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1. 发明申请

US20070292601A1 Thin Film Devices Utilizing Hexabenzocoronenes 审中-公开
标题翻译：利用六苯并三烯的薄膜器件
公开(公告)号：US20070292601A1
公开(公告)日：2007-12-20
申请号：US11566437
申请日：2006-12-04
申请人： Colin Nuckolls , Xuefeng Guo , Philip Kim , Shengxiong Xiao , Matthew Myers
发明人： Colin Nuckolls , Xuefeng Guo , Philip Kim , Shengxiong Xiao , Matthew Myers
IPC分类号： B05D5/12 , C07C15/20 , C07C43/20 , C07C53/44
CPC分类号： H01L51/0048 , B82Y10/00 , B82Y30/00 , C07C15/20 , C07C43/2055 , C07C43/215 , C07C2603/54 , H01L51/0049 , H01L51/0056 , H01L51/05 , H01L51/0595
摘要： The present invention generally relates to the fabrication of molecular electronics devices from molecular wires and Single Wall Nanotubes (SWNT). In one embodiment, the cutting of a SWNT is achieved by opening a window of small width by lithography patterning of a protective layer on top of the SWNT, followed by applying an oxygen plasma to the exposed SWNT portion. In another embodiment, the gap of a cut SWNT is reconnected by one or more difunctional molecules having appropriate lengths reacting to the functional groups on the cut SWNT ends to form covalent bonds. In another embodiment, the gap of a cut SWNT gap is filled with a self-assembled monolayer from derivatives of novel contorted hexabenzocoranenes. In yet another embodiment, a device based on molecular wire reconnected a cut SWNT is used as a sensor to detect a biological binding event.
摘要翻译：本发明一般涉及从分子线和单壁纳米管（SWNT）制造分子电子器件。在一个实施例中，通过在SWNT顶部上的保护层的光刻图案化，然后将氧等离子体施加到暴露的SWNT部分，打开小宽度的窗口来实现SWNT的切割。在另一个实施方案中，切割的SWNT的间隙通过一个或多个具有与切割的SWNT末端上的官能团反应形成共价键的适当长度的双功能分子重新连接。在另一个实施方案中，切割的SWNT间隙的间隙填充有自组装单层，由新颖扭转的六苯并三硼酸衍生物填充。在另一个实施方案中，基于重新连接切割SWNT的分子线的装置用作传感器以检测生物结合事件。

2. 发明申请

US20110275062A1 Systems And Methods For Integrating A Single DNA Molecule Into A Molecular Electronic Device 审中-公开
标题翻译：将单个DNA分子整合到分子电子装置中的系统和方法
公开(公告)号：US20110275062A1
公开(公告)日：2011-11-10
申请号：US12955310
申请日：2010-11-29
申请人： Xuefeng Guo , Colin Nuckolls , James Hone , Alon Gorodetsky , Jacqueline K. Barton
发明人： Xuefeng Guo , Colin Nuckolls , James Hone , Alon Gorodetsky , Jacqueline K. Barton
IPC分类号： C12Q1/68 , B05D5/12 , C23F1/02 , G01R27/28 , H01L51/30 , G01N33/68 , B05D3/00 , B82Y99/00
CPC分类号： H01L51/0001 , B82Y10/00 , G01N27/04 , G01N33/5308 , G01N33/54373 , H01L51/0049 , H01L51/0093 , H01L51/0595
摘要： The disclosed subject matter provides a techniques for precisely and/or functionally cutting carbon nanotubes, e.g., single walled carbon nanotubes (“SWNTs”) and integrating a single nucleic acid molecule (e.g., a DNA molecule) into a gap formed into the carbon nanotubes. In one aspect, a method of fabricating a molecular electronic device includes disposing a SWNT on a base layer, forming a gap in the SWNT using a lithographic process, and disposing a single DNA strand across the gap so that each end of the nucleic acid contacts a gap termini. The disclosed subject matter also provides techniques for measuring the electrical properties (charge transport) of a DNA molecule which is integrated into an SWNT. Furthermore, a molecular electronic device including an SWNT with an integrated nucleic acid molecule is disclosed.
摘要翻译：所公开的主题提供了用于精确和/或功能性地切割碳纳米管的技术，例如单壁碳纳米管（“SWNT”）并将单个核酸分子（例如，DNA分子）整合到形成碳纳米管的间隙中。一方面，制造分子电子器件的方法包括在基底层上设置SWNT，使用光刻工艺在SWNT中形成间隙，并且在间隙上设置单个DNA链，使得核酸的每个末端接触一个差距终点。所公开的主题还提供了用于测量整合到SWNT中的DNA分子的电特性（电荷转移）的技术。此外，公开了包含具有整合的核酸分子的SWNT的分子电子器件。

3. 发明申请

US20110168562A1 Nanopore and Carbon Nanotube Based DNA Sequencer 有权
标题翻译：纳米孔和碳纳米管的DNA测序仪
公开(公告)号：US20110168562A1
公开(公告)日：2011-07-14
申请号：US12920817
申请日：2009-03-18
申请人： Colin Nuckolls , Jinyao Tang , Stuart Lindsay , Jin He , Peiming Zhang , Kevin Reinhart
发明人： Colin Nuckolls , Jinyao Tang , Stuart Lindsay , Jin He , Peiming Zhang , Kevin Reinhart
IPC分类号： G01N27/00 , B32B37/24 , C23F1/00 , B82Y99/00
CPC分类号： G01N33/48721 , C12Q1/6869 , C12Q2565/631
摘要： The present invention provides a device for analyzing the composition of a heteropolymer comprising a carbon nanotube through which the heteropolymer is driven by electrophoresis. The carbon nanotube also serves as one electrode in a reading circuit. One end of the carbon nanotube is held in close proximity to a second electrode, and each end of the carbon nanotube is functionalized with flexibly-tethered chemical-recognition moieties, such that one will bind one site on the emerging polymer, and the second will bind another site in close proximity, generating an electrical signal between the two electrodes when the circuit is completed by the process of chemical recognition.
摘要翻译：本发明提供一种用于分析包含碳纳米管的杂聚物的组成的装置，通过该电极驱动该杂聚物。碳纳米管也用作读取电路中的一个电极。碳纳米管的一端保持靠近第二电极，并且碳纳米管的每一端用柔性系带的化学识别部分功能化，使得将结合新出现的聚合物上的一个位点，而第二个在另一个位置紧密接合，当通过化学识别过程完成电路时，在两个电极之间产生电信号。

4. 发明申请

US20090027036A1 SENSING DEVICES FROM MOLECULAR ELECTRONIC DEVICES UTILIZING HEXABENZOCORONENES 审中-公开
标题翻译：来自分子式电子装置的传感装置利用十六烷基二氯甲烷
公开(公告)号：US20090027036A1
公开(公告)日：2009-01-29
申请号：US12139207
申请日：2008-06-13
申请人： Colin Nuckolls , Xuefeng Guo , Philip Kim , Shengxiong Xiao , Mathew Benjamin Myers
发明人： Colin Nuckolls , Xuefeng Guo , Philip Kim , Shengxiong Xiao , Mathew Benjamin Myers
IPC分类号： G01N27/00 , B05D5/12
CPC分类号： G01N33/5438 , B82Y10/00 , C12Q1/002 , G01N27/128 , G01N2610/00 , H01L27/285 , H01L51/0036 , H01L51/0048 , H01L51/0056 , H01L51/0076 , H01L51/0083 , H01L51/0591 , Y10S977/701 , Y10S977/721
摘要： The present invention generally relates to the fabrication of molecular electronics devices from molecular wires and Single Wall Nanotubes (SWNT). In one embodiment, the cutting of a SWNT is achieved by opening a window of small width by lithography patterning of a protective layer on top of the SWNT, followed by applying an oxygen plasma to the exposed SWNT portion. In another embodiment, the gap of a cut SWNT is reconnected by one or more difunctional molecules having appropriate lengths reacting to the functional groups on the cut SWNT ends to form covalent bonds. In another embodiment, the gap of a cut SWNT gap is filled with a self-assembled monolayer from derivatives of novel contorted hexabenzocoranenes. In yet another embodiment, a device based on molecular wire reconnecting a cut SWNT is used as a sensor to detect a biological binding event.
摘要翻译：本发明一般涉及从分子线和单壁纳米管（SWNT）制造分子电子器件。在一个实施例中，通过在SWNT顶部上的保护层的光刻图案化，然后将氧等离子体施加到暴露的SWNT部分，打开小宽度的窗口来实现SWNT的切割。在另一个实施方案中，切割的SWNT的间隙通过一个或多个具有与切割的SWNT末端上的官能团反应形成共价键的适当长度的双功能分子重新连接。在另一个实施方案中，切割的SWNT间隙的间隙填充有自组装单层，由新颖扭转的六苯并三硼酸衍生物填充。在另一个实施例中，使用基于重新连接切割SWNT的分子线的装置作为传感器来检测生物结合事件。

5. 发明授权

US08961757B2 Nanopore and carbon nanotube based DNA sequencer 有权
标题翻译：纳米孔和基于碳纳米管的DNA测序仪
公开(公告)号：US08961757B2
公开(公告)日：2015-02-24
申请号：US12920817
申请日：2009-03-18
申请人： Colin Nuckolls , Jinyao Tang , Stuart Lindsay , Jin He , Peiming Zhang , Kevin Reinhart
发明人： Colin Nuckolls , Jinyao Tang , Stuart Lindsay , Jin He , Peiming Zhang , Kevin Reinhart
IPC分类号： G01N27/327 , C12Q1/68 , G01N33/487
CPC分类号： G01N33/48721 , C12Q1/6869 , C12Q2565/631
摘要： The present invention provides a device for analyzing the composition of a heteropolymer comprising a carbon nanotube through which the heteropolymer is driven by electrophoresis. The carbon nanotube also serves as one electrode in a reading circuit. One end of the carbon nanotube is held in close proximity to a second electrode, and each end of the carbon nanotube is functionalized with flexibly-tethered chemical-recognition moieties, such that one will bind one site on the emerging polymer, and the second will bind another site in close proximity, generating an electrical signal between the two electrodes when the circuit is completed by the process of chemical recognition.
摘要翻译：本发明提供一种用于分析包含碳纳米管的杂聚物的组成的装置，通过该电极驱动该杂聚物。碳纳米管也用作读取电路中的一个电极。碳纳米管的一端保持靠近第二电极，并且碳纳米管的每一端用柔性系带的化学识别部分功能化，使得将结合新出现的聚合物上的一个位点，而第二个在另一个位置紧密接合，当通过化学识别过程完成电路时，在两个电极之间产生电信号。

6. 发明授权

US07928432B2 Sensing devices from molecular electronic devices 有权
标题翻译：分子电子设备的感应装置
公开(公告)号：US07928432B2
公开(公告)日：2011-04-19
申请号：US12139218
申请日：2008-06-13
申请人： Colin Nuckolls , Xuefeng Guo , Philip Kim
发明人： Colin Nuckolls , Xuefeng Guo , Philip Kim
IPC分类号： H01L35/24
CPC分类号： G01N33/5438 , B82Y10/00 , C12Q1/002 , G01N27/128 , G01N2610/00 , H01L27/285 , H01L51/0036 , H01L51/0048 , H01L51/0056 , H01L51/0076 , H01L51/0083 , H01L51/0591 , Y10S977/701 , Y10S977/721
摘要： The present invention generally relates to the fabrication of molecular electronics devices from molecular wires and Single Wall Nanotubes (SWNT). In one embodiment, the cutting of a SWNT is achieved by opening a window of small width by lithography patterning of a protective layer on top of the SWNT, followed by applying an oxygen plasma to the exposed SWNT portion. In another embodiment, the gap of a cut SWNT is reconnected by one or more difunctional molecules having appropriate lengths reacting to the functional groups on the cut SWNT ends to form covalent bonds. In another embodiment, the gap of a cut SWNT gap is filled with a self-assembled monolayer from derivatives of novel contorted hexabenzocoranenes. In yet another embodiment, a device based on molecular wire reconnecting a cut SWNT is used as a sensor to detect a biological binding event.
摘要翻译：本发明一般涉及从分子线和单壁纳米管（SWNT）制造分子电子器件。在一个实施例中，通过在SWNT顶部上的保护层的光刻图案化，然后将氧等离子体施加到暴露的SWNT部分，打开小宽度的窗口来实现SWNT的切割。在另一个实施方案中，切割的SWNT的间隙通过一个或多个具有与切割的SWNT末端上的官能团反应形成共价键的适当长度的双功能分子重新连接。在另一个实施方案中，切割的SWNT间隙的间隙填充有自组装单层，由新颖扭转的六苯并三硼酸衍生物填充。在另一个实施例中，使用基于重新连接切割SWNT的分子线的装置作为传感器来检测生物结合事件。

7. 发明申请

US20090017571A1 SENSING DEVICES FROM MOLECULAR ELECTRONIC DEVICES 有权
标题翻译：从分子电子设备传感器件
公开(公告)号：US20090017571A1
公开(公告)日：2009-01-15
申请号：US12139218
申请日：2008-06-13
申请人： Colin Nuckolls , Xuefeng Guo , Philip Kim
发明人： Colin Nuckolls , Xuefeng Guo , Philip Kim
IPC分类号： H01L21/00 , B01J19/00
CPC分类号： G01N33/5438 , B82Y10/00 , C12Q1/002 , G01N27/128 , G01N2610/00 , H01L27/285 , H01L51/0036 , H01L51/0048 , H01L51/0056 , H01L51/0076 , H01L51/0083 , H01L51/0591 , Y10S977/701 , Y10S977/721
摘要： The present invention generally relates to the fabrication of molecular electronics devices from molecular wires and Single Wall Nanotubes (SWNT). In one embodiment, the cutting of a SWNT is achieved by opening a window of small width by lithography patterning of a protective layer on top of the SWNT, followed by applying an oxygen plasma to the exposed SWNT portion. In another embodiment, the gap of a cut SWNT is reconnected by one or more difunctional molecules having appropriate lengths reacting to the functional groups on the cut SWNT ends to form covalent bonds. In another embodiment, the gap of a cut SWNT gap is filled with a self-assembled monolayer from derivatives of novel contorted hexabenzocoranenes. In yet another embodiment, a device based on molecular wire reconnecting a cut SWNT is used as a sensor to detect a biological binding event.
摘要翻译：本发明一般涉及从分子线和单壁纳米管（SWNT）制造分子电子器件。在一个实施例中，通过在SWNT顶部上的保护层的光刻图案化，然后将氧等离子体施加到暴露的SWNT部分，打开小宽度的窗口来实现SWNT的切割。在另一个实施方案中，切割的SWNT的间隙通过一个或多个具有与切割的SWNT末端上的官能团反应形成共价键的适当长度的双功能分子重新连接。在另一个实施方案中，切割的SWNT间隙的间隙填充有自组装单层，由新颖扭转的六苯并三硼酸衍生物填充。在另一个实施例中，使用基于重新连接切割SWNT的分子线的装置作为传感器来检测生物结合事件。

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