会员体验
专利管家(专利管理)
工作空间(专利管理)
风险监控(情报监控)
数据分析(专利分析)
侵权分析(诉讼无效)
联系我们
交流群
官方交流:
QQ群: 891211   
微信请扫码    >>>
现在联系顾问~
热词
    • 3. 发明授权
    • Polyesters polyols prepared from glutaric acid, succinic acid and adipic
acid, and polyurethanes prepared therefrom
    • 由戊二酸,琥珀酸和己二酸制备的聚酯多元醇和由其制备的聚氨酯
    • US4716213A
    • 1987-12-29
    • US867617
    • 1986-05-27
    • George N. AltounianDaniel Grenier
    • George N. AltounianDaniel Grenier
    • C08G18/42C08G63/12
    • C08G18/4236C08G63/12
    • The preparation of the polyols involves the following steps: (a) introducing in a reactor a mixture of acids comprising about 50 to 70% by weight of glutaric acid, about 15 to 30% by weight of succinic acid and about 10 to 20% by weight of adipic acid, or esters or anhydrides of these acids, with at least one polyhydroxy alcohol selected from the group consisting of secondary alcohols, tertiary alcohols and highly cluttered primary alcohols, with a catalyst selected from the group consisting of stannous and stannic chlorides and alkyl-tin compounds; (b) the reaction mixture is flushed with an inert gas; (c) the reaction mixture is heated while stirring at a temperature which does not exceed about 225.degree. C.; (d) removing 90 to 95% of the water or methanol formed in step (c); (e) introducing into the reactor at least one slightly cluttered primary alcohol; (f) heating at about 225.degree. C. and removing the maximum amount of water or methanol by distillation; (g) ending the reaction by creating a vacuum in the reactor in order to remove all traces of water or methanol in the reaction mixture and continuing this operation until the polyol obtained has an acid value lower than 3, a hydroxyl functionality at least equal to 2.0 and a hydroxyl number lower than 600. Polyols prepared in this manner are also disclosed.
    • 多元醇的制备包括以下步骤:(a)在反应器中将包含约50至70重量%的戊二酸,约15至30重量%的琥珀酸和约10至20重量%的琥珀酸和约10至20重量% 这些酸的己二酸或这些酸的酯或酸酐与至少一种选自仲醇,叔醇和高度杂质的伯醇的多羟基醇与选自亚锡和氯化锡的催化剂和 烷基锡化合物; (b)用惰性气体冲洗反应混合物; (c)将反应混合物在不超过约225℃的温度下搅拌加热; (d)除去步骤(c)中形成的90至95%的水或甲醇; (e)将至少一种稍微混杂的伯醇引入反应器; (f)在约225℃加热并通过蒸馏除去最大量的水或甲醇; (g)通过在反应器中产生真空来终止反应,以便除去反应混合物中的所有痕量的水或甲醇,并继续该操作,直到得到的多元醇的酸值低于3,羟基官能度至少等于 2.0,羟基数低于600.也公开了以这种方式制备的多元醇。