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    • 5. 发明授权
    • Device and method for producing ammonia from solid urea pellets
    • 从固体尿素颗粒生产氨的装置和方法
    • US07294313B2
    • 2007-11-13
    • US11218255
    • 2005-09-01
    • Eberhard JacobErwin Stiermann
    • Eberhard JacobErwin Stiermann
    • B01J8/02B01J7/00C01C1/08F01N3/08B01D53/34
    • F01N3/2066B01D53/90B01D53/9409B01D2251/2062F01N2610/02F01N2610/12Y02T10/24
    • A device for producing ammonia from urea pellets includes a pellet dispensing device, a pellet accelerator, a pellet shooting channel, and an ammonia reactor having a chamber or zone for shooting in urea pellets and a pellet deflector arranged on an end of the shooting path. The device further includes a urea pellet evaporation device and a hydrolytic catalytic converter. The urea pellets are removed from the reservoir in a regulated number/quantity by a dispensing device and transported to the accelerating device, where the pellets are moved from the pellet shooting channel into the ammonia reactor, where they are broken down into small pieces by impacting a pellet deflector at the end of the shooting path. The pieces are converted into a gas mixture containing ammonia and isocyanic acid by means of a urea evaporation device. The isocyanic acid is subsequently converted into ammonia and carbon dioxide.
    • 用于从尿素颗粒生产氨的装置包括颗粒分配装置,颗粒加速器,颗粒射击通道和具有用于在尿素颗粒中拍摄的室或区域的氨反应器和布置在拍摄路径的端部上的颗粒偏转器。 该装置还包括尿素颗粒蒸发装置和水解催化转化器。 尿素颗粒通过分配装置以规定数量/数量从储存器中取出并运送到加速装置,其中颗粒从颗粒射流通道移动到氨反应器中,在那里它们通过冲击分解成小块 在射击路径尽头的一个小球偏转器。 通过尿素蒸发装置将片状物转化成含有氨和异氰酸的气体混合物。 异氰酸随后转化成氨和二氧化碳。
    • 6. 发明授权
    • Sorptive catalyst for the sorptive and oxidative cleaning of exhaust
gases from diesel engines
    • 用于吸附和氧化清洁柴油发动机废气的吸附催化剂
    • US5591414A
    • 1997-01-07
    • US499674
    • 1995-07-07
    • Eberhard JacobMichael Harris
    • Eberhard JacobMichael Harris
    • B01D53/86B01D53/92B01D53/94B01J20/06B01J23/652B01J27/053B01J27/199F02B3/06B01D53/34F01N3/10
    • B01D53/9481B01D53/944B01J23/6527B01J27/053B01D2255/1021F02B3/06
    • The invention relates to a sorption catalytic converter for the combined chemo-sorptive and oxidative cleaning of diesel engine exhaust gases with a high blocking activity for highly volatile organic exhaust gas components, compounds sorbed on particles, moderately and scarcely volatile organic compounds (SOF), materials with a pungent odor, irritating materials, and ammonia, using an upstream NO.sub.x reducing catalytic converter, with measurable blocking activity for minute high carbon particles, with a high oxidation activity for CO and a restricted oxidation activity for NO and SO.sub.2 with a working range from the ambient temperature to 650.degree. C., comprising a monolithic honeycomb structure having channels adapted for free flow of diesel exhaust gas therethrough of the active mass or of inert carrier material, coated with the active mass, the active mass preferably being composed of V.sub.2 O.sub.5 /WO.sub.3 /MoO.sub.3 mixed oxides borne on sulfatized titanium dioxide, same being doped with platinum metal oxides at a concentration very low in comparison with oxidation catalytic converters, for increasing sorption and oxidation activity. The active mass is employed with 250-1400 g/1 coating composition, whereas for oxidation catalytic converters 50-200 g/1 of coating composition is typical. The significant inhibition of oxidation activity as compared with SO.sub.2 and NO results from a dilution effect (low level of platinum metal; high active mass) and a possible multi-layer structure with a platinum-free or platinum-depleted covering layer. The enhancement of the sorption and oxidation activity is rendered possible by the employment of covering layers with a high pore volume on a honeycomb structure consisting of an active mass whose pore volume is moderately high for reasons of mechanical strength.
    • 本发明涉及用于对高挥发性有机废气组分,吸附在颗粒上的化合物,适度和几乎不挥发的有机化合物(SOF)的高阻塞活性的柴油发动机废气的组合化学吸附和氧化清洁的吸附催化转化器, 使用上游NOx还原催化转化器具有刺激性气味,刺激性物质和氨的材料,对于微小高碳颗粒具有可测量的阻塞活性,对CO具有高氧化活性和对工作范围的NO和SO2具有限制的氧化活性 从环境温度到650℃,包括具有适于自由流动柴油机废气通过其中的活性物质或惰性载体材料的通道的整体蜂窝结构,涂覆有活性物质,活性物质优选由V 2 O 5 / WO3 / MoO3混合氧化物承载在硫酸化二氧化钛上,同时掺杂有铂金属氧化物 与氧化催化转化器相比浓度非常低,用于增加吸附和氧化活性。 活性物质采用250-1400g / l涂料组合物,而对于氧化催化转化器,涂料组合物为50-200g / l是典型的。 与SO2和NO相比,氧化活性的显着抑制是由于稀释效应(铂金属含量低,活性物质浓度高)以及可能的多层结构,而不含铂或铂的覆盖层。 通过在由机械强度的孔隙体积适度高的活性物质组成的蜂窝结构上使用具有高孔体积的覆盖层,可以提高吸附和氧化活性。
    • 7. 发明授权
    • Method of decomposing organic halogen compounds in gaseous phase
    • 在气相中分解有机卤素化合物的方法
    • US4935212A
    • 1990-06-19
    • US353951
    • 1989-05-19
    • Eberhard Jacob
    • Eberhard Jacob
    • B01J27/053
    • B01J27/053
    • A method of decomposing organic halogen compounds including fluorinated hydrocarbons in the gaseous phase on superacid catalysts comprising titanium dioxide, with the formation of carbon doixide and hydrogen halides and particularly hydrolysis of perhalogenated methane derivatives on a sulfated titanium dioxide catalyst, and hydrolysis and oxidation of organic halogen compounds on a catalyst of sulfated copper oxide and sulfated titanium dioxide. The hydrogen halides liberated by the decomposition of the organic halogen compounds can be easily removed by conventional methods such as scrubbing with water.
    • 在包含二氧化钛的超酸催化剂上分解包含氟化烃在内的有机卤素化合物的方法,其形成碳二氮化物和卤化氢,特别是在硫酸化二氧化钛催化剂上水解全卤代甲烷衍生物,以及有机物的水解和氧化 在硫酸铜氧化物和硫酸化二氧化钛的催化剂上的卤素化合物。 通过有机卤素化合物的分解释放的卤化氢可以通过常规方法例如用水洗涤容易地除去。
    • 10. 发明授权
    • Self-igniting internal combustion engine with ether fumigation of the combustion air for vehicles and a method for ether fumigation of the combustion air in a self-igniting internal combustion engine for vehicles
    • 用于车辆燃烧空气的乙醚熏蒸的自燃内燃机和用于车辆的自燃式内燃机中的燃烧空气的醚熏蒸方法
    • US09261053B2
    • 2016-02-16
    • US12735833
    • 2009-07-08
    • Eberhard Jacob
    • Eberhard Jacob
    • F02D19/06F02M25/07F01N5/02F02B3/06F02B29/04
    • F02D19/06F01N5/02F01N2240/02F02B3/06F02B29/0425F02M26/05F02M26/25F02M26/28F02M26/35F02M26/36F02M26/44Y02T10/121Y02T10/16
    • The invention relates to a self-igniting internal combustion engine (10) with ether fumigation of the combustion air for vehicles, wherein to provide for ether fumigation, a feed means (1, 2, 3) is provided for an alkanol fuel in the flow direction, an exhaust gas heat exchanger (4) is provided for cooling a portion of the exhaust gas arising from the firing of the internal combustion engine (10) and for vaporizing the alkanol fuel fed while at the same time absorbing the thermal energy to be dissipated during cooling of the exhaust gas, and a catalyst (5) is provided for dehydrating the evaporated alkanol fuel to form ether, and wherein the feed means (1, 2, 3), the exhaust gas heat exchanger (4) and the catalyst (5) are connected to the combustion chamber of the internal combustion engine (10) and adapted in such a way that a portion of the fuel required to fire the internal combustion engine (10) can be fed to the combustion chamber of the internal combustion engine (10) by way of the ether fumigation of the combustion air while mixing in the exhaust gas cooled in the exhaust gas heat exchanger (4). The invention further relates to a method for ether fumigation of the combustion air in a self-igniting internal combustion engine for vehicles.
    • 本发明涉及一种具有用于车辆的燃烧空气的乙醚熏蒸的自燃内燃机(10),其中为了提供乙醚熏蒸,为流体中的链烷醇燃料提供了进料装置(1,2,3) 提供排气热交换器(4),用于冷却由内燃机(10)的燃烧产生的一部分废气,并使进料的烷醇燃料汽化,同时吸收热能即可 在排气的冷却期间消散,并且提供催化剂(5),用于使蒸发的链烷醇燃料脱水以形成醚,并且其中进料装置(1,2,3),排气热交换器(4)和催化剂 (5)连接到内燃机(10)的燃烧室,并且适于使得内燃机(10)所需的一部分燃料可以被供给到内燃机的燃烧室 发动机(10) 同时在排气热交换器(4)中冷却的排气中混合燃烧空气。 本发明还涉及一种用于车辆的自燃式内燃机中的助燃空气醚熏蒸的方法。