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    • 2. 发明授权
    • Electrolytic plating of tin-nickel, tin-cobalt or tin-nickel-cobalt on a metal base and acid bath for said plating
    • 金镍基电解镀锌,金属镍或锡镍钴,用于镀层金属基底和酸浴
    • US3772168A
    • 1973-11-13
    • US3772168D
    • 1972-08-10
    • DILLENBERG H
    • DILLENBERG H
    • C25D3/60C23B5/32C23B5/38
    • C25D3/60
    • A method for electrolytic plating of tin-nickel, tin-cobalt or tin-nickel-cobalt on a metal base and acid bath for said plating in which a bivalent salt of tin and nickel or tin and cobalt or tin, nickel and cobalt is dissolved in an aqueous acid bath containing an alkali metal or ammonium fluoride or fluoborate which is reacted with at least about 2 volume percent of an amine to form the fluoride or fluoborate amine salt dissolved in said bath. Preferred amines which form salts are petrylene diamine, diethylene triamine, triethylene tetramine, mono, di or tri ethanolamine and pyridine. Heavy, lustrous ductile coatings are deposited from the bath at pH 3.8 - 5.5 under current intensity of 0.1 - 5 amps/dm2 and at a temperature of 40* - 90*C.
    • 在金属基体上的锡镍,锡钴或锡镍钴的电解电镀方法,其中锡和镍或锡,钴或锡,镍和钴的二价盐溶解在所述电镀中 在含有碱金属或氟化铵或氟硼酸盐的含水酸浴中,其与至少约2体积%的胺反应以形成溶解在所述浴中的氟化物或氟硼酸盐盐。 形成盐的优选胺是碳二胺,二亚乙基三胺,三亚乙基四胺,一元,二或三乙醇胺和吡啶。 在电流强度为0.1-5安培/ dm 2,温度为40-90℃的条件下,从pH 3.8〜5.5的浴中沉积重光泽的延性涂层。