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1. 发明授权

US4363797A Polyaspartic acid derivatives, their preparation and their use in cosmetic composition 失效
标题翻译：聚天冬氨酸衍生物，其制备方法及其在化妆品组合物中的应用
公开(公告)号：US4363797A
公开(公告)日：1982-12-14
申请号：US100882
申请日：1979-12-06
申请人： Bernard Jacquet , Christos Papantoniou , Gerard Land , Serge Forestier
发明人： Bernard Jacquet , Christos Papantoniou , Gerard Land , Serge Forestier
IPC分类号： A61K8/73 , A61K8/88 , A61Q5/02 , A61Q5/06 , C08G69/42 , C08G73/10 , D06P3/04
CPC分类号： A61Q5/06 , A61K8/731 , A61K8/88 , A61Q5/02 , C08G69/42 , C08G73/1092
摘要： Novel polymers useful, in particular, in cosmetic compositions for application to the hair are described. These random polymers can be represented by the general formula: ##STR1## in which: Z represents a mercapto radical or a sulphonic acid radical, which is free or is in the form of an alkali metal or an alkaline earth metal salt,x is an integer from 2 to 6,R represents a hydrogen atom or a lower alkyl radical,each R' independently represents a hydrogen atom, a lower hydroxyalkyl group, an alkyl group having 1 to 18 carbon atoms or an alkenyl group having at most 18 carbon atoms,each R" independently represents a hydrogen atom, a lower hydroxyalkyl group or a lower alkyl group, orR' and R", together with the nitrogen atom to which they are attached, form a 6-membered ring, which can contain, apart from the said nitrogen atom, an oxygen or nitrogen atom,M represents a hydrogen atom, an alkali metal atom or half an atom of an alkaline earth metal,D represents a ##STR2## group, R, x, Z, R', R" and M being as defined above, m is a positive integer corresponding to the number of units A in the polymer,p and q are each independently 0 or a positive integer corresponding to the number of units B and C, respectively, in the polymer, such that the sum m+p+q is from about 15 to about 500.
摘要翻译：描述了可用于特别是在用于头发的化妆品组合物中的新型聚合物。这些无规聚合物可以由以下通式表示：其中：Z表示巯基或磺酸基团，其自由或呈碱金属或碱土金属的形式金属盐，x是2〜6的整数，R表示氢原子或低级烷基，各R'独立地表示氢原子，低级羟烷基，碳原子数1〜18的烷基或烯基具有至多18个碳原子，每个R“独立地表示氢原子，低级羟烷基或低级烷基，或R'和R”与它们所连接的氮原子一起形成6- 除了所述氮原子外，氧原子或氮原子可以含有，M表示氢原子，碱金属原子或碱土金属的半原子，D表示R基， x，Z，R'，R“和M如上所定义，m是对应于num的正整数在聚合物中，p和q各自各自独立地为0或对应于聚合物中单元B和C的数量的正整数，使得总和m + p + q为约15至约 500。

2. 发明授权

US4828819A Compositions containing bis-(quaternary ammonium) derivatives for the treatment of keratin materials and natural non-keratin or synthetic textile materials 失效
标题翻译：含有用于治疗角蛋白材料和天然非角蛋白或合成纺织材料的双（季铵）衍生物的组合物
公开(公告)号：US4828819A
公开(公告)日：1989-05-09
申请号：US207624
申请日：1988-06-16
申请人： Gerard Land , Serge Forestier
发明人： Gerard Land , Serge Forestier
IPC分类号： C07C233/00 , C07C233/89 , C07C275/14 , C07C307/02 , C07D273/04 , C11D1/62 , C11D3/30 , D06M13/325 , D06M13/467
CPC分类号： A61Q5/12 , A61K8/416 , A61Q5/02 , C07C275/14 , C07D273/04 , D06M13/467 , A61Q5/04 , A61Q5/06 , A61Q5/08 , A61Q5/10 , Y10S424/01 , Y10S424/04 , Y10S514/846 , Y10S514/847 , Y10S514/88 , Y10S514/937 , Y10S514/938 , Y10S514/944 , Y10S514/945
摘要： The composition of the invention comprises, in a medium suitable for the treatment of keratin materials, and natural non-keratin or synthetic textile materials, at least one bis-(quaternary ammonium) derivative having the formula: ##STR1## in which R.sub.1, R.sub.2, R.sub.4 and R.sub.5 are identical or different and denote lower alkyl or lower hydroxyalkyl radicals, R.sub.3 is an alkyl, cycloalkyl, alkenyl, hydroxyalkyl or optionally substituted aralkyl radical containing a maximum of 20 carbon atoms, A.sub.1 and A.sub.2, which are identical or different, represent optionally substituted alkylene or arylene radicals which can contain up to 20 carbon atoms, Z=--SO.sub.2 -- or --CO--.sub.p, in which p=1 or 2, R.sub.6 and R.sub.7, which are identical or different, are hydrogen atoms or lower alkyl radicals, or alternatively, if Z=--CO--.sub.p in which p=1, R.sub.6 and R.sub.7 can together form a group: ##STR2## R.sub.8 and R.sub.9 being hydrogen atoms or lower alkyl radicals, and X.sup..crclbar. denotes an inorganic or organic anion derived from low molecular weight acids.
摘要翻译：本发明的组合物包括在适于治疗角蛋白材料的介质和天然非角蛋白或合成纺织材料中，至少一种具有下式的至少一种双（季铵）衍生物：其中 R1，R2，R4和R5相同或不同，表示低级烷基或低级羟烷基，R3是含有最多20个碳原子的烷基，环烷基，链烯基，羟基烷基或任选取代的芳烷基，A1和A2相同或不同的，表示可以含有至多20个碳原子的任选取代的亚烷基或亚芳基，Z = -SO 2 - 或-CO-p，其中p = 1或2，相同或不同的R 6和R 7是氢原子或低级烷基，或者如果Z = -CO-p，其中p = 1，则R6和R7可以一起形成基团：R 8和R 9是氢原子或低级烷基，X（ - ）表示衍生自低分子量酸的无机或有机阴离子。

3. 发明授权

US4879284A Naphthalene derivatives having retinoid type action, the process for preparation thereof and medicinal and cosmetic compositions containing them 失效
标题翻译：具有类视黄醇作用的萘衍生物，其制备方法和含有它们的药物和化妆品组合物
公开(公告)号：US4879284A
公开(公告)日：1989-11-07
申请号：US2708
申请日：1986-12-05
申请人： Gerard Land , Jean Maignan , Serge Restle , Gerard Malle
发明人： Gerard Land , Jean Maignan , Serge Restle , Gerard Malle
IPC分类号： C07C69/618 , A61K8/00 , A61K8/30 , A61K8/35 , A61K8/36 , A61K8/368 , A61K8/37 , A61K8/41 , A61K8/42 , A61K8/49 , A61K8/67 , A61K31/11 , A61K31/12 , A61K31/16 , A61K31/165 , A61K31/19 , A61K31/215 , A61K31/33 , A61P17/00 , A61P29/00 , A61P37/08 , A61Q5/00 , A61Q5/02 , A61Q7/00 , A61Q17/04 , A61Q19/00 , A61Q19/10 , C07C33/18 , C07C45/00 , C07C45/46 , C07C45/68 , C07C47/23 , C07C47/232 , C07C47/27 , C07C47/277 , C07C49/20 , C07C49/217 , C07C49/223 , C07C49/248 , C07C49/255 , C07C51/00 , C07C51/353 , C07C57/42 , C07C59/52 , C07C59/64 , C07C67/00 , C07C67/343 , C07C69/73 , C07C69/732 , C07C69/734 , C07C69/736 , C07C69/738 , C07C231/12 , C07C233/11 , C07C233/22 , C07C235/34 , C07C235/38 , C07D521/00
CPC分类号： A61Q19/008 , A61K31/19 , A61K31/215 , A61K8/671 , A61Q19/00 , A61Q7/00 , C07C33/18 , C07C45/46 , C07C47/232 , C07C47/27 , C07C47/277 , C07C49/223 , C07C49/248 , C07C49/255 , C07C57/42 , C07C59/64 , A61Q19/10 , A61Q5/02
摘要： The invention relates to a compound of formula: ##STR1## in which formula: R.sub.1 to R.sub.4 denote, independently, H, OH, C.sub.1 -C.sub.6 alkyl or C.sub.1 -C.sub.6 alkoxy; andA denotes --COR.sub.5, R.sub.5 being H when at least one of the substituents R.sub.1 to R.sub.4 is other than H; C.sub.1 -C.sub.6 alkyl; amino; (C.sub.1 -C.sub.6)alkylamino; di(C.sub.1 -C.sub.6) alkylamino; arylamino; benzylamino; amino drived from a cyclic or heterocyclic amine; (--COR.sub.5 being able, when it is an amide group, to be the amide group of an amino acid or of a glucosamine); or alternatively R.sub.5 denotes --OR.sub.6, R.sub.6 being H or (C.sub.1 -C.sub.6)alkyl; C.sub.1 -C.sub.6 mono- or polyhydroxyalkyl, or aryl or benzyl, both optionally substituted; --OR.sub.6 also being able to be derived from a sugar; and the salts and isomers of this compound. The invention also relates to a process for preparing this compound and medicinal and cosmetic compositions containing them.
摘要翻译： PCT No.PCT / FR86 / 00123 Sec。 371日期1986年12月5日第 102（e）日期1986年12月5日PCT申请日1986年4月14日PCT公布。出版物WO86 / 06064 1986年10月23日。本发明涉及下式化合物：其中式R1至R4独立地表示H，OH，C1-C6烷基或C1-C6烷氧基; 并且A表示-COR 5，当至少一个取代基R 1至R 4不是H时，R 5为H; C1-C6烷基; 氨基; （C 1 -C 6）烷基氨基; 二（C1-C6）烷基氨基; 芳基氨基; 苄基氨基; 由环状或杂环胺驱动的氨基; （-COR5当酰胺基时可以是氨基酸或葡糖胺的酰胺基）; 或者R5表示-OR6，R6表示H或（C1-C6）烷基; C1-C6单或多羟基烷基，或芳基或苄基，均为任选取代的; -OR6也可以从糖中衍生出来; 和该化合物的盐和异构体。本发明还涉及一种制备该化合物的方法和含有它们的药物和化妆品组合物。

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