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1. 发明授权

US4837361A A process for the preparation of cysteine from cystine 失效
公开(公告)号：US4837361A
公开(公告)日：1989-06-06
申请号：US122725
申请日：1987-11-18
申请人： Shih-Ger Chang , David K. Liu , Elizabeth A. Griffiths , David Littlejohn
发明人： Shih-Ger Chang , David K. Liu , Elizabeth A. Griffiths , David Littlejohn
IPC分类号： B01D53/60
CPC分类号： B01D53/60
摘要： The present invention in one aspect relates to a process for the simultaneous removal of NO.sub.x and SO.sub.2 from a fluid stream comprising mixtures thereof and in another aspect relates to the separation, use and/or regeneration of various chemicals contaminated or spent in the process and which includes the steps of:(A) contacting the fluid stream at a temperature of between about 105.degree. and 180.degree. C. with a liquid aqueous slurry or solution comprising an effective amount of an iron chelate of an amino acid moiety having at least one --SH group;(B) separating the fluid stream from the particulates formed in step (A) comprising the chelate of the amino acid moiety and fly ash;(C) washing and separating the particulates of step (B) with an aqeous solution having a pH value of between about 5 to 8;(D) subsequently washing and separating the particulates of step (C) with a strongly acidic aqueous solution having a pH value of between about 1 to 3;(E) washing and separating the particulates of step (D) with an basic aqueous solution having a pH value of between about 9 to 12;(F) optionally adding additional amino acid moiety, iron (II) and alkali to the aqueous liquid from step (D) to produce an aqueous solution or slurry similar to that in step (A) having a pH value of between about 4 to 12; and(G) recycling the aqueous slurry of step (F) to the contacting zone of step (A).Steps (D) and (E) can be carried out in the reverse sequence, however the preferred order is (D) and then (E).In a preferred embodiment the present invention provides an improved process for the preparation (regeneration) of cysteine from cystine, which includes reacting an aqueous solution of cystine at a pH of between about 9 to 13 with a reducing agent selected from hydrogen sulfide or alkali metal sulfides, sulfur dioxide, an alkali metal sulfite or mixtures thereof for a time and at a temperature effective to cleave and reduce the cystine to cysteine with subsequent recovery of the cysteine.In another preferred embodiment the present invention provides a process for the removal of NO.sub.x, SO.sub.2 and particulates from a fluid stream which includes the steps of (A) injecting into a reaction zone an aqueous solution itself comprising (i) an amino acid moiety selected from those described above; (ii) iron (II) ion; and (iii) an alkali, wherein the aqueous solution has a pH of between about 4 and 11; followed by solids separation and washing as is described in steps (B), (C), (D) and (E) above. The overall process is useful to reduce acid rain components from combustion gas sources.

2. 发明授权

US4732744A Process for the combined removal of SO.sub.2 and NO.sub.x from flue gas 失效
公开(公告)号：US4732744A
公开(公告)日：1988-03-22
申请号：US923541
申请日：1986-10-27
申请人： Shih-Ger Chang , David K. Liu , Elizabeth A. Griffiths , David Littlejohn
发明人： Shih-Ger Chang , David K. Liu , Elizabeth A. Griffiths , David Littlejohn
IPC分类号： B01D53/60 , C01B21/00 , C01B17/00
CPC分类号： B01D53/60
摘要： The present invention in one aspect relates to a process for the simultaneous removal of NO.sub.x and SO.sub.2 from a fluid stream comprising mixtures thereof and in another aspect relates to the separation, use and/or regeneration of various chemicals contaminated or spent in the process and which includes the steps of:(A) contacting the fluid stream at a temperature of between about 105.degree. and 180.degree. C. with a liquid aqueous slurry or solution comprising an effective amount of an iron chelate of an amino acid moiety having at least one --SH group;(B) separating the fluid stream from the particulates formed in step (A) comprising the chelate of the amino acid moiety and fly ash;(C) washing and separating the particulates of step (B) with an aqueous solution having a pH value of between about 5 to 8;(D) subsequently washing and separating the particulates of step (C) with a strongly acidic aqueous solution having a pH value of between about 1 to 3;(E) washing and separating the particulates of step (D) with an basic aqueous solution having a pH value of between about 9 to 12;(F) optionally adding additional amino acid moiety, iron (II) and alkali to the aqueous liquid from step (D) to produce an aqueous solution or slurry similar to that in step (A) having a pH value of between about 4 to 12; and(G) recycling the aqueous slurry of step (F) to the contacting zone of step (A).Steps (D) and (E) can be carried out in the reverse sequence, however the preferred order is (D) and then (E).In another preferred embodiment the present invention provides a process for the removal of NO.sub.x, SO.sub.2 and particulates from a fluid stream which includes the steps of (A) injecting into a reaction zone an aqueous solution itself comprising (i) an amino acid moiety selected from those described above; (ii) iron (II) ion; and (iii) an alkali, wherein the aqueous solution has a pH of between about 4 and 11; followed by solids separation and washing as is described in steps (B), (C), (D) and (E) above. The overall process is useful to reduce acid rain components from combustion gas sources.

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