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1. 发明申请

US20100282591A1 Removal of Hydrocarbons from an Aqueous Stream 有权
标题翻译：从水流中去除碳氢化合物
公开(公告)号：US20100282591A1
公开(公告)日：2010-11-11
申请号：US12808368
申请日：2008-12-22
申请人： Henrik Andtsjo , Maarit Aarni-Sirvio
发明人： Henrik Andtsjo , Maarit Aarni-Sirvio
IPC分类号： C02F1/04 , C02F1/26
CPC分类号： C07C37/72 , B01D3/143 , B01D17/0211 , B01D17/0214 , B01D17/047 , C02F1/04 , C02F1/26 , C02F2101/32 , C02F2101/345 , C02F2209/06 , C07C37/685 , C07C37/74 , C07C39/04
摘要： The present application concerns a process for the removal of hydrocarbons from an aqueous stream, which process may include conducting a phenol-containing water stream into a separation column, separating the phenol-containing water in the column using heat to form an overhead portion and a bottoms portion, and collecting the overhead portion as well as the bottoms portion. Further, the process may include adding an eluent to an aqueous stream, thereby forming an aqueous mixture, subsequently conducting the aqueous mixture into a separation vessel, wherein it is allowed to settle into two phases, which form a hydrocarbon stream and a phenol-containing water stream, subsequently collecting the hydrocarbon stream, and conducting the phenol-containing water stream to the separation column for further separation.
摘要翻译：本申请涉及从水流中除去烃的方法，该方法可以包括将含苯酚的水流导入分离塔，使用热分离柱中的含苯酚的水以形成塔顶馏分和底部部分，以及收集顶部部分以及底部部分。此外，该方法可以包括向含水物流中加入洗脱液，从而形成水性混合物，随后将含水混合物导入分离容器中，其中将其沉降为两相，其形成烃流和含苯酚的水流，随后收集烃流，并将含苯酚的水流导入分离塔进行进一步分离。

2. 发明授权

US5326835A Multi-stage process for producing polyethylene 失效
标题翻译：生产聚乙烯的多阶段工艺
公开(公告)号：US5326835A
公开(公告)日：1994-07-05
申请号：US920569
申请日：1992-08-20
申请人： Antero Ahvenainen , Kari Sarantila , Henrik Andtsjo , Jouni Takakarhu , Ari Palmroos
发明人： Antero Ahvenainen , Kari Sarantila , Henrik Andtsjo , Jouni Takakarhu , Ari Palmroos
IPC分类号： C08F2/00 , B01J8/24 , B01J19/24 , C08F2/06 , C08F2/34 , C08F10/00 , C08F10/02 , C08F110/02 , C08F297/08 , C08L23/08
CPC分类号： C08F297/083 , B01J19/2435 , B01J8/24 , C08F110/02 , Y02P20/544 , Y10S526/905
摘要： The invention concerns a multi-stage process for producing polyethylene having a bimodal and/or broad molecular weight distribution in the presence of an ethylene polymerizing catalyst system in a multistep reaction sequence, in which the first reaction step is a liquid phase polymerization step and the second reaction step is formed by one or more gas-phase polymerization steps. According to the process of the invention in the first reaction step ethylene is polymerized in a loop reactor (10) in an inert low-boiling hydrocarbon medium the residence time being at least 10 minutes, reaction mixture is discharged from the loop reactor (10) and at least a substantial part of the inert hydrocarbon mixture is separated and the polymer is transferred into one or more gas-phase reactors (30), where the polymerization is completed in the presence of ethylene and optionally hydrogen and a comonomer. As an inert hydrocarbon medium in the loop reactor (10) propane can be used and the polymerization can be carried out also so that the mixture of inert hydrocarbon, monomer, hydrogen and optional comonomer is under supercritical conditions.
摘要翻译： PCT No.PCT / FI91 / 00406 Sec。 371日期：1992年8月20日 102（e）日期1992年8月20日PCT 1991年12月20日PCT PCT。出版物WO92 / 12182 日本1992年7月23日。本发明涉及在多步反应序列中在乙烯聚合催化剂体系存在下生产具有双峰和/或宽分子量分布的聚乙烯的多阶段方法，其中第一反应步骤为通过一个或多个气相聚合步骤形成液相聚合步骤和第二反应步骤。根据本发明在第一反应步骤中的方法，乙烯在环状反应器（10）中在惰性低沸点烃介质中聚合，停留时间为至少10分钟，反应混合物从环管反应器（10）排出，并且将至少大部分惰性烃混合物分离并将聚合物转移到一个或多个气相反应器（30）中，其中聚合在乙烯和任选的氢气和共聚单体存在下完成。作为环管反应器（10）中的惰性烃介质，可以使用丙烷，也可以进行聚合，使得惰性烃，单体，氢和任选的共聚单体的混合物处于超临界条件下。

3. 发明申请

US20080045674A1 Process for Producing Polyethylene 有权
标题翻译：生产聚乙烯的方法
公开(公告)号：US20080045674A1
公开(公告)日：2008-02-21
申请号：US10592638
申请日：2005-04-28
申请人： Henrik Andtsjo
发明人： Henrik Andtsjo
IPC分类号： C08F110/02 , B01J19/24 , C08F2/06 , C08F10/02
CPC分类号： C08F10/02 , C08F110/02 , C08F2/14
摘要： Process and apparatus for continuously producing olefin polymers in a slurry phase reactor in a hydrocarbon diluent or liquid monomer. The process comprises continuously withdrawing from the slurry phase reactor a polymer slurry containing polymer and a fluid phase, which contains hydrocarbons and optionally hydrogen, and concentrating the slurry with a self-cleaning screen by removing a part of the fluid phase to provide a concentrated slurry. The openings of the screen, which can have a planar or cylindrical configuration, are smallest at the inflow surface of the screen and increases towards the outflow surface. By the present invention, the need for service and maintenance is significantly reduced.
摘要翻译：在烃稀释剂或液体单体中的淤浆相反应器中连续生产烯烃聚合物的方法和设备。该方法包括连续地从淤浆相反应器中取出含有聚合物的聚合物浆料和含有烃和任选的氢的流体相，并通过除去一部分流体相使自清洁筛网浓缩浆料以提供浓缩浆料。屏幕的开口可以具有平面或圆柱形构造，在屏幕的流入表面处最小，并朝着流出表面增加。通过本发明，显着地减少了对服务和维护的需求。

4. 发明授权

US08758573B2 Removal of hydrocarbons from an aqueous stream 有权
标题翻译：从水流中去除烃
公开(公告)号：US08758573B2
公开(公告)日：2014-06-24
申请号：US12808368
申请日：2008-12-22
申请人： Henrik Andtsjo , Maarit Aarni-Sirvio
发明人： Henrik Andtsjo , Maarit Aarni-Sirvio
IPC分类号： C02F1/04 , B01D3/34 , C07C39/04 , B01D17/02
CPC分类号： C07C37/72 , B01D3/143 , B01D17/0211 , B01D17/0214 , B01D17/047 , C02F1/04 , C02F1/26 , C02F2101/32 , C02F2101/345 , C02F2209/06 , C07C37/685 , C07C37/74 , C07C39/04
摘要： The present application concerns a process for the removal of hydrocarbons from an aqueous stream, which process may include conducting a phenol-containing water stream into a separation column, separating the phenol-containing water in the column using heat to form an overhead portion and a bottoms portion, and collecting the overhead portion as well as the bottoms portion. Further, the process may include adding an eluent to an aqueous stream, thereby forming an aqueous mixture, subsequently conducting the aqueous mixture into a separation vessel, wherein it is allowed to settle into two phases, which form a hydrocarbon stream and a phenol-containing water stream, subsequently collecting the hydrocarbon stream, and conducting the phenol-containing water stream to the separation column for further separation.
摘要翻译：本申请涉及从水流中除去烃的方法，该方法可以包括将含苯酚的水流导入分离塔，使用热分离柱中的含苯酚的水以形成塔顶馏分和底部部分，以及收集顶部部分以及底部部分。此外，该方法可以包括向含水物流中加入洗脱液，从而形成水性混合物，随后将含水混合物导入分离容器中，其中将其沉降为两相，其形成烃流和含苯酚的水流，随后收集烃流，并将含苯酚的水流导入分离塔进行进一步分离。

5. 发明申请

US20060052552A1 Process and apparatus for producing olefin polymers 有权
公开(公告)号：US20060052552A1
公开(公告)日：2006-03-09
申请号：US10532607
申请日：2003-10-27
申请人： Marianna Vuorikari , Esa Korhonen , Henrik Andtsjo , Samuli Zitting
发明人： Marianna Vuorikari , Esa Korhonen , Henrik Andtsjo , Samuli Zitting
IPC分类号： C08F2/00 , B01J19/18 , B01J19/00
CPC分类号： B01J19/2435 , B01J8/0055 , B01J8/20 , B01J8/26 , B01J2219/00006 , B01J2219/0004 , B01J2219/00254 , C08F10/00 , C08F110/02 , C08F210/16 , C08F2/01 , C08F2/001 , C08F2/34 , C08F2/14 , C08F2500/12 , C08F210/08
摘要： The present invention concerns a process and an apparatus for continuous polymerisation of olefin monomers in a cascade of polymerisation reactors. According to the process, an olefin monomer is polymerised first in slurry phase in an inert hydrocarbon diluent in at least one loop reactor and then, subsequently, in gas phase in at least one gas phase reactor. According to the invention, a polymer slurry is continuously withdrawn from the loop reactor and optionally concentrated. The concentrated slurry is conducted to a high pressure flash unit in order to remove the remaining fluid phase, and fed to the gas phase reactor. With the process described in this invention, it is possible to produce bimodal polyethylene with good properties. The operation of the process is stable because of the truly continuous operation.

6. 发明授权

US5616662A Method for polymerizing olefins in a fluid-bed reactor 失效
标题翻译：在流化床反应器中聚合烯烃的方法
公开(公告)号：US5616662A
公开(公告)日：1997-04-01
申请号：US578642
申请日：1996-01-04
申请人： Jukka Koskinen , Henrik Andtsjo , Jouni Takakarhu , Kari Sarantila
发明人： Jukka Koskinen , Henrik Andtsjo , Jouni Takakarhu , Kari Sarantila
IPC分类号： B01F13/02 , B01J8/24 , B01J8/38 , C08F2/34
CPC分类号： B01J8/382 , B01F13/0216 , B01J8/1872 , Y10S526/901
摘要： A fluidized bed polymerization process in which a central mixing element sweeps the interior of the bed. The mixing element contains agitator arm which pass adjacent to the reactor walls and a have a perforated surface. Gas is directed to the central mixing shaft and distributed to the agitator arms.
摘要翻译： PCT No.PCT / FI94 / 00304 Sec。 371日期1996年1月4日 102（e）日期1996年1月4日PCT提交1994年7月1日PCT公布。公开号WO95 / 01831 日期1995年1月19日一种流化床聚合方法，其中中央混合元件扫过床的内部。混合元件包括通过邻近反应器壁的搅拌臂，和a具有穿孔表面。气体被引导到中心混合轴并分配到搅拌器臂。

7. 发明授权

US08916660B2 Method for recovering polymer and apparatus therefor 有权
标题翻译：回收聚合物的方法及其设备
公开(公告)号：US08916660B2
公开(公告)日：2014-12-23
申请号：US14237366
申请日：2012-11-16
申请人： Klaus Nyfors , Jari Aarila , Jari Hatonen , Henrik Andtsjo , Eira Johansson , Mikko Lylykangas
发明人： Klaus Nyfors , Jari Aarila , Jari Hatonen , Henrik Andtsjo , Eira Johansson , Mikko Lylykangas
IPC分类号： C08F2/34 , C08F6/00 , B01J8/00 , B01J8/44 , C08F2/01 , B01J8/18 , C08F10/00 , C08J11/04 , C08F10/02 , C08F10/06
CPC分类号： C08F2/01 , B01J8/003 , B01J8/005 , B01J8/1809 , B01J2208/00548 , B01J2208/0061 , B01J2208/00761 , B01J2219/00247 , B01J2219/00254 , C08F2/34 , C08F10/00 , C08J11/04 , Y10S526/92 , C08F110/06 , C08F2500/12 , C08F210/16 , C08F210/08
摘要： Process and apparatus for recovering polymer from a gas phase reactor having a distribution plate via an outlet vessel comprising at least one apparatus for the breakup of polymeric agglomerates, the apparatus further comprising a feed pipe connecting the gas phase reactor and the outlet vessel a return gas line connecting the gas phase reactor and the outlet vessel, means for varying the flow rate through the return gas line from the outlet vessel to the gas phase reactor, and means for varying the outlet rate of polymer product from the outlet vessel.
摘要翻译：用于从具有分布板的气相反应器中回收聚合物的方法和装置，所述反应器具有经由出口容器的出口容器，所述出口容器包括用于分解聚合物附聚物的至少一种装置，该装置还包括将气相反应器和出口容器连接的回流气体连接气相反应器和出口容器的管线，用于改变通过从出口容器到气相反应器的回气管线的流速的装置，以及用于改变聚合物产物从出口容器的出口速率的装置。

8. 发明申请

US20140171611A1 METHOD FOR RECOVERING POLYMER AND APPARATUS THEREFOR 有权
标题翻译：用于回收聚合物及其装置的方法
公开(公告)号：US20140171611A1
公开(公告)日：2014-06-19
申请号：US14237366
申请日：2012-11-16
申请人： Klaus Nyfors , Jari Aarila , Jari Hatonen , Henrik Andtsjo , Eira Johansson , Mikko Lylykangas
发明人： Klaus Nyfors , Jari Aarila , Jari Hatonen , Henrik Andtsjo , Eira Johansson , Mikko Lylykangas
IPC分类号： B01J8/00 , C08F2/01
CPC分类号： C08F2/01 , B01J8/003 , B01J8/005 , B01J8/1809 , B01J2208/00548 , B01J2208/0061 , B01J2208/00761 , B01J2219/00247 , B01J2219/00254 , C08F2/34 , C08F10/00 , C08J11/04 , Y10S526/92 , C08F110/06 , C08F2500/12 , C08F210/16 , C08F210/08
摘要： Process and apparatus for recovering polymer from a a gas phase reactor having a distribution plate via an outlet vessel comprising at least one apparatus for the breakup of polymeric agglomerates, the apparatus further comprising a feed pipe connecting the gas phase reactor and the outlet vessel a return gas line connecting the gas phase reactor and the outlet vessel, means for varying the flow rate through the return gas line from the outlet vessel to the gas phase reactor, and means for varying the outlet rate of polymer product from the outlet vessel.
摘要翻译：用于从具有分布板的气相反应器中回收聚合物的方法和装置，所述气相反应器具有经由出口容器的出口容器，所述出口容器包括至少一种用于分解聚合物附聚物的装置，该装置还包括将气相反应器和出口容器连接的回流气体连接气相反应器和出口容器的管线，用于改变通过从出口容器到气相反应器的回气管线的流速的装置，以及用于改变聚合物产物从出口容器的出口速率的装置。

9. 发明申请

US20080039597A1 Process And Apparatus For Producing Olefin Polymers 有权
标题翻译：用于生产烯烃聚合物的工艺和设备
公开(公告)号：US20080039597A1
公开(公告)日：2008-02-14
申请号：US11578138
申请日：2005-04-29
申请人： Marianna Vuorikari , Esa Korhonen , Henrik Andtsjo , Samuli Zitting
发明人： Marianna Vuorikari , Esa Korhonen , Henrik Andtsjo , Samuli Zitting
IPC分类号： C08J11/04 , B01J19/00
CPC分类号： B01J19/1837 , B01J8/0015 , B01J2208/00274 , B01J2208/003 , B01J2208/00761 , B01J2219/00006 , C08F6/003 , C08F6/20 , C08F10/02 , C08F110/02 , C08F210/16 , C08L23/04 , C08F2/14 , C08F210/08
摘要： The present invention concerns a process and an apparatus for continuous polymerisation of olefin monomers. In particular, the present invention concerns a process and an apparatus for continuous polymerisation olefin monomers like ethylene and other monomers, wherein an olefin monomer is polymerised in slurry phase in an inert hydrocarbon diluent in at least one loop reactor. According to the invention, a polymer slurry is continuously withdrawn from the loop reactor and concentrated. The concentrated slurry is conducted to a flash unit in order to remove the remaining fluid phase, and gas obtained is compressed in a flash gas compressor before it is being fed to a distillation section. By means of the present invention it is possible reduce the size of the flash gas compressor and the capacity of the distillation sections. This significantly reduces investment cost for a continuously operated polymerization apparatus.
摘要翻译：本发明涉及烯烃单体连续聚合的方法和设备。特别地，本发明涉及用于连续聚合烯烃单体如乙烯和其它单体的方法和设备，其中烯烃单体在淤浆相中在惰性烃稀释剂中在至少一个环管反应器中聚合。根据本发明，聚合物浆液从环流反应器中连续取出并浓缩。将浓缩的浆料送入闪蒸装置以除去剩余的流体相，所获得的气体在进料到蒸馏段之前在闪蒸气体压缩机中被压缩。通过本发明，可以减小闪蒸气体压缩机的尺寸和蒸馏段的容量。这显着降低了连续操作的聚合装置的投资成本。

10. 发明授权

US6084041A Process for making propylene homo or copolymers 失效
标题翻译：制备丙烯均聚物或共聚物的方法
公开(公告)号：US6084041A
公开(公告)日：2000-07-04
申请号：US650104
申请日：1996-05-17
申请人： Henrik Andtsjo , Ismo Pentti , Ali Harlin
发明人： Henrik Andtsjo , Ismo Pentti , Ali Harlin
IPC分类号： C08F2/00 , C08F110/06
CPC分类号： C08F110/06 , Y02P20/544 , Y10S526/901 , Y10S526/904 , Y10S526/905
摘要： A process for homo or copolymerizing propylene, wherein propylene is polymerized in the presence of a catalyst at an elevated temperature in a reaction medium in which a major part of the reaction medium is propylene and the polymerization is carried in at least one CSTR or loop reactor, where the polymerization is carried out at a temperature and a pressure which are above the corresponding critical temperature and the pressure of the reaction medium and where the residence time is at least 15 minutes. The process can also comprise a supercritical loop polymerization before the supercritical stage polymerization or a gas phase polymerization after the supercritical stage polymerization.
摘要翻译：丙烯均聚或共聚的方法，其中丙烯在催化剂存在下在升高的温度下在反应介质中聚合，其中大部分反应介质是丙烯，聚合在至少一个CSTR或环管反应器其中聚合在温度和压力高于相应的临界温度和反应介质的压力以及停留时间至少为15分钟的条件下进行。该方法还可以包括在超临界阶段聚合之前的超临界环路聚合或超临界阶段聚合之后的气相聚合。

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