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1. 发明授权

US09209461B2 Process for the preparation of LiFePO4-carbon composites 有权
标题翻译：制备LiFePO4-碳复合材料的方法
公开(公告)号：US09209461B2
公开(公告)日：2015-12-08
申请号：US13379048
申请日：2010-06-23
申请人： Simon Schroedle , Hartmut Hibst , Brian Roberts , Kirill Bramnik , Jordan Keith Lampert
发明人： Simon Schroedle , Hartmut Hibst , Brian Roberts , Kirill Bramnik , Jordan Keith Lampert
IPC分类号： H01B1/24 , H01M4/525 , H01M4/58 , C01B25/45 , C01B25/455 , H01M4/131 , H01M4/1315 , H01M4/133 , H01M4/485 , H01M4/505 , H01M4/583 , H01M10/0525
CPC分类号： H01M4/5825 , C01B25/45 , C01B25/455 , H01B1/24 , H01M4/131 , H01M4/1315 , H01M4/133 , H01M4/485 , H01M4/505 , H01M4/525 , H01M4/583 , H01M10/0525 , Y02E60/122
摘要： The present invention relates to a process for the preparation of particles comprising at least one compound according to general formula (I) M1aM2bM3cOoNnFf (I) wherein M1, M2, M3 O, N, F, a, b, c, o, n and f have the following meanings: M1 at least one alkaline metal, M2 at least one transition metal in oxidation state +2, M3 at least one non-metal chosen form S, Se, P, As, Si, Ge and/or B, O oxygen, N nitrogen, F fluorine, a 0.8-4.2, b 0.8-1.9, c 0.8-2.2, o 1.0-8.4, n 0-2.0 and f 0-2.0, wherein a, b, c, o, n and f are chosen to ensure electroneutrality of the compound according to general formula (I), and carbon, comprising at least the following steps: (A) providing an essentially aqueous mixture comprising at least one compound comprising M1, at least one compound comprising M2 having at least partially an oxidation state higher than +2, optionally at least one compound comprising M3, at least one compound comprising N, if present, and/or at least one compound comprising F, if present, at least one polysaccharide comprising glucose having a molecular weight M of at least 50000 g/mol as carbon precursor and at least one reducing agent, (B) drying the mixture provided in step (A), in order to obtain a solid particle and (C) calcining the solid particle obtained from step (B) at a temperature of 300 to 950° C.
摘要翻译：本发明涉及一种制备颗粒的方法，所述颗粒包含至少一种根据通式（I）的M1aM2bM3cOoNnFf（I）的化合物，其中M1，M2，M3O，N，F，a，b，c，o，n和 f具有以下含义：M1至少一种碱金属，M2至少一种氧化态过渡金属+2，M3至少一种非金属选择形式S，Se，P，As，Si，Ge和/或B， O氧，N氮，F氟，0.8-4.2，b 0.8-1.9，c 0.8-2.2，o 1.0-8.4，n 0-2.0和f 0-2.0，其中a，b，c，o，n和选择f以确保根据通式（I）的化合物和包含至少以下步骤的碳的电中性：（A）提供基本上含水的混合物，其包含至少一种包含M1，至少一种包含M2的化合物，其包含具有至少部分地高于+2的氧化态，任选地至少一种包含M3的化合物，至少一种包含N的化合物（如果存在）和/或至少一种包含F的化合物送出至少一种包含分子量M至少为50000g / mol的葡萄糖作为碳前体和至少一种还原剂的至少一种多糖，（B）干燥步骤（A）中提供的混合物，以获得固体颗粒和（C）在300-950℃的温度下煅烧由步骤（B）得到的固体颗粒。

2. 发明授权

US08506847B2 Process for the preparation of crystalline lithium-, vanadium-and phosphate-comprising materials 失效
标题翻译：用于制备结晶的含锂，钒和磷酸盐的材料的方法
公开(公告)号：US08506847B2
公开(公告)日：2013-08-13
申请号：US12680797
申请日：2008-09-18
申请人： Hartmut Hibst , Brian Roberts , Jordan Keith Lampert , Kirill Bramnik
发明人： Hartmut Hibst , Brian Roberts , Jordan Keith Lampert , Kirill Bramnik
IPC分类号： H01B1/06 , H05B7/085 , H01M4/88
CPC分类号： C01B25/45 , H01M4/5825 , H01M10/0525
摘要： The present invention relates to a process for the preparation of compounds of general formula (I) Lia-bM1bV2-cM2c(PO4)x (I) with M1: Na, K, Rb and/or Cs, M2: Ti, Zr, Nb, Cr, Mn, Fe, Co, Ni, Al, Mg and/or Sc, a: 1.5-4.5, b: 0-0.6, c: 0-1.98 and x: number to equalize the charge of Li and V and M1 and/or M2, if present, wherein a−b is >0, by providing an essentially aqueous mixture comprising at least one lithium-comprising compound, at least one vanadium-comprising compound in which vanadium has the oxidation state +5 and/or +4, and at least one M1-comprising compound, if present, and/or at least one M2-comprising compound, if present, and at least one reducing agent which is oxidized to at least one compound comprising at least one phosphorous atom in oxidation state +5, drying and calcining.
摘要翻译：本发明涉及制备具有M1：Na，K，Rb和/或Cs，M2：Ti，Zr，Nb的通式（I）Lia-bM1bV2-cM2c（PO4）x（Ⅰ）的化合物的方法，Cr，Mn，Fe，Co，Ni，Al，Mg和/或Sc，a：1.5-4.5，b：0-0.6，c：0-1.98和x：等于Li和V和M1的电荷和/或M2，如果存在，其中ab> 0，通过提供基本上含水的混合物，其包含至少一种含锂化合物，至少一种含钒化合物，其中钒具有+5和/或+4的氧化态和至少一种含M1化合物（如果存在）和/或至少一种含M2化合物（如果存在）和至少一种还原剂被氧化成至少一种包含至少一个氧化态磷原子的化合物 +5，干燥和煅烧。

3. 发明授权

US08377311B2 Selective materials separation using modified magnetic particles 有权
标题翻译：使用改性磁性颗粒的选择性材料分离
公开(公告)号：US08377311B2
公开(公告)日：2013-02-19
申请号：US13054713
申请日：2009-07-15
申请人： Imme Domke , Alexej Michailovski , Norbert Mronga , Hartmut Hibst , Juergen Tropsch , Susanne Stutz
发明人： Imme Domke , Alexej Michailovski , Norbert Mronga , Hartmut Hibst , Juergen Tropsch , Susanne Stutz
IPC分类号： B03C1/005
CPC分类号： H01F1/44 , B03C1/015 , B82Y25/00 , H01F1/0045
摘要： The present invention relates to a process of the invention for separating at least one first material from a mixture comprising this at least one first material and at least one second material, which comprises the steps: (A) Contacting of at least one magnetic particle and at least one bifunctional molecule or an adduct of the two with the mixture comprising the at least one first material and at least one second material so that an adduct is formed from the at least one magnetic particle, the bifunctional compound of the general formula (I) and the at least one first material, (B) suspension of the adduct obtained in step (A) in a suitable suspension medium, (C) separation of the adduct present in the suspension from step (B) from the suspension by application of a magnetic field, (D) if appropriate, dissociation of the adduct separated off in step (C) in order to obtain the at least one first material. a corresponding adduct and the use of such an adduct for the separation of mixtures of materials.
摘要翻译：本发明涉及一种本发明的方法，用于从包含该至少一种第一材料和至少一种第二材料的混合物中分离至少一种第一材料，其包括以下步骤：（A）接触至少一种磁性颗粒和至少一种双功能分子或两者的加合物与混合物包含至少一种第一材料和至少一种第二材料，使得加合物由至少一个磁性颗粒形成，通式（I）的双官能化合物）和所述至少一种第一材料，（B）步骤（A）中获得的加合物的悬浮液在合适的悬浮介质中，（C）通过施用将来自步骤（B）的悬浮液中存在的加合物与悬浮液（D）如果合适，在步骤（C）中分离的加合物的解离以获得至少一种第一材料。相应的加合物和这种加合物用于分离材料混合物的用途。

4. 发明申请

US20120106139A1 ELECTRO-OPTICALLY SWITCHABLE SYSTEM 审中-公开
标题翻译：电光开关系统
公开(公告)号：US20120106139A1
公开(公告)日：2012-05-03
申请号：US13382583
申请日：2010-07-06
申请人： Bastian Ewald , Dirk Gerhard , Hartmut Hibst
发明人： Bastian Ewald , Dirk Gerhard , Hartmut Hibst
IPC分类号： F21V33/00 , G02F1/163 , G02F1/1347 , G02F1/1334 , G02F1/01 , G02F1/13
CPC分类号： B65D65/16 , B65D81/30 , B65D2201/00
摘要： An electro-optically switchable system that includes an optically active element and a momentary switch, a container that includes such an electro-optically switchable system and use of such an electro-optically switchable system for providing containers that allow increased light to pass through into the interior thereof only for the duration of a control intervention.
摘要翻译：一种电光可切换系统，其包括光学有源元件和瞬时开关，容器包括这种电光可切换系统，并且使用这种电光可切换系统来提供允许增加的光通过的容器其内部仅在控制干预的持续时间内。

5. 发明申请

US20110206753A1 NANOPARTICULATE COPPER COMPOUNDS 审中-公开
标题翻译：纳米复合铜化合物
公开(公告)号：US20110206753A1
公开(公告)日：2011-08-25
申请号：US13002812
申请日：2009-07-02
申请人： Andrey Karpov , Hartmut Hibst , Michael Triller , Eike Hupe , Michael Maier , Jörg Habicht
发明人： Andrey Karpov , Hartmut Hibst , Michael Triller , Eike Hupe , Michael Maier , Jörg Habicht
IPC分类号： A01N25/34 , A01N55/02 , B01J31/06 , A01P1/00 , C08G63/91 , B82Y5/00 , B82Y30/00 , B82Y40/00
CPC分类号： C01G3/00 , A01N59/20 , B82Y30/00 , C01G3/006 , C01P2004/64 , A01N25/04 , A01N25/34 , A01N2300/00
摘要： The present invention relates to processes for the preparation of surface-modified nanoparticulate copper compounds and of aqueous suspensions which comprise surface-modified nanoparticulate copper compounds. The invention furthermore relates to the surface-modified nanoparticulate copper compounds obtainable by these processes and aqueous suspensions of these copper compounds and their use as an antimicrobial active substance or catalyst.
摘要翻译：本发明涉及制备表面改性的纳米微粒铜化合物的方法和包含表面改性的纳米微粒铜化合物的水性悬浮液的方法。本发明还涉及通过这些方法获得的表面改性的纳米微粒铜化合物和这些铜化合物的水悬浮液及其作为抗微生物活性物质或催化剂的用途。

6. 发明申请

US20110049443A1 PROCESS FOR THE PREPARATION OF CRYSTALLINE LITHIUM-, IRON- AND PHOSPHATE-COMPRISING MATERIALS 审中-公开
标题翻译：制备结晶锂，铁和磷酸盐包覆材料的方法
公开(公告)号：US20110049443A1
公开(公告)日：2011-03-03
申请号：US12988418
申请日：2009-04-16
申请人： Hartmut Hibst , Brian Roberts , Jordan Keith Lampert , Kirill Bramnik
发明人： Hartmut Hibst , Brian Roberts , Jordan Keith Lampert , Kirill Bramnik
IPC分类号： H01B1/08 , H01B1/10
CPC分类号： H01M4/48 , C01B25/30 , C01B25/45 , C01P2006/40 , H01B1/02 , H01B1/08 , H01M4/525 , H01M4/5825 , H01M4/625 , H01M10/0525
摘要： The present application relates to a process for the preparation of compounds of general formula (I) Lia-bM1bFe1-cM2cPd-eM3eOx (I), wherein M1, M2, M3, a, b, c, d, e and x: M1: Na, K, Rb and/or Cs, M2: Mn, Mg, Ca, Ti, Co, Ni, Cr, V, M3: Si, S, a: 0.8-1.9, b: 0-0.3, c: 0-0.9, d: 0.8-1.9, e: 0-0.5, x: 1.0-8, depending on the amount and oxidation state of L1, M1, Fe, M2, P, M3, wherein compounds of general formula (I) are neutrally charged, comprising the following steps (A) providing an essentially aqueous mixture comprising at least one lithium-comprising compound, FeOOH as iron-comprising compound and at least one M1-comprising compound, if present, and/or at least one M2-comprising compound, if present, and/or least one M3-comprising compound, if present, at least one compound comprising at least one phosphorous atom and at least one reducing agent, (B) drying the mixture provided in step (A), in order to obtain a solid compound and (C) calcining the solid compound obtained from step (A) or (B) at a temperature of 300 to 950° C.
摘要翻译：本申请涉及制备通式（I）Lia-bM1bFe1-cM2cPd-eM3eOx（Ⅰ）的化合物的方法，其中M1，M2，M3，a，b，c，d，e和x：M1： Na，K，Rb和/或Cs，M2：Mn，Mg，Ca，Ti，Co，Ni，Cr，V，M3：Si，S，a：0.8-1.9，b：0-0.3，c： 0.9，d：0.8-1.9，e：0-0.5，x：1.0-8，取决于L1，M1，Fe，M2，P，M3的量和氧化态，其中通式（I）的化合物是中性的包括以下步骤（A），其提供基本上含水的混合物，其包含至少一种含锂化合物，作为含铁化合物的FeOOH和至少一种含M1化合物（如果存在）和/或至少一种含M2的化合物化合物（如果存在）和/或至少一种含M3化合物（如果存在）至少一种包含至少一个磷原子和至少一种还原剂的化合物，（B）按顺序干燥步骤（A）中提供的混合物得到固体化合物，（C）煅烧由步骤获得的固体化合物（A）或（B）在300〜950℃的温度下进行。

7. 发明申请

US20100044651A1 METHOD FOR THE PRODUCTION OF LITHIUM-RICH METAL OXIDES 有权
标题翻译：生产富含金属氧化物的方法
公开(公告)号：US20100044651A1
公开(公告)日：2010-02-25
申请号：US12595794
申请日：2008-04-14
申请人： Kirill Bramnik , Hartmut Hibst , Julian Prölss
发明人： Kirill Bramnik , Hartmut Hibst , Julian Prölss
IPC分类号： C01G31/02 , C01D1/02 , H01B1/08
CPC分类号： C01G31/00 , C01P2002/72 , C01P2006/12 , C01P2006/40 , H01M4/131 , H01M4/485 , H01M10/052 , H01M2300/0082 , H01M2300/0091
摘要： The present invention relates to a process for preparing lithium-rich metal oxides and also the lithium-rich metal oxides which can be obtained by this process. Furthermore, the invention relates to the use of lithium-rich metal oxides for producing a cathode for a battery, in particular a lithium ion battery, and also a cathode for a lithium ion battery which comprises lithium-rich metal oxides.
摘要翻译：本发明涉及一种制备富锂金属氧化物的方法，还涉及可通过该方法获得的富锂金属氧化物。此外，本发明涉及富锂金属氧化物用于制造电池阴极，特别是锂离子电池的用途，以及包含富锂金属氧化物的锂离子电池用阴极。

8. 发明授权

US07524792B2 Preparation of catalytically active multielement oxide materials which contain at least one of the elements Nb and W and the elements Mo, V and Cu 有权
标题翻译：制备催化活性多元素氧化物材料，其含有元素Nb和W中的至少一种元素Mo，V和Cu
公开(公告)号：US07524792B2
公开(公告)日：2009-04-28
申请号：US10840745
申请日：2004-05-07
申请人： Martin Dieterle , Hartmut Hibst , Wolfgang Juergen Poepel , Jochen Petzoldt , Klaus Joachim Mueller-Engel
发明人： Martin Dieterle , Hartmut Hibst , Wolfgang Juergen Poepel , Jochen Petzoldt , Klaus Joachim Mueller-Engel
IPC分类号： B01J23/00
CPC分类号： B01J23/002 , B01J23/8877 , B01J23/8885 , B01J35/0006 , B01J37/08 , B01J2523/00 , C07C51/215 , C07C51/235 , C07C57/04 , B01J2523/17 , B01J2523/68 , B01J2523/69
摘要： Catalytically active multielement oxide materials which contain at least one of the elements Nb and W and the elements Mo, V and Cu are prepared by a process in which an intimate dry blend containing ammonium ions is prepared and said dry blend is subjected to a thermal treatment in an atmosphere having a low molecular oxygen content at elevated temperatures, a portion of the ammonium ions contained in the intimate dry blend being decomposed with liberation of ammonia and the oxygen content of the thermal treatment atmosphere being increased in the course of the thermal treatment.
摘要翻译：含有至少一种元素Nb和W以及元素Mo，V和Cu的催化活性多元素氧化物材料通过其中制备含有铵离子的紧密干混合物并对所述干混合物进行热处理的方法制备在升高的温度下具有低分子氧含量的气氛中，紧密干燥混合物中所含的一部分铵离子被氨释放分解，热处理气氛的氧含量在热处理过程中增加。

9. 发明授权

US07495132B2 Catalytically active composition and the use thereof in dehydration methods 失效
标题翻译：催化活性组合物及其在脱水方法中的应用
公开(公告)号：US07495132B2
公开(公告)日：2009-02-24
申请号：US10587191
申请日：2005-01-28
申请人： Christian Walsdorff , Thorsten Johann , Beatrice Roessler , Hartmut Hibst , Joaquim Henrique Teles , Sebastian Storck , Jens Klein
发明人： Christian Walsdorff , Thorsten Johann , Beatrice Roessler , Hartmut Hibst , Joaquim Henrique Teles , Sebastian Storck , Jens Klein
IPC分类号： C07C45/65 , B01J23/42
CPC分类号： C07C45/65 , B01J23/6445 , B01J23/6447 , B01J23/6522 , B01J23/681 , B01J23/8973 , B01J35/008 , B01J37/0201 , B01J37/0221 , B01J37/03 , C07C47/21 , C07C49/603
摘要： The present invention relates to a catalytically active composition comprising as active component Pd and Bi and at least one element selected from the group (a) consisting of Rh, Au, Sb, V, Cr, W, Mn, Fe, Co, Ni, Na, Cs and Ba, or Pd, Rh and Bi and optionally an element selected from the group (a′) consisting of Au, Sb, V, Cr, W, Mn, Fe, Co, Ni, Pt, Cu, Ag, Na, Cs, Mg, Ca and Ba. The present invention further provides a process for dehydrogenating hydrocarbons, preferably oxo-functionalized hydrocarbons such as cyclopentanone, cyclohexanone and isovaleraldehyde, using the catalytically active composition.
摘要翻译：本发明涉及包含作为活性成分Pd和Bi的至少一种元素的催化活性组合物和选自由Rh，Au，Sb，V，Cr，W，Mn，Fe，Co，Ni组成的组（a）中的至少一种元素， Na，Cs和Ba或Pd，Rh和Bi以及任选的选自Au，Sb，V，Cr，W，Mn，Fe，Co，Ni，Pt，Cu，Ag， Na，Cs，Mg，Ca和Ba。本发明还提供了一种使用催化活性组合物使烃优选氧化官能化烃如环戊酮，环己酮和异戊醛脱氢的方法。

10. 发明申请

US20090045374A1 ELECTRICALLY CONDUCTIVE, MAGNETIC COMPOSITE MATERIAL, PROCESS FOR ITS PRODUCTION, AND ITS USE 审中-公开
标题翻译：电导体，磁性复合材料，其生产工艺及其使用
公开(公告)号：US20090045374A1
公开(公告)日：2009-02-19
申请号：US12192610
申请日：2008-08-15
申请人： Dirk LAWRENZ , Ingolf Hennig , Andrey Karpov , Stefan Kirsch , Hartmut Hibst , Juergen Kaczun , Uta Holzenkamp , Stephen Ems , Harry Thomas Mills , Paul Edwin Gloor
发明人： Dirk LAWRENZ , Ingolf Hennig , Andrey Karpov , Stefan Kirsch , Hartmut Hibst , Juergen Kaczun , Uta Holzenkamp , Stephen Ems , Harry Thomas Mills , Paul Edwin Gloor
IPC分类号： H01F1/00 , C01G49/08
CPC分类号： H05B6/64
摘要： Electrically conductive, magnetic composite material, comprising (A) pulverulent, inorganic, magnetic material which is electrically not or only poorly conductive, and (B) an electrically conductive material, selected from the group consisting of pulverulent and liquid carbon-comprising organic materials and pulverulent carbon allotropes, in a ratio by weight of (A):(B)=from 1:100 to 100:1; a process for its production, and its use, and also ferrimagnetic mixed oxide (A) of the general formula I: M″M′″O4 (I), in which M″ is a first metal component which comprises divalent metal cations; and M′″ is a second metal component which comprises trivalent metal cations; capable of production by reacting, in a quantitative ratio such that the resultant ferromagnetic mixed oxide (A) is electrically neutral, divalent metal cations M″ and trivalent metal cations M′″ in aqueous solution and/or dispersion, comprising at least one electrically conductive material (B) and/or at least one material which differs therefrom and which is a binder (C) which dries physically or else is crosslinkable thermally and/or by actinic radiation.
摘要翻译：导电性磁性复合材料，其包含（A）不具有导电性或导电性差的粉状，无机，磁性材料，和（B）导电材料，其选自由含有粉状和液态碳的有机材料和粉末碳同素异形体，以（A）:( B）的重量比= 1:100至100:1; 其制备方法及其用途，以及通式I的亚铁磁性混合氧化物（A）：<？in-line-formula description =“In-line formula”end =“lead”？> M'M ''O4（I），<？in-line-formula description =“In-line Formulas”end =“tail”？>其中M“是包含二价金属阳离子的第一金属成分; M“是包含三价金属阳离子的第二金属组分; 能够通过使得所得铁磁混合氧化物（A）电中性的数量比使水溶液和/或分散体中的二价金属阳离子M“和三价金属阳离子M”反应而制备，包含至少一种导电材料（B）和/或与其不同的至少一种材料，其是物理上干燥的或者是通过光化辐射可交联的粘合剂（C）。

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