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1. 发明授权

US5847005A Benzamidoxime derivatives, process production thereof, and agrohorticultural bactericide 失效
标题翻译：苯甲酰胺肟衍生物，其工艺生产和农业园艺杀菌剂
公开(公告)号：US5847005A
公开(公告)日：1998-12-08
申请号：US849811
申请日：1997-08-14
申请人： Isamu Kasahara , Hirohito Ooka , Shinsuke Sano , Hiroyasu Hosokawa , Homare Yamanaka
发明人： Isamu Kasahara , Hirohito Ooka , Shinsuke Sano , Hiroyasu Hosokawa , Homare Yamanaka
IPC分类号： A01N37/52 , A01N43/10 , A01N43/36 , A01N43/56 , A01N43/58 , C07C259/18 , C07C317/18 , C07C317/22 , C07C317/44 , C07C319/20 , C07C323/12 , C07C323/60 , C07C323/62 , C07D207/337 , C07D231/12 , C07D333/24 , C07D521/00 , A01N37/18 , C07C233/05
CPC分类号： A01N37/52 , A01N43/10 , A01N43/56 , C07C259/18 , C07C317/18 , C07C317/22 , C07C317/44 , C07C323/12 , C07C323/60 , C07C323/62 , C07D231/12 , C07D233/56 , C07D249/08 , C07D333/24 , C07C2101/02 , C07C2101/08 , C07C2101/14 , C07C2101/16
摘要： The present invention relates to benzamidoxime derivatives represented by the formula �I!; ##STR1## wherein R.sup.1 is unsubstituted or substituted C.sub.1 -C.sub.4 alkyl, unsubstituted or substituted C.sub.2 -C.sub.4 alkenyl or unsubstituted or substituted C.sub.2 -C.sub.4 alkynyl, R.sup.2 is phenyl optionally having substituents or heterocycle optionally having substituents, X.sup.1, X.sup.2, X.sup.3 and X.sup.4 are each independently hydrogen, halogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 haloalkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 haloalkoxy, C.sub.1 -C.sub.4 alkylthio or the like, and r.sub.1 and r.sub.2 are each independently hydrogen, C.sub.1 -C.sub.4 alkyl or the like, having excellent fungicidal activity and being useful as a fungicide for agricultural and horticultural use, and methods for preparation thereof.
摘要翻译： PCT No.PCT / JP95 / 02596 Sec。 371日期1997年8月14日 102（e）日期1997年8月14日PCT 1995年12月18日PCT PCT。 WO96 / 19442 PCT公开号日期：1996年6月27日本发明涉及式[I]表示的苯甲酰胺肟衍生物。取代的C 1 -C 4烷基，未取代或取代的C 2 -C 4烯基或未取代或取代的C 2 -C 4炔基，R 2是任选具有取代基的苯基或任选具有取代基的杂环，X 1，X 2，X 3和X 4各自独立地为氢，卤素， C4烷基，C1-C4卤代烷基，C1-C4烷氧基，C1-C4卤代烷氧基，C1-C4烷硫基等，并且r1和r2各自独立地为氢，C1-C4烷基等，具有优异的杀真菌活性并且是有用的作为农业和园艺用杀真菌剂及其制备方法。

2. 发明授权

US06410749B1 Process for the preparation of optically active amino alcohols 有权
标题翻译：制备光学活性氨基醇的方法
公开(公告)号：US06410749B1
公开(公告)日：2002-06-25
申请号：US09889595
申请日：2001-07-17
申请人： Eiji Katayama , Daisuke Sato , Hirohito Ooka , Tsutomu Inoue
发明人： Eiji Katayama , Daisuke Sato , Hirohito Ooka , Tsutomu Inoue
IPC分类号： C07D20948
CPC分类号： C07D209/48 , C07B2200/07 , C07C231/18 , C07C269/06 , C07C303/40 , C07C311/51 , C07C233/58 , C07C271/08 , C07C271/12
摘要： Process for preparing optically active &bgr;-amino alcohols represented by a general formula (2): Ra—C*H(OH)—C*H(Rb)—Rc wherein Ra and Rc are each independently hydrogen, optionally substituted alkyl, optionally substituted cycloalkyl, Rb is one member selected from among groups represented by the following general formulae; (3) R1CO(R2)N—, and (4) R1CO(R1′CO)N—, and C* is an asymmetric carbon atom, characterized by reacting a racemic &agr;-aminocarbonyl compound represented by the general formula (1): Ra—CO—CH(Rb)—Rc, with hydrogen in the presence of an optically active transition metal compound represented by a general formula (7): MaXY(Px)m(Nx)n wherein Ma represents a metal atom belonging to VIII-group of the periodic law, X and Y represent each independently hydrogen, halogeno, Px represents a phosphine ligand, Nx represents an amine ligand, at least one of Px and Nx is optically active, and m and n each independently represent 0 or an integer of 1 through 4 and a base.
摘要翻译：用于制备由通式（2）表示的光学活性β-氨基醇的方法：Ra-C * H（OH）-C * H（Rb）-Rc其中R a和R c各自独立地为氢，任选取代的烷基，环烷基，Rb是选自下列通式表示的基团中的一个：（3）R1CO（R2）N-和（4）R1CO（R1'CO）N-和C *是不对称碳原子，其特征在于使由通式（1）表示的外消旋α-氨基羰基化合物：在由通式（7）表示的光学活性的过渡金属化合物的存在下，用氢气将Ra-CO-CH（Rb）-Rc：MaXY（Px）m（Nx）n表示，其中Ma表示属于VIII的金属原子 - 周期定律的组，X和Y各自独立地表示氢，卤素，Px表示膦配体，Nx表示胺配体，Px和Nx中的至少一个是光学活性的，m和n各自独立地表示0或 1到4的整数和一个碱基。

3. 发明授权

US5942538A Benzamidoxime derivatives, method for preparation thereof and fungicide for agricultural and horticultural use 失效
标题翻译：苯甲脒衍生物，其制备方法和用于农业和园艺用途的杀真菌剂
公开(公告)号：US5942538A
公开(公告)日：1999-08-24
申请号：US104540
申请日：1998-06-26
申请人： Isamu Kasahara , Hirohito Ooka , Shinsuke Sano , Hiroyasu Hosokawa , Homare Yamanaka
发明人： Isamu Kasahara , Hirohito Ooka , Shinsuke Sano , Hiroyasu Hosokawa , Homare Yamanaka
IPC分类号： A01N37/52 , A01N43/10 , A01N43/36 , A01N43/56 , A01N43/58 , C07C259/18 , C07C317/18 , C07C317/22 , C07C317/44 , C07C319/20 , C07C323/12 , C07C323/60 , C07C323/62 , C07D207/337 , C07D231/12 , C07D333/24 , C07D521/00 , C07D207/30
CPC分类号： A01N37/52 , A01N43/10 , A01N43/56 , C07C259/18 , C07C317/18 , C07C317/22 , C07C317/44 , C07C323/12 , C07C323/60 , C07C323/62 , C07D231/12 , C07D233/56 , C07D249/08 , C07D333/24 , C07C2101/02 , C07C2101/08 , C07C2101/14 , C07C2101/16
摘要： The present invention relates to benzamidoxime derivatives represented by the formula �I!; ##STR1## wherein R.sup.1 is unsubstituted or substituted C.sub.1 -C.sub.4 alkyl, unsubstituted or substituted C.sub.2 -C.sub.4 alkenyl or unsubstituted or substituted C.sub.2 -C.sub.4 alkynyl, R.sup.2 is phenyl optionally having substituents or heterocycle optionally having substituents X.sup.1, X.sup.2, X.sup.3 and X.sup.4 are each independently hydrogen, halogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 haloalkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 haloalkoxy, C.sub.1 -C.sub.4 alkylthio or the like, and r.sub.1 and r.sub.2 are each independently hydrogen, C.sub.1 -C.sub.4 alkyl or the like, having excellent fungicidal activity and being useful as a fungicide for agricultural and horticultural use, and methods for preparation thereof.
摘要翻译：本发明涉及由式[I]表示的苯甲酰胺肟衍生物。其中R1是未取代的或取代的C1-C4烷基，未取代或取代的C2-C4烯基或未取代或取代的C2-C4炔基，R2是任选具有取代基的苯基或任选具有取代基X1，X2，X3和X4的杂环各自独立地为氢，卤素，C1-C4烷基，C1-C4卤代烷基，C1-C4烷氧基，C1-C4卤代烷氧基，C1-C4烷硫基等，并且r1和r2各自独立地为氢，C1-C4烷基等，具有优异的杀真菌性活性和用作农业和园艺用途的杀真菌剂及其制备方法。

4. 发明授权

US5763688A Method for producing an alcohol 失效
标题翻译：醇的制造方法
公开(公告)号：US5763688A
公开(公告)日：1998-06-09
申请号：US568589
申请日：1995-12-07
申请人： Takao Ikariya , Takeshi Ohkuma , Hirohito Ooka , Shohei Hashiguchi , Nobuo Seido , Ryoji Noyori
发明人： Takao Ikariya , Takeshi Ohkuma , Hirohito Ooka , Shohei Hashiguchi , Nobuo Seido , Ryoji Noyori
IPC分类号： C07B41/02 , C07B53/00 , C07C29/145 , C07C41/26 , C07C67/31 , C07D213/30 , C07F17/02 , C07C29/36
CPC分类号： C07D213/30 , C07B41/02 , C07B53/00 , C07C29/145 , C07C403/08 , C07C41/26 , C07C67/31 , C07F17/02 , C07B2200/07 , C07B2200/09 , C07C2101/14 , C07C2101/16 , C07C2102/10 , C07C2103/18 , C07C2103/26
摘要： The present invention provides a method for producing a alcohol including an optically active alcohol by hydrogenating a carbonyl compound in the presence of a homogeneous catalyst, a base and a nitrogen-containing organic compound. Thus, the reaction employs an inexpensive catalyst and proceeds in high yield and high efficiency.
摘要翻译：本发明提供通过在均相催化剂，碱和含氮有机化合物的存在下氢化羰基化合物来制备包含光学活性醇的醇的方法。因此，反应采用廉价的催化剂，并以高产率和高效率进行。

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