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1. 发明授权

US06534568B1 Powder coating or adhesives employing silanes or silane treated fillers 失效
标题翻译：使用硅烷或硅烷处理填料的粉末涂料或粘合剂
公开(公告)号：US06534568B1
公开(公告)日：2003-03-18
申请号：US09446609
申请日：2000-04-19
申请人： Lawrence E. Katz , Herbert E. Petty , Shiu-Chin Huang Su , Bruce A. Waldman , Bruce C. Barbera
发明人： Lawrence E. Katz , Herbert E. Petty , Shiu-Chin Huang Su , Bruce A. Waldman , Bruce C. Barbera
IPC分类号： C08K906
CPC分类号： C08K5/54 , C08G18/289 , C08G18/3206 , C08G18/3225 , C08G18/718 , C08G2150/20 , Y10S524/904
摘要： Powder coating or adhesive formulations include as a component thereof a silane of formula (I) or hydrolyzates or condensates thereof where R1 is a hydrocarbon, acyl, alkylsilyl, or alkoxysilyl group, R2 is a monovalent hydrocarbon group; R3 is alkylene, optionally interrupted with one or more ether oxygen atoms; a is 0 or 1; Z is a direct bond or a divalent linking group; X is an m-valent organic group or H; and m is 1-20. The silanes are useful as crosslinkers, property modifiers and/or adhesion promoters. Powder adhesives may be similarly formed with the silanes of formula (I). Fillers or pigments, such as titanium dioxide fillers, which are treated with silanes, especially silanes having alkyl, epoxy, acryl, methacryl, polyether, amino, acid anhydride, hydroxyalkyl, carbamato or ureido functionality, may also be usefully employed in powder coating formulations.
摘要翻译：粉末涂料或粘合剂制剂包括作为其组分的式（I）的硅烷或其水解产物或缩合物，其中R 1是烃，酰基，烷基甲硅烷基或烷氧基甲硅烷基，R 2是单价烃基; R3是亚烷基，任选地被一个或多个醚氧原子间隔; a是0或1; Z是直接键或二价连接基团; X是m价有机基团或H; m为1-20。硅烷可用作交联剂，特性改性剂和/或粘合促进剂。粉末粘合剂可以类似地与式（I）的硅烷形成。用硅烷处理的填料或颜料，例如二氧化钛填料，特别是具有烷基，环氧基，丙烯基，甲基丙烯酰基，聚醚，氨基，酸酐，羟基烷基，氨基甲酰基或脲基官能团的硅烷也可用于粉末涂料配方。

2. 发明授权

US4927898A Polysiloxanes with sterically hindered heterocyclic moiety 失效
标题翻译：具有空间位阻杂环部分的聚硅氧烷
公开(公告)号：US4927898A
公开(公告)日：1990-05-22
申请号：US240505
申请日：1988-09-06
申请人： Roswell; E. King, III , George N. Foster , Herbert E. Petty
发明人： Roswell; E. King, III , George N. Foster , Herbert E. Petty
IPC分类号： C07F7/10 , C07F7/08 , C07F7/18 , C07F7/21 , C08G77/04 , C08G77/26 , C08G77/28 , C08G77/388 , C08K5/544
CPC分类号： C08G77/388 , C07F7/0858 , C07F7/21 , C08G77/045 , C08K5/5442
摘要： A polysiloxane having pendant, sterically-hindered heterocyclic moieties attached to a siloxane chain, and their use in stabilizing synthetic polymer compositions.

3. 发明授权

US4831081A Method for crosslinking reactive polyolefins via a rhodium catalyzed hydrosilation reaction using polyorganosiloxane crosslinkers 失效
标题翻译：使用聚有机硅氧烷交联剂通过铑催化硅氢化反应交联反应性聚烯烃的方法
公开(公告)号：US4831081A
公开(公告)日：1989-05-16
申请号：US102910
申请日：1987-09-30
申请人： Roswell E. King, III , Herbert E. Petty
发明人： Roswell E. King, III , Herbert E. Petty
IPC分类号： C08K5/5419 , C08L23/02 , C08L43/04
CPC分类号： C08L43/04 , C08K5/5419 , C08L23/02
摘要： The present invention is directed to a method for crosslinking reactive polyolefins using a rhodium catalyzed hydrosilation reaction and novel siloxanes as crosslinkers.Also disclosed are novel siloxane compounds which are useful in the crosslinking of polyolefins and polyolefin compositions which have been crosslinked through use of the claimed process and siloxane crosslinkers.

4. 发明授权

US06395856B1 Silicone oligomers and curable compositions containing same 有权
标题翻译：硅氧烷低聚物和含有它们的可固化组合物
公开(公告)号：US06395856B1
公开(公告)日：2002-05-28
申请号：US09445080
申请日：1999-12-02
申请人： Herbert E. Petty , Robert Pickwell , Frederick D. Osterholtz , Shiu-Chin Huang Su
发明人： Herbert E. Petty , Robert Pickwell , Frederick D. Osterholtz , Shiu-Chin Huang Su
IPC分类号： C08G7708
CPC分类号： C08G77/485 , C08F290/148 , C08G77/045 , C08G77/12 , C08G77/18 , C08G77/20 , C08G77/442 , C08K5/5425 , C09D183/10 , C08L23/16 , C08L83/10 , C08L83/00
摘要： Oligomers of the formula: [R3SiO1/2]m[O1/2Si(R2)O1/2]n[SiO3/2R]o[SiO4/2]p (I) wherein each R is selected individually from the group consisting of B, R1, —OR2, R3 and R4; B is an organosilyl functional group bridged to the Si atom of the siloxane oligomer backbone by an Si—C bond; each R1 is independently a saturated aliphatic hydrocarbon group of 1 to 16 carbon atoms; each R2 is independently a group as defined for R1, an aromatic hydrocarbon group or an acyl group; each R3 is independently a monovalent organic radical containing an aliphatically unsaturated hydrocarbon group and each R4 is a monovalent organic radical linked to the Si atom of the siloxane oligomer backbone by an Si—C bond, which does not include an aliphatically unsaturated hydrocarbon group and which has thereon one or more members of the group selected from aromatic hydrocarbon, ether, ester, carbamate, thioether, polysulfide, blocked mercaptan, amide, epoxy, cyano and oximato groups; and with the provisos that at least one quarter of all R groups are —OR2; either at least one silicon atom of the oligomer has an R3 group thereon or at least one R is a B, or both; if there is a group R3 which is a vinyl group, there is at least one other group which is a B group, an R3 group other than vinyl, or an R4 group; m=2 to 20; n=0 to 50; o=0 to 20; and p=0 to 10, are useful as coupling agents in curable compositions of filled organic polymers used for wire and cable insulation. The oligomers also have utility as crosslinkers, as adhesion promoters, to provide a dual radical/moisture cure mechanism, and/or to provide moisture resistance in coating, in other compositions, such as curable adhesives and coatings.
摘要翻译：下式的低聚物：其中R独立地选自B，R 1，-OR 2，R 3和R 4; B是通过Si-C键桥接到硅氧烷低聚物主链的Si原子上的有机甲硅烷基官能团; 每个R 1独立地为1至16个碳原子的饱和脂族烃基; 每个R 2独立地是如R1所定义的基团，芳族烃基或酰基; 每个R 3独立地是含有脂族不饱和烃基的一价有机基团，并且每个R 4是通过不包含脂族不饱和烃基的Si-C键与硅氧烷低聚物主链的Si原子连接的一价有机基团，具有一个或多个选自芳族烃，醚，酯，氨基甲酸酯，硫醚，多硫化物，封端的硫醇，酰胺，环氧基，氰基和肟基的基团的成员; 并且条件是所有R组中至少四分之一为-OR2; 低聚物的至少一个硅原子在其上具有R 3基团或至少一个R是B或两者; 如果存在作为乙烯基的基团R 3，则至少另外一个为B基团，除乙烯基以外的R 3基团或R 4基团的基团; m = 2〜20; n = 0〜50; o = 0〜20; 和p = 0至10，可用作用于电线和电缆绝缘的填充有机聚合物的可固化组合物中的偶联剂。低聚物在其它组合物如可固化粘合剂和涂料中也可用作交联剂，作为粘合促进剂，以提供双重自由基/湿度固化机理和/或提供涂层中的耐湿性。

5. 发明授权

US4895885A Polymer compositions stabilized with polysiloxanes containing sterically hindered heterocyclic moiety 失效
标题翻译：用含空间位阻杂环部分的聚硅氧烷稳定的聚合物组合物
公开(公告)号：US4895885A
公开(公告)日：1990-01-23
申请号：US240739
申请日：1988-09-06
申请人： George N. Foster , Herbert E. Petty , Roswell E. King, III
发明人： George N. Foster , Herbert E. Petty , Roswell E. King, III
IPC分类号： C08L23/00 , C08G77/388 , C08K5/3435 , C08K5/5419 , C08K5/544 , C08L23/02 , C08L87/00
CPC分类号： C08K5/3435 , C08G77/388 , C08K5/5442 , C08L23/02
摘要： The present invention relates to olefin polymers stabilized with polysiloxanes containing sterically hindered heterocyclic moieties, said polysiloxanes represented by the general formula M*.sub.v D.sub.x D*.sub.y T.sub.z Q.sub.w M*.sub.v.

6. 发明授权

US4526996A Process for the preparation of N-substituted aminoalkylsilanes 失效
标题翻译：制备N-取代氨基烷基硅烷的方法
公开(公告)号：US4526996A
公开(公告)日：1985-07-02
申请号：US622176
申请日：1984-06-19
申请人： John A. Kilgour , Herbert E. Petty
发明人： John A. Kilgour , Herbert E. Petty
IPC分类号： C07F7/10 , B01J23/00 , B01J23/40 , C07B61/00 , C07F7/18
CPC分类号： C07F7/1892
摘要： N-substituted aminoalkylsilanes are obtained via a selective process which comprises reacting a cyanoalkylsilane with a primary or secondary amine in the presence of a heterogeneous hydrogenation catalyst selected from the group consisting of rhodium, platinum and palladium.
摘要翻译：通过选择性方法获得N-取代的氨基烷基硅烷，其包括在选自铑，铂和钯的多相氢化催化剂的存在下使氰基烷基硅烷与伯胺或仲胺反应。

7. 发明授权

US4217294A Method for producing mercaptan-containing organosilicon compounds 失效
标题翻译：制备含硫醇的有机硅化合物的方法
公开(公告)号：US4217294A
公开(公告)日：1980-08-12
申请号：US25658
申请日：1979-03-30
申请人： Herbert E. Petty
发明人： Herbert E. Petty
IPC分类号： C07F7/18 , C07F7/10
CPC分类号： C07F7/1836 , C07F7/1892
摘要： A two-stage process for producing gamma-mercaptopropyltrialkoxysilane which comprises reacting beta-cyanoethyltrialkoxysilane with hydrogen sulfide in the presence of an amide to form a novel gamma-trialkoxysilylthiopropionamide intermediate followed by reducing said intermediate with hydrogen in the presence of a transition metal polysulfide.
摘要翻译：制备γ-巯基丙基三烷氧基硅烷的两阶段方法，其包括在酰胺存在下使β-氰基乙基三烷氧基硅烷与硫化氢反应形成新的γ-三烷氧基甲硅烷基硫代丙酰胺中间体，然后在过渡金属多硫化物的存在下用氢还原所述中间体。

8. 发明授权

US06455158B1 Treatment of minerals with alkylsilanes and alkylsilane copolymers 有权
标题翻译：用烷基硅烷和烷基硅烷共聚物处理矿物
公开(公告)号：US06455158B1
公开(公告)日：2002-09-24
申请号：US09596113
申请日：2000-06-16
申请人： Henry L. Mei , Louis M. Panzer , Herbert E. Petty , Philbert E. Ramdatt , Robert E. Christie , Juan Alfonso
发明人： Henry L. Mei , Louis M. Panzer , Herbert E. Petty , Philbert E. Ramdatt , Robert E. Christie , Juan Alfonso
IPC分类号： B32B1502
CPC分类号： C08K9/06 , Y10T428/2991 , Y10T428/2993 , Y10T428/2995 , Y10T428/2998
摘要： The present invention relates to the silanization or surface treatment of minerals with alkylsilanes and alkylsilane copolymers. More specifically, the present invention relates to alkylsilane copolymers useful for surface treating pigments or fillers. The alkylsilane copolymers comprise at least two different monomers. The copolymers find particular utility for the surface treatment of white pigments, such as titanium dioxide, for improving the dispersibility and processibility of the pigments when compounded with a polymeric material, in particular, when compounded with polyolefins.
摘要翻译：本发明涉及具有烷基硅烷和烷基硅烷共聚物的矿物的硅烷化或表面处理。更具体地，本发明涉及可用于表面处理颜料或填料的烷基硅烷共聚物。烷基硅烷共聚物包含至少两种不同的单体。共聚物特别适用于白色颜料（如二氧化钛）的表面处理，用于提高与聚合物材料混合时颜料的分散性和加工性，特别是当与聚烯烃配合时。

9. 发明授权

US06258914B1 Silane functional oligomer 有权
标题翻译：硅烷官能低聚物
公开(公告)号：US06258914B1
公开(公告)日：2001-07-10
申请号：US09418658
申请日：1999-10-15
申请人： Shiu-Chin Huang Su , Herbert E. Petty , Fredrick D. Osterholtz
发明人： Shiu-Chin Huang Su , Herbert E. Petty , Fredrick D. Osterholtz
IPC分类号： C08G7768
CPC分类号： C08G77/485 , C08F290/148 , C08G77/045 , C08G77/12 , C08G77/18 , C08G77/20 , C08G77/442 , C08K5/5425 , C09D183/10 , C08L23/16 , C08L83/10 , C08L83/00
摘要： Alkoxy silane oligomers which have a non-hydrolyzable carbon bridged bond to another silane functionality are taught herein, as well as their manufacture and utility.
摘要翻译：本文教导了具有与其它硅烷官能团不可水解的碳桥连键的烷氧基硅烷低聚物及其制造和实用性。

10. 发明授权

US06191286B1 Imidosilane compositions 有权
标题翻译：二嵌段硅烷组合物
公开(公告)号：US06191286B1
公开(公告)日：2001-02-20
申请号：US09140473
申请日：1998-08-26
申请人： Michael L. Gunther , Eric R. Pohl , Herbert E. Petty
发明人： Michael L. Gunther , Eric R. Pohl , Herbert E. Petty
IPC分类号： C07D207444
CPC分类号： C08K5/544 , C07F7/1804 , C08K5/5442
摘要： Unsaturated imidosilanes which are essentially free of siloxanes are taught herein for use surface treatments for inorganic solid materials. Novel methods to make such silanes, which do not yield water or siloxanes as a by-product are also taught. Compositions consisting essentially of imidosilane treated inorganic solid materials, resinuous materials and optionally a free radical generator, especially glass fiber reinforced composites, are taught.
摘要翻译：本文教导了基本上不含硅氧烷的不饱和酰亚胺硅烷，用于无机固体材料的表面处理。还教导了不产生水或硅氧烷作为副产物的这种硅烷的新方法。教导了基本上由酰亚胺硅烷处理的无机固体材料，树脂材料和任选的自由基发生剂，特别是玻璃纤维增强复合材料组成的组合物。

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