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1. 发明授权

US07422787B2 Oriented strand boards 失效
标题翻译：定向刨花板
公开(公告)号：US07422787B2
公开(公告)日：2008-09-09
申请号：US10561942
申请日：2004-06-28
申请人： Lars Evers , Rodolphus Antonius Theodorus Maria Benthem, Van , Jozef Maria Johannes Mattheij , Jose Guadalupe Gomez Bueso , Jacobus Adriaan Antonius Vermeulen
发明人： Lars Evers , Rodolphus Antonius Theodorus Maria Benthem, Van , Jozef Maria Johannes Mattheij , Jose Guadalupe Gomez Bueso , Jacobus Adriaan Antonius Vermeulen
IPC分类号： B32B21/10
CPC分类号： B32B21/14 , B27N3/002 , B27N3/04 , B32B7/12 , B32B21/02 , B32B2307/514 , B32B2317/16 , C08G12/38 , C09J161/28 , Y10T428/249925 , Y10T428/249939 , Y10T428/2933
摘要： Oriented strand board (OSB), comprising a core layer and two face layers, whereby the face layers comprise an adhesive composition, wherein the adhesive composition in at least one of the face layers comprises a resin composition comprising melamine, formaldehyde, optionally urea and aromatic hydroxyl compounds, wherein the molar ratio of melamine to formaldehyde is 1:0.8-4.0, the molar ratio of melamine to urea is 1:0-2.0 and the molar ratio of melamine to aromatic hydroxyl compounds is 1:0-2.0. In a preferred embodiment, both the face layers and the core layer comprise the said adhesive composition. The OSB's according to the invention can meet the OSB/3 and even the OSB/4 requirements in the EN 300 standards.
摘要翻译：定向刨花板（OSB），包括芯层和两个面层，由此面层包括粘合剂组合物，其中至少一个面层中的粘合剂组合物包含包含三聚氰胺，甲醛，任选的尿素和芳族化合物的树脂组合物羟胺化合物，其中三聚氰胺与甲醛的摩尔比为1:0.8-4.0，三聚氰胺与尿素的摩尔比为1:0-2.0，三聚氰胺与芳族羟基化合物的摩尔比为1:0-2.0。在优选的实施方案中，面层和芯层都包含所述粘合剂组合物。根据本发明的OSB可以满足EN 300标准中的OSB / 3甚至OSB / 4要求。

2. 发明申请

US20080160303A1 ORIENTED STRAND BOARDS 审中-公开
标题翻译：面向板条
公开(公告)号：US20080160303A1
公开(公告)日：2008-07-03
申请号：US12041360
申请日：2008-03-03
申请人： Lars EVERS , Rudolphus Antonius Theodorus Maria Benthem, Van , Jozef Maria Johannes Mattheij , Jose Guadalupe Gomez Bueso , Jacobus Adriaan Antonius Vermeulen
发明人： Lars EVERS , Rudolphus Antonius Theodorus Maria Benthem, Van , Jozef Maria Johannes Mattheij , Jose Guadalupe Gomez Bueso , Jacobus Adriaan Antonius Vermeulen
IPC分类号： B27N3/00
CPC分类号： B32B21/14 , B27N3/002 , B27N3/04 , B32B7/12 , B32B21/02 , B32B2307/514 , B32B2317/16 , C08G12/38 , C09J161/28 , Y10T428/249925 , Y10T428/249939 , Y10T428/2933
摘要： Oriented strand board (OSB), comprising a core layer and two face layers, whereby the face layers comprise an adhesive composition, wherein the adhesive composition in at least one of the face layers comprises a resin composition comprising melamine, formaldehyde, optionally urea and aromatic hydroxyl compounds, wherein the molar ratio of melamine to formaldehyde is 1:0.84.0, the molar ratio of melamine to urea is 1:0-2.0 and the molar ratio of melamine to aromatic hydroxyl compounds is 1:0-2.0. In a preferred embodiment, both the face layers and the core layer comprise the said adhesive composition. The OSB's according to the invention can meet the OSB/3 and even the OSB/4 requirements in the EN 300 standards.
摘要翻译：定向刨花板（OSB），包括芯层和两个面层，由此面层包括粘合剂组合物，其中至少一个面层中的粘合剂组合物包含包含三聚氰胺，甲醛，任选的尿素和芳族化合物的树脂组合物羟胺化合物，其中三聚氰胺与甲醛的摩尔比为1:0.84.0，三聚氰胺与尿素的摩尔比为1:0-2.0，三聚氰胺与芳族羟基化合物的摩尔比为1:0-2.0。在优选的实施方案中，面层和芯层都包含所述粘合剂组合物。根据本发明的OSB可以满足EN 300标准中的OSB / 3甚至OSB / 4要求。

3. 发明申请

US20070149753A1 Nitrogen-containing compound, the preparation thereof and application in amino-aldehyde resins 失效
标题翻译：含氮化合物，其制备方法和在氨基醛树脂中的应用
公开(公告)号：US20070149753A1
公开(公告)日：2007-06-28
申请号：US11707952
申请日：2007-02-20
申请人： Rudolfus Antonius Theodorus Maria Van Benthem , Renier Henricus Maria Kierkels , Jacobus Adriaan Antonius Vermeulen
发明人： Rudolfus Antonius Theodorus Maria Van Benthem , Renier Henricus Maria Kierkels , Jacobus Adriaan Antonius Vermeulen
IPC分类号： C08G12/30
CPC分类号： C07D251/56 , C07D251/70 , C08G12/34 , C08G12/36 , C08G12/38
摘要： The invention relates to a compound of formula I: where: X is equal to NR5; R4 is equal to a C1-C12 alkyl group, aryl group, aralkyl group or cycloalkyl group. R1, R2, R3, R5 are equal to an H, alkyl, cycloalkyl, aryl of heterocyclic group; where R1, R2, and R5 or R1, R2, and R3 may together form a heterocyclic group. The invention also relates to a method for the preparation of this compound by reaction of an amino compound with an alkanol hemiacetal. The invention also relates to amino-aldehyde resins containing this compound and the application of these resins in adhesive compositions, laminates, shaped articles and transparent coatings.
摘要翻译：本发明涉及式I化合物：其中：X等于NR 5; R 4等于C 1 -C 12烷基，芳基，芳烷基或环烷基。 R 1，R 2，R 3，R 5等于H，烷基，环烷基，芳基的杂环基; 其中R 1，R 2和R 5或R 1，R 2，O 2， >，且R 3可以一起形成杂环基。本发明还涉及通过氨基化合物与烷醇半缩醛的反应来制备该化合物的方法。本发明还涉及含有该化合物的氨基醛树脂以及这些树脂在粘合剂组合物，层压材料，成型制品和透明涂层中的应用。

4. 发明申请

US20140228484A1 POLYMER, PROCESS AND USE 审中-公开
公开(公告)号：US20140228484A1
公开(公告)日：2014-08-14
申请号：US14128174
申请日：2012-06-21
申请人： Echt Petronella Friederichs , Jacobus Adriaan Antonius Vermeulen , Marco Marcus Matheus Driessen , Johan Franz Gradus Antonius Jansen , Jan Hendrikus Udding
发明人： Echt Petronella Friederichs , Jacobus Adriaan Antonius Vermeulen , Marco Marcus Matheus Driessen , Johan Franz Gradus Antonius Jansen , Jan Hendrikus Udding
IPC分类号： C08G69/26 , C09D175/04 , C04B24/28 , C09D177/06
CPC分类号： C08G69/26 , C04B24/287 , C08G69/00 , C08G69/42 , C08G83/005 , C09D175/04 , C09D177/06
摘要： There is described a process for producing a gel free hyperbranched polyamide polymer P having a polydispersity of at least 1.1 and a weight average molecular weight of at least 300 daltons, having primary amino groups (useful as a crosslinker). The process comprises the step of reacting Reagent A, a compound comprising at least one amino group (—NH2) and one functional group selected from the group consisting of a further amino group (—NH2), thiol (—SH) and a secondary amine radical (—NHR); (where R denotes a hydrocarbo group) (=functional amine) and Reagent B, an alpha-beta unsaturated Michael-reactive ester comprising a plurality of ester groups (=diester); in a molar ratio of amine A to diester B greater than 1 but less than 3 (preferably 2.1 to 2.9); to form the polyamide in a two stage reaction Michael addition and then amidation. The amine in kept in excess with at least 5% of water by total weight of the amine and diester, a reaction temperature less than the boiling point of the amine; and is held under reduced pressure (30 mbar to 1 atms). Gelation does not occur even after substantially all ethylenic (—C═C—) double bonds; and >95% ester [—C(O)═O] groups have reacted. This violates the Flory rules which predict a gel would form based on the number of functional groups present and their degree of conversion. These polymers may be used as a replacement for polyethylene imine (PEI) for example on plastics; in coatings, colours and/or adhesives; with metals; on textiles and fibres; in water treatment, paper, mineral processing and/or chemically modified Various chemical modifications and further reactions of these polymers are also described. A diverse range of other uses are also described including as additives for composite compositions, such as specialty additives for super-plasticizers in concrete admixtures.

5. 发明申请

US20130211003A1 POLYMER, PROCESS AND COMPOSITION 有权
标题翻译：聚合物，工艺和组合物
公开(公告)号：US20130211003A1
公开(公告)日：2013-08-15
申请号：US13517333
申请日：2010-12-21
申请人： Joseph Petronella Friederichs , Jacobus Adriaan Antonius Vermeulen , Marco Marcus Matheus Driessen
发明人： Joseph Petronella Friederichs , Jacobus Adriaan Antonius Vermeulen , Marco Marcus Matheus Driessen
IPC分类号： C08G69/26
CPC分类号： C08G69/26 , C08G81/00 , C08G83/005
摘要： There is described a process for producing a gel free hyperbranched polyamide polymer having primary amino groups (useful as a crosslinker). The process comprises the step of reacting at least one diamine and at least one unsaturated diester in a molar ratio of diamine to diester greater than 1 but less than 3 (preferably 2.1 to 2.9); to form the polyamide in a two stage reaction Michael addition and then amidation. The diamine in kept in excess with at least 5% of water by total weight of the diamine and diester, a reaction temperature less than the boiling point of the diamine; and is held under reduced pressure (30 mbar to 1 atms). Gelation does not occur even after substantially all ethylenic (—C═C—) double bonds; and >95% ester [—C(O)═O] groups have reacted. This violates the Flory rules which predict a gel would form based on the number of functional groups present and their degree of conversion.
摘要翻译：描述了制备具有伯氨基的无凝胶超支化聚酰胺聚合物（可用作交联剂）的方法。该方法包括使至少一种二胺和至少一种二胺与二酯的不饱和二酯与大于1但小于3（优选2.1-2.9）的二酯反应的步骤; 在两步反应中形成聚酰胺迈克尔加成然后酰胺化。二胺以二胺和二酯的总重量与至少5％的水保持过量，反应温度低于二胺的沸点; 并保持在减压（30mbar至1atms）下。即使在基本上所有的乙烯基（-C = C-）双键之后，凝胶也不会发生; 和> 95％酯[-C（O）= O]基团已经反应。这违反了Flory规则，根据存在的功能组的数量及其转化程度，预测凝胶将形成。

6. 发明授权

US07354987B2 Nitrogen-containing compound, the preparation thereof and application in amino-aldehyde resins 失效
标题翻译：含氮化合物，其制备方法和在氨基醛树脂中的应用
公开(公告)号：US07354987B2
公开(公告)日：2008-04-08
申请号：US11707952
申请日：2007-02-20
申请人： Rudolfus Antonius Theodorus Maria Van Benthem , Renier Henricus Maria Kierkels , Jacobus Adriaan Antonius Vermeulen
发明人： Rudolfus Antonius Theodorus Maria Van Benthem , Renier Henricus Maria Kierkels , Jacobus Adriaan Antonius Vermeulen
IPC分类号： C08G12/30 , C08G12/32
CPC分类号： C07D251/56 , C07D251/70 , C08G12/34 , C08G12/36 , C08G12/38
摘要： The invention relates to a compound of formula I: where: X is equal to NR5; R4 is equal to a C1-C12 alkyl group, aryl group, aralkyl group or cycloalkyl group. R1, R2, R3, R5 are equal to an H, alkyl, cycloalkyl, aryl of heterocyclic group; where R1, R2, and R5 or R1, R2, and R3 may together form a heterocyclic group. The invention also relates to a method for the preparation of this compound by reaction of an amino compound with an alkanol hemiacetal. The invention also relates to amino-aldehyde resins containing this compound and the application of these resins in adhesive compositions, laminates, shaped articles and transparent coatings.
摘要翻译：本发明涉及式I化合物：其中：X等于NR 5; R 4等于C 1 -C 12烷基，芳基，芳烷基或环烷基。 R 1，R 2，R 3，R 5等于H，烷基，环烷基，芳基的杂环基; 其中R 1，R 2和R 5或R 1，R 2，O 2， >，且R 3可以一起形成杂环基。本发明还涉及通过氨基化合物与烷醇半缩醛的反应来制备该化合物的方法。本发明还涉及含有该化合物的氨基醛树脂以及这些树脂在粘合剂组合物，层压材料，成型制品和透明涂层中的应用。

7. 发明授权

US09296860B2 Polymer, process and composition 有权
标题翻译：聚合物，工艺和组成
公开(公告)号：US09296860B2
公开(公告)日：2016-03-29
申请号：US13517333
申请日：2010-12-21
申请人： Joseph Petronella Friederichs , Jacobus Adriaan Antonius Vermeulen , Marco Marcus Matheus Driessen
发明人： Joseph Petronella Friederichs , Jacobus Adriaan Antonius Vermeulen , Marco Marcus Matheus Driessen
IPC分类号： C08G69/26 , C08G81/00 , C08G83/00
CPC分类号： C08G69/26 , C08G81/00 , C08G83/005
摘要： There is described a process for producing a gel free hyperbranched polyamide polymer having primary amino groups (useful as a crosslinker). The process comprises the step of reacting at least one diamine and at least one unsaturated diester in a molar ratio of diamine to diester greater than 1 but less than 3 (preferably 2.1 to 2.9); to form the polyamide in a two stage reaction Michael addition and then amidation. The diamine in kept in excess with at least 5% of water by total weight of the diamine and diester, a reaction temperature less than the boiling point of the diamine; and is held under reduced pressure (30 mbar to 1 atms). Gelation does not occur even after substantially all ethylenic (—C═C—) double bonds; and >95% ester [—C(O)═O] groups have reacted. This violates the Flory rules which predict a gel would form based on the number of functional groups present and their degree of conversion.
摘要翻译：描述了制备具有伯氨基的无凝胶超支化聚酰胺聚合物（可用作交联剂）的方法。该方法包括使至少一种二胺和至少一种二胺与二酯的不饱和二酯与大于1但小于3（优选2.1-2.9）的二酯反应的步骤; 在两步反应中形成聚酰胺迈克尔加成然后酰胺化。二胺以二胺和二酯的总重量与至少5％的水保持过量，反应温度低于二胺的沸点; 并保持在减压（30mbar至1atms）下。即使在基本上所有烯键式（-C≡C-）双键之后，也不会发生凝胶化; 和> 95％酯[-C（O）= O]基团已经反应。这违反了Flory规则，根据存在的功能组的数量及其转化程度，预测凝胶将形成。

8. 发明授权

US08334352B2 Branched polyesteramine acrylate 失效
标题翻译：支链聚酯胺丙烯酸酯
公开(公告)号：US08334352B2
公开(公告)日：2012-12-18
申请号：US12678571
申请日：2008-09-19
申请人： Jacobus Adriaan Antonius Vermeulen , Alfred Jean Paul Buckmann , Rudolfus Antonius Theodorus Maria Benthem , Emilio Martin Bouwens , Stijn Witters
发明人： Jacobus Adriaan Antonius Vermeulen , Alfred Jean Paul Buckmann , Rudolfus Antonius Theodorus Maria Benthem , Emilio Martin Bouwens , Stijn Witters
IPC分类号： C08F26/00 , C08F8/30 , C08F8/00 , C08J3/28
CPC分类号： C08F290/06 , C07C229/12 , C08F222/1006 , C08F290/061 , C08F290/062 , C08F290/065 , C08F290/14 , C08F290/141 , C08F290/142 , C08F290/145 , C08G65/3322 , C08G65/33306 , C09D7/20
摘要： The present invention relates to a method for preparing a branched non dendrimeric macromolecule, comprising: a) providing an addition product of an α,β-olefinically unsaturated compound and an amine comprising at least two hydroxyl groups; and b) esterifying at least part of the hydroxyl groups of the addition product with an olefinically unsaturated carboxylic acid, an olefinically unsaturated carboxylate anion or an olefinically unsaturated carboxylic acid anhydride. The invention further relates to macromolecules obtainable by a method of the invention.
摘要翻译：本发明涉及一种制备支链非树枝状大分子的方法，其包括：a）提供α，β-烯属不饱和化合物和包含至少两个羟基的胺的加成产物; 和b）用烯属不饱和羧酸，烯属不饱和羧酸根阴离子或烯属不饱和羧酸酐酯化加成产物的至少部分羟基。本发明还涉及通过本发明的方法获得的大分子。

9. 发明申请

US20120135149A1 IMPROVED ANTI-BIOFOULING COATING 审中-公开
标题翻译：改进抗生素涂料
公开(公告)号：US20120135149A1
公开(公告)日：2012-05-31
申请号：US13257850
申请日：2010-03-25
申请人： Pascal Josef Paul Buskens , Jacobus Adriaan Antonius Vermeulen , Ronnie de Rijk , Jens Christoph Thies , Jun Qiu
发明人： Pascal Josef Paul Buskens , Jacobus Adriaan Antonius Vermeulen , Ronnie de Rijk , Jens Christoph Thies , Jun Qiu
IPC分类号： B05D5/00 , C09D5/16
CPC分类号： C08F283/12 , C08F291/00 , C08J7/047 , C08L51/003 , C08L51/085 , C09D5/1637 , C09D151/003 , C09D151/085 , C09D201/005 , C08L2666/02
摘要： The invention relates to a coating material suitable for providing a substrate with an anti-biofouling coating, the coating material comprising a macromolecule comprising: (A) a macromolecular scaffold comprising a reactive group capable of undergoing a Michael type reaction between a Michael type acceptor group and a Michael type donor group, (B) at least one functional moiety attached to the macromolecular scaffold, said at least one functional moiety comprising a hydrophilic moiety, wherein the functional moiety is derivable from a Michael type reaction, involving the reactive group on the macromolecular scaffold and a reactive hydrophilic moiety and (C) at least one moiety capable of crosslinking the coating material.
摘要翻译：本发明涉及一种适用于提供具有抗生物污损涂层的基材的涂层材料，所述涂层材料包含大分子，其包含：（A）大分子支架，其包含能够在迈克尔型受体基团之间经历迈克尔型反应的反应性基团和（B）至少一个与大分子支架连接的功能部分，所述至少一个功能部分包含亲水部分，其中所述功能部分可衍生自迈克尔型反应，涉及所述反应性基团大分子支架和反应性亲水部分和（C）能够交联涂层材料的至少一个部分。

10. 发明申请

US20110003908A1 BRANCHED POLYESTERAMINE ACRYLATE 失效
标题翻译：分散丙烯酰胺丙烯酸酯
公开(公告)号：US20110003908A1
公开(公告)日：2011-01-06
申请号：US12678571
申请日：2008-09-19
申请人： Jacobus Adriaan Antonius Vermeulen , Alfred Jean Paul Buckmann , Rudolfus Antonius Theodorus Maria Benthem , Emilio Martin Bouwens , Stijn Witters
发明人： Jacobus Adriaan Antonius Vermeulen , Alfred Jean Paul Buckmann , Rudolfus Antonius Theodorus Maria Benthem , Emilio Martin Bouwens , Stijn Witters
IPC分类号： C08F2/46 , C08F26/02 , C08L39/00
CPC分类号： C08F290/06 , C07C229/12 , C08F222/1006 , C08F290/061 , C08F290/062 , C08F290/065 , C08F290/14 , C08F290/141 , C08F290/142 , C08F290/145 , C08G65/3322 , C08G65/33306 , C09D7/20
摘要： The present invention relates to a method for preparing a branched non dendrimeric macromolecule, comprising: a) providing an addition product of an α,β-olefinically unsaturated compound and an amine comprising at least two hydroxyl groups; and b) esterifying at least part of the hydroxyl groups of the addition product with an olefinically unsaturated carboxylic acid, an olefinically unsaturated carboxylate anion or an olefinically unsaturated carboxylic acid anhydride. The invention further relates to macromolecules obtainable by a method of the invention.
摘要翻译：本发明涉及一种制备支链非树枝状大分子的方法，其包括：a）提供α，β-烯属不饱和化合物和包含至少两个羟基的胺的加成产物; 和b）用烯属不饱和羧酸，烯属不饱和羧酸根阴离子或烯属不饱和羧酸酐酯化加成产物的至少部分羟基。本发明还涉及通过本发明的方法获得的大分子。

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