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1. 发明申请

US20070093624A1 Catalysts for polymerizing cyclic olefin 有权
标题翻译：用于聚合环烯烃的催化剂
公开(公告)号：US20070093624A1
公开(公告)日：2007-04-26
申请号：US11542166
申请日：2006-10-04
申请人： Young Chung , Il Jung , Sung Chun , Young Park , Sung Yoon , TaeSun Lim , Jungmin Lee , Dai Choi
发明人： Young Chung , Il Jung , Sung Chun , Young Park , Sung Yoon , TaeSun Lim , Jungmin Lee , Dai Choi
IPC分类号： C08F4/80
CPC分类号： C07F15/006 , C08F4/7034 , C08F4/80
摘要： Provided is a metal catalyst complex for preparing a cyclic olefin-based polymer by addition polymerization of a cyclic olefin-based monomer, which is represented by Formula 1 below: [M(L1)x(L′2)y(L3)z]a[Ani]b wherein M is a Group X metal; [M(L1)x(L′2)y(L3)z] is a cationic precatalyst; L1 is an anionic hydrocarbyl-containing ligand; L′2 is a neutral ligand; L3 is an N-heterocyclic carbene ligand; [Ani] is an anion capable of weakly coordinating with the metal M; x is 1 or 2; y is 0 to 4; z is 1 or 2; 2≦x+y+z≦6; a and b are each 1 to 10. The metal catalyst complex has an N-heterocyclic carbene ligand, and thus, is excellent in thermal stability and reactivity.
摘要翻译：本发明提供一种通过下述式1表示的环状烯烃系单体的加成聚合制备环状烯烃系聚合物的金属催化剂配合物：＆lt;线内配方说明=“在线式”末端= “铅”？> [M（L 1）（L'2 ）（L _{（L 3）（L 3 >）Z是阳离子预催化剂; L 1是含阴离子烃基的配体; L'2是中性配体; L 3是N-杂环卡宾配体; [Ani]是能够与金属M弱配位的阴离子; x为1或2; y为0〜4; z为1或2; 2 <= x + y + z <= 6; a和b各自为1〜10。金属催化剂配合物具有N-杂环卡宾配体，因此具有优异的热稳定性和反应性。}

2. 发明申请

US20060058477A1 Catalyst system for polymerizing cyclic olefin having polar functional group, polymerizing method using the catalyst system, olefin polymer produced by the method and optical anisotropic film comprising the olefin polymer 有权
标题翻译：用于聚合具有极性官能团的环烯烃的催化剂体系，使用催化剂体系的聚合方法，通过该方法制备的烯烃聚合物和包含烯烃聚合物的光学各向异性膜
公开(公告)号：US20060058477A1
公开(公告)日：2006-03-16
申请号：US11227093
申请日：2005-09-16
申请人： Sung Yoon , Young Won , Young Park , Sung Chun , Dai Choi , Won Kim , Taesun Lim , Heon Kim , Jung Lee , Kyung Paik
发明人： Sung Yoon , Young Won , Young Park , Sung Chun , Dai Choi , Won Kim , Taesun Lim , Heon Kim , Jung Lee , Kyung Paik
IPC分类号： C08F4/06 , B01J31/00
CPC分类号： C08F4/70
摘要： A catalyst system capable of producing a cyclic olefin polymer having a polar functional group and a high molecular weight with a high yield in which a catalyst is not deactivated due to polar functional groups of monomers, and a method of producing polymers using the same are provided. The catalyst system for polymerization of olefin according to the present invention has good thermal and chemical stability, and thus, in the method of preparing polyolefin using the catalyst system, the deactivation of a catalyst due to a polar functional group of the monomer can be prevented, and thus a high yield of the cyclic olefin polymer with a high molecular weight can be obtained when a ratio of the catalyst to the monomer is 1:5000, and the removal of a catalyst residue is not required.
摘要翻译：提供一种催化剂体系，其能够制备具有极性官能团和高分子量的环状烯烃聚合物，其高产率，其中由于单体的极性官能团而不使催化剂失活，以及使用其制备聚合物的方法。本发明的烯烃聚合用催化剂体系具有良好的热稳定性和化学稳定性，因此在使用该催化剂体系的聚烯烃的制造方法中，可以防止由于单体的极性官能团引起的催化剂的失活因此，当催化剂与单体的比例为1:5000时，可以获得高产率的具有高分子量的环状烯烃聚合物，并且不需要除去催化剂残余物。

3. 发明授权

US06730801B2 Method for producing dinuclear transition metal complexes as olefin polymerization catalyst 失效
标题翻译：生产双核过渡金属络合物作为烯烃聚合催化剂的方法
公开(公告)号：US06730801B2
公开(公告)日：2004-05-04
申请号：US10316111
申请日：2002-12-11
申请人： Eun-Il Kim , Seung Dai Choi
发明人： Eun-Il Kim , Seung Dai Choi
IPC分类号： C07F1700
CPC分类号： C07F17/00 , Y10S526/943
摘要： The object of the present invention is to provide a method for producing a dinuclear transition metal complex of formula (1) by reacting cyclopentadienyl ligand compound of formula (2) and substituted transition metal of formula (3). Cp-Si(R)2HNANHSi(R)2-Cp (Formula 2) wherein, A represents C2-30 alkylene, substituted alkylene, arylene, substituted arylene, cycloalkylene, substituted cycloalkylene, biarylene or substituted biarylene; Cp represents a ligand compound having cyclopentadienyl skeleton selected from the group consisting of cyclopentadienyl, substituted cyclopentadienyl, indenyl, substituted indenyl, fluorenyl and substituted fluorenyl; R represents C1-20 alkyl or substituted alkyl; H represents hydrogen atom; Si represents silicon atom; and N represents nitrogen atom. M(NR2′)4 (Formula 3) M represents transition metal of Periodic Table IV selected from titanium, zirconium and hafnium; R′ represents C1-6 alkyl. wherein, X represents halogen atom or alkylamine; and A, R, Si, N, Cp and M are same as defined above.
摘要翻译：本发明的目的是提供一种通过使式（2）的环戊二烯基配体化合物与式（3）的取代的过渡金属反应制备式（1）的双核过渡金属配合物的方法，其中A代表C2-30 亚烷基，取代的亚烷基，亚芳基，取代的亚芳基，亚环烷基，取代的亚环烷基，双亚芳基或取代的亚芳基; Cp表示具有选自环戊二烯基，取代的环戊二烯基，茚基，取代的茚基，芴基和取代的芴基的环戊二烯基骨架的配体化合物; R 表示C 1-20烷基或取代烷基; H表示氢原子; Si表示硅原子; 并且N表示氮原子.M表示选自钛，锆和铪的周期表IV的过渡金属; R'表示C 1-6烷基。其中，X表示卤素原子或烷基胺; 并且A，R，Si，N，Cp和M与上述相同。

4. 外观设计

USD448502S1 Compact fluorescent lamp 失效
公开(公告)号：USD448502S1
公开(公告)日：2001-09-25
申请号：US29135329
申请日：2001-01-11
申请人： Keun dai Choi
设计人： Keun dai Choi
CPC分类号： Y02B20/19

5. 外观设计

USD449122S1 Compact fluorescent lamp 失效
公开(公告)号：USD449122S1
公开(公告)日：2001-10-09
申请号：US29135330
申请日：2001-01-11
申请人： Keun dai Choi
设计人： Keun dai Choi
CPC分类号： Y02B20/19

6. 外观设计

USD430318S Compact fluorescent lamp 失效
公开(公告)号：USD430318S
公开(公告)日：2000-08-29
申请号：US115192
申请日：1999-12-10
申请人： Keun Dai Choi
设计人： Keun Dai Choi

7. 外观设计

USD439681S1 Compact fluorescent lamp 失效
标题翻译：紧凑型荧光灯
公开(公告)号：USD439681S1
公开(公告)日：2001-03-27
申请号：US29126503
申请日：2000-07-19
申请人： Keun dai Choi
设计人： Keun dai Choi
CPC分类号： Y02B20/19

8. 外观设计

USD437946S1 Compact fluorescent lamp 失效
公开(公告)号：USD437946S1
公开(公告)日：2001-02-20
申请号：US29123604
申请日：2000-05-23
申请人： Keun dai Choi
设计人： Keun dai Choi

9. 外观设计

USD448501S1 Compact fluorescent lamp 失效
公开(公告)号：USD448501S1
公开(公告)日：2001-09-25
申请号：US29135328
申请日：2001-01-11
申请人： Keun dai Choi
设计人： Keun dai Choi
CPC分类号： Y02B20/19

10. 发明申请

US20070123666A1 Polymerization methods using the catalysts 有权
公开(公告)号：US20070123666A1
公开(公告)日：2007-05-31
申请号：US11581470
申请日：2006-10-17
申请人： Young Chung , Il Jung , Sung Chun , Young Park , Dai Choi , Sung Yoon , TaeSun Lim , Jungmin Lee
发明人： Young Chung , Il Jung , Sung Chun , Young Park , Dai Choi , Sung Yoon , TaeSun Lim , Jungmin Lee
IPC分类号： C08F4/80
CPC分类号： C08F4/70 , C08F32/08
摘要： Provided is a method of preparing a cyclic olefin polymer by addition polymerization of a cyclic olefin monomer, the method including contacting a metal catalyst complex represented by Formula 1 below with a cyclic olefin monomer represented by Formula 2 below: [M(L1)x(L′2)y(L3)z]a[Ani]b wherein M is a Group X metal; [M(L1)x(L′2)y(L3)z] is a cationic complex; L1 is an anionic hydrocarbyl-containing ligand; L′2 is a neutral ligand; L3 is an N-heterocyclic carbene ligand; [Ani] is an anion capable of weakly coordinating with the metal M; x is 1 or 2; y is 0 to 4; z is 1 or 2; 2≦x+y+z≦6; a and b are respectively the number of cations and the number of anions capable of weakly coordinating with the metal M and are each a number of 1-10 which is used to satisfy the net charge balance of the metal catalyst complex, and wherein for each of L1, L′2, and L3, when a plurality of ligands are present in a molecule of the metal catalyst complex, the ligands may be the same or different, and wherein m is an integer of 0 to 4; and R7, R′7, R″7, and R″′7 are each independently a polar functional group or a nonpolar functional group. According to the method of the present invention, a high molecular weight cyclic olefin addition polymer can be produced in a high yield even when using a polar functional group-containing cyclic olefin monomer. A polymer produced using the method shows good thermal stability.

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