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    • 6. 发明授权
    • Hydrocarbon conversion process and catalysts
    • 烃转化过程和催化剂
    • US4857171A
    • 1989-08-15
    • US55672
    • 1987-05-29
    • Arend HoekTom HuizingaIan E. Maxwell
    • Arend HoekTom HuizingaIan E. Maxwell
    • B01J29/08B01J29/14B01J29/16C10G47/16C10G47/20
    • B01J29/166C10G47/16
    • A process for converting hydrocarbon oils into products of low average molecular weight and lower average boiling point comprising contacting a hydrocarbon oil at elevated temperature and pressure in the presence of hydrogen with a catalyst comprising a modified Y zeolite having a unit cell size below 24.45 .ANG., a degree of crystallinity which is at least retained at increasing SiO.sub.2 /Al.sub.2 O.sub.3 molar ratios, a water adsorption capacity (at 25.degree. C. and p/p.sub.o value of 0.2) of at least 8% by weight of modified zeolite and a pore volume of at least 0.25 ml/g wherein between 10% and 60% of the total pore volume is made up of pores having a diameter of at least 8 nm, an amorphous cracking component, a binder and at least one hydrogenation component of a Group VI metal and/or at least one hydrogenation component of a Group VIII metal. The invention also relates to catalyst compositions suitable for use in said process.
    • 一种将烃油转化成低平均分子量和较低平均沸点的产物的方法,包括在氢气存在下在升高的温度和压力下将烃油与包含单元尺寸低于24.45的改性Y沸石的催化剂接触, 至少在增加的SiO 2 / Al 2 O 3摩尔比下保持结晶度,水吸附容量(25℃,p / po值为0.2)为至少8重量%的改性沸石,并且孔容积 至少0.25ml / g,其中总孔体积的10%至60%由直径至少为8nm的孔组成,无定形裂解组分,粘合剂和至少一种第VI族金属氢化组分 和/或至少一种第VIII族金属的氢化组分。 本发明还涉及适用于所述方法的催化剂组合物。
    • 7. 发明授权
    • Hydrocarbon conversion catalysts
    • 烃转化催化剂
    • US4857170A
    • 1989-08-15
    • US55652
    • 1987-05-29
    • Arend HoekTom HuizingaIan E. Maxwell
    • Arend HoekTom HuizingaIan E. Maxwell
    • B01J29/08B01J29/14B01J29/16C10G47/02C10G47/16C10G47/20
    • C10G47/16B01J29/166
    • Composition of matter suitable as a catalyst (base) in hydroprocessing comprising a crystalline aluminosilicate zeolite and a binder wherein the crystalline aluminosilicate comprises a modified Y zeolite having a unit cell size below 24.35 .ANG., a degree of crystallinity which is at least retained at increasing SiO.sub.2 /Al.sub.2 O.sub.3 molar ratios, a water adsorption capacity (at 25.degree. C. and a p/p.sub.o value of 0.2) of at least 8% by weight of modified zeolite and a pore volume of at least 0.25 ml/g wherein between 10% and 60% of the total pore volume is made up of pores having a diameter of at least 8 nm. The invention also relates to hydroconversion catalysts and processes based on said compositions of matter.
    • 在加氢处理中适合作为催化剂(碱)的物质的组成,其包含结晶硅铝酸盐沸石和粘合剂,其中结晶硅铝酸盐包含单元尺寸低于24.35的改性Y沸石,结晶度至少在增加SiO 2时保持 / Al 2 O 3摩尔比,至少为8重量%的改性沸石的水吸附能力(25℃,ap / po值为0.2),孔体积为至少0.25ml / g,其中10%至60% 总孔体积的%由直径至少为8nm的孔组成。 本发明还涉及基于所述物质组合物的加氢转化催化剂和方法。