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1. 发明申请

US20070037911A1 Adhesive composition and process for adhesion using the adhesive composition 审中-公开
标题翻译：粘合剂组合物和使用粘合剂组合物的粘合方法
公开(公告)号：US20070037911A1
公开(公告)日：2007-02-15
申请号：US11501035
申请日：2006-08-09
申请人： Shinichiro Sugi , Emil Giza , Yuji Kitamura , Kenji Sato
发明人： Shinichiro Sugi , Emil Giza , Yuji Kitamura , Kenji Sato
IPC分类号： C08K3/10
CPC分类号： C09J119/006 , C08F279/02 , C08K3/08 , C08K3/10 , C08L19/00 , C08L51/00 , C08L51/04 , C08L2666/02 , C09J11/04 , C09J151/04
摘要： The present invention provides an adhesive composition exhibiting a great adhesive strength between an adherend and an adhesive composition and providing remarkably improved workability in attaching a sheet of an unvulcanized rubber composition by forming a hardened surface of an adhesive layer comprising the adhesive composition and a process for adhesion using the adhesive. The adhesive composition comprises a conjugated diene-based polymer (A) having at least one functional group having a photo-curable unsaturated hydrocarbon group at a chain end, a polymerizable compound (B), a photopolymerization initiator (C) and at least one of an active energy ray-shielding agent (D1) and a metal and/or metal compound (D2).
摘要翻译：本发明提供一种粘合剂组合物，其在被粘物和粘合剂组合物之间具有很大的粘合强度，并且通过形成包含粘合剂组合物的粘合剂层的硬化表面，并且提供显着提高的未硫化橡胶组合物片的加工性，使用粘合剂粘合。粘合剂组合物包含在链端具有至少一个具有光固化性不饱和烃基的官能团的共轭二烯系聚合物（A），可聚合化合物（B），光聚合引发剂（C）和至少一种活性能量射线屏蔽剂（D1）和金属和/或金属化合物（D2）。

2. 发明授权

US07329693B2 Adhesive composition and method for bonding to rubber 有权
标题翻译：粘合剂组合物和粘合橡胶的方法
公开(公告)号：US07329693B2
公开(公告)日：2008-02-12
申请号：US10478673
申请日：2002-05-22
申请人： Emil Giza , Masaaki Nakamura , Masato Yoshikawa
发明人： Emil Giza , Masaaki Nakamura , Masato Yoshikawa
IPC分类号： C08F2/46
CPC分类号： C09J109/00 , B60C1/00 , B60C9/00 , B60C9/0042 , C08J5/124 , C08J2321/00 , C08K5/17 , C08K5/18 , C08K5/29 , C08K5/34 , C08K5/405 , C09J115/00 , Y10T428/2852 , Y10T428/2883 , Y10T428/31826 , Y10T428/31855
摘要： An adhesive composition of the present invention comprises (A) a conjugated diene polymer having a weight-average molecular weight of 500 to 100,000 and (B) an electron pair-donating basic compound; or comprises (A) a conjugated diene polymer having a weight-average molecular weight of 500 to 100,000, (C) a compound having in its molecule three or more functional groups selected from the group consisting of acryloyloxy group, methacryloyloxy group and groups represented by the following formula I: wherein R1, R2 and m are the same as defined in the specification, and (D) a compound having in its molecule one or two functional groups selected from the group consisting of acryloyloxy group and methacryloyloxy group. At least a part of the surface of an adherend is coated with the adhesive composition to form an adhesive layer. After optionally irradiating the adhesive layer with ultraviolet light or radiation, the vulcanization is preformed while bringing an unvulcanized rubber into press-contact with the adhesive layer, thereby attaining a strong adhesion between the rubber and the adherend. The rubber/adherend composite thus produced is suitably used for the production of rubber-reinforcing materials and rubber articles.
摘要翻译：本发明的粘合剂组合物包含（A）重均分子量为500〜100,000的共轭二烯聚合物和（B）电子对给予碱性化合物; 或者包含（A）重均分子量为500〜100,000的共轭二烯系聚合物，（C）分子中具有选自由丙烯酰氧基，甲基丙烯酰氧基组成的组中的3个以上官能团的化合物和下式I：其中R 1，R 2和m与说明书中所定义的相同，和（D）在其分子中具有一个或两个官能团选自丙烯酰氧基和甲基丙烯酰氧基的基团。粘合剂组合物涂覆被粘物表面的至少一部分以形成粘合剂层。在可选地用紫外线或辐射照射粘合剂层之后，在使未硫化橡胶与粘合剂层压接的同时预硫化，从而在橡胶和被粘物之间获得牢固的粘合。由此制造的橡胶/被粘物组合物适合用于生产橡胶增强材料和橡胶制品。

3. 发明申请

US20120041113A1 ADHESIVE COMPOSITION FOR ORGANIC FIBER CORDS, RUBBER-REINFORCING MATERIAL USING SAME, TIRE AND BONDING METHOD 有权
标题翻译：有机纤维胶粘剂组合物，使用相同的橡胶增强材料，轮胎和粘合方法
公开(公告)号：US20120041113A1
公开(公告)日：2012-02-16
申请号：US13266367
申请日：2010-04-26
申请人： Yuji Ikeda , Emil Giza
发明人： Yuji Ikeda , Emil Giza
IPC分类号： C08K5/1515 , B32B37/12 , B32B37/14 , B32B37/02
CPC分类号： D06M15/693 , C08G18/58 , C08J5/06 , C08J2321/00 , C08K5/1515 , C08K5/29 , C08L9/08 , C08L77/02 , C08L2205/16 , C09J5/00 , C09J109/08 , C09J175/04 , C09J2400/263 , C09J2421/00 , C09J2463/00 , C09J2467/006 , C09J2477/006 , D06M13/11 , D06M13/325 , D06M13/395 , D06M2101/32 , D06M2101/34
摘要： Provided is an adhesive composition for organic fiber cords which does not contain resorcinol and formaldehyde and has a good adhesive property and is good for the environment, particularly for the work environment, and a rubber reinforcing material, a tire and a bonding method using the same. Also provided is an adhesive composition for organic fiber cords which contains (blocked) isocyanate compound and/or amine-based curing agent (A), epoxy compound (B), rubber latex(C), and a rubber reinforcing material, a tire and a bonding method using the same. The ratio of the mass of the (blocked) isocyanate compound and/or amine curing agent (A) a to the mass of the epoxy compound (B) b (the mass of (blocked) isocyanate compound and/or amine curing agent/the mass of epoxy compound), a/b is preferably not smaller than 0.1 and not larger than 30.
摘要翻译：本发明提供一种不含间苯二酚和甲醛的有机纤维帘线用粘合剂组合物，具有良好的粘合性，对环境，特别是对于工作环境良好的粘合剂组合物，橡胶增强材料，轮胎及使用其的粘合方法。还提供了一种含有（封闭的）异氰酸酯化合物和/或胺类固化剂（A），环氧化合物（B），橡胶胶乳（C）和橡胶增强材料的轮胎的有机纤维帘线用粘合剂组合物，使用其的接合方法。（封闭的）异氰酸酯化合物和/或胺固化剂（A）a的质量与环氧化合物（B）b的质量（（封端的）异氰酸酯化合物和/或胺固化剂的质量/ 环氧化合物的质量），a / b优选为0.1以上30以下。

4. 发明授权

US09394647B2 Adhesive composition for organic fiber cords, rubber-reinforcing material using same, tire and bonding method 有权
标题翻译：有机纤维帘线用粘合剂组合物，使用其的橡胶增强材料，轮胎和粘合方法
公开(公告)号：US09394647B2
公开(公告)日：2016-07-19
申请号：US13266367
申请日：2010-04-26
申请人： Yuji Ikeda , Emil Giza
发明人： Yuji Ikeda , Emil Giza
IPC分类号： C08K5/15 , D04H13/00 , D06M15/693 , C08G18/58 , C08J5/06 , C09J5/00 , C09J109/08 , C09J175/04 , D06M13/11 , D06M13/325 , D06M13/395 , C08K5/1515 , C08K5/29 , C08L77/02 , D06M101/32 , D06M101/34
CPC分类号： D06M15/693 , C08G18/58 , C08J5/06 , C08J2321/00 , C08K5/1515 , C08K5/29 , C08L9/08 , C08L77/02 , C08L2205/16 , C09J5/00 , C09J109/08 , C09J175/04 , C09J2400/263 , C09J2421/00 , C09J2463/00 , C09J2467/006 , C09J2477/006 , D06M13/11 , D06M13/325 , D06M13/395 , D06M2101/32 , D06M2101/34
摘要： Provided is an adhesive composition for organic fiber cords which does not contain resorcinol and formaldehyde and has a good adhesive property and is good for the environment, particularly for the work environment, and a rubber reinforcing material, a tire and a bonding method using the same. Also provided is an adhesive composition for organic fiber cords which contains (blocked) isocyanate compound and/or amine-based curing agent (A), epoxy compound (B), rubber latex (C), and a rubber reinforcing material, a tire and a bonding method using the same. The ratio of the mass of the (blocked) isocyanate compound and/or amine curing agent (A) a to the mass of the epoxy compound (B) b (the mass of (blocked) isocyanate compound and/or amine curing agent/the mass of epoxy compound), a/b is preferably not smaller than 0.1 and not larger than 30.
摘要翻译：本发明提供一种不含间苯二酚和甲醛的有机纤维帘线用粘合剂组合物，具有良好的粘合性，对环境，特别是对于工作环境良好的粘合剂组合物，橡胶增强材料，轮胎及使用其的粘合方法。还提供了一种含有（封闭的）异氰酸酯化合物和/或胺类固化剂（A），环氧化合物（B），橡胶胶乳（C）和橡胶增强材料的轮胎的有机纤维帘线用粘合剂组合物，使用其的接合方法。（封闭的）异氰酸酯化合物和/或胺固化剂（A）a的质量与环氧化合物（B）b的质量（（封端的）异氰酸酯化合物和/或胺固化剂的质量/ 环氧化合物的质量），a / b优选为0.1以上30以下。

5. 发明申请

US20070042115A1 Manufacturing method for tire cord and adhesive material for tire cord 审中-公开
标题翻译：轮胎帘线的制造方法和轮胎帘线的粘合材料
公开(公告)号：US20070042115A1
公开(公告)日：2007-02-22
申请号：US10567154
申请日：2004-07-02
申请人： Emil Giza
发明人： Emil Giza
IPC分类号： B05D5/10
CPC分类号： B29D30/40
摘要： There is provided a novel production method for a tire cord capable of suppressing the use of a diluent accompanying the fuming of harmful substances and energy consumption. The production of a tire cord 7 comprising a twisted cord 6 and an adhesive layer for rubber on the surface of the twisted cord 6 is characterized by comprising a step of spraying an adhesive material onto the twisted cord 6 for coating. A coating apparatus 1 can be used. The coating apparatus 1 comprises a plurality of coaters 2 for spraying an adhesive onto the surface of the twisted cord 6. The coater 2 comprises a coating nozzle and a coating guide. The coating apparatus 1 further comprises an interlacer 3, a low speed pump 4 and an adhesive tank 5 filled with the adhesive.
摘要翻译：提供了一种能够抑制伴随有害物质的发烟和能量消耗的稀释剂的使用的轮胎帘线的新型制造方法。在绞合线6的表面上制造包括扭绞线6和橡胶用粘合剂层的轮胎帘线7的特征在于包括将粘合剂材料喷涂到扭绞线6上以进行涂覆的步骤。可以使用涂布装置1。涂覆装置1包括用于将粘合剂喷射到扭绞线6的表面上的多个涂布机2.涂布机2包括涂布喷嘴和涂布引导件。涂布装置1还包括填充有粘合剂的交织器3，低速泵4和粘合剂罐5。

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