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1. 发明授权

US08506298B2 Dental filling/restoration kit 有权
标题翻译：牙科填充/恢复套件
公开(公告)号：US08506298B2
公开(公告)日：2013-08-13
申请号：US12602921
申请日：2008-06-05
申请人： Takeshi Suzuki , Hideki Kazama
发明人： Takeshi Suzuki , Hideki Kazama
IPC分类号： A61C5/04 , A61C5/00
CPC分类号： A61K6/083 , C08L33/00 , C08L43/02
摘要： Provided is a dental filling/restoration kit, in which a pretreatment material and a filling/restoring material can be cured by only one irradiation with light, which enables further improved adhesion between a tooth and the filling/restoring material, which prevents the filling/restoring material from being easily colored, to thereby exhibit its excellent sensuousness. Specifically provided is a dental filling/restoration kit which includes: a filling/restoring material (A) containing 100 parts by mass of a radical-polymerizable monomer (a) containing 3 to 30 parts by mass of a water-soluble radical-polymerizable monomer having no acidic group (a1), a photopolymerization initiator (b), and a filler (c), the filler (c) being contained in an amount of 80 to 2,000 parts by mass relative to 100 parts by mass of the radical-polymerizable monomer (a); and a pretreatment material (B) containing a radical-polymerizable monomer having an acidic group (d) and water (e).
摘要翻译：提供了一种牙科填充/恢复套件，其中预处理材料和填充/恢复材料可以仅通过一次光照射而固化，这使得能够进一步改善牙齿和填充/恢复材料之间的粘附性，从而防止填充/ 恢复材料容易着色，从而表现出优异的感觉。具体地提供一种牙科填充/修复试剂盒，其包括：含有100质量份含有3〜30质量份水溶性自由基聚合性单体的自由基聚合性单体（a）的填充恢复材料（A）没有酸性基团（a1），光聚合引发剂（b）和填料（c），填料（c）相对于100质量份的可自由基聚合的组分为80〜2000质量份单体（a）; 和含有具有酸性基团（d）和水（e）的自由基聚合性单体的预处理材料（B）。

2. 发明授权

US06759449B2 Dental adhesive composition 有权
标题翻译：牙科粘合剂组成
公开(公告)号：US06759449B2
公开(公告)日：2004-07-06
申请号：US10181413
申请日：2002-07-23
申请人： Mikio Kimura , Koji Matsushige , Hideki Kazama
发明人： Mikio Kimura , Koji Matsushige , Hideki Kazama
IPC分类号： A61K6083
CPC分类号： C09J4/06 , A61K6/0023 , C09J4/00 , C08F220/26 , C08F265/06 , C08L33/00
摘要： This invention discloses a dental adhesive composition comprising (A) a polymerizable monomer comprising an acidic-group containing polymerizable monomer such as 11-methacryloyloxy-1,1-undecane dicarboxylic acid, (B) a mixed filler of a spherical filler substantially consisting of a non-crosslinking polymethyl methacrylate and a spherical filler substantially consisting of a non-crosslinking polyethyl methacrylate; and (C) a polymerization initiator; and a dental adhesive kit comprising the above dental adhesive composition in combination with a dental primer comprising (D) an acidic-group containing polymerizable monomer, (E) an aryl borate, (F) an organosulfinic acid salt and (G) water. The dental adhesive composition exhibits good operability and improved adhesion performance.
摘要翻译：本发明公开了一种牙科用粘合剂组合物，其包含（A）包含含有酸性基团的可聚合单体如11-甲基丙烯酰氧基-1,1-十一烷二羧酸的可聚合单体，（B）基本上由非交联聚甲基丙烯酸甲酯和基本上由非交联聚甲基丙烯酸乙酯组成的球形填料; 和（C）聚合引发剂; 和含有（D）含酸性基团的可聚合单体，（E）芳基硼酸盐，（F）有机亚磺酸盐和（G）水）的牙科底漆组合的上述牙科粘合剂组合物的牙科粘合剂试剂盒。牙科粘合剂组合物表现出良好的可操作性和改进的粘合性能。

3. 发明授权

US5475074A Polymerizable composition, organic glass and ophthalmic lens 失效
标题翻译：可聚合组合物，有机玻璃和眼科镜片
公开(公告)号：US5475074A
公开(公告)日：1995-12-12
申请号：US187475
申请日：1994-01-28
申请人： Shingo Matsuoka , Hideki Kazama , Tadashi Hara , Tomonori Matsunaga , Hiroshi Suga
发明人： Shingo Matsuoka , Hideki Kazama , Tadashi Hara , Tomonori Matsunaga , Hiroshi Suga
IPC分类号： C08F212/34 , G02B1/04 , C08F236/20
CPC分类号： G02B1/04 , C08F212/34
摘要： A polymerizable composition containing;(A) 100 parts by weight of a vinylbenzyl compound of the formula (I), ##STR1## wherein each of R.sup.1 and R.sup.2 is independently a halogen atom, each of h and i is independently 0, 1 or 2, each of X.sup.1, X.sup.2 and X.sup.3 is independently an oxygen atom or a sulfur atom, and each of j, k and m is 0 or 1, provided that when k is 0, j is 0, that when m is 0, each of j and k is 0, that when j is 0 and when each of k and m is 1, X.sup.1 and X.sup.2 cannot be sulfur atoms at the same time, and that when each of m, k and j is 1, X.sup.1, X.sup.2 and X.sup.3 cannot be sulfur atoms at the same time,and(B) 0.1 to 20 parts by weight of 2,4-diphenyl-4-methyl-1-pentene.The polymerizable composition can give a molded article which is free from coloring in heat treatment, has sufficient properties as an ophthalmic lens such as a high refractive index, a high Abbe's number and a low specific gravity, is excellent in transparency, light resistance, heat resistance and impact resistance, and is therefore suitable as an organic glass such as an ophthalmic lens and a lens for an optical device.
摘要翻译：一种可聚合组合物，（A）100重量份式（I）的乙烯基苄基化合物，其中R 1和R 2各自独立地为卤素原子，h和i各自独立地为0,1或如图2所示，X1，X2和X3各自独立地为氧原子或硫原子，j，k和m各自为0或1，条件是当k为0时，j为0，当m为0时， j和k为0时，当j为0时，当k和m各自为1时，X1和X2不能同时为硫原子，当m，k和j分别为1时，X1，X2 并且X3不能同时为硫原子，（B）为0.1〜20重量份的2,4-二苯基-4-甲基-1-戊烯。可聚合组合物可以得到在热处理中不着色的模塑制品，作为高折射率，高阿贝数和低比重的眼用透镜具有足够的性能，透明性，耐光性，耐热性优异电阻和抗冲击性，因此适合作为有机玻璃如眼用透镜和用于光学装置的透镜。

4. 发明授权

US08307160B2 Interface apparatus, calculation processing apparatus, interface generation apparatus, and circuit generation apparatus 失效
标题翻译：接口装置，计算处理装置，接口生成装置和电路生成装置
公开(公告)号：US08307160B2
公开(公告)日：2012-11-06
申请号：US12694556
申请日：2010-01-27
申请人： Hideki Kazama
发明人： Hideki Kazama
IPC分类号： G06F12/00
CPC分类号： G06F12/084
摘要： There is provided is an interface apparatus including: a stream converter receiving write-addresses and write-data, storing the received data in a buffer, and sorting the stored write-data in the order of the write-addresses to output the write-data as stream-data; a cache memory storing received stream-data if a load-signal indicates that the stream-data are necessarily loaded and outputting data stored in a storage device corresponding to an input cache-address as cache-data; a controller determining whether or not data allocated with a read-address have already been loaded, outputting the load-signal instructing the loading on the cache memory if not loaded, and outputting a load-address indicating a load-completed-address of the cache memory; and at least one address converter calculating which one of the storage devices the allocated data are stored in, by using the load-address, outputting the calculated value as the cache-address to the cache memory, and outputting the cache-data as read-data.
摘要翻译：提供了一种接口装置，包括：流转换器，其接收写入地址和写入数据，将接收的数据存储在缓冲器中，并且以写入地址的顺序对存储的写入数据进行排序以输出写入数据作为流数据; 如果负载信号指示所述流数据必须被加载并且存储在与输入的高速缓存地址相对应的存储设备中的数据作为高速缓存数据，则存储接收流数据的高速缓冲存储器; 控制器确定分配有读地址的数据是否已经被加载，如果没有加载则输出指示加载到高速缓冲存储器上的负载信号，并输出指示高速缓存的加载完成地址的加载地址记忆; 并且至少一个地址转换器通过使用所述负载地址来计算所分配的数据中的哪一个存储装置，将计算出的值作为高速缓存地址输出到高速缓冲存储器，数据。

5. 发明授权

US07365106B2 Cationically curable composition for dental use 有权
标题翻译：用于牙科用途的阳离子可固化组合物
公开(公告)号：US07365106B2
公开(公告)日：2008-04-29
申请号：US11114086
申请日：2005-04-26
申请人： Takeshi Suzuki , Hideki Kazama
发明人： Takeshi Suzuki , Hideki Kazama
IPC分类号： C08F2/46 , A61K6/08 , A61K6/087 , A61C5/00
CPC分类号： A61K6/087 , C08L63/00 , C08L71/00
摘要： A cationically curable composition for dental use containing a cationic polymerization initiator (I) and cationically polymerizable monomers (II), the cationically polymerizable monomers (II) containing an oxetane compound and an epoxy compound or an alkenyl ether compound at a ratio of amounts that satisfy the conditions expressed by the following formula, (a×A):(b×B)=91:9 to 45:55 wherein A is a mol number of the oxetane compound, “a” is an average number of the oxetane functional group contained in one molecule of the oxetane compound, B is a mol number of the epoxy compound or the alkenyl ether compound, and “b” is an average number of the epoxy functional group contained in one molecule of the epoxy compound or an average number of the alkenyl ether functional group contained in one molecule of the alkenyl ether compound. The composition is not hindered by oxygen from being polymerized, cures quickly even without using a special polymerizable monomer or a particular polymerization initiator, little forms an unpolymerized layer on the surface even when polymerized and cured in a highly humid environment such as in the oral cavity, and is suited as a filling/restorative material for dental use.
摘要翻译：一种含有阳离子聚合引发剂（I）和阳离子可聚合单体（II）的阳离子可固化组合物，含有氧杂环丁烷化合物和环氧化合物或烯基醚化合物的阳离子可聚合单体（II）以满足由以下公式表示的条件<？in-line-formula description =“In-line Formulas”end =“lead”？>（axA）:( bxB）= 91：9至45:55 <？ -formulae description =“In-line Formulas”end =“tail”？>其中A是氧杂环丁烷化合物的摩尔数，“a”是一分子氧杂环丁烷化合物中含有的氧杂环丁烷官能团的平均数，B 是环氧化合物或烯基醚化合物的摩尔数，“b”是一分子环氧化合物中含有的环氧官能团的平均数或1分子中含有的链烯基醚官能团的平均数烯基醚化合物。该组合物不受氧的聚合阻碍，即使不使用特殊的可聚合单体或特定的聚合引发剂也能快速固化，即使在高度潮湿的环境（例如在口腔中）聚合和固化，表面上几乎不形成未聚合的层，并且适合用作牙科使用的填充/修复材料。

6. 发明申请

US20050250868A1 Cationically curable composition for dental use 有权
标题翻译：用于牙科用途的阳离子可固化组合物
公开(公告)号：US20050250868A1
公开(公告)日：2005-11-10
申请号：US11114086
申请日：2005-04-26
申请人： Takeshi Suzuki , Hideki Kazama
发明人： Takeshi Suzuki , Hideki Kazama
IPC分类号： A61K6/083 , A61K6/087 , C08F2/50 , C08G65/18 , C08G2/00
CPC分类号： A61K6/087 , C08L63/00 , C08L71/00
摘要： A cationically curable composition for dental use containing a cationic polymerization initiator (I) and cationically polymerizable monomers (II), the cationically polymerizable monomers (II) containing an oxetane compound and an epoxy compound or an alkenyl ether compound at a ratio of amounts that satisfy the conditions expressed by the following formula, (a×A):(b×B)=91:9 to 45:55 wherein A is a mol number of the oxetane compound, “a” is an average number of the oxetane functional group contained in one molecule of the oxetane compound, B is a mol number of the epoxy compound or the alkenyl ether compound, and “b” is an average number of the epoxy functional group contained in one molecule of the epoxy compound or an average number of the alkenyl ether functional group contained in one molecule of the alkenyl ether compound. The composition is not hindered by oxygen from being polymerized, cures quickly even without using a special polymerizable monomer or a particular polymerization initiator, little forms an unpolymerized layer on the surface even when polymerized and cured in a highly humid environment such as in the oral cavity, and is suited as a filling/restorative material for dental use.
摘要翻译：一种含有阳离子聚合引发剂（I）和阳离子可聚合单体（II）的阳离子可固化组合物，含有氧杂环丁烷化合物和环氧化合物或烯基醚化合物的阳离子可聚合单体（II）以满足由以下公式表示的条件<？in-line-formula description =“In-line Formulas”end =“lead”？>（axA）:( bxB）= 91：9至45:55 <？ -formulae description =“In-line Formulas”end =“tail”？>其中A是氧杂环丁烷化合物的摩尔数，“a”是一分子氧杂环丁烷化合物中含有的氧杂环丁烷官能团的平均数，B 是环氧化合物或烯基醚化合物的摩尔数，“b”是一分子环氧化合物中所含的环氧官能团的平均数或1分子中含有的链烯基醚官能团的平均数烯基醚化合物。该组合物不受氧的聚合阻碍，即使不使用特殊的可聚合单体或特定的聚合引发剂也能快速固化，即使在高度潮湿的环境（例如在口腔中）聚合和固化，表面上几乎不形成未聚合的层，并且适合用作牙科使用的填充/修复材料。

7. 发明授权

US06815470B2 Dental catalyst for chemical polymerization and use thereof 有权
标题翻译：用于化学聚合的牙科催化剂及其用途
公开(公告)号：US06815470B2
公开(公告)日：2004-11-09
申请号：US10610704
申请日：2003-07-02
申请人： Kazuya Ibaragi , Hideki Kazama , Makoto Oguri
发明人： Kazuya Ibaragi , Hideki Kazama , Makoto Oguri
IPC分类号： A61K6083
CPC分类号： A61K6/083 , A61K6/0023 , C08L33/00
摘要： A dental catalyst for chemical polymerization comprising an acidic compound, an organic peroxide such as cumene hydroperoxide, and aryl borate compound such as sodium tetraphenylborate, but without substantially containing amine compound. This catalyst is chemically highly stable, is easy to handle, is highly active, is less likely to be impaired by polymerization, and does not cause the cured product to be tinted or discolored, and is very useful for the dental restorative.

8. 发明授权

US06660784B2 Dental catalyst for chemical polymerization and use thereof 有权
公开(公告)号：US06660784B2
公开(公告)日：2003-12-09
申请号：US09957025
申请日：2001-09-21
申请人： Kazuya Ibaragi , Hideki Kazama , Makoto Oguri
发明人： Kazuya Ibaragi , Hideki Kazama , Makoto Oguri
IPC分类号： A61K6083
CPC分类号： A61K6/083 , A61K6/0023 , C08L33/00
摘要： A dental catalyst for chemical polymerization comprising an acidic compound, an organic peroxide such as cumene hydroperoxide, and aryl borate compound such as sodium tetraphenylborate, but without substantially containing amine compound. This catalyst is chemically highly stable, is easy to handle, is highly active, is less likely to be impaired by polymerization, and does not cause the cured product to be tinted or discolored, and is very useful for the dental restorative.

9. 发明授权

US5744511A Visible ray polymerization initiator and visible ray polymerizable composition 失效
标题翻译：可见光聚合引发剂和可见光可聚合组合物
公开(公告)号：US5744511A
公开(公告)日：1998-04-28
申请号：US634259
申请日：1996-04-18
申请人： Hideki Kazama , Takeshi Satoh , Makoto Oguri
发明人： Hideki Kazama , Takeshi Satoh , Makoto Oguri
IPC分类号： C08F2/50 , C09J4/02 , G03F7/029 , C08K3/20 , C08K3/36
CPC分类号： G03F7/029 , Y10S522/908
摘要： A visible-ray polymerizable composition comprising: (1) a monomer comprising a (meth)acrylate monomer; and (2) a visible-ray polymerization initiator comprising: (A) a coumarin dye; (B) at least one photo acid generator selected from the group consisting of a halo-alkyl substituted s-triazine derivative and a diphenyliodonium salt compound; and (C) an aryl borate compound.
摘要翻译：一种可见光可聚合组合物，其包含：（1）包含（甲基）丙烯酸酯单体的单体; 和（2）可见光聚合引发剂，其包含：（A）香豆素染料; （B）选自卤代烷基取代的s-三嗪衍生物和二苯基碘鎓盐化合物的至少一种光酸反应产物; 和（C）芳基硼酸盐化合物。

10. 发明授权

US08796354B2 Dental adhesive composition 有权
标题翻译：牙科粘合剂组成
公开(公告)号：US08796354B2
公开(公告)日：2014-08-05
申请号：US12999464
申请日：2009-07-22
申请人： Hidetoshi Gyakushi , Takeshi Suzuki , Mihoko Kajikawa , Hideki Kazama
发明人： Hidetoshi Gyakushi , Takeshi Suzuki , Mihoko Kajikawa , Hideki Kazama
IPC分类号： C08L43/02
CPC分类号： A61K6/0023 , C08L43/02
摘要： [Problems] A dental adhesive composition containing an acid group-containing polymerizable monomer, that can be used as a dental adhesive material or a primer. The dental adhesive composition has excellent durability of adhesion exhibiting further improved adhering strength and durability of adhesion enabling teeth to be more strongly adhered to a composite resin or a prosthetic over extended periods of time.[Means for Solution] The dental adhesive composition contains a polymerizable monomer and ions of an element of the Group IV as basic components, at least 10 mass % of the polymerizable monomer being a polymerizable monomer having a hydrogenphosphate diester group, such as bis(2-methacryloyloxyethyl)hydrogenphosphate or 2-methacryloyloxyethylphenyl hydrogenphosphate, and the content of ions of the element of the Group IV such as titanium ions or zirconium ions in the composition being 0.1 to 1.0 in terms of mole ratio to the hydrogenphosphate diester groups of the polymerizable monomer that has the hydrogenphosphate diester group.
摘要翻译： [问题]含有含酸基的可聚合单体的牙科粘合剂组合物，其可以用作牙科粘合剂材料或底漆。牙科粘合剂组合物具有优异的粘合耐久性，其显示出进一步改善的粘合强度和粘合的耐久性，使得齿能够在长时间内更加牢固地粘附到复合树脂或假体上。 [解决方案]牙科用粘合剂组合物含有聚合性单体和IV族元素作为碱性成分的离子，至少10质量％的可聚合单体是具有磷酸二酯基的可聚合单体，例如双（2 - 甲基丙烯酰氧基乙基）磷酸氢盐或2-甲基丙烯酰氧基乙基苯基磷酸氢盐，组合物中IV族元素如钛离子或锆离子的离子含量与可聚合单体的磷酸氢二酯基的摩尔比为0.1至1.0 具有磷酸氢二酯组。

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