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1. 发明授权

US09175185B2 Coating compositions having high weathering resistance, process for preparation thereof and use thereof 有权
标题翻译：具有高耐候性的涂料组合物，其制备方法和用途
公开(公告)号：US09175185B2
公开(公告)日：2015-11-03
申请号：US12173338
申请日：2008-07-15
申请人： Thomas Fichtner , Harald Petri , Stephan Krieger , Ivan Cabrera
发明人： Thomas Fichtner , Harald Petri , Stephan Krieger , Ivan Cabrera
IPC分类号： C08L31/02 , C08L31/04 , C09D131/04 , C09D5/02 , C09D7/12 , C09D133/12 , C08K3/00
CPC分类号： C09D131/04 , C08K3/013 , C09D5/024 , C09D7/60 , C09D133/12
摘要： What are described are coating compositions comprising pigments and/or fillers and multistage polyvinyl ester dispersions as binders. These binders are produced by a selected multistage process in which a polyvinyl ester dispersion is obtained in a first stage, monomers in dissolved or pure form or in the form of an emulsion are added to the reaction mixture in a second stage and then the polymerization is started again. The polyvinyl ester dispersions comprise polymerized silanes and/or epoxides or the polyvinyl ester dispersions have only a small content of protective colloids, if any. The coating compositions formulated with the multistage polyvinyl ester dispersions obtained in this way are notable for a very high weathering resistance.
摘要翻译：所描述的是包含颜料和/或填料和作为粘合剂的多级聚乙烯酯分散体的涂料组合物。这些粘合剂通过选择的多级方法制备，其中在第一阶段获得聚乙烯基酯分散体，在第二阶段中将溶解或纯形式的单体或乳液形式加入反应混合物中，然后聚合反应再次开始聚乙烯酯分散体包括聚合的硅烷和/或环氧化物，或聚乙烯酯分散体仅具有少量保护胶体（如果有的话）。用以这种方式获得的多级聚乙烯酯分散体配制的涂料组合物具有非常高的耐候性。

2. 发明申请

US20090203832A1 Process for Preparing Polymer Dispersions, the Resulting Dispersions and Their Use 有权
标题翻译：制备聚合物分散体的方法，所得的分散体及其用途
公开(公告)号：US20090203832A1
公开(公告)日：2009-08-13
申请号：US12367039
申请日：2009-02-06
申请人： Harmin Muller , Harald Petri , Thomas Drechsel
发明人： Harmin Muller , Harald Petri , Thomas Drechsel
IPC分类号： C08L29/04 , C08F2/44
CPC分类号： C08F2/24
摘要： A description is given of a process of emulsion polymerization of free-radically polymerizable ethylenically unsaturated monomers selected from the group of the monoesters or diesters of ethylenically unsaturated monocarboxylic or dicarboxylic acids with alkanols, vinyl esters and/or vinylaromatics and, if desired, further monomers copolymerizable therewith, at least 60% of the total conversion in the polymerization taking place at a temperature of 100° C. to 160° C., the polymerization being performed in the presence of emulsifiers and an amount of 0% to 1% by weight, based on the total amount of the monomers used, of protective colloid.The process can be used to obtain significantly faster conversions for comparable quality of the process products.The dispersions obtained can be employed in a wide variety of different applications, such as binders for paints or as adhesives.
摘要翻译：描述了可自由基聚合的烯键式不饱和单体的乳液聚合方法，该单体选自烯键式不饱和单羧酸或二羧酸的单酯或二酯与链烷醇，乙烯基酯和/或乙烯基芳族化合物，以及如果需要，其它单体可与其共聚的聚合反应的总转化率的至少60％在100℃至160℃的温度下进行，聚合反应在乳化剂存在下进行，其量为0重量％至1重量％，基于所用单体的总量，保护胶体。该过程可用于获得显着更快的转化率，以达到可比较的过程产品质量。所获得的分散体可以用于各种不同的应用，例如用于油漆的粘合剂或粘合剂。

3. 发明申请

US20090203814A1 Aqueous Plastic Dispersions, Method for Producing the Same and Their Use 有权
标题翻译：水性塑料分散体，其制备方法及其用途
公开(公告)号：US20090203814A1
公开(公告)日：2009-08-13
申请号：US11994881
申请日：2006-06-27
申请人： Harald Petri , Ivan Cabrera
发明人： Harald Petri , Ivan Cabrera
IPC分类号： C09D167/00 , C08L1/00 , C08L3/02 , C08K5/3415 , C08K5/5317 , C08K5/41 , C08K5/06 , C08F263/02 , C08K3/00 , C09J167/00
CPC分类号： C08F2/24 , C08F263/02 , C08L51/003 , C08L53/00 , C08L2205/02 , C09D143/04 , C09D151/003 , C09D153/00 , C08L2666/02 , C08L2666/04
摘要： Multistage polymers predominantly stabilized by nonionic emulsifiers and derived from hard and soft monomer compositions containing vinyl esters, of which at least one monomer composition must contain an unsaturated compromisable organosilicon compound, are described.The plastic dispersions can be used as binders in emulsion paints and finishes and impart to these excellent scrub resistance in addition to good blocking resistance.
摘要翻译：主要由非离子乳化剂稳定并衍生自含有乙烯基酯的硬和软单体组合物的多级聚合物，其中至少一种单体组合物必须含有不饱和的有害硅化合物。塑料分散体可以用作乳液漆和表面处理剂中的粘合剂，并赋予这些优异的耐擦洗性以及良好的抗粘连性。

4. 发明申请

US20080214722A1 Coating Agent With High Abrasion Resistance Method For Production And Application Thereof 审中-公开
标题翻译：具有高耐磨性的涂层剂生产和应用
公开(公告)号：US20080214722A1
公开(公告)日：2008-09-04
申请号：US11912066
申请日：2006-04-10
申请人： Harald Petri , Ivan Cabrera
发明人： Harald Petri , Ivan Cabrera
IPC分类号： C08L23/00
CPC分类号： C08F218/08 , C08L2312/08 , C09D5/024 , C09D131/04
摘要： A description is given of coating compositions comprising at least one pigment and/or filler and at least one aqueous dispersion of a selected emulsifier-stabilized vinyl ester copolymer which comprises as its stabilizer a mixture of at least one nonionic emulsifier and at least one salt of a bisester of a sulfonated dicarboxylic acid having 4 to 8 carbon atoms.The coating compositions formulated with these binders feature high scrub resistance.
摘要翻译：给出了包含至少一种颜料和/或填料的至少一种颜料和/或填料和至少一种所选择的乳化剂稳定的乙烯基酯共聚物的水性分散体的涂料组合物的描述，其包含至少一种非离子乳化剂和至少一种非离子乳化剂的盐的混合物作为其稳定剂具有4至8个碳原子的磺化二羧酸的双酯。用这些粘合剂配制的涂料组合物具有高耐擦洗性。

5. 发明授权

US08053511B2 Process for preparing polymer dispersions, the resulting dispersions and their use 有权
标题翻译：制备聚合物分散体的方法，所得分散体及其用途
公开(公告)号：US08053511B2
公开(公告)日：2011-11-08
申请号：US12367039
申请日：2009-02-06
申请人： Harmin Muller , Harald Petri , Thomas Drechsel
发明人： Harmin Muller , Harald Petri , Thomas Drechsel
IPC分类号： C08L29/04 , C08F2/44
CPC分类号： C08F2/24
摘要： A description is given of a process of emulsion polymerization of free-radically polymerizable ethylenically unsaturated monomers selected from the group of the monoesters or diesters of ethylenically unsaturated monocarboxylic or dicarboxylic acids with alkanols, vinyl esters and/or vinylaromatics and, if desired, further monomers copolymerizable therewith, at least 60% of the total conversion in the polymerization taking place at a temperature of 100° C. to 160° C., the polymerization being performed in the presence of emulsifiers and an amount of 0% to 1% by weight, based on the total amount of the monomers used, of protective colloid.The process can be used to obtain significantly faster conversions for comparable quality of the process products.The dispersions obtained can be employed in a wide variety of different applications, such as binders for paints or as adhesives.
摘要翻译：描述了可自由基聚合的烯键式不饱和单体的乳液聚合方法，该单体选自烯键式不饱和单羧酸或二羧酸的单酯或二酯与链烷醇，乙烯基酯和/或乙烯基芳族化合物，以及如果需要，其它单体可与其共聚的聚合反应的总转化率的至少60％在100℃至160℃的温度下进行，聚合反应在乳化剂存在下进行，其量为0重量％至1重量％，基于所用单体的总量，保护胶体。该过程可用于获得显着更快的转化率，以达到可比较的过程产品质量。所获得的分散体可以用于各种不同的应用，例如用于油漆的粘合剂或粘合剂。

6. 发明授权

US08030391B2 Aqueous plastic dispersions, method for producing the same and their use 有权
标题翻译：水性塑料分散体，其制造方法及其用途
公开(公告)号：US08030391B2
公开(公告)日：2011-10-04
申请号：US11994881
申请日：2006-06-27
申请人： Harald Petri , Ivan Cabrera
发明人： Harald Petri , Ivan Cabrera
IPC分类号： C08J3/02 , C08J5/18 , C08K7/10 , C08K7/08 , C08K5/05 , C08K5/09 , C08K5/15 , C08K5/45
CPC分类号： C08F2/24 , C08F263/02 , C08L51/003 , C08L53/00 , C08L2205/02 , C09D143/04 , C09D151/003 , C09D153/00 , C08L2666/02 , C08L2666/04
摘要： Multistage polymers predominantly stabilized by nonionic emulsifiers and derived from hard and soft monomer compositions containing vinyl esters, of which at least one monomer composition must contain an unsaturated compromisable organosilicon compound, are described.The plastic dispersions can be used as binders in emulsion paints and finishes and impart to these excellent scrub resistance in addition to good blocking resistance.
摘要翻译：主要由非离子乳化剂稳定并衍生自含有乙烯基酯的硬和软单体组合物的多级聚合物，其中至少一种单体组合物必须含有不饱和的有害硅化合物。塑料分散体可以用作乳液漆和表面处理剂中的粘合剂，并赋予这些优异的耐擦洗性以及良好的抗粘连性。

7. 发明申请

US20090069495A1 Coating Compositions Having High Weathering Resistance, Process for Preparation Thereof and Use Thereof 有权
标题翻译：具有高耐候性的涂料组合物，其制备方法和用途
公开(公告)号：US20090069495A1
公开(公告)日：2009-03-12
申请号：US12173338
申请日：2008-07-15
申请人： Thomas Fichtner , Harald Petri , Stephan Krieger , Ivan Cabrera
发明人： Thomas Fichtner , Harald Petri , Stephan Krieger , Ivan Cabrera
IPC分类号： C08L77/00 , C08L83/00 , C08L67/07
CPC分类号： C09D131/04 , C08K3/013 , C09D5/024 , C09D7/60 , C09D133/12
摘要： What are described are coating compositions comprising pigments and/or fillers and multistage polyvinyl ester dispersions as binders. These binders are produced by a selected multistage process in which a polyvinyl ester dispersion is obtained in a first stage, monomers in dissolved or pure form or in the form of an emulsion are added to the reaction mixture in a second stage and then the polymerization is started again. The polyvinyl ester dispersions comprise polymerized silanes and/or epoxides or the polyvinyl ester dispersions have only a small content of protective colloids, if any. The coating compositions formulated with the multistage polyvinyl ester dispersions obtained in this way are notable for a very high weathering resistance.
摘要翻译：所描述的是包含颜料和/或填料和作为粘合剂的多级聚乙烯酯分散体的涂料组合物。这些粘合剂通过选择的多级方法制备，其中在第一阶段获得聚乙烯基酯分散体，在第二阶段中将溶解或纯形式的单体或乳液形式加入反应混合物中，然后聚合反应再次开始聚乙烯酯分散体包括聚合的硅烷和/或环氧化物，或聚乙烯酯分散体仅具有少量保护胶体（如果有的话）。用以这种方式获得的多级聚乙烯酯分散体配制的涂料组合物具有非常高的耐候性。

8. 发明授权

US07078455B2 Aqueous plastic material dispersions method for producing the same and use thereof 有权
标题翻译：水性塑料分散体的制造方法及其用途
公开(公告)号：US07078455B2
公开(公告)日：2006-07-18
申请号：US10472110
申请日：2002-03-14
申请人： Carsten Heldmann , Harald Petri , Thomas Wirth
发明人： Carsten Heldmann , Harald Petri , Thomas Wirth
IPC分类号： C09D131/02 , C09D5/02 , C08J3/02
CPC分类号： C08J3/005 , C08J2331/02 , C08L2205/02 , C09D131/04 , C09D143/04 , Y10S525/902 , C08L2666/04
摘要： The present invention relates to aqueous plastic material dispersions based on vinyl ester copolymers, having a solids content of up to 80% by weight and a minimum film formation temperature below 20° C., which is substantially stabilized by ionic components, the vinyl ester copolymers containing at least one homo- or copolymer A and at least one homo- or copolymer B, methods for producing the same and the use thereof.
摘要翻译：本发明涉及基于乙烯基酯共聚物的水性塑料材料分散体，其固体含量高达80重量％，最低成膜温度低于20℃，其基本上由离子组分稳定，乙烯基酯共聚物含有至少一种均聚物或共聚物A和至少一种均聚物或共聚物B，其制备方法及其用途。

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