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1. 发明授权

US4761250A Process for preparing 1,5-diazido-3-nitrazapentane 失效
标题翻译：制备1,5-二叠氮基-3-硝基氮烷的方法
公开(公告)号：US4761250A
公开(公告)日：1988-08-02
申请号：US764048
申请日：1985-08-09
申请人： Milton B. Frankel , Edward F. Witucki
发明人： Milton B. Frankel , Edward F. Witucki
IPC分类号： C07C247/04 , C06B25/34 , C07C67/00 , C07C241/00 , C07C117/00
CPC分类号： C07C247/00
摘要： A process for producing 1,5-diazido-3-nitrazapentane (DANPE) which comprises the steps of nitrating diethanolamine with nitric acid in a halogenated solvent such as methylene chloride to form 1,5-dinitrato-3-nitrazapentane (DINA) as intermediate, solvent transferring such intermediate from the halogenated solvent to dimethylsulfoxide, adding sodium azide to the resulting solution to form DANPE as product, and solvent transferring such product from the dimethylsulfoxide to another halogenated solvent, e.g. methylene chloride. Thus, both DINA intermediate and DANPE product are prepared in solution, and both can also be purified in solution, eliminating the necessity for isolating the neat, hazardous compounds. The DANPE product can be further solvent transferred from the halogenated solvent to ethyl acetate to form an ethyl acetate solution of DANPE, which can be used to furnish the DANPE as an energetic plasticizer, e.g. in the production of gun propellants.
摘要翻译：一种制备1,5-二叠氮基-3-硝基氮烷（DANPE）的方法，其包括在卤化溶剂如二氯甲烷中用硝酸硝化二乙醇胺以形成中间体1,5-二硝基-3-硝基氮烷（DINA）将这样的中间体从卤代溶剂转移到二甲基亚砜中，向所得溶液中加入叠氮化钠以形成DANPE作为产物，以及将这种产物从二甲基亚砜转移到另一种卤化溶剂中的溶剂，例如二氯甲烷。因此，在溶液中制备了DINA中间体和DANPE产品，并且两者都可以在溶液中纯化，从而无需分离纯净的有害化合物。 DANPE产物可以进一步从卤化溶剂转移到乙酸乙酯中以形成DANPE的乙酸乙酯溶液，其可用于提供DANPE作为能量增塑剂，例如，在枪式推进剂的生产中。

2. 发明授权

US4697000A Process for producing polypyrrole powder and the material so produced 失效
标题翻译：聚吡咯粉末的制造方法和如此制造的材料
公开(公告)号：US4697000A
公开(公告)日：1987-09-29
申请号：US883202
申请日：1986-07-08
申请人： Edward F. Witucki , Leslie F. Warren
发明人： Edward F. Witucki , Leslie F. Warren
IPC分类号： H01B1/12 , H01B1/14 , H05K1/09 , H05K3/18 , C07D207/30 , C08G73/20
CPC分类号： H01B1/14 , H01B1/127 , H05K3/188 , H05K1/09
摘要： Production of electrically conductive polypyrrole powder, by treating a liquid pyrrole with a solution of a strong oxidant, capable of oxidizing pyrrole to a pyrrole polymer, and oxidizing the pyrrole by such strong oxidant in the presence of a substantially non-nucleophilic anion and precipitating a conductive polypyrrole powder. The strong oxidant, e.g., Fe.sup.3+ ion, and non-nucleophilic anion, e.g., sulfate or chloride ion, can be derived from a single compound, e.g., FeCl.sub.3 or Fe.sub.2 (SO.sub.4).sub.3. The anion serves as dopant for the polypyrrole. The reaction can be carried out in aqueous solution or in an organic solvent medium, such as acetonitrile.
摘要翻译：通过用能够将吡咯氧化吡咯聚合物的强氧化剂溶液处理液体吡咯，并在基本上不亲核的阴离子存在下用这种强氧化剂氧化吡咯，生产导电聚吡咯粉末，并沉淀导电聚吡咯粉。强氧化剂，例如Fe 3+离子和非亲核阴离子，例如硫酸根离子或氯离子可以衍生自单一化合物，例如FeCl 3或Fe 2（SO 4）3。阴离子用作聚吡咯的掺杂剂。该反应可以在水溶液中或有机溶剂介质如乙腈中进行。

3. 发明授权

US4419286A Azido esters 失效
标题翻译：叠氮酯
公开(公告)号：US4419286A
公开(公告)日：1983-12-06
申请号：US370235
申请日：1982-04-21
申请人： Edward F. Witucki , Joseph E. Flanagan
发明人： Edward F. Witucki , Joseph E. Flanagan
IPC分类号： C06B45/10 , C07C117/00
CPC分类号： C07C247/00 , C06B45/105
摘要： This invention involves the synthesis of a novel family of azido esters and their utilization as energetic plasticizers for advanced solid propellant compositions. This family includes as an illustrative member, the novel compound 6-azidohexyl-6-azidohexanoate.
摘要翻译：本发明涉及一种新型叠氮基家族的合成及其作为高级固体推进剂组合物的高能增塑剂的用途。该家族包括作为说明性成员的新型化合物6-叠氮基己基-6-叠氮基己酸酯。

4. 发明授权

US4379894A Aqueous process for the quantitative conversion of polyepichlorohydrin to glycidyl azide polymer 失效
标题翻译：用于将聚表氯醇定量转化为缩水甘油基叠氮化物聚合物的水性方法
公开(公告)号：US4379894A
公开(公告)日：1983-04-12
申请号：US330405
申请日：1981-12-14
申请人： Milton B. Frankel , Edward F. Witucki , Dean O. Woolery, II
发明人： Milton B. Frankel , Edward F. Witucki , Dean O. Woolery, II
IPC分类号： C08G65/325 , C08G65/24 , C08G65/32
CPC分类号： C08G65/325
摘要： An aqueous process for the quantitative conversion of polyepichlorodrin (PECH) to glycidyl azide polymer (GAP), using a phase transfer catalyst, is disclosed.
摘要翻译：公开了一种使用相转移催化剂将聚氯二烯（PECH）定量转化为缩水甘油基叠氮化物聚合物（GAP）的水性方法。

5. 发明授权

US4147731A Process for nitroform isolation 失效
标题翻译：硝基分离方法
公开(公告)号：US4147731A
公开(公告)日：1979-04-03
申请号：US871904
申请日：1978-01-24
申请人： Milton B. Frankel , Frederick D. Raniere , Wallace W. Thompson , Edward F. Witucki , Dean O. Woolery, II
发明人： Milton B. Frankel , Frederick D. Raniere , Wallace W. Thompson , Edward F. Witucki , Dean O. Woolery, II
IPC分类号： C07C201/16 , C07C76/02
CPC分类号： C07C201/16
摘要： A method of isolating nitroform from a solution of nitric acid, nitroform, and water by adding sulfuric acid and preferentially extracting the nitroform with methylene chloride. The nitroform is then extracted from the methylene chloride solution into water. It is a particular advantage of the present method that no distillations involving nitroform are required.
摘要翻译：一种通过加入硫酸从硝酸，硝基和水溶液中分离硝基的方法，并用二氯甲烷优先萃取硝基。然后将硝基形式从二氯甲烷溶液中提取到水中。本方法的特别优点是不需要涉及硝基的蒸馏。

6. 发明授权

US4141910A Azido compounds 失效
标题翻译：叠氮化合物
公开(公告)号：US4141910A
公开(公告)日：1979-02-27
申请号：US824376
申请日：1977-08-15
申请人： Joseph E. Flanagan , Milton B. Frankel , Edward F. Witucki
发明人： Joseph E. Flanagan , Milton B. Frankel , Edward F. Witucki
IPC分类号： C07C117/00
CPC分类号： C07C247/00
摘要： Organic azide compounds containing other energetic moieties such as fluorodinitro, trinitromethyl, nitramino, and gem-difluoroamino.
摘要翻译：含有其它能量部分如氟二硝基，三硝基甲基，硝基甲基和偕二氟氨基的有机叠氮化合物。

7. 发明授权

US4696835A Process for applying an electrically conducting polymer to a substrate 失效
标题翻译：将导电聚合物施加到基底的方法
公开(公告)号：US4696835A
公开(公告)日：1987-09-29
申请号：US883260
申请日：1986-07-08
申请人： Louis Maus , Edward F. Witucki , Leslie F. Warren
发明人： Louis Maus , Edward F. Witucki , Leslie F. Warren
IPC分类号： H01B1/12 , H01B1/14 , H05K1/09 , H05K3/18 , B05D3/02 , B05D5/12
CPC分类号： H05K3/188 , H01B1/127 , H01B1/14 , H05K1/09
摘要： Production of electrically conductive composite or structural materials comprising a dielectric substrate, e.g. fiberglass fabric, and a layer of a pyrrole polymer on the substrate, by treating the substrate with a solution of a strong oxidant containing a substantially non-nucleophilic anion, e.g. ferric chloride, drying the substrate and exposing the so treated substrate with the vapors of a pyrrole and oxidizing the pyrrole by the strong oxidant and depositing a polypyrrole layer or film on the substrate.
摘要翻译：导电复合材料或包括电介质基底的结构材料的生产。玻璃纤维织物和一层吡咯聚合物，通过用含有基本上非亲核阴离子的强氧化剂的溶液处理底物，例如，氯化铁，干燥基材并用吡咯的蒸气暴露如此处理的底物，并通过强氧化剂氧化吡咯并在基材上沉积聚吡咯层或膜。

8. 发明授权

US4692225A Method of stabilizing conductive polymers 失效
标题翻译：稳定导电聚合物的方法
公开(公告)号：US4692225A
公开(公告)日：1987-09-08
申请号：US883253
申请日：1986-07-08
申请人： Edward F. Witucki , Leslie F. Warren, Jr. , Paul R. Newman
发明人： Edward F. Witucki , Leslie F. Warren, Jr. , Paul R. Newman
IPC分类号： C08G61/12 , C08J5/24 , C08L63/00 , H01B1/12 , H05K1/09 , H05K3/28 , C25B3/00
CPC分类号： H01B1/128 , C08G61/124 , C08J5/24 , C08L63/00 , H01B1/127 , H05K1/09 , H05K3/28 , Y10T428/31511 , Y10T428/31721 , Y10T442/2459 , Y10T442/2992
摘要： A method of stabilizing electrically conductive polymers to hostile environments is disclosed. The method comprises encapsulating the conductive polymer, e.g., polypyrrole or polyaniline, as a powder, a free-standing film or preferably in the form of a composite of a substrate, such as fiberglass fabric, impregnated with the conductive polymer, with a suitable resin, preferably an epoxy resin, as an encapsulating agent. The preferred method involves pre-pregging the fabric of the conductive composite with an epoxy resin and curing the resulting system.
摘要翻译：公开了一种将导电聚合物稳定到恶劣环境的方法。该方法包括将导电聚合物，例如聚吡咯或聚苯胺，作为粉末，独立的薄膜或优选以基材（例如浸渍有导电聚合物的玻璃纤维织物）与合适的树脂，优选环氧树脂，作为包封剂。优选的方法包括用环氧树脂预先导电导电复合材料，并固化所得到的体系。

9. 发明授权

US4432815A Azido fluorodinitro amines 失效
标题翻译：叠氮基二氟硝基胺
公开(公告)号：US4432815A
公开(公告)日：1984-02-21
申请号：US484328
申请日：1983-04-12
申请人： Milton B. Frankel , Edward F. Witucki
发明人： Milton B. Frankel , Edward F. Witucki
IPC分类号： C06B45/10 , C06D5/06
CPC分类号： C07C247/00 , C06B45/10
摘要： This invention involves the synthesis of a novel family of azido fluorodinitro amines and their utilization as energetic plasticizers for advanced solid propellant compositions.
摘要翻译：本发明涉及一种叠氮基氟二硝基胺的新型家族的合成及其作为高级固体推进剂组合物的高能增塑剂的用途。

10. 发明授权

US4432814A Azido esters 失效
标题翻译：叠氮酯
公开(公告)号：US4432814A
公开(公告)日：1984-02-21
申请号：US484735
申请日：1983-04-13
申请人： Edward F. Witucki , Joseph E. Flanagan
发明人： Edward F. Witucki , Joseph E. Flanagan
IPC分类号： C06B45/10 , C06D5/06
CPC分类号： C07C247/00 , C06B45/105
摘要： This invention involves the synthesis of a novel family of azido esters and their utilization as energetic plasticizers for advanced solid propellant compositions. This family includes as an illustrative member, the novel compound 6-azidohexyl-6-azidohexanoate.
摘要翻译：本发明涉及一种新型叠氮基家族的合成及其作为高级固体推进剂组合物的高能增塑剂的用途。该家族包括作为说明性成员的新型化合物6-叠氮基己基-6-叠氮基己酸酯。

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