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1. 发明申请

US20180002481A1 ALKENE ISOMERIZATION AS AN ENTRY TO EFFICIENT ALTERNATING RING-OPEINING METATHESIS POLYMERIZATION (i-AROMP) 审中-公开
公开(公告)号：US20180002481A1
公开(公告)日：2018-01-04
申请号：US15545580
申请日：2016-03-21
申请人： The Research Foundation for The State University of New York
发明人： Nicole S. Sampson , Li Tan , Kathlyn Parker
IPC分类号： C08G61/08 , C07C13/18 , B01J31/22 , C08F232/04 , C09D165/00 , C07C13/06 , C07C13/32
CPC分类号： C08G61/08 , B01J31/2265 , C07C13/06 , C07C13/18 , C07C13/32 , C08F232/04 , C08G2261/124 , C08G2261/1426 , C08G2261/3323 , C08G2261/3325 , C08G2261/418 , C09D165/00
摘要： This invention relates to the field of polymers and olefin polymerization, and more specifically olefin metathesis polymerization. Specifically, the present invention provides a polymer comprising rigorously alternating AB subunits and methods of formation of the AB alternating polymers. In the polymers and process of the invention, the A monomer is derived from a cyclobutene derivative, and the B monomer is derived from a cyclohexene derivative. The polymerization takes place in the presence of an olefin metathesis catalyst.

2. 发明授权

US09758737B1 Renewable diamondoid fuels 有权
公开(公告)号：US09758737B1
公开(公告)日：2017-09-12
申请号：US15297285
申请日：2016-10-19
申请人： The United States of America as represented by the Secretary of the Navy
发明人： Benjamin G. Harvey
IPC分类号： C06B47/00 , D03D23/00 , D03D43/00 , C10L1/16 , C07C5/03 , C07C5/31 , C10L1/185 , C10L10/12 , C07C45/68
CPC分类号： C10L1/1608 , C06B47/00 , C07C1/22 , C07C5/03 , C07C5/29 , C07C5/31 , C07C45/455 , C07C45/68 , C07C2103/74 , C07C2521/18 , C07C2523/42 , C07C2523/44 , C07C2527/126 , C07C2602/28 , C07C2602/36 , C07C2603/74 , C07C2603/78 , C07C2603/94 , C10L1/04 , C10L1/08 , C10L1/1857 , C10L10/12 , C10L2200/0469 , C10L2270/026 , C10L2270/04 , C10L2290/24 , Y02E50/13 , C07C13/32 , C07C13/50 , C07C13/72 , C07C13/605 , C07C13/615 , C07C49/323
摘要： A method to generate dense, multi-cyclic diamondoid fuels from bio-derived sesquiterpenes. This process can be conducted with both heterogeneous and homogenous catalysts and produces the targeted isomers in high yield. The resulting multi-cyclic structures impart significantly higher densities and volumetric net heats of combustion while maintaining low viscosities which allow for use at low temperature/high altitude. Moreover, bio-derived sesquiterpenes can be produced from renewable biomass sources. Use of these fuels will decrease Navy dependence on fossil fuels and will also reduce net carbon emissions.

3. 发明授权

US06806327B2 Substituted polycyclic, fused ring compounds, metal complexes and polymerization process 有权
标题翻译：取代的多环，稠环化合物，金属络合物和聚合过程
公开(公告)号：US06806327B2
公开(公告)日：2004-10-19
申请号：US10124269
申请日：2002-04-16
申请人： Richard E. Campbell, Jr. , Jerzy Klosin , Ravi B. Shankar , Francis J. Timmers , Robert K. Rosen , Shaoguang Feng
发明人： Richard E. Campbell, Jr. , Jerzy Klosin , Ravi B. Shankar , Francis J. Timmers , Robert K. Rosen , Shaoguang Feng
IPC分类号： C08F444
CPC分类号： C07C13/32 , C07C13/66 , C07C2602/14 , C07F7/10 , C07F17/00 , C08F4/65908 , C08F4/65912 , C08F4/65922 , C08F210/02 , C08F2420/02 , C08F2420/05 , C08F4/6592 , C08F212/08
摘要： Metal complexes comprising a polycyclic, fused ring ligand or inertly substituted derivative thereof comprising at least: (1) a cyclopentadienyl ring, (2) a 7 membered polyatomic ring, and (3) one or more aromatic ring systems, with the proviso that said 7 membered ring (2), is fused to both the cyclopentadienyl ring (1), and said one or more aromatic ring systems (3), and substituted in at least one ring position with a substituent group resulting in sp2 hybridization on the ring atom bonded thereto; polymerization catalysts; and olefin polymerization processes using the same are disclosed.
摘要翻译：包含多环，稠环配体或其惰性取代的衍生物的金属络合物至少包含：（1）环戊二烯基环，（2）7元多原子环，和（3）一个或多个芳环体系，条件是所述 7元环（2）与环戊二烯基环（1）和所述一个或多个芳族环体系（3）融合，并且在至少一个环位置被取代基取代，导致sp 2杂交与其结合的环原子; 聚合催化剂; 并且公开了使用其的烯烃聚合方法。

4. 发明申请

US20020151662A1 Substituted polycyclic, fused ring compounds, metal complexes and polymerization process 有权
标题翻译：取代的多环，稠环化合物，金属络合物和聚合过程
公开(公告)号：US20020151662A1
公开(公告)日：2002-10-17
申请号：US10124269
申请日：2002-04-16
发明人： Richard E. Campbell JR. , Jerzy Klosin , Ravi B. Shankar , Francis J. Timmers , Robert K. Rosen , Shaoguang Feng
IPC分类号： C08F004/44
CPC分类号： C07C13/32 , C07C13/66 , C07C2602/14 , C07F7/10 , C07F17/00 , C08F4/65908 , C08F4/65912 , C08F4/65922 , C08F210/02 , C08F2420/02 , C08F2420/05 , C08F4/6592 , C08F212/08
摘要： Metal complexes comprising a polycyclic, fused ring ligand or inertly substituted derivative thereof comprising at least: (1) a cyclopentadienyl ring, (2) a 7 membered polyatomic ring, and (3) one or more aromatic ring systems, with the proviso that said 7 membered ring (2), is fused to both the cyclopentadienyl ring (1), and said one or more aromatic ring systems (3), and substituted in at least one ring position with a substituent group resulting in sp2 hybridization on the ring atom bonded thereto; polymerization catalysts; and olefin polymerization processes using the same are disclosed.
摘要翻译：包含多环，稠环配体或其惰性取代的衍生物的金属络合物至少包含：（1）环戊二烯基环，（2）7元多原子环和（3）一个或多个芳族环体系，条件是所述 7元环（2）与环戊二烯基环（1）和所述一个或多个芳族环体系（3）融合，并且在至少一个环位置被取代基取代，导致在环原子上产生sp2杂交与之结合; 聚合催化剂; 并且公开了使用其的烯烃聚合方法。

5. 发明授权

US5900517A Cyclopentadienyl derivatives and process for their preparation 失效
标题翻译：环戊二烯基衍生物及其制备方法
公开(公告)号：US5900517A
公开(公告)日：1999-05-04
申请号：US695400
申请日：1996-08-12
申请人： Paolo Biagini , Roberto Santi , Giampiero Borsotti , Gabriele Lugli , Viviano Banzi
发明人： Paolo Biagini , Roberto Santi , Giampiero Borsotti , Gabriele Lugli , Viviano Banzi
IPC分类号： B01J27/16 , B01J31/22 , C07B61/00 , C07C2/00 , C07C13/28 , C07C13/32 , C07C13/36 , C07C13/39 , C07C13/45 , C07C13/47 , C07C13/52 , C07C13/615 , C07C1/32
CPC分类号： C07C13/32 , C07C13/52 , C07C2102/14 , C07C2102/30 , C07C2102/32
摘要： Cyclopentadienyl derivatives are described having general formula (I) ##STR1## where R, R.sub.1, R.sub.2, R.sub.4, equivalent to or different from one another, are selected from: --H, alkyl radicals having a number of carbon atoms from 1 to 5, cycloalkyl radicals having a number of carbon atoms from 5 to 8, aryl and alkylaryl radicals having a number of carbon atoms from 6 to 8, aralkyl radicals having a number of carbon atoms from 7 to 9; n is an integer from 2 to 18; with the proviso that the number of R different from H does not exceed 2; with the exclusion of the compound having n=3, R.dbd.R.sub.1 .dbd.R.sub.2 .dbd.R.sub.4 .dbd.H. The invention a-so describes the process for the preparation of the above-mentioned cyclopentadienyl derivatives.
摘要翻译：描述了具有通式（I）的环戊二烯基衍生物，其中R，R 1，R 2，R 4彼此相当或不同，选自：-H，具有1至5个碳原子数的烷基，环烷基具有 5至8个碳原子数，6至8个碳原子数的芳基和烷芳基，7至9个碳原子的芳烷基; n是2至18的整数; 条件是与H不同的R数不超过2; 排除n = 3的化合物，R = R 1 = R 2 = R 4 = H。本发明a-描述了制备上述环戊二烯基衍生物的方法。

6. 发明授权

US4032585A 1-Ethyl-cyclooctadiene-1,5 失效
标题翻译： 1-乙基 - 环己烷-1,5
公开(公告)号：US4032585A
公开(公告)日：1977-06-28
申请号：US585287
申请日：1975-06-09
申请人： Gunther Wilke , Paul Heimbach
发明人： Gunther Wilke , Paul Heimbach
IPC分类号： C07C2/02 , C07C2/42 , C07C13/00 , C07C13/20 , C07C13/263 , C07C13/271 , C07C13/277 , C07C13/28 , C07C13/32 , C07C13/605 , C07C13/26
CPC分类号： C07C13/605 , C07C13/00 , C07C13/20 , C07C13/263 , C07C13/271 , C07C13/277 , C07C13/28 , C07C13/32 , C07C2/02 , C07C2/42 , C07C2101/14 , C07C2101/16 , C07C2101/18 , C07C2101/20 , C07C2103/84
摘要： A series of mono, bi and tricarbocyclic compounds, most of which have olefinic unsaturation in the ring, which may or may not have substituents thereon. While the bi and tricyclic rings may be unsubstituted, these compounds which have olefinic unsaturation, particularly multiple olefinic unsaturation, are polymerizable and copolymerizable in known polymerization systems. They are particularly good crosslinking agents. These compounds are further useful in the sense that they can be cleaved oxidatively, to corresponding carboxylic acids, aldehydes and/or alcohols which have known utility in the plasticizer and detergent arts. The compounds which do not have olefinic unsaturation can also be oxidatively cleaved to produce oxygenated, e.g., acid, alcohol or aldehyde, compounds having known utility.

7. 发明授权

US3929921A Ring compounds 失效
标题翻译：环化合物
公开(公告)号：US3929921A
公开(公告)日：1975-12-30
申请号：US46308774
申请日：1974-04-22
申请人： STUDIENGESELLSCHAFT KOHLE MBH
发明人： WILKE GUNTHER , HEIMBACH PAUL
IPC分类号： B01J31/16 , B01J31/18 , C07C13/277 , C07C13/32 , C07C45/34 , C07C13/00
CPC分类号： B01J31/185 , B01J2231/20 , B01J2531/847 , C07C13/277 , C07C13/32 , C07C45/34 , C07C2601/20 , C07C2602/32 , C07C2603/38 , C07C2603/84 , C07C49/185
摘要： A series of mono, bi and tricarbocyclic compounds, most of which have olefinic unsaturation in the ring, which may or may not have substituents thereon. While the bi and tricyclic rings may be unsubstituted, these compounds which have olefinic unsaturation, particularly multiple olefinic unsaturation, are polymerizable and copolymerizable in known polymerization systems. They are particularly good crosslinking agents. These compounds are further useful in the sense that they can be cleaved oxidatively, to corresponding carboxylic acids, aldehydes and/or alcohols which have known utility in the plasticizer and detergent arts. The compounds which do not have olefinic unsaturation can also be oxidatively cleaved to produce oxygenated, e.g., acid, alcohol or aldehyde, compounds having known utility.
摘要翻译：一系列单环，双和三环化合物，其中大多数在环中具有烯属不饱和键，其可以具有或不具有取代基。虽然双环和三环可以是未取代的，但是具有烯属不饱和键，特别是多个烯属不饱和键的这些化合物在已知的聚合体系中是可聚合的和可共聚的。它们是特别好的交联剂。这些化合物在它们可以被氧化裂解的意义上可进一步用于在增塑剂和洗涤剂领域已知有用的相应的羧酸，醛和/或醇。不具有烯属不饱和键的化合物也可被氧化裂解以产生氧化的，例如酸，醇或醛，已知有用的化合物。

8. 发明授权

US3849506A 1,2-dimethyl cyclooctadiene-1,5 失效
标题翻译： 1,2-二甲基环己烷-1,5
公开(公告)号：US3849506A
公开(公告)日：1974-11-19
申请号：US10994971
申请日：1971-01-26
申请人： STUDIENGESELLSCHAFT KOHLE MBH
发明人： WILKE G , HEIMBACH P
IPC分类号： C07C2/02 , C07C2/42 , C07C13/00 , C07C13/20 , C07C13/263 , C07C13/271 , C07C13/277 , C07C13/28 , C07C13/32 , C07C13/605 , C07C45/34 , C07C49/185 , C07C13/26
CPC分类号： C07C49/185 , C07C2/02 , C07C2/42 , C07C13/00 , C07C13/20 , C07C13/263 , C07C13/271 , C07C13/277 , C07C13/28 , C07C13/32 , C07C13/605 , C07C45/34 , C07C2531/22 , C07C2601/14 , C07C2601/16 , C07C2601/18 , C07C2601/20 , C07C2602/32 , C07C2603/38 , C07C2603/84
摘要： 1. 1,2-DIMETHYL CYCLOOCTADIENE-1,5.

9. 发明授权

US2966527A Preparation of bicycloalkadienes 失效
标题翻译：双链烯二烯的制备
公开(公告)号：US2966527A
公开(公告)日：1960-12-27
申请号：US61479656
申请日：1956-10-09
申请人： UNIVERSAL OIL PROD CO
发明人： LOUIS SCHMERLING
IPC分类号： C07C1/30 , C07C13/32 , C07C17/30
CPC分类号： C07C1/30 , C07C13/32 , C07C17/30 , C07C2602/42 , C07C13/39 , C07C23/30 , C07C23/20

10. 发明授权

US2340908A Hydrocarbon synthesis 失效
公开(公告)号：US2340908A
公开(公告)日：1944-02-08
申请号：US46694042
申请日：1942-11-25
申请人： UNIVERSAL OIL PROD CO
发明人： THOMAS CHARLES L
IPC分类号： C07C2/50 , C07C13/32 , C07C13/42
CPC分类号： C07C13/42 , C07C2/50 , C07C13/32 , C07C2602/00 , C07C2602/42

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