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    • 1. 发明授权
    • Preparation of 4,4'-dihydroxy-alpha-alkylstilbenes and
4,4'-dihydroxy-alpha, alpha'-dialkylstilbenes
    • 制备4,4'-二羟基-α-烷基茋和4,4'-二羟基-α,α'-二烷基茋
    • US5414150A
    • 1995-05-09
    • US162517
    • 1993-12-03
    • Robert E. Hefner, Jr.Maria I. VillarrealDavid A. Carr
    • Robert E. Hefner, Jr.Maria I. VillarrealDavid A. Carr
    • C07C37/20C07C39/215
    • C07C39/215C07C37/20
    • 4,4'-Dihydroxy-alpha-alkylstilbenes of high purity are prepared by reacting at a temperature of from about -20.degree. C. to about 20.degree. C. a mixture of (1) at least one alpha-haloketone, (2) at least one phenolic hydroxyl-containing compound or alkoxy-containing aromatic compound, and (3) at least one strong protonic acid or Lewis acid; such that the mole ratio of phenolic hydroxyl-containing compound or alkoxy-containing aromatic compound:alpha-haloketone(s) is from 0.1:1 to 1.9:1, and the mole ratio of phenolic hydroxyl-containing compound or alkoxy-containing aromatic compound:alpha-haloketone(s):strong protonic acid or Lewis acid is from about 0.1:1:0.0026 to about 1.9:1:0.95. The high purity 4,4'-dihydroxy-alpha-alkylstilbenes are useful for the advancement of epoxy resins, for the preparation of phenoxy resins and for the preparation of epoxy resins.
    • 通过在约-20℃至约20℃的温度下反应制备(1)至少一种α-卤代酮的混合物,(2)至少一种α-卤代酮, 至少一种含酚羟基的化合物或含烷氧基的芳族化合物,和(3)至少一种强质子酸或路易斯酸; 使得含酚羟基的化合物或含烷氧基的芳族化合物:α-卤代酮的摩尔比为0.1:1至1.9:1,并且含酚羟基的化合物或含烷氧基的芳族化合物的摩尔比 :α-卤代酮:强质子酸或路易斯酸为约0.1:1:0.0026至约1.9:1:0.95。 高纯度4,4'-二羟基-α-烷基芪可用于环氧树脂的前进,苯氧基树脂的制备和环氧树脂的制备。
    • 3. 发明申请
    • LIGHT BEAM GUIDED LIQUID DELIVERY DEVICE
    • 光束引导液体输送装置
    • US20130315797A1
    • 2013-11-28
    • US13955789
    • 2013-07-31
    • David A. CARRJennifer W. WELLER
    • David A. CARRJennifer W. WELLER
    • B01L3/02F21V21/30
    • B01L3/021A61B90/13A61B90/30F21V21/30F21V33/0084Y10T29/49959
    • A light beam guided liquid delivery device, including: a liquid delivery device; a light beam generator; and a bracket coupling the light beam generator to the liquid delivery device such that a beam of light is selectively delivered approximate to a tip of the liquid delivery device. The bracket couples the light beam generator to the liquid delivery device at a first attachment point. The bracket includes one or more hinges at the first attachment point for varying the orientation of the light beam generator. Optionally, the bracket also couples the light beam generator to the liquid delivery device at a second contact point. The bracket includes a support member at the second contact point for varying the orientation of the light beam generator. Optionally, the support member is translatable with respect to the one or more hinges along a length of the bracket.
    • 一种光束引导液体输送装置,包括:液体输送装置; 光束发生器; 以及将光束发生器耦合到液体输送装置的支架,使得光束被选择性地输送到液体输送装置的尖端。 支架将光束发生器连接到第一附接点处的液体输送装置。 支架包括在第一附接点处的一个或多个铰链,用于改变光束发生器的取向。 可选地,托架还在第二接触点处将光束发生器耦合到液体输送装置。 支架包括在第二接触点处的用于改变光束发生器的取向的支撑构件。 可选地,支撑构件可相对于沿支架的长度的一个或多个铰链平移。
    • 4. 发明授权
    • Process for preparing and recovering 4,4'-dihydroxy-alpha-alkylstilbene
or 4,4'-dihydroxy-alpha, alpha'dialkylstilbene
    • US5723693A
    • 1998-03-03
    • US713906
    • 1996-09-13
    • Robert E. Hefner, Jr.David A. Carr
    • Robert E. Hefner, Jr.David A. Carr
    • C07C37/20C07C39/215
    • C07C37/20C07C37/002C07C37/84
    • A process for preparing a 4,4'-dihydroxy-alpha-alkylstilbene or 4,4'-dihydroxy-alpha,alpha'-dialkylstilbene which includes the steps of (A) reacting at a temperature of from -20.degree. C. to 20.degree. C. a mixture of: (1) at least one alpha-haloketone; (2) at least one compound containing one phenolic hydroxyl group or aromatic alkoxy group per molecule such that the mole ratio of phenolic hydroxyl group-containing or aromatic alkoxy group-containing compound(s):alpha-haloketone(s) is at least 0.1:1; and (3) either (a) at least one strong protonic acid or (b) at least one Lewis acid, or (c) any combination thereof; thereby forming a reaction product containing at least one halogen-containing bisphenol compound which, upon being dehydrohalogenated, forms a 4,4'-dihydroxy-alpha-alkylstilbene or 4,4'-dihydroxy-alpha, alpha'-dialkylstilbene; (B) reducing the acid content of the product resulting from step (A) to less than 10,000 ppm; (C) dehydrohalogenating the product obtained from step (B), thereby forming a dehydrohalogenated product containing 4,4'-dihydroxy-alpha-alkylstilbene or 4,4'-dihydroxy-alpha,alpha'-dialkylstilbene; (D) adding water to the product of step (C) in amounts sufficient to crystallize at least a portion of the, 4,4'-dihydroxy-alpha-alkylstilbene or 4,4'-dihydroxy-alpha,alpha'-dialkylstilbene and recovering the crystals and the remaining organic phase separately; (E) independently repeating steps (A), (B), and (C) to obtain a dehydrohalogenated product; (F) mixing at least a portion of organic phase obtained in step (D) with the product obtained in step (E); and (G) adding water to the mixture obtained in step (F) in amounts sufficient to crystallize at least a portion of the 4,4'-dihydroxy-alpha-alkylstilbene or 4,4'-dihydroxy-alpha,alpha'-dialkylstilbene and recovering the crystals.
    • 5. 发明授权
    • Preparation of 4,4'-dihydroxy-alpha'-dialkylstilbenes and 4,
4'-dihydroxy-alpha'-dialkylstilbenes
    • 4,4'-二羟基-α'-二烷基茋和4,4'-二羟基-α'-二烷基茋的制备
    • US5475155A
    • 1995-12-12
    • US374282
    • 1995-01-18
    • Robert E. Hefner, Jr.Maria I. VillarrealDavid A. Carr
    • Robert E. Hefner, Jr.Maria I. VillarrealDavid A. Carr
    • C07C37/20C07C39/215
    • C07C39/215C07C37/20
    • 4,4'-Dihydroxy-alpha-alkylstilbenes of high purity are prepared by reacting at a temperature of from about -20.degree. C. to about 20.degree. C. a mixture of (1) at least one alpha-haloketone, (2) at least one phenolic hydroxyl-containing compound or alkoxy-containing aromatic compound, and (3) at least one strong protonic acid or Lewis acid; such that the mole ratio of phenolic hydroxyl-containing compound or alkoxy-containing aromatic compound:alpha-haloketone(s) is from 0.1:1 to 1.9:1, and the mole ratio of phenolic hydroxyl-containing compound or alkoxy-containing aromatic compound:alpha-haloketone(s):strong protonic acid or Lewis acid is from about 0.1:1:0.0026 to about 1.9:1:0.95. The high purity 4,4'-dihydroxy-alpha-alkylstilbenes are useful for the advancement of epoxy resins, for the preparation of phenoxy resins and for the preparation of epoxy resins.
    • 通过在约-20℃至约20℃的温度下反应制备(1)至少一种α-卤代酮的混合物,(2)至少一种α-卤代酮, 至少一种含酚羟基的化合物或含烷氧基的芳族化合物,和(3)至少一种强质子酸或路易斯酸; 使得含酚羟基的化合物或含烷氧基的芳族化合物:α-卤代酮的摩尔比为0.1:1至1.9:1,并且含酚羟基的化合物或含烷氧基的芳族化合物的摩尔比 :α-卤代酮:强质子酸或路易斯酸为约0.1:1:0.0026至约1.9:1:0.95。 高纯度4,4'-二羟基-α-烷基芪可用于环氧树脂的前进,苯氧基树脂的制备和环氧树脂的制备。