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    • 1. 发明授权
    • Organosilicone having a carboxyl functional group thereon
    • 在其上具有羧基官能团的有机硅氧烷
    • US06565837B2
    • 2003-05-20
    • US09850302
    • 2001-05-07
    • Dennis L. FostAbe Berger
    • Dennis L. FostAbe Berger
    • A61K706
    • C08G77/388C08G77/392
    • A method for producing polysiloxane compositions, including an amphoteric class of organosilicone compositions, is provided. The polysiloxane compositions are characterized as having the formula: wherein: R1, which can be the same or different, is selected from R2, an amine or diamine containing group of the formula —F1—Bn3—F—NH2, —OR11, and at least one pyrrolidone-containing functional carboxyl group of the general formula: wherein R5 is hydrogen, lower alkyl (C1-6) or alkali metal; F1 is linear or branched alkylene; F is linear or branched alkylene of 1-10 carbon atoms; n2 is 0 or 1, B is —NR9, wherein R9 is hydrogen or lower alkyl (C1-6); R11 is hydrogen or lower alkyl (C1-6), R2 can be the same or different and is selected from alkyl, aryl or olefinic; R3 and R4, which may be the same or different are selected from alkyl, aryl, capped or uncapped polyoxyalkylene, alkaryl, aralkylene or alkenyl; a is an integer from 0 to 50,000; and b is an integer from 0 to 100.
    • 提供了一种制备包括两性类有机硅组合物的聚硅氧烷组合物的方法。 聚硅氧烷组合物的特征在于具有下式:其中:R 1可以相同或不同,选自R 2,含有式-F 1 -Bn 3 -F-NH 2,-OR 11的胺或二胺基团,并且在 含有以下通式的至少一种含吡咯烷酮的官能羧基:其中R5是氢,低级烷基(C1-6)或碱金属; F1是直链或支链亚烷基; F是1-10个碳原子的直链或支链亚烷基; n2为0或1,B为-NR9,其中R9为氢或低级烷基(C1-6); R 11为氢或低级烷基(C 1-6),R 2可以相同或不同,选自烷基,芳基或烯基; R3和R4可以相同或不同,选自烷基,芳基,封端或未封端的聚氧化烯,烷芳基,亚芳基或烯基; a为0〜50,000的整数; b为0〜100的整数。
    • 3. 发明授权
    • Organosilicone having a carboxyl functional group thereon
    • 在其上具有羧基官能团的有机硅氧烷
    • US5817730A
    • 1998-10-06
    • US651730
    • 1996-05-22
    • Abe BergerDennis L. Fost
    • Abe BergerDennis L. Fost
    • C08G77/388C08G77/392C08G77/04
    • C08G77/388C08G77/392
    • A polysiloxane composition including an amphoteric class of organosilicone composition is provided having the formula: ##STR1## wherein: R.sub.1, which can be the same or different, is selected from R.sub.2, a diamine containing group of the forumula --F.sub.1 --B--F--NH.sub.3 and at least one pyrrolidone-containing functional carboxyl group of the general formula: ##STR2## wherein R.sub.5 is hydrogen, lower alkyl (C.sub.1-6) or alkali metal; F.sub.1 is linear or branched alkylene; F is linear or branched alkylene of 1-10 carbon atoms; B is --NR.sub.9, wherein R.sub.9 is hydrogen or lower alkyl (C.sub.1-6); R.sub.2 can be the same or different and is selected from alkyl, aryl or olefinic; R.sub.3 and R.sub.4, which may be the same or different are selected from alkyl, aryl, capped or uncapped polyoxyalkylene, alkaryl, aralkylene or alkenyl; a is an integer from 0 to 50,000; and b is an integer from 0 to 100.
    • 提供了包含两性类有机硅氧烷组合物的聚硅氧烷组合物,其具有下式:其中:R1可相同或不同,选自R2,含二氟甲基的基团-F 1-BF-NH 3基团和 至少一种具有以下通式的含吡咯烷酮的官能羧基:其中R 5是氢,低级烷基(C 1-6)或碱金属; F1是直链或支链亚烷基; F是1-10个碳原子的直链或支链亚烷基; B是-NR 9,其中R 9是氢或低级烷基(C 1-6); R2可以相同或不同,并且选自烷基,芳基或烯属; R3和R4可以相同或不同,选自烷基,芳基,封端或未封端的聚氧化烯,烷芳基,亚芳基或烯基; a为0〜50,000的整数; b为0〜100的整数。
    • 7. 发明授权
    • Organosilicone having a carboxyl functional group thereon
    • 在其上具有羧基官能团的有机硅氧烷
    • US06228967B1
    • 2001-05-08
    • US09167167
    • 1998-10-06
    • Dennis L. FostAbe Berger
    • Dennis L. FostAbe Berger
    • C08G7704
    • C08G77/392C08G77/388
    • Polysiloxane composition is provided having the formula: wherein: R1, which can be the same or different, is selected from R2, an amine containing group of the formula —(CH2)n—Fn1—Bn2F—NH2 or a functional group of the general formula: wherein at least one R1 is a pyrrolidone-containing ester or amide functional group as shown; R5 is hydrogen, alkyl or polyoxyalkylene; D is oxygen or nitrogen, x is 1 or 2, F is linear or branched alkylene; B is —NR9, oxygen or sulfur, wherein R9 is hydrogen or lower alkyl (C1-6); R2 can be the same or different and is selected from alkyl, aryl, alkenyl or alkeynyl; R3 and R4, which may be the same or different are selected from alkyl, aryl, capped or uncapped polyoxyalkylene, alkaryl, aralkylene or alkenyl; a is an integer from 0 to 50,000; and b is an integer from 0 to 100.
    • 提供具有下式的聚硅氧烷组合物:其中:可以相同或不同的R 1选自式R 2,式 - (CH 2)n -Fn1-Bn2F-NH 2的含胺基团或一般的官能团 式:其中至少一个R 1是所示的含吡咯烷酮的酯或酰胺官能团; R 5是氢,烷基或聚氧化烯; D为氧或氮,x为1或2,F为直链或支链亚烷基; B是-NR 9,氧或硫,其中R 9是氢或低级烷基(C 1-6); R 2可以相同或不同,并且选自烷基,芳基,烯基或烷基; R3和R4可以相同 或不同的选自烷基,芳基,封端或未封端的聚氧化烯,烷芳基,芳烷基或烯基; a为0至50,000的整数; 和b是从0到100的整数。
    • 9. 发明授权
    • Silicone modified phospholipid compositions
    • 硅氧烷改性磷脂组合物
    • US5688496A
    • 1997-11-18
    • US630177
    • 1996-04-10
    • Dennis L. FostAbe Berger
    • Dennis L. FostAbe Berger
    • A61K8/55A61K8/896A61Q5/00A61Q5/02A61Q19/00C07F9/10C08G77/388C08G77/392C08G77/395A61K7/06
    • C08G77/395A61K8/553A61K8/896A61Q19/00A61Q5/00C07F9/10C08G77/388C08G77/392A61K2800/57A61Q5/02Y10S514/844
    • A cosmetic composition for the care of skin and hair is provided which contains from 0.1% to 10% of a silicone-containing phospholipid composition having the general formula: ##STR1## wherein: A is selected from H, M or R--Y--; A.sub.1 is selected from H, OH, OM or R--Y--O--; M is a cation; Y is alkylene or substantially alkylene; x is 0 or an integer from 1-5; and R is a quaternized organosilicone amidoamine reactant moiety of the formula: ##STR2## wherein: R.sub.10 is the silicone backbone chain to which at least one pyrrolidone containing amidoamine functional group is attached; R.sub.6 is hydrogen or alkyl, hydroxyalkyl or alkenyl of up to 6 carbon atoms each, cycloalkyl of up to 6 carbon atoms, or polyoxyalkylene of up to 10 carbon atoms within the oxyalkylene unit; R.sub.7 and R.sub.8 are selected from alkyl, hydroxyalkyl, carboxyalkyl of up to 6 carbon atoms in each alkyl moiety and polyoxyalkylene of up to 10 carbon atoms; F is linear or branched alkylene of 1-12 carbon atoms; X.sup.- is an anion; n is 0 or 2; n.sup.1 is 0 or 1; n.sup.2 is 0 or 1; n.sup.3 is an integer from 2 to 12. B is --NR.sub.11 sulfur or oxygen, wherein R11 hydrogen or lower alkyl (C.sub.1-6); with the proviso that when n.sup.1 is 0 and n.sup.2 is 1, n.sup.1 is 1, when n is 2 and n.sup.2 is 1, n.sup.1 is 0 or 1 and when n is 2 and n.sup.2 is 0, n.sup.1 is 0; and; d is one or greater.
    • 提供了用于护理皮肤和毛发的化妆品组合物,其含有0.1%至10%的具有以下通式的含硅氧烷的磷脂组合物:其中:A选自H,M或R-Y-; A1选自H,OH,OM或R-Y-O-; M是阳离子; Y是亚烷基或基本上亚烷基; x为0或1-5的整数; R是具有下式的季铵化有机硅酰氨基胺反应物部分:其中:R 10是至少一个含有酰胺基胺官能团的吡咯烷酮所连接的硅氧烷主链; R6是氢或至多6个碳原子的烷基,羟基烷基或烯基,至多6个碳原子的环烷基,或氧化烯单元中至多10个碳原子的聚氧化烯; R7和R8选自烷基部分中最多6个碳原子的烷基,羟基烷基,羧基烷基和至多10个碳原子的聚氧化烯; F是1-12个碳原子的直链或支链亚烷基; X-是阴离子; n为0或2; n1为0或1; n2为0或1; n 3是2至12的整数.B是-NR 11硫或氧,其中R 11氢或低级烷基(C 1-6); 条件是当n1为0且n2为1时,n1为1,当n为2,n2为1时,n1为0或1,当n为2,n2为0时,n1为0; 和; d是一个或多个。
    • 10. 发明授权
    • Synthetic detergent bars and method of making the same
    • 合成洗涤剂条及其制造方法
    • US5543072A
    • 1996-08-06
    • US332457
    • 1994-10-31
    • Dennis L. FostJoseph A. KomorMario Novakovic
    • Dennis L. FostJoseph A. KomorMario Novakovic
    • C11D1/12C11D1/37C11D3/20C11D17/00C11D9/32C11D1/28
    • C11D3/2079C11D1/37C11D17/006C11D1/123C11D1/126
    • There is provided a mild detergent toilet bar (syndet bar) composition containing from at least 25 percent up to about 65 percent by weight of synthetic surface active agents, which lathers, foams and wears well, exhibits minimal slushing and curd-forming properties in all types of water, possesses good plasticity and tactile properties while also being mild and non-injurious to the user's skin and readily processed with conventional soap-making equipment. The syndet bar compositions containa) from about 15 to 35 percent by weight of acyl esters of isethionic acid salts;b) at least one sulfosuccinate in an amount from about 10 to about 30 percent by weight wherein the weight ratio of said acyl isethionate esters to sulfosuccinate is 0.5:1 to 2:1;c) free fatty acid in an amount from about 25 to 40 percent by weight;d) at least two percent up to about 10 percent by weight of an organic hydrophilic agent;e) an organic binder/filler in an amount from about five percent up to about 20 percent by weight; andf) Water in an amount from about two to 10 percent by weight.
    • 提供了一种温和的洗涤剂马桶条(合成条)组合物,其含有至少25重量%至约65重量%的合成表面活性剂,其起泡,泡沫和磨损良好,表现出最小的冲洗和凝乳形成性能 水的类型具有良好的可塑性和触觉性,同时对使用者的皮肤也是轻度且无害的,并且可以用传统的肥皂设备进行加工。 合成棒组合物含有a)约15至35重量%的羟乙磺酸盐的酰基酯; b)至少一种量为约10至约30重量%的磺基琥珀酸盐,其中所述酰基羟乙基磺酸酯与磺基琥珀酸酯的重量比为0.5:1至2:1; c)游离脂肪酸的量为约25至40重量%; d)有机亲水剂的至少2重量%至多约10重量% e)约5重量%至约20重量%的有机粘合剂/填料; 和f)约2至10重量%的水。