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1. 发明授权

US08314188B2 Process for the continuous hydrogenation of carbon-carbon double bonds in an unsaturated polymer to produce a hydrogenated polymer 有权
标题翻译：在不饱和聚合物中连续氢化碳 - 碳双键以制备氢化聚合物的方法
公开(公告)号：US08314188B2
公开(公告)日：2012-11-20
申请号：US12506510
申请日：2009-07-21
申请人： Garry Rempel , Qinmin Pan , Lifeng Zhang
发明人： Garry Rempel , Qinmin Pan , Lifeng Zhang
IPC分类号： C08F36/00 , C08F236/00 , C08F136/08 , B01J19/18
CPC分类号： C08C19/02 , C08L15/005
摘要： Proposed is a process for the continuous hydrogenation of carbon-carbon double bonds in an unsaturated polymer to produce a hydrogenated polymer, said unsaturated polymer being based on a conjugated diolefin and at least one other copolymerizable monomer, in the presence of a homogeneous or heterogeneous catalyst, wherein said unsaturated polymer, hydrogen and said homogeneous or heterogeneous catalyst is passed through a multistage agitated reactor, comprising a cylindrical, elongated shell having closed ends and separated by baffles into a multiplicity of discrete chambers with access from one chamber to another through concentric circular openings, axially centered with said baffles and a continuous rotatable shaft extending concentric with said baffles within said shell with at least one impeller attached thereto positioned in each chamber, said continuous rotatable shaft and said circular openings providing annular openings and said hydrogenated polymer being withdrawn at the opposite end of the multistage agitated reactor at which the feed is introduced.
摘要翻译：提出了在不饱和聚合物中连续氢化碳 - 碳双键以制备氢化聚合物的方法，所述不饱和聚合物基于共轭二烯烃和至少一种其它可共聚单体，在均相或非均相催化剂存在下，其中所述不饱和聚合物，氢气和所述均相或非均相催化剂通过多级搅拌反应器，其包括具有封闭端并由挡板分隔成多个离散室的圆柱形细长壳体，所述多个离散室室从一个室通过同心圆开口，与所述挡板轴向居中，以及与所述壳体内的所述挡板同心延伸的连续可旋转轴，其中至少一个叶片连接到每个室中，所述连续可旋转轴和所述圆形开口提供环形开口，并且所述氢化聚合物在对手引入进料的多级搅拌反应器的位置端。

2. 发明申请

US20090281248A1 HYDROGENATION OF DIENE-BASED POLYMER LATEX 有权
标题翻译：基于二烯的聚合物的加氢反应
公开(公告)号：US20090281248A1
公开(公告)日：2009-11-12
申请号：US12335978
申请日：2008-12-16
申请人： Qinmin PAN , Garry REMPEL , Zehnli WEI
发明人： Qinmin PAN , Garry REMPEL , Zehnli WEI
IPC分类号： C08F8/04
CPC分类号： C08C19/02
摘要： The present invention relates to a process for the hydrogenation of the carbon-carbon double bonds in a diene-based polymer latex in the absence of any organic solvent by a catalytically active system prepared in-situ based on a first main catalyst component and a secondary water-insoluble catalyst component.
摘要翻译：本发明涉及一种在不存在任何有机溶剂的情况下通过基于第一主要催化剂组分和第二主要催化剂组分原位制备的催化活性体系在二烯基聚合物胶乳中氢化碳 - 碳双键的方法水不溶性催化剂组分。

3. 发明申请

US20090270563A1 HYDROGENATION OF DIENE-BASED POLYMERS 有权
标题翻译：基于二烯的聚合物的氢化
公开(公告)号：US20090270563A1
公开(公告)日：2009-10-29
申请号：US12336062
申请日：2008-12-16
申请人： Qinmin PAN , Garry REMPEL , Jialong WU
发明人： Qinmin PAN , Garry REMPEL , Jialong WU
IPC分类号： C08F8/04
CPC分类号： C08C19/02 , C08F8/04 , C08F297/04
摘要： The present invention relates to a process for the hydrogenation of the carbon-carbon double bonds in diene-based polymers in bulk form by treatment of said diene-based polymer with hydrogen in the presence of an iridium containing catalyst and in the absence of any organic solvent.
摘要翻译：本发明涉及通过在含铱催化剂的存在下用氢处理所述二烯基聚合物并且在没有任何有机物的情况下，以体积方式氢化二烯基聚合物中的碳 - 碳双键的方法溶剂。

4. 发明授权

US08084548B2 Hydrogenation of diene-based polymers 有权
标题翻译：二烯基聚合物的氢化
公开(公告)号：US08084548B2
公开(公告)日：2011-12-27
申请号：US12336062
申请日：2008-12-16
申请人： Qinmin Pan , Garry Rempel , Jialong Wu
发明人： Qinmin Pan , Garry Rempel , Jialong Wu
IPC分类号： C08F8/14
CPC分类号： C08C19/02 , C08F8/04 , C08F297/04
摘要： The present invention relates to a process for the hydrogenation of the carbon-carbon double bonds in diene-based polymers in bulk form by treatment of said diene-based polymer with hydrogen in the presence of an iridium containing catalyst and in the absence of any organic solvent.
摘要翻译：本发明涉及通过在含铱催化剂的存在下用氢处理所述二烯基聚合物并且在没有任何有机物的情况下，以体积方式氢化二烯基聚合物中的碳 - 碳双键的方法溶剂。

5. 发明授权

US07897695B2 Hydrogenation of diene-based polymers 有权
标题翻译：二烯基聚合物的氢化
公开(公告)号：US07897695B2
公开(公告)日：2011-03-01
申请号：US12335927
申请日：2008-12-16
申请人： Qinmin Pan , Garry Rempel , Jialong Wu
发明人： Qinmin Pan , Garry Rempel , Jialong Wu
IPC分类号： C08C19/02 , C08F8/04 , C08F236/12
CPC分类号： C08C19/02
摘要： The present invention relates to a process for the selective hydrogenation of the carbon-carbon double bonds in diene-based polymers in bulk form by treatment of the polymer with hydrogen in the presence of a platinum group metal containing catalyst and in the absence of any organic solvent.
摘要翻译：本发明涉及通过在含有铂族金属的催化剂存在下和在没有任何有机物的情况下用氢处理聚合物来选择氢化二烯基聚合物中的碳 - 碳双键的方法溶剂。

6. 发明授权

US07803883B2 Hydrogenation of diene-based polymer latex 有权
标题翻译：二烯基聚合物胶乳的氢化
公开(公告)号：US07803883B2
公开(公告)日：2010-09-28
申请号：US12336099
申请日：2008-12-16
申请人： Qinmin Pan , Garry Rempel , Zhenli Wei
发明人： Qinmin Pan , Garry Rempel , Zhenli Wei
IPC分类号： C08F8/04
CPC分类号： C08C19/02
摘要： The present invention relates to a process for the selective hydrogenation of the carbon-carbon double bonds in a diene-based polymer latex using a water-soluble catalyst and simultaneously a water-insoluble co-catalyst.
摘要翻译：本发明涉及使用水溶性催化剂和同时使用水不溶性助催化剂选择氢化二烯系聚合物胶乳中的碳 - 碳双键的方法。

7. 发明申请

US20100093932A1 PROCESS FOR THE CONTINUOUS HYDROGENATION OF CARBON-CARBON DOUBLE BONDS IN AN UNSATURATED POLYMER 审中-公开
标题翻译：在不饱和聚合物中碳碳双重连续加氢的方法
公开(公告)号：US20100093932A1
公开(公告)日：2010-04-15
申请号：US12506528
申请日：2009-07-21
申请人： GARRY REMPEL , QINMIN PAN , CHANDRA MOULI MADHURANTHAKAM
发明人： GARRY REMPEL , QINMIN PAN , CHANDRA MOULI MADHURANTHAKAM
IPC分类号： C08F8/04
CPC分类号： C08F236/08 , B01F5/0619 , B01F5/10 , B01F7/18 , B01J10/00 , B01J19/1881 , B01J19/32 , B01J2219/00094 , B01J2219/0011 , B01J2219/00184 , B01J2219/32206 , B01J2219/32262 , B01J2219/32265 , B01J2219/3306 , B01J2219/3322 , C08C19/02 , C08F236/10 , C08F236/12
摘要： Proposed is a process for the continuous hydrogenation of carbon-carbon double bonds in an unsaturated polymer based on a conjugated diolefin and at least one other copolymerizable monomer to produce a hydrogenated polymer, in the presence of a solvent and a homogeneous or heterogeneous catalyst, wherein said unsaturated polymer, said homogeneous or heterogeneous catalyst and hydrogen are passed through a reactor equipped with static internal elements.
摘要翻译：提出了在溶剂和均相或非均相催化剂存在下，基于共轭二烯烃和至少一种其它可共聚单体的不饱和聚合物中碳 - 碳双键的连续氢化生产氢化聚合物的方法，其中所述不饱和聚合物，所述均相或非均相催化剂和氢气通过装有静态内部元件的反应器。

8. 发明申请

US20100093931A1 PROCESS FOR THE CONTINUOUS HYDROGENATION OF CARBON-CARBON DOUBLE BONDS IN AN UNSATURATED POLYMER TO PRODUCE A HYDROGENATED POLYMER 有权
标题翻译：在不饱和聚合物中碳碳双重连续加氢以生产氢化聚合物的方法
公开(公告)号：US20100093931A1
公开(公告)日：2010-04-15
申请号：US12506510
申请日：2009-07-21
申请人： GARRY REMPEL , QINMIN PAN , LIFENG ZHANG
发明人： GARRY REMPEL , QINMIN PAN , LIFENG ZHANG
IPC分类号： C08F136/00 , C08G63/91 , C08F136/08 , C08F136/06 , C08F120/10
CPC分类号： C08C19/02 , C08L15/005
摘要： Proposed is a process for the continuous hydrogenation of carbon-carbon double bonds in an unsaturated polymer to produce a hydrogenated polymer, said unsaturated polymer being based on a conjugated diolefin and at least one other copolymerizable monomer, in the presence of a homogeneous or heterogeneous catalyst, wherein said unsaturated polymer, hydrogen and said homogeneous or heterogeneous catalyst is passed through a multistage agitated reactor, comprising a cylindrical, elongated shell having closed ends and separated by baffles into a multiplicity of discrete chambers with access from one chamber to another through concentric circular openings, axially centered with said baffles and a continuous rotatable shaft extending concentric with said baffles within said shell with at least one impeller attached thereto positioned in each chamber, said continuous rotatable shaft and said circular openings providing annular openings and said hydrogenated polymer being withdrawn at the opposite end of the multistage agitated reactor at which the feed is introduced.
摘要翻译：提出了在不饱和聚合物中连续氢化碳 - 碳双键以制备氢化聚合物的方法，所述不饱和聚合物基于共轭二烯烃和至少一种其它可共聚单体，在均相或非均相催化剂存在下，其中所述不饱和聚合物，氢气和所述均相或非均相催化剂通过多级搅拌反应器，其包括具有封闭端并由挡板分隔成多个离散室的圆柱形细长壳体，所述多个离散腔室从一个室通过同心圆开口，与所述挡板轴向居中，以及与所述壳体内的所述挡板同心延伸的连续可旋转轴，其中至少一个叶片连接到每个室中，所述连续可旋转轴和所述圆形开口提供环形开口，并且所述氢化聚合物在对手引入进料的多级搅拌反应器的位置端。

9. 发明申请

US20090270562A1 HYDROGENATION OF DIENE-BASED POLYMERS 有权
标题翻译：基于二烯的聚合物的氢化
公开(公告)号：US20090270562A1
公开(公告)日：2009-10-29
申请号：US12335927
申请日：2008-12-16
申请人： Qinmin PAN , Garry REMPEL , Jialong WU
发明人： Qinmin PAN , Garry REMPEL , Jialong WU
IPC分类号： C08F8/04
CPC分类号： C08C19/02
摘要： The present invention relates to a process for the selective hydrogenation of the carbon-carbon double bonds in diene-based polymers in bulk form by treatment of the polymer with hydrogen in the presence of a platinum group metal containing catalyst and in the absence of any organic solvent.
摘要翻译：本发明涉及通过在含有铂族金属的催化剂存在下和在没有任何有机物的情况下用氢处理聚合物来选择氢化二烯基聚合物中的碳 - 碳双键的方法溶剂。

10. 发明申请

US20090258996A1 HYDROGENATION OF DIENE-BASED POLYMER LATEX 有权
标题翻译：基于二烯的聚合物的加氢反应
公开(公告)号：US20090258996A1
公开(公告)日：2009-10-15
申请号：US12336099
申请日：2008-12-16
申请人： Qinmin PAN , Garry REMPEL , Zhenli Wei
发明人： Qinmin PAN , Garry REMPEL , Zhenli Wei
IPC分类号： C08C19/02
CPC分类号： C08C19/02
摘要： The present invention relates to a process for the selective hydrogenation of the carbon-carbon double bonds in a diene-based polymer latex using a water-soluble catalyst and simultaneously a water-insoluble co-catalyst.
摘要翻译：本发明涉及使用水溶性催化剂和同时使用水不溶性助催化剂选择氢化二烯系聚合物胶乳中的碳 - 碳双键的方法。

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