
摘要翻译：沸石催化的枯烯合成方法，其中苯和丙烯原料被预处理以除去催化剂毒物。苯原料在压力下通过在约200至500℃的温度下与“热”粘土床接触进行预处理，然后蒸馏苯原料以将苯与由烯烃形成的较高分子量材料分离热粘土处理期间的毒药。苯进料也经受“冷”粘土处理，其中苯馏分与环境温度粘土接触。丙烯原料通过与氧化铝接触来预处理以除去痕量的钠化合物和水分，分子筛以除去水分，以及两种改性的氧化铝以除去催化剂毒物。然后将预处理的丙烯和苯原料在沸石催化剂的存在下反应以形成异丙苯，而不会引起催化剂活性的快速降解。

3. 发明授权

US4956519A Catalyst for hydrocarbon conversion and conversion process utilizing the same 失效
标题翻译：用于烃转化和转化方法的催化剂
公开(公告)号：US4956519A
公开(公告)日：1990-09-11
申请号：US434743
申请日：1989-11-13
申请人： Elmer J. Hollstein , James T. Wei , Chao-Yang Hsu
发明人： Elmer J. Hollstein , James T. Wei , Chao-Yang Hsu
IPC分类号： B01J23/84 , B01J23/889 , B01J27/053 , C07C5/22 , C07C5/27
CPC分类号： C07C5/2213 , B01J23/84 , B01J23/8892 , B01J27/053 , C07C5/2206 , C07C5/2772 , C07C2521/02 , C07C2521/06 , C07C2523/18 , C07C2523/20 , C07C2523/22 , C07C2523/26 , C07C2523/28 , C07C2523/30 , C07C2523/34 , C07C2523/36 , C07C2523/42 , C07C2523/44 , C07C2523/46 , C07C2523/745 , C07C2523/75
摘要： A sulfated calcined solid catalyst is provided which comprises (1) oxide or hydroxide of Group III or Group IV, e.g. zirconium, metal, (2) oxide or hydroxide of Group V, Group VI or Group VII, e.g. manganese, metal and (3) oxide or hydroxide of Group VIII, e.g. iron, metal. In one embodiment of the invention, the catalyst is used to isomerize normal alkanes having 4 to 7 carbon atoms per molecule, to obtain high octane number blending components for motor fuel and/or valuable chemical intermediates.
摘要翻译：提供硫酸化煅烧固体催化剂，其包含（1）III族或IV族的氧化物或氢氧化物，例如锆，金属，（2）氧化物或V族，VI族或VII族的氢氧化物。锰，金属和（3）第VIII族的氧化物或氢氧化物，例如铁，金属。在本发明的一个实施方案中，催化剂用于异构化每分子具有4至7个碳原子的正构烷烃，以获得用于运动燃料和/或有价值的化学中间体的高辛烷值混合组分。

4. 发明授权

US4918041A Catalyst for hydrocarbon conversion and conversion process utilizing the same 失效
标题翻译：用于烃转化和转化方法的催化剂
公开(公告)号：US4918041A
公开(公告)日：1990-04-17
申请号：US247225
申请日：1988-09-21
申请人： Elmer J. Hollstein , James T. Wei , Chao-Yang Hsu
发明人： Elmer J. Hollstein , James T. Wei , Chao-Yang Hsu
IPC分类号： B01J23/84 , B01J23/889 , B01J27/053 , C07B61/00 , C07C1/00 , C07C5/22 , C07C5/27 , C07C9/12 , C07C9/16 , C07C67/00
CPC分类号： C07C5/2213 , B01J23/84 , B01J23/8892 , B01J27/053 , C07C5/2206 , C07C5/2772 , C07C2521/02 , C07C2521/06 , C07C2523/18 , C07C2523/20 , C07C2523/22 , C07C2523/26 , C07C2523/28 , C07C2523/30 , C07C2523/34 , C07C2523/36 , C07C2523/42 , C07C2523/44 , C07C2523/46 , C07C2523/745 , C07C2523/75
摘要： A sulfated calcined solid catalyst is provided which comprises (1) oxide or hydroxide or Group III or Group IV, e.g. zirconium, metal, (2) oxide or hydroxide or Group V, Group VI or Group VII, e.g. manganese, metal and (3) oxide or hydroxide or Group VIII, e.g. iron, metal. In one embodiment of the invention, the catalyst is used to isomerize normal alkanes having 4 to 7 carbon atoms per molecule, to obtain high octane number blending components for motor fuel and/or valuable chemical intermediates.

5. 发明授权

US5780383A Solid superacid catalyst comprising group VII metal and having H.sub.o less than -18 失效
标题翻译：固体超强酸催化剂，其包含第Ⅶ族金属并且具有小于-18的Ho
公开(公告)号：US5780383A
公开(公告)日：1998-07-14
申请号：US989729
申请日：1992-12-10
申请人： Elmer J. Hollstein , James T. Wei , Chao-Yang Hsu
发明人： Elmer J. Hollstein , James T. Wei , Chao-Yang Hsu
IPC分类号： B01J23/34 , B01J23/889 , B01J27/053 , B01J23/32 , C01B17/74
CPC分类号： B01J27/053 , B01J23/34 , B01J23/889 , B01J23/8892
摘要： The invention is a solid catalyst having acid strength H.sub.o less than -18. Such catalysts are characterized by the ability to react with very weak bases, such as butane, at relatively low temperatures, for example temperatures in the range from 20.degree. to 200.degree. C. The catalysts have exceptionally high activity for various hydrocarbon conversion processes, for example, because of their exceptionally high acid strength.
摘要翻译：本发明是具有小于-18的酸强度H 2的固体催化剂。这样的催化剂的特征在于能够在相当低的温度例如丁烷等非常弱的碱（例如丁烷）下反应，例如温度在20℃至200℃。对于各种烃转化方法，催化剂具有非常高的活性，对于例如，由于其特别高的酸强度。

6. 发明授权

US5648590A Liquid phase isomerization of alkanes 失效
标题翻译：烷烃的液相异构化
公开(公告)号：US5648590A
公开(公告)日：1997-07-15
申请号：US292164
申请日：1994-08-17
申请人： Chao-Yang Hsu , Vasant K. Patel , David H. Vahlsing , James T. Wei , Harry K. Myers, Jr.
发明人： Chao-Yang Hsu , Vasant K. Patel , David H. Vahlsing , James T. Wei , Harry K. Myers, Jr.
IPC分类号： C07C5/27 , C07C5/13
CPC分类号： C07C5/2781 , C07C2521/06 , C07C2523/656 , C07C2523/745 , C07C2523/75 , C07C2523/889
摘要： Acyclic hydrocarbons having 4 to 7 carbon atoms per molecule are isomerized in the liquid phase by contact with a solid superacid catalyst comprising sulfated oxide or hydroxide of a metal selected from the group consisting of Group III and Group IV metals, to obtain high octane number blending components for motor fuel and/or valuable chemical and fuel intermediates.
摘要翻译：每分子具有4至7个碳原子的非环状烃通过与包含选自III和IV族金属的金属的硫酸化氧化物或氢氧化物的固体超强酸催化剂接触而在液相中异构化，以获得高辛烷值共混汽车燃料和/或有价值的化学和燃料中间体的组分。

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