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    • 1. 发明授权
    • Crosslinkable creping adhesive formulations
    • 可交联起皱粘合剂配方
    • US06812281B2
    • 2004-11-02
    • US09904102
    • 2001-07-13
    • Phuong Van LuuCristian M. NeculescuDawn M. Mews
    • Phuong Van LuuCristian M. NeculescuDawn M. Mews
    • G08F842
    • B31F1/12D21H17/06D21H17/07D21H17/18D21H17/36D21H17/56D21H21/146D21H21/22Y10T428/24446Y10T428/24455Y10T428/24463Y10T428/3188Y10T428/31884Y10T428/31895
    • Disclosed are adhesive formulations as creping process aids for producing an absorbent creped cellulosic sheet having a high level of surface-perceived softness that comprises continuously forming a web of cellulosic papermaking fibers, adhering said web to a thermal drying means by means of adhesive compositions comprising polymers having at least one primary or secondary amine group in the backbone such as chitosan, polyvinylamine, polyvinyl alcohol-vinyl amine and polyaminoamide in combination with crosslinking agents such as dialdehydes or zirconium compounds having a valence of plus four including ammonium zirconium carbonate, zirconium acetylacetonate, zirconium acetate, zirconium carbonate, zirconium sulfate, zirconium phosphate, potassium zirconium carbonate, zirconium sodium phosphate and sodium zirconium tartrate and creping said treated web from said thermal drying means. In the method for producing the absorbent creped cellulosic sheets, the zirconium crosslinking agent is advantageously applied directly and separately on the Yankee dryer at the time the base polymer is applied to the surface. Alternatively, when using dialdehydes, the dialdehydes are mixed with the base polymer just prior to application to the Yankee dryer surface without having the crosslinking reaction take place with the base polymer prior to reaching the heated Yankee surface. These sheets are useful in the manufacture of tissue and towel.
    • 公开了作为起皱加工助剂的粘合剂制剂,其用于生产具有高水平表面感觉柔软性的吸收性起皱纤维素片材,其包括连续地形成纤维素造纸纤维网,通过粘合剂组合物将所述纤维网粘附到热干燥装置,所述粘合剂组合物包含聚合物 在骨架中具有至少一个伯胺或仲胺基团,例如壳聚糖,聚乙烯胺,聚乙烯醇 - 乙烯基胺和聚氨基酰胺,与交联剂如具有四价的二醛或锆化合物的组合,包括碳酸锆锆,乙酰丙酮酸锆, 乙酸锆,碳酸锆,硫酸锆,磷酸锆,碳酸钾锆,磷酸锆钠和酒石酸锆钠,并从所述热干燥装置起皱所述处理过的纤维网。 在制造吸收性起皱纤维素片的方法中,锆基交联剂有利地在将基础聚合物施加到表面上时在Yankee干燥器上分开施用。 或者,当使用二醛时,二恶醛在施用于扬克烘缸表面之前与基础聚合物混合,而不会在到达加热的扬基表面之前与基础聚合物发生交联反应。 这些片材在组织和毛巾的制造中是有用的。
    • 10. 发明授权
    • Crosslinkable creping adhesive formulations
    • 可交联起皱粘合剂配方
    • US06689250B1
    • 2004-02-10
    • US09496821
    • 2000-02-02
    • Phuong Van LuuCristian M. NeculescuDawn M. Mews
    • Phuong Van LuuCristian M. NeculescuDawn M. Mews
    • D21H1500
    • D21H21/146B31F1/12D21H17/06D21H17/07D21H17/18D21H17/36D21H17/56D21H21/22Y10T428/24446Y10T428/24455Y10T428/24463
    • Disclosed are adhesive formulations as creping process aids for producing an absorbent creped cellulosic sheet having a high level of surface-perceived softness that comprises continuously forming a web of cellulosic papermaking fibers, adhering said web to a thermal drying means by means of adhesive compositions comprising polymers having at least one primary or secondary amine group in the backbone such as chitosan, plolyvinylamine, polyvinyl alcohol-vinyl amine and polyaminoamide in combination with crosslinking agents such as zirconium compounds having a valence of plus four including ammonium zirconium carbonate, zirconium acetylacetonate, zirconium acetate, zirconium carbonate, zirconium sulfate, zirconium phosphate, potassium zirconium carbonate, zirconium sodium phosphate and sodium zirconium tartrate and creping said treated web from said thermal drying means. In the method for producing the absorbent creped cellulosic sheets, the zirconium crosslinking agent is advantageously applied directly and separately on the Yankee dryer at the time the base polymer is applied to the surface. The crosslinking agent functions to crosslink the polymer to the fibrous web. The absorbent paper products are used as bathroom tissue and towels.
    • 公开了作为起皱加工助剂的粘合剂制剂,其用于生产具有高水平表面感觉柔软性的吸收性起皱纤维素片材,其包括连续地形成纤维素造纸纤维网,通过粘合剂组合物将所述纤维网粘附到热干燥装置,所述粘合剂组合物包含聚合物 在主链中具有至少一个伯或仲胺基团,例如壳聚糖,聚乙烯胺,聚乙烯醇 - 乙烯基胺和聚氨基酰胺与交联剂如具有四价的锆化合物的组合包括碳酸锆锆,乙酰丙酮锆,乙酸锆 ,碳酸锆,硫酸锆,磷酸锆,碳酸钾锆,磷酸锆钠和酒石酸锆钠,并从所述热干燥装置起皱所述处理的纤维网。 在制造吸收性起皱纤维素片的方法中,锆基交联剂有利地在将基础聚合物施加到表面上时在Yankee干燥器上分开施用。 交联剂用于将聚合物交联至纤维网。 吸水纸产品用作卫生纸和毛巾。