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    • 4. 发明授权
    • Preparation of thermoplastics
    • 热塑性塑料的制备
    • US5910276A
    • 1999-06-08
    • US620310
    • 1996-03-22
    • Norbert GuntherbergJurgen HofmannHilmar OhligElmar MailahnKlaus BusBernhard CzaudernaSven Grabowski
    • Norbert GuntherbergJurgen HofmannHilmar OhligElmar MailahnKlaus BusBernhard CzaudernaSven Grabowski
    • B29B7/88B29B7/48B29B7/58B29C47/40B29C47/76C08G85/00C08J3/20C08J3/205C08L25/04C08L27/06C08L33/04C08L33/12C08L33/18C08L33/20C08L51/00C08L51/04C08L55/02C08L101/00
    • B29C47/767B29C47/40B29C47/6031B29C47/6056B29C47/62B29C47/64B29C47/76C08J3/205C08L51/04C08L55/02B29C47/0011B29C47/0019B29C47/0023B29C47/762
    • Toughened thermoplastics are prepared by mechanically dewatering a water-moist elastomer component A containing up to 60% by weight of residual water and mixing the resulting dewatered elastomer component A' with a thermoplastic polymer B in an extruder, by a process in which the elastomer component A is fed to a twin-screw extruder which has corotating, in each case double-flight, screws and essentially includes, in the transport direction,a metering section in which the elastomer component A is fed to the extruder by a metering means,at least one squeeze section which serves for dewatering and contains at least one retarding element and in each case at least one associated dewatering orifice,at least one section provided with a conveying screw or at least one section provided with mixing, kneading or other plasticating elements or combinations of these elements,at least one section in which the thermoplastic polymer B is introduced as a melt into the extruder,at least one section provided with mixing, kneading or other plasticating elements or combinations of these elements,at least one devolatilization section which is provided with at least one devolatilization orifice and in which the residual water is removed as steam, anda discharge zone,the water emerging from the dewatering orifices being present partially or completely in the liquid phase, and the extruder being operated at a screw speed of from 50 to 600 min.sup.-1 and average shear rates of from 20 to 240 s.sup.-1.
    • 通过机械脱水含有高达60重量%的残余水的水分弹性体组分A并将所得脱水的弹性体组分A'与热塑性聚合物B混合在挤出机中,通过以下方法制备增韧的热塑性塑料,其中弹性体组分 A被输送到双螺杆挤出机,双螺杆挤出机在每个情况下都具有旋转螺旋,并且在输送方向上基本上包括计量部分,其中弹性体组分A通过计量装置进料到挤出机, 至少一个挤压部分,其用于脱水并且包含至少一个延迟元件,并且在每种情况下包括至少一个相关联的脱水孔,设置有输送螺杆的至少一个部分或设置有混合,捏合或其它塑化元件的至少一个部分, 这些元件的组合,将热塑性聚合物B作为熔体引入挤出机中的至少一个部分,至少一个部分 n具有混合,捏合或其它塑化元件或这些元素的组合,至少一个脱挥发段,其设置有至少一个脱挥发分孔,残留水作为蒸汽除去,以及排出区,从 脱水孔部分或完全在液相中存在,挤出机以50至600分钟-1的螺杆速度和20至240s -1的平均剪切速率操作。
    • 7. 发明授权
    • Preparation of thermoplastics
    • 热塑性塑料的制备
    • US5852113A
    • 1998-12-22
    • US620309
    • 1996-03-22
    • Norbert GuntherbergJurgen HofmannElmar MailahnHilmar OhligSven GrabowskiBernhard CzaudernaKlaus Bus
    • Norbert GuntherbergJurgen HofmannElmar MailahnHilmar OhligSven GrabowskiBernhard CzaudernaKlaus Bus
    • B29B7/48B29B7/58B29B7/88B29B13/06B29C47/76C08J3/20C08L9/00C08L21/00C08L25/04C08L27/06C08L33/04C08L33/12C08L51/00C08L51/04C08G63/48
    • B29C47/76B29B13/06C08L51/04B29C47/0011B29C47/0019B29C47/0023B29C47/003B29C47/762B29K2055/02B29K2096/02
    • Toughened thermoplastics are prepared by mixing a water-moist elastomer component A containing up to 60% by weight of residual water with a thermoplastic polymer B and further polymers C and additives D in an extruder with mechanical dewatering of the elastomer component A, by a process in which the components A, B, C and D are fed to a twin-screw extruder which has corotating screws and essentially comprises, in the transport direction, at least one metering section in which the elastomer component A is fed to the extruder by a metering means, at least one squeeze section which serves for dewatering the component A and contains at least one retarding element and in each case at least one associated dewatering orifice, at least one section in which the thermoplastic polymer B is introduced as a melt into the extruder, at least one section provided with mixing, kneading or other plasticating elements or combinations of these elements, at least one devolatilization section which is provided with at least one devolatilization orifice and in which the residual water is removed as steam, and a discharge zone, the water emerging from the dewatering orifices being present partially or completely in the liquid phase, and the components C or D or mixtures thereof, together or separately from one another, being fed to one or more of the stated extruder sections, either together with the component A or B or mixtures thereof or separately from A and B.
    • 增韧的热塑性塑料通过将包含高达60重量%的残余水的水分润湿性组分A与热塑性聚合物B混合,并且在挤出机中将另外的聚合物C和添加剂D混合在一起,通过一种方法将该弹性体组分A机械脱水 其中将组分A,B,C和D进料到具有同向旋转螺杆的双螺杆挤出机中,并且在输送方向上基本上包括至少一个计量段,其中弹性体组分A通过 计量装置,至少一个挤压部分,其用于对部件A进行脱水并且包含至少一个延迟元件,并且在每种情况下包含至少一个相关联的脱水孔,至少一个部分,其中热塑性聚合物B作为熔体引入其中 挤出机,至少一个具有混合,捏合或其它塑化元件或这些元件的组合的部分,至少一个脱挥发段 与至少一个脱挥发孔一起使用,其中残留的水作为蒸汽除去,以及排出区,从脱水孔中排出的水部分或完全存在于液相中,以及组分C或D或其混合物, 一起或彼此分开地,被供给到一个或多个所述的挤出机部分,与组分A或B一起或其混合物或与A和B分开。
    • 8. 发明授权
    • Preparation of thermoplastics
    • 热塑性塑料的制备
    • US5851463A
    • 1998-12-22
    • US620259
    • 1996-03-22
    • Norbert GuntherbergJurgen HofmannElmar MailahnHilmar Ohlig
    • Norbert GuntherbergJurgen HofmannElmar MailahnHilmar Ohlig
    • C08J3/20B29B7/48B29B7/58B29C47/76C08L25/04C08L27/06C08L33/04C08L33/12C08L51/00C08L55/02B29C47/40
    • B29C47/76C08L55/02B29C47/0011B29C47/0019B29C47/0023B29C47/003B29C47/762
    • Toughened thermoplastics are prepared by mechanically dewatering a water-moist elastomer component A containing up to 50% by weight of residual water and mixing the resulting dewatered elastomer component A' with a thermoplastic polymer B in a mixing unit, by a process in which the elastomer component A is fed to a twin-screw extruder which has corotating, in each case triple-flight, screws and essentially includes, in the transport direction, one unheated metering section in which the elastomer component A is fed to the extruder by a metering means, at least one squeeze section which serves for dewatering and contains at least one retarding element and in each case at least one associated dewatering orifice, at least one section in which the thermoplastic polymer B is introduced as a melt into the extruder, at least one section provided with mixing, kneading or other plasticating elements or combinations of these elements, at least one devolatilization section which is provided with at least one devolatilization orifice and in which the residual water is removed as steam, and unheated discharge zone, and in which the water emerging from the dewatering orifices is present partially or completely in the liquid phase.
    • 增韧的热塑性塑料通过机械脱水含有高达50重量%的残余水的水分弹性体组分A,并将所得脱水的弹性体组分A'与热塑性聚合物B混合在混合单元中,通过其中弹性体 组分A被输送到双螺杆挤出机,该双螺杆挤出机在每种情况下都具有共旋转的螺旋,并且在输送方向上基本上包括一个未加热的计量部分,其中弹性体组分A通过计量装置 至少一个挤压部分,其用于脱水并且包含至少一个延迟元件,并且在每种情况下包含至少一个相关联的脱水孔,至少一个部分,其中热塑性聚合物B作为熔体引入挤出机中,至少一个 其具有混合,捏合或其它塑化元件或这些元素的组合,至少一个脱挥发段,其设置有 至少一个脱挥发孔,其中残余水作为蒸汽和未加热排放区除去,其中从脱水孔出来的水部分地或完全地存在于液相中。
    • 9. 发明授权
    • Imidation of polymers based on esters of methacrylic acid and acrylic
acid
    • 基于甲基丙烯酸和丙烯酸酯的聚合物的酰亚胺化
    • US06077911A
    • 2000-06-20
    • US97117
    • 1993-07-27
    • Siegmund BeseckeAndreas DeckersJuergen HofmannHarald KroegerHilmar Ohlig
    • Siegmund BeseckeAndreas DeckersJuergen HofmannHarald KroegerHilmar Ohlig
    • C08F8/32C08F8/48C08F8/30
    • C08F8/48C08F2800/20
    • Polymers essentially comprising units of the formula I ##STR1## in which R.sup.1 and R.sup.2 are hydrogen or methyl andR.sup.3 is hydrogen, C.sub.1 -C.sub.18 -alkyl, C.sub.5 -C.sub.12 -cycloalkyl, C.sub.6 -C.sub.10 -aryl or C.sub.6 -C.sub.10 -aryl-C.sub.1 -C.sub.4 -alkyl, it being possible for these radicals, with the exception of the C.sub.1 -C.sub.18 -alkyl radicals, to be up to trisubstituted by radicals selected from the group consisting of C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy and halogen, are prepared by reacting a polymer based on C.sub.1 -C.sub.20 -alkyl esters of acrylic acid, methacrylic acid or mixtures thereof with ammonia or a primary amine in an extruder, by mixing the ammonia or the primary amine by mixing intensively with a melt of the polymer to be reacted, at at most 250.degree. C., before the imidation is carried out, and are used for producing thermoplastic moldings, films or fibers.
    • 聚合物基本上包含式I的单元,其中R 1和R 2是氢或甲基,R 3是氢,C 1 -C 18烷基,C 5 -C 12环烷基,C 6 -C 10 - 芳基或C 6 -C 10 - 芳基-C 1 -C 4 - 烷基,除了C 1 -C 18烷基之外,这些基团可以被选自C1-C4-烷基,C1-C4-烷氧基和卤素的基团三取代, 通过在挤出机中使基于丙烯酸,甲基丙烯酸或其混合物的C1-C20烷基酯的聚合物与氨或伯胺反应,通过将聚合物的熔体与聚合物的熔体密集混合而将氨或伯胺混合为 在进行酰亚胺化之前,至多250℃下反应,并用于生产热塑性模制品,薄膜或纤维。