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    • 6. 发明授权
    • Aqueous dispersions of polyurethanes which are crosslinkable by the
action of high energy radiation
    • 通过高能量辐射作用可交联的聚氨酯的水分散度
    • US5135963A
    • 1992-08-04
    • US507465
    • 1990-04-11
    • Karl HaeberlePeter WeylandGuenter EckertHans Renz
    • Karl HaeberlePeter WeylandGuenter EckertHans Renz
    • C08F299/06C08F290/00C08G18/00C08G18/08C08G18/12C08G18/28C08G18/67C14C11/00
    • C14C11/006C08G18/12C08G18/2815C08G18/672
    • Aqueous dispersions of polyurethanes which are crosslinkable by the action of high energy radiation contain (a) a polyisocyanate, (b) a polyol having a molecular weight of from 400 to 6,000 g/mol, (c) if required, a polyol having a molecular weight of from 62 to 399 g/mol, (d) if required, a polyamine having two or more amino groups which are reactive to isocyanate, (e) if required, an aminoalcohol having one or more amino groups which are reactive to isocyanate, (f) a compound containing ionic groups or groups which can be converted into ionic groups and one or more hydroxyl or amino groups which are reactive to isocyanate (g) if required, a monofunctional polyetheral and (h) a compound having one or more ethylenically unsaturated groups and one or more hydroxyl groups. The compound having an ethylenically unsaturated group (h) is used in amounts corresponding to 0.02-0.08 gram equivalent, based on the polyisocyanate (a), of OH, and the polyurethane, dissolved in dimethylformamide, has a Fikentscher K value greater than 40 or is insoluble in dimethylformamide.
    • 通过高能量辐射的作用可交联的聚氨酯的水分散体包含(a)多异氰酸酯,(b)分子量为400至6,000g / mol的多元醇,(c)如果需要,具有分子量 (d)如果需要,具有两个或多个与异氰酸酯反应的氨基的多胺,(e)如果需要,具有一个或多个与异氰酸酯反应的氨基的氨基醇, (f)含有离子基团的化合物,如果需要可以转化为离子基团和一个或多个与异氰酸酯(g)反应的羟基或氨基,单官能聚醚和(h)具有一个或多个烯键式 不饱和基团和一个或多个羟基。 具有烯键式不饱和基团(h)的化合物的使用量相对于OH的多异氰酸酯(a)为0.02-0.08克当量,溶解在二甲基甲酰胺中的聚氨酯的Fikentscher K值大于40或 不溶于二甲基甲酰胺。