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    • 1. 发明授权
    • Method of forming antislip surfaces on thermoformed products
    • 在热成型产品上形成防滑表面的方法
    • US5858508A
    • 1999-01-12
    • US776478
    • 1997-04-21
    • Thomas M. SturtevantEdward E. Cullivan
    • Thomas M. SturtevantEdward E. Cullivan
    • B05D5/02B24D3/00B29B11/14B29C51/02B29C51/10B60R13/01B32B9/00
    • B60R13/01B05D5/02B24D3/002B29B11/14B29C51/02B29C51/10B29K2023/065B29K2995/0072B29L2031/3005Y10S264/72Y10T428/23957Y10T428/24355Y10T428/24372Y10T428/2438Y10T428/24405Y10T428/254Y10T428/2998
    • A process for selectively forming an antislip surface on a product thermoformed from a plastic sheet is applied to truck bed liners, for example. The surface of a plastic sheet of HDPE or other thermoplastic material is cleaned and masked, preparing a good molecular bonding surface on the selected surface areas. A sprayable or liquid polymer designed to achieve desired characteristics of hardness and toughness without brittleness, such as a thermosetting elastomeric polymer, is formed into droplets, which are sprayed or otherwise applied onto the exposed surface area. The droplets form a stippled pattern of primarily separate bumps, occupying substantially less than 50% of the exposed area. After partial hardening of the bumps, the plastic sheet is thermoformed to produce the thermoformed product. Thermoforming tightly bonds the droplets to the sheet, hardens the droplets forming macroscopic asperities, increases or enhances the three dimensional surface relief, and explodes some droplets with entrapped air to increase surface roughness.
    • PCT No.PCT / US95 / 09193 Sec。 371日期1997年04月21日 102(e)日期1997年4月21日PCT提交1995年7月19日PCT公布。 公开号WO96 / 03270 日期:1996年2月8日例如,将从塑料片热成型的产品上选择性地形成防滑表面的方法应用于卡车床垫。 HDPE或其他热塑性材料的塑料片的表面被清洁和掩蔽,在所选择的表面区域上制备良好的分子结合表面。 被设计为实现所需硬度和韧性而不脆性的可喷涂或液体聚合物,例如热固性弹性体聚合物,被形成为喷雾或以其它方式施加到暴露的表面区域上的液滴。 液滴形成主要分离的凸起的点状图案,占据显着小于暴露面积的50%。 在凸起部分硬化之后,将塑料片热成型以产生热成型产品。 热成型将液滴紧密地粘合到片材上,硬化形成宏观粗糙度的液滴,增加或增强三维表面浮雕,并且利用夹带的空气爆炸一些液滴以增加表面粗糙度。
    • 2. 发明授权
    • Thermoplastic products having antislip surfaces
    • 具有防滑表面的热塑性产品
    • US06509084B2
    • 2003-01-21
    • US09779059
    • 2000-12-05
    • Thomas M. SturtevantEdward E. Cullivan
    • Thomas M. SturtevantEdward E. Cullivan
    • D06N704
    • B29C51/02B05D5/02B24D3/002B29B11/14B29C51/10B29K2023/065B29K2995/0072B29L2031/3005B60R13/01Y10T428/24355Y10T428/24372Y10T428/24405Y10T428/31
    • Thermoplastic products such as vehicle cargo area liners, floor mats, recreational and playground equipment, cargo pallets, and wet area walking surfaces are provided with an antislip surface treatment. The antislip surface is made up of individual non-interconnected asperities of an antislip polymer material, which do not form a continuous film over the surface of the thermoplastic product. The thermoplastic product is especially made of high density polyethylene. The antislip polymer is preferably a thermoset polymer, and most particularly is a polyurea/isocyanate polymer. The antislip polymer is preferably applied by spraying, and then the product is heat treated at a temperature in the range from 100 to 200° F., or is thermoformed at a temperature in the range from 250 to 550° F. The antislip asperities are durably bonded onto the thermoplastic base material, and provide a significantly increased coefficient of friction. The asperity size, height, and hardness can be controlled by adjusting the processing conditions. The asperities may have an increased surface relief due to a so-called “moth effect” and an increased surface roughness due to cratering as a result of a so-called “volcano effect” in the process using thermoforming.
    • 汽车货物区域衬垫,地板垫,娱乐和游乐场设备,货物托盘和湿区行走表面等热塑性产品设有防滑表面处理。 防滑表面由防滑聚合物材料的单独的非互连的凹凸构成,其在热塑性产品的表面上不形成连续的膜。 热塑性产品特别是由高密度聚乙烯制成。 防滑聚合物优选为热固性聚合物,最特别是聚脲/异氰酸酯聚合物。 防滑聚合物优选通过喷涂施加,然后将产物在100至200°F的温度下进行热处理,或在250至550°F的温度下热成型。防滑粗糙度为 耐久地粘合到热塑性基材上,并提供显着增加的摩擦系数。 通过调整加工条件可以控制粗糙度,高度和硬度。 由于所谓的“飞蛾效应”,由于在使用热成型的方法中所谓的“火山效应”造成的凹坑,表面粗糙度可能增加。
    • 3. 发明授权
    • Method of forming antislip surfaces on thermoformed products
    • 在热成型产品上形成防滑表面的方法
    • US5648031A
    • 1997-07-15
    • US282219
    • 1994-07-28
    • Thomas M. SturtevantEdward E. Cullivan
    • Thomas M. SturtevantEdward E. Cullivan
    • B05D5/02B24D3/00B29B11/14B29C51/02B29C51/10B60R13/01
    • B60R13/01B05D5/02B24D3/002B29B11/14B29C51/02B29C51/10B29K2023/065B29K2995/0072B29L2031/3005Y10S264/72Y10T428/23957Y10T428/24355Y10T428/24372Y10T428/2438Y10T428/24405Y10T428/254Y10T428/2998
    • A process for selectively forming an antislip surface on a product thermoformed from a plastic sheet is applied to truck bed liners, for example. The surface of the plastic sheet of HDPE or other thermoplastic material is cleaned and masked, to prepare a good molecular bonding surface on selected surface areas. A sprayable or liquid polymer selected to achieve desired characteristics of hardness and toughness without brittleness, such as a thermosetting elastomeric polymer, is formed into droplets, which are sprayed or otherwise applied onto the selected surface area. The droplets form a stippled pattern of primarily separate bumps across the selected surface area to be treated, occupying substantially less than 50% of the exposed area. After partial hardening of the bumps, the plastic sheet is thermoformed at thermoforming temperatures to produce the thermoformed product. Thermoforming tightly bonds the bumps or droplets to the thermoplastic sheet material, hardens the droplets forming macroscopic asperities, increases or enhances the three dimensional surface relief, and explodes some droplets with entrapped air to increase surface roughness.
    • 例如,在从塑料片材热成型的产品上选择性地形成防滑表面的方法被应用于卡车床垫。 HDPE或其他热塑性材料的塑料片的表面被清洁和掩蔽,以在选定的表面区域上制备良好的分子结合表面。 选择用于实现所需硬度和韧性而不脆性的可喷涂或液体聚合物,例如热固性弹性体聚合物,被形成为喷雾或以其它方式施加到所选择的表面区域上的液滴。 液滴形成了主要分离的凸块跨越所选择的待处理表面区域的点状图案,占据显着小于暴露面积的50%。 在凸起部分硬化之后,在热成型温度下将塑料片热成型以产生热成型产品。 热成型将凸起或液滴紧密地粘合到热塑性片材上,硬化形成宏观粗糙度的液滴,增加或增强三维表面浮雕,并且利用夹带的空气爆炸一些液滴以增加表面粗糙度。