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1. 发明申请

US20080319147A1 Catalyst Composition II 失效
标题翻译：催化剂组合物II
公开(公告)号：US20080319147A1
公开(公告)日：2008-12-25
申请号：US12099940
申请日：2008-04-09
申请人： Gregory Adam Solan , Christopher James Davies
发明人： Gregory Adam Solan , Christopher James Davies
IPC分类号： C08F4/695 , C08F4/606 , C08F4/70
CPC分类号： C07C2/32 , B01J31/143 , B01J31/146 , B01J31/1805 , B01J31/1815 , B01J2231/122 , B01J2231/20 , B01J2531/0258 , B01J2531/16 , B01J2531/72 , B01J2531/842 , B01J2531/845 , B01J2531/847 , C07C2531/26 , C07F13/005 , C07F15/025 , C07F15/045 , C07F15/065 , C08F10/00 , C08F110/02 , C07C11/02 , C08F2500/02 , C08F4/60089 , C08F4/7042 , C08F4/50 , C08F4/7081
摘要： This invention relates to a transition metal catalyst compound represented by the formula: LMX2 or (LMX2)2 wherein each M is independently a Group 7 to 11 metal, preferably a Group 7, 8, 9, or 10 metal; each L is, independently, a tridentate or tetradentate neutrally charged ligand that is bonded to M by three or four nitrogen atoms, (where at least one of the nitrogen atoms is a central nitrogen atom and at least two of the nitrogen atoms are terminal nitrogen atoms), and at least two terminal nitrogen atoms are substituted with one C3-C50 hydrocarbyl and one hydrogen atom or two hydrocarbyls wherein at least one hydrocarbyl is a C3-C50 hydrocarbyl, and the central nitrogen atom is bonded to three different carbon atoms or two different carbon atoms and one hydrogen atom; X is independently a monoanionic ligand, or two X may join together to form a bidentate dianionic ligand.
摘要翻译：本发明涉及由下式表示的过渡金属催化剂化合物：LMX2或（LMX2）2，其中每个M独立地是7-11族金属，优选第7,8,9或10族金属; 每个L独立地是三齿或四齿中性带电的配体，其通过三个或四个氮原子（其中至少一个氮原子是中心氮原子，并且至少两个氮原子是末端氮）键合到M上原子），并且至少两个末端氮原子被一个C 3 -C 50烃基和一个氢原子或两个烃基取代，其中至少一个烃基是C 3 -C 50烃基，并且中心氮原子键合到三个不同的碳原子或两个不同的碳原子和一个氢原子; X独立地是单阴离子配体，或两个X可以连接在一起以形成二齿二离子配体。

2. 发明授权

US07217675B2 Catalyst composition 失效
标题翻译：催化剂组成
公开(公告)号：US07217675B2
公开(公告)日：2007-05-15
申请号：US10802514
申请日：2004-03-17
申请人： Gregory Adam Solan , Christopher James Davies
发明人： Gregory Adam Solan , Christopher James Davies
IPC分类号： C07F15/00 , C08F4/44 , B01J31/00
CPC分类号： B01J31/143 , B01J31/1616 , B01J31/1815 , B01J2231/122 , B01J2231/20 , B01J2531/0258 , B01J2531/72 , B01J2531/842 , B01J2531/845 , B01J2531/847 , C07C2/32 , C07C2531/14 , C07C2531/22 , C07F1/005 , C07F13/005 , C07F15/025 , C07F15/045 , C07F15/065 , C08F10/00 , C08F110/02 , C08F2410/03 , C08F2500/02 , C08F4/7042 , C08F4/7081
摘要： This invention relates to transition metal catalyst compounds represented by the formula: LMX2 wherein M is a Group 7 to 11 metal; L is a tridentate or tetradentate neutrally charged ligand that is bonded to M by least three or four nitrogen atoms, and at least one terminal nitrogen atom is part of a pyridinyl ring, a different terminal nitrogen atom is substituted with one C3–C50 hydrocarbyl, and one hydrogen atom or two hydrocarbyls; wherein at least one hydrocarbyl is a C3–C50 hydrocarbyl, and the central nitrogen atom is bonded to at least three different carbon atoms or two different carbon atoms, and one hydrogen atom; X is independently a monoanionic ligand or both X are joined together to form a bidentate dianionic ligand.
摘要翻译：本发明涉及由下式表示的过渡金属催化剂化合物：其中M是7-11族金属; L是三齿或四齿中性带电的配体，其通过至少三个或四个氮原子与M键合，并且至少一个末端氮原子是吡啶基环的一部分，不同的末端氮原子被一个C 3 一个或多个烃基，一个氢原子或两个烃基; 其中至少一个烃基是C 3 -C 50烃基，并且中心氮原子键合至至少三个不同的碳原子或两个不同的碳原子，一个氢原子; X独立地是单阴离子配体，或者两者X连接在一起以形成二齿二离子配体。

3. 发明授权

US08058372B2 Catalyst composition II 失效
标题翻译：催化剂组合物II
公开(公告)号：US08058372B2
公开(公告)日：2011-11-15
申请号：US12099940
申请日：2008-04-09
申请人： Gregory Adam Solan , Christopher James Davies
发明人： Gregory Adam Solan , Christopher James Davies
IPC分类号： C08F4/72 , C08F4/64 , B01J31/22 , C07C2/32
CPC分类号： C07C2/32 , B01J31/143 , B01J31/146 , B01J31/1805 , B01J31/1815 , B01J2231/122 , B01J2231/20 , B01J2531/0258 , B01J2531/16 , B01J2531/72 , B01J2531/842 , B01J2531/845 , B01J2531/847 , C07C2531/26 , C07F13/005 , C07F15/025 , C07F15/045 , C07F15/065 , C08F10/00 , C08F110/02 , C07C11/02 , C08F2500/02 , C08F4/60089 , C08F4/7042 , C08F4/50 , C08F4/7081
摘要： This invention relates to a transition metal catalyst compound represented by the formula: LMX2 or (LMX2)2 wherein each M is independently a Group 7 to 11 metal, preferably a Group 7, 8, 9, or 10 metal; each L is, independently, a tridentate or tetradentate neutrally charged ligand that is bonded to M by three or four nitrogen atoms, (where at least one of the nitrogen atoms is a central nitrogen atom and at least two of the nitrogen atoms are terminal nitrogen atoms), and at least two terminal nitrogen atoms are substituted with one C3-C50 hydrocarbyl and one hydrogen atom or two hydrocarbyls wherein at least one hydrocarbyl is a C3-C50 hydrocarbyl, and the central nitrogen atom is bonded to three different carbon atoms or two different carbon atoms and one hydrogen atom; X is independently a monoanionic ligand, or two X may join together to form a bidentate dianionic ligand.
摘要翻译：本发明涉及由下式表示的过渡金属催化剂化合物：LMX2或（LMX2）2，其中每个M独立地是7-11族金属，优选第7,8,9或10族金属; 每个L独立地是三齿或四齿中性带电的配体，其通过三个或四个氮原子（其中至少一个氮原子是中心氮原子，并且至少两个氮原子是末端氮）键合到M上原子），并且至少两个末端氮原子被一个C 3 -C 50烃基和一个氢原子或两个烃基取代，其中至少一个烃基是C 3 -C 50烃基，并且中心氮原子键合到三个不同的碳原子或两个不同的碳原子和一个氢原子; X独立地是单阴离子配体，或两个X可以连接在一起以形成二齿二离子配体。

4. 发明授权

US07820582B2 Catalyst composition 失效
标题翻译：催化剂组成
公开(公告)号：US07820582B2
公开(公告)日：2010-10-26
申请号：US11712881
申请日：2007-03-01
申请人： Gregory Adam Solan , Christopher James Davies
发明人： Gregory Adam Solan , Christopher James Davies
IPC分类号： C07F15/06 , B01J31/00 , C08F4/06
CPC分类号： B01J31/143 , B01J31/1616 , B01J31/1815 , B01J2231/122 , B01J2231/20 , B01J2531/0258 , B01J2531/72 , B01J2531/842 , B01J2531/845 , B01J2531/847 , C07C2/32 , C07C2531/14 , C07C2531/22 , C07F1/005 , C07F13/005 , C07F15/025 , C07F15/045 , C07F15/065 , C08F10/00 , C08F110/02 , C08F2410/03 , C08F2500/02 , C08F4/7042 , C08F4/7081
摘要： This invention relates to catalyst compounds, catalysts systems and methods to oligomerize or polymerize monomers where the catalyst compound and the catalyst system comprise compounds of formula: LMX2 or (LMX2)2 wherein: M is a Group 7, 8, 9, 10 or 11 transition metal; L is a tridentate or tetradentate neutrally charged ligand that is bonded to M by at least three nitrogen atoms; at least one of the nitrogen atoms is a central non-pyridinal nitrogen atom and is not bonded to its adjacent atoms by a multibond; at least two of the nitrogen atoms are terminal nitrogen atoms; at least one terminal nitrogen atom is part of a pyridinyl ring; at least one other terminal nitrogen atom is substituted with at least one C3-C50 hydrocarbyl or halobydrocarbyl; the central nitrogen atom is bonded to at least two different carbon atoms; and each X is an anionic monodentate ligand.
摘要翻译：本发明涉及催化剂化合物，催化剂体系和使单体低聚或聚合的方法，其中催化剂化合物和催化剂体系包含式：LMX2或（LMX2）2的化合物，其中：M为第7,8,9,10或11族过渡金属; L是三齿或四齿中性带电的配体，其通过至少三个氮原子与M键合; 氮原子中的至少一个是中心非吡啶基氮原子，并且不通过多键与其相邻原子键合; 至少两个氮原子是末端氮原子; 至少一个末端氮原子是吡啶环的一部分; 至少一个其它末端氮原子被至少一个C 3 -C 50烃基或卤代烃基取代; 中心氮原子与至少两个不同的碳原子键合; 并且每个X是阴离子单齿配体。

5. 发明授权

US06831143B2 Polymerization catalysts 有权
标题翻译：聚合催化剂
公开(公告)号：US06831143B2
公开(公告)日：2004-12-14
申请号：US10222811
申请日：2002-08-19
申请人： George Johan Peter Britovsek , Birgit Angelika Dorer , Vernon Charles Gibson , Brian Stephen Kimberley , Gregory Adam Solan
发明人： George Johan Peter Britovsek , Birgit Angelika Dorer , Vernon Charles Gibson , Brian Stephen Kimberley , Gregory Adam Solan
IPC分类号： C08F1002
CPC分类号： C07D213/53 , C07F13/005 , C07F15/0053 , C07F15/025 , C07F15/065 , C08F4/65912 , C08F4/65916 , C08F4/65925 , C08F10/00 , C08F10/02 , C08F110/02 , C08F210/16 , C08F2410/04 , C08F4/61904 , C08F2500/04 , C08F2500/07 , C08F2500/12 , C08F210/14 , C08F2500/10 , C08F2500/26 , C08F2500/03 , C08F4/60089 , C08F4/7042 , C08F4/6546
摘要： Catalyst systems useful for the polymerisation of 1-olefins are disclosed, which contain nitrogen-containing transition metal compounds comprising the skeletal unit depicted in Formula (B), wherein M is Fe[II], Fe[III], Ru[II], Ru[III] or Ru[IV]; X represents an atom or group covalently or ionically bonded to the transition metal M; T is the oxidation state of the transition metal M and b is the valency of the atom or group X; R1, R2, R3, R4 and R6 are independently selected from hydrogen, halogen, hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl or substituted heterohydrocarbyl; R5 and R7 are independently selected from hydrogen, halogen, hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl or substituted heterohydrocarbyl.
摘要翻译：公开了可用于1-烯烃聚合的催化剂体系，其含有包含式（B）所示骨架单元的含氮过渡金属化合物，其中M为Fe [II]，Fe [III]，Ru [II]， Ru [III]或Ru [IV]; X表示与过渡金属M共价或离子键合的原子或基团; T是过渡金属M的氧化态，b是原子或基团X的化合价; R 1，R 2，R 3，R 4和R 6独立地选自氢，卤素，烃基，取代的烃基，杂烃基或取代的杂烃基; R 5和R 7独立地选自氢，卤素，烃基，取代的烃基，杂烃基或取代的杂烃基。

6. 发明授权

US06683141B1 Polymerization catalysts 失效
标题翻译：聚合催化剂
公开(公告)号：US06683141B1
公开(公告)日：2004-01-27
申请号：US09702745
申请日：2000-11-01
申请人： Vernon Charles Gibson , Brian Stephen Kimberley , Gregory Adam Solan
发明人： Vernon Charles Gibson , Brian Stephen Kimberley , Gregory Adam Solan
IPC分类号： C08F444
CPC分类号： C08F10/00 , C07F7/003 , C07F9/005 , C07F11/005 , C07F15/025 , C07F15/065 , C08F110/02 , C08F4/68284 , C08F4/025 , C08F4/69224 , C08F4/64089 , C08F2500/04 , C08F4/7042 , C08F4/7054 , C08F4/7044
摘要： A complex suitable for the polymerization of l-olefins is disclosed, having the Formula A wherein M is a transition metal, lanthanide or actinide; X represents an atom or group covalently or ionically bonded to the transition metal M; b is the valency of the atom or group X; Z1 is N or P; Z2 is N, P, N−, P−or NR5; Z3 is one of N, P, O, S, NHR3, NR3R4, OH, OR3, SH, SR3, PHR3, PR3R4, (NR3)−, O−, S−, (PR3)−, P(R3R4)O, NR3 or PR3 to the proviso that one of Z2 and Z3 is anionic; T is the oxidation state of the transition metal M when both Z2 or Z3 are neutral, and is one less than the oxidation state of M when one of Z2 or Z3 is anionic; A and B are independently hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl or substituted heterohydrocarbyl, and may together with Z2 form part of a heterocyclic substituent; B may be joined to Z3 by either a single or a double bond; R1 to R5 are each independently selected from hydrogen, halogen, hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl or substituted heterohydrocarbyl, and any two or more of R1 to R5 when hydrocarbyl may be joined together to form a ring; L is a solvate molecule, and n is from 0 to 5. The complex is useful as a polymerization catalyst in a process for the polymerization and copolymerization of olefins.
摘要翻译：公开了适用于1-烯烃聚合的络合物，其具有式A，其中M是过渡金属，镧系元素或锕系元素; X表示与过渡金属M共价或离子键合的原子或基团; b是原子或基团X的化合价; Z 1是N或P; Z 2是N，P，N，P或NR 5; Z 3是N，P，O，S，NHR 3，NR 3 R 4，OH，OR 3，SH，SR 3，PHR 3，PR < （R 3）R 3，（NR 3） - ，O - ，S - ，（PR 3） - ，P（R 3 R 4） NR 3或PR 3，条件是Z 2和Z 3中的一个为阴离子; 当Z 2或Z 3均为中性时，T是过渡金属M的氧化态，当Z 2或Z 3中的一个为阴离子时，其摩尔比小于M的氧化态; A和B独立地是烃基，取代的烃基，杂烃基或取代的杂烃基，并且可以与Z 2一起形成杂环取代基的一部分; B可以通过单键或双键与Z 3连接; R 1至R 5各自独立地选自氢，卤素，烃基，取代的烃基，杂烃基或取代的杂烃基，当烃基可以连接在一起时，R 1至R 5中的任何两个或多个形成戒指 L是溶剂化物分子，n为0至5.该络合物可用作烯烃聚合和共聚方法中的聚合催化剂。

7. 发明授权

US07371803B2 Catalyst composition II 失效
标题翻译：催化剂组合物II
公开(公告)号：US07371803B2
公开(公告)日：2008-05-13
申请号：US11602897
申请日：2006-11-21
申请人： Gregory Adam Solan , Christopher James Davies
发明人： Gregory Adam Solan , Christopher James Davies
IPC分类号： C08F4/70 , C08F4/80
CPC分类号： C07C2/32 , B01J31/143 , B01J31/146 , B01J31/1805 , B01J31/1815 , B01J2231/122 , B01J2231/20 , B01J2531/0258 , B01J2531/16 , B01J2531/72 , B01J2531/842 , B01J2531/845 , B01J2531/847 , C07C2531/26 , C07F13/005 , C07F15/025 , C07F15/045 , C07F15/065 , C08F10/00 , C08F110/02 , C07C11/02 , C08F2500/02 , C08F4/60089 , C08F4/7042 , C08F4/50 , C08F4/7081
摘要： This invention relates to a transition metal catalyst compound represented by the formula: LMX2 or (LMX2)2 wherein each M is independently a Group 7 to 11 metal, preferably a Group 7, 8, 9, or 10 metal; each L is, independently, a tridentate or tetradentate neutrally charged ligand that is bonded to M by three or four nitrogen atoms, (where at least one of the nitrogen atoms is a central nitrogen atom and at least two of the nitrogen atoms are terminal nitrogen atoms), and at least two terminal nitrogen atoms are substituted with one C3-C50 hydrocarbyl and one hydrogen atom or two hydrocarbyls wherein at least one hydrocarbyl is a C3-C50 hydrocarbyl, and the central nitrogen atom is bonded to three different carbon atoms or two different carbon atoms and one hydrogen atom; X is independently a monoanionic ligand, or two X may join together to form a bidentate dianionic ligand.
摘要翻译：本发明涉及由下式表示的过渡金属催化剂化合物：LMX 2或（LMX 2）2 N，其中每个M独立地为基团 7至11个金属，优选第7,8,9或10族金属; 每个L独立地是三齿或四齿中性带电的配体，其通过三个或四个氮原子（其中至少一个氮原子是中心氮原子，并且至少两个氮原子是末端氮）键合到M上原子），并且至少两个末端氮原子被一个C 3 -C 50烃基和一个氢原子或两个烃基取代，其中至少一个烃基是C < 并且中心氮原子键合到三个不同的碳原子或两个不同的碳原子和一个氢原子上; X独立地是单阴离子配体，或两个X可以连接在一起以形成二齿二离子配体。

8. 发明授权

US07189791B2 Catalyst composition II 失效
标题翻译：催化剂组合物II
公开(公告)号：US07189791B2
公开(公告)日：2007-03-13
申请号：US10855585
申请日：2004-05-27
申请人： Gregory Adam Solan , Christopher James Davies
发明人： Gregory Adam Solan , Christopher James Davies
IPC分类号： C08F4/695 , C08F4/70 , B01J31/12 , B01J31/14 , C07F13/00 , C07F15/00 , C07F15/04
CPC分类号： C07C2/32 , B01J31/143 , B01J31/146 , B01J31/1805 , B01J31/1815 , B01J2231/122 , B01J2231/20 , B01J2531/0258 , B01J2531/16 , B01J2531/72 , B01J2531/842 , B01J2531/845 , B01J2531/847 , C07C2531/26 , C07F13/005 , C07F15/025 , C07F15/045 , C07F15/065 , C08F10/00 , C08F110/02 , C07C11/02 , C08F2500/02 , C08F4/60089 , C08F4/7042 , C08F4/50 , C08F4/7081
摘要： This invention relates to a transition metal catalyst compound represented by the formula: LMX2 or (LMX2)2 wherein each M is independently a Group 7 to 11 metal, preferably a Group 7, 8, 9, or 10 metal; each L is, independently, a tridentate or tetradentate neutrally charged ligand that is bonded to M by three or four nitrogen atoms, (where at least one of the nitrogen atoms is a central nitrogen atom and at least two of the nitrogen atoms are terminal nitrogen atoms), and at least two terminal nitrogen atoms are substituted with one C3–C50 hydrocarbyl and one hydrogen atom or two hydrocarbyls wherein at least one hydrocarbyl is a C3–C50 hydrocarbyl, and the central nitrogen atom is bonded to three different carbon atoms or two different carbon atoms and one hydrogen atom; X is independently a monoanionic ligand, or two X may join together to form a bidentate dianionic ligand.
摘要翻译：本发明涉及由下式表示的过渡金属催化剂化合物：LMX 2或（LMX 2）2 N，其中每个M独立地为基团 7至11个金属，优选第7,8,9或10族金属; 每个L独立地是三齿或四齿中性带电的配体，其通过三个或四个氮原子（其中至少一个氮原子是中心氮原子，并且至少两个氮原子是末端氮）与M键合原子），并且至少两个末端氮原子被一个C 3 -C 50烃基和一个氢原子或两个烃基取代，其中至少一个烃基是C < 并且中心氮原子键合到三个不同的碳原子或两个不同的碳原子和一个氢原子上; X独立地是单阴离子配体，或两个X可以连接在一起以形成二齿二离子配体。

9. 发明授权

US06451939B1 Polymerization catalysts 有权
标题翻译：聚合催化剂
公开(公告)号：US06451939B1
公开(公告)日：2002-09-17
申请号：US09520127
申请日：2000-03-06
申请人： George Johan Peter Britovsek , Birgit Angelika Dorer , Vernon Charles Gibson , Brian Stephen Kimberley , Gregory Adam Solan
发明人： George Johan Peter Britovsek , Birgit Angelika Dorer , Vernon Charles Gibson , Brian Stephen Kimberley , Gregory Adam Solan
IPC分类号： C08F460
CPC分类号： C07D213/53 , C07F13/005 , C07F15/0053 , C07F15/025 , C07F15/065 , C08F4/65912 , C08F4/65916 , C08F4/65925 , C08F10/00 , C08F10/02 , C08F110/02 , C08F210/16 , C08F2410/04 , C08F4/61904 , C08F2500/04 , C08F2500/07 , C08F2500/12 , C08F210/14 , C08F2500/10 , C08F2500/26 , C08F2500/03 , C08F4/60089 , C08F4/7042 , C08F4/6546
摘要： Catalyst systems for the polymerization or copolymerization of 1-olefins which contain nitrogen-containing transition metal compounds comprising the skeletal unit depicted in formula (B), wherein M is Fe[II] Fe[III], Co[I], Co[II], Co[III], Mn[I], Mn[II], Mn[III], Mn[IV], Ru[II], Ru[III] or Ru[IV]; X is an atom or group covalently or ionically bonded to the transition metal M; T is the oxidation state of the transition metal M and b is the valency of the atom or group X; and R1-R7 are independently selected from hydrogen, halogen, hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl or substituted heterohydrocarbyl.
摘要翻译：用于含有包含式（B）所示骨架单元的含氮过渡金属化合物的1-烯烃聚合或共聚的催化剂体系，其中M为Fe [II] Fe [III]，Co [I]，Co [II ]，Co [III]，Mn [I]，Mn [II]，Mn [III]，Mn [IV]，Ru [II]，Ru [III]或Ru [IV] X是与过渡金属M共价或离子键合的原子或基团; T是过渡金属M的氧化态，b是原子或基团X的化合价; 和R 1 -R 7独立地选自氢，卤素，烃基，取代的烃基，杂烃基或取代的杂烃基。

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