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    • 7. 发明授权
    • Method for achieving a highly reliable oxide film
    • 实现高可靠性氧化膜的方法
    • US5591681A
    • 1997-01-07
    • US253771
    • 1994-06-03
    • Dirk J. WristersDim-Lee KwongH. Jim Fulford, Jr.
    • Dirk J. WristersDim-Lee KwongH. Jim Fulford, Jr.
    • C23C16/56H01L21/28H01L21/318H01L21/324H01L21/336H01L21/8247H01L29/51H01L29/78H01L29/788H01L29/792H01L21/3115
    • H01L21/28185C23C16/56H01L27/11521H01L27/11524H01L29/518H01L21/28194H01L21/28202H01L21/28211Y10S438/909Y10S438/954
    • High quality oxides utilized in tunnel oxides and CMOS gate oxides are formed using a process that includes annealing a semiconductor substrate, after the oxide has been formed, in an ambient comprised of NO to form a surface layer in the oxide containing a concentration of nitrogen. A high-quality tunnel oxide, suitable for EEPROM devices, is formed upon a surface region of a semiconductor body over a heavily-doped N+ layer by first oxidizing the semiconductor body to form an oxide upon the surface region of the semiconductor body over the heavily-doped N+ layer. Next, the semiconductor body is annealed, under a gettering ambient, to densify the oxide and to dope the oxide at its surface and for a portion thereinto near its surface with a gettering agent. The semiconductor body is then oxidized, under an oxidizing ambient, to thicken the oxide. The annealing step in NO improves characteristics for both the gate and tunnel oxides of the device at a temperature substantially reduced from prior art methods and in an ambient atmosphere containing significantly more NO. The NO anneal can be performed in a variety of ways including an RTP anneal, a furnace anneal and can be performed on processes where the oxides are formed using CVD and PECVD.
    • 在隧道氧化物和CMOS栅极氧化物中使用的高质量氧化物使用包括在形成氧化物的氧化物在由NO组成的环境中退火半导体衬底以在含有一定浓度的氮的氧化物中形成表面层的工艺来形成。 通过首先氧化半导体体以在半导体主体的表面区域上形成氧化物,在重掺杂的N +层上的半导体本体的表面区域上形成适用于EEPROM器件的高品质隧道氧化物, 掺杂的N +层。 接下来,在吸气环境下,将半导体本体退火以使氧化物致密化并在其表面上掺杂氧化物,并在其表面附近用吸杂剂掺杂一部分。 然后在氧化环境下氧化半导体体,使氧化物变稠。 NO中的退火步骤在从现有技术方法显着降低的温度下和在含有显着更多的NO的环境气氛中改善器件的栅极和隧道氧化物的特性。 NO退火可以以各种方式进行,包括RTP退火,炉退火,并且可以在使用CVD和PECVD形成氧化物的工艺上进行。