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1. 发明申请

US20120149935A1 Plasticiser Alcohol And Production Improvement 有权
标题翻译：增塑酒精和生产改进
公开(公告)号：US20120149935A1
公开(公告)日：2012-06-14
申请号：US13401257
申请日：2012-02-21
申请人： Eddy Van Driessche , Jean-Jacques G. Muls , Arie Van Vliet , Carl R. Beck , Charles M. Yarbrough
发明人： Eddy Van Driessche , Jean-Jacques G. Muls , Arie Van Vliet , Carl R. Beck , Charles M. Yarbrough
IPC分类号： C07C67/08 , C07C29/04
CPC分类号： C07C29/141 , C07C29/149 , C07C31/125
摘要： Embodiments of the invention disclosed herein relate to a process for the production of a C6-C15 alcohol mixture comprising the steps of: hydroformylating an olefin mixture comprising a branched C5-C14 olefin to form a hydroformylation product comprising aldehydes and formate esters, whereby the hydroformylation product has a net cold sap number from 15 to 38 mg KOH/g, and converting the aldehydes and formate esters to alcohols in a hydrogenation step comprising at least one first hydrogenation reactor comprising a fixed bed of a heterogeneous sulphided bimetallic catalyst.
摘要翻译：本文公开的本发明的实施方案涉及制备C 6 -C 15醇混合物的方法，其包括以下步骤：将包含支链C 5 -C 14烯烃的烯烃混合物加氢甲酰化以形成包含醛和甲酸酯的加氢甲酰化产物，由此加氢甲酰化产物具有15至38mg KOH / g的净冷液体数，并且在氢化步骤中将醛和甲酸酯转化为醇，所述氢化步骤包括至少一个包含异质硫化双金属催化剂的固定床的第一氢化反应器。

2. 发明授权

US08183420B2 Preparation of alkylaromatic hydrocarbons and alkylaryl sulfonates 失效
标题翻译：烷基芳烃和烷基芳基磺酸盐的制备
公开(公告)号：US08183420B2
公开(公告)日：2012-05-22
申请号：US12575948
申请日：2009-10-08
申请人： Carolyn B. Duncan , David Wayne Turner , Jane C. Cheng , Charles M. Yarbrough , Raphael Frans Caers , Ramzi Y. Saleh , James L. Propp
发明人： Carolyn B. Duncan , David Wayne Turner , Jane C. Cheng , Charles M. Yarbrough , Raphael Frans Caers , Ramzi Y. Saleh , James L. Propp
IPC分类号： C07C15/107
CPC分类号： C07C2/66 , C07C15/107 , C07C303/06 , C07C2527/1206 , C07C2527/126 , C07C2527/173 , C07C2529/70 , C07C309/31
摘要： An alkylaromatic hydrocarbon composition prepared by the process which comprises oligomerizing an olefin selected from the group consisting of propylene, n-butene and mixtures thereof over an oligomerization catalyst, to form a oligomerization product comprising at least 95% by weight of mono-olefin oligomers of the empirical formula: CnH2n wherein n is greater than or equal to 10, the mono-olefin oligomers comprise at least 20% by weight of olefins having at least 12 carbon atoms, and the olefins having at least 12 carbon atoms having an average of from 0.8 to 2.0 C1-C3 alkyl branches per carbon chain. Sulfonation of the alkylaromatic hydrocarbon product produces an alkylaryl sulfonate mixture that exhibits advantageous properties, such as biodegradability and hard and cold water performance.
摘要翻译：通过该方法制备的烷基芳族烃组合物，其包括在低聚催化剂上使选自丙烯，正丁烯及其混合物的烯烃低聚以形成低聚产物，其包含至少95重量％的单烯烃低聚物经验式：C n H 2n其中n大于或等于10，单烯烃低聚物包含至少20重量％的具有至少12个碳原子的烯烃，并且具有至少12个碳原子的烯烃具有平均为每个碳链0.8至2.0个C1-C3烷基支链。烷基芳族烃产物的磺化产生显示出有利性质的烷基芳基磺酸盐混合物，例如生物降解性和冷水和冷水性能。

3. 发明授权

US08143459B2 Plasticiser alcohol and production improvement 有权
标题翻译：增塑酒精和生产改善
公开(公告)号：US08143459B2
公开(公告)日：2012-03-27
申请号：US12767343
申请日：2010-04-26
申请人： Eddy Van Driessche , Jean-Jacques G. Muls , Arie Van Vliet , Carl R. Beck , Charles M. Yarbrough
发明人： Eddy Van Driessche , Jean-Jacques G. Muls , Arie Van Vliet , Carl R. Beck , Charles M. Yarbrough
IPC分类号： C07C29/04 , C07C67/08
CPC分类号： C07C29/141 , C07C29/149 , C07C31/125
摘要： Oxo-alcohols in the plasticizer range typically contain small amounts of methyl esters having the same alkyl chain as the alcohol itself. These methyl esters are causing product quality problems and environmental problems because of transesterification in the esterification process where the plasticizer ester derivatives are produced. A process using controlled oxonation and hydrogenation conditions is disclosed for the production of alcohols containing low amounts of methyl esters. Plasticizer esters with low amounts of aliphatic di-alkyl esters are also disclosed.
摘要翻译：在增塑剂范围内的氧代醇通常含有少量与醇本身具有相同烷基链的甲基酯。这些甲酯在产生增塑剂酯衍生物的酯化过程中由于酯交换而引起产品质量问题和环境问题。公开了一种使用受控的氧化和氢化条件的方法，用于生产含有少量甲酯的醇。还公开了具有少量脂族二烷基酯的增塑剂酯。

4. 发明授权

US06733637B1 Process for producing ultra-high purity isopropanol 失效
标题翻译：生产超高纯异丙醇的方法
公开(公告)号：US06733637B1
公开(公告)日：2004-05-11
申请号：US09587103
申请日：2000-06-02
申请人： Paul E. Burton , Dennis J. Davoren , Timothy P. Dean , John P. Motlow , Charles M. Yarbrough
发明人： Paul E. Burton , Dennis J. Davoren , Timothy P. Dean , John P. Motlow , Charles M. Yarbrough
IPC分类号： B01D300
CPC分类号： C07C29/80 , Y10S203/20 , C07C31/10
摘要： A process for producing high purity isopropyl alcohol. In one embodiment, the process includes the steps of: (a) feeding a feed stream comprising at least about 99.9 wt. % isopropyl alcohol into a separation column; (b) separating the isopropyl alcohol into an overhead stream taken overhead from the separation column and a bottoms stream taken as bottoms from the separation column; and (c) removing the high purity isopropyl alcohol at a point: (i) below where the feed stream enters the separation column but above the bottoms stream, or (ii) above where the feed stream enters the separation column but below the overhead stream. The high purity isopropyl alcohol has a metals content of less than about 1 ppb and a water content of less than about 100 ppm. Optionally, the process includes the step of passing the high purity isopropyl alcohol through an ion exchange resin after removing the high purity isopropyl alcohol from the separation column, thereby forming an ultra-high purity isopropyl alcohol that contains less than 100 ppt of any metal impurity.
摘要翻译：一种生产高纯度异丙醇的方法。在一个实施方案中，该方法包括以下步骤：（a）进料包含至少约99.9wt。％异丙醇进入分离柱; （b）将异丙醇分离成塔顶馏出物，塔顶馏出塔和从分离塔中取出的底部物流; 和（c）在以下点：（i）除去高纯度异丙醇，其中进料流进入分离塔但高于塔底流，或（ii）上述进料流进入分离塔但低于塔顶流。高纯度异丙醇的金属含量小于约1ppb，水含量低于约100ppm。任选地，该方法包括在从分离塔中除去高纯度异丙醇之后使高纯度异丙醇通过离子交换树脂的步骤，从而形成含有小于100ppt的任何金属杂质的超高纯度异丙醇。

5. 发明申请

US20100197978A1 IPA From Propylene Using Mixed Metal Oxides 审中-公开
标题翻译：使用混合金属氧化物的丙烯的IPA
公开(公告)号：US20100197978A1
公开(公告)日：2010-08-05
申请号：US12598009
申请日：2008-04-10
申请人： Jihad M. Dakka , Doron Levin , Stephen McCarthy , Travis Allen Reine , Mary Jo Schneider , James C. Vartuli , Charles M. Yarbrough
发明人： Jihad M. Dakka , Doron Levin , Stephen McCarthy , Travis Allen Reine , Mary Jo Schneider , James C. Vartuli , Charles M. Yarbrough
IPC分类号： C07C29/04 , B01J23/10 , B01J21/06
CPC分类号： B01J37/03 , B01J21/066 , B01J23/002 , B01J23/10 , B01J23/24 , B01J23/34 , B01J23/72 , B01J23/745 , B01J23/85 , B01J23/888 , B01J27/053 , B01J37/10 , B01J2523/00 , C07C29/04 , B01J2523/3712 , B01J2523/48 , B01J2523/69 , B01J2523/72 , B01J2523/17 , C07C31/10
摘要： The invention relates to the production of isopropyl alcohol (IPA) by direct hydration of propylene over mixed transition metal oxides co-precipitated with ZrO2. In embodiments the mixed metal oxides have improved hydrolytic stability and are active over a wider temperature range than existing direct hydration catalysts.
摘要翻译：本发明涉及通过在与ZrO 2共沉淀的混合过渡金属氧化物上直接水合丙烯来生产异丙醇（IPA）。在实施方案中，混合金属氧化物具有改善的水解稳定性，并且在比现有直接水合催化剂更宽的温度范围内具有活性。

6. 发明授权

US07399891B2 Process for alcohol production by selective ether decomposition 失效
标题翻译：通过选择性醚分解生产酒精的方法
公开(公告)号：US07399891B2
公开(公告)日：2008-07-15
申请号：US11147919
申请日：2005-06-08
申请人： Charles M Yarbrough , Brian William Roberts , Dennis Jay Davoren , Kenneth Joseph Buturla , Carl Stotz Katzenstein , Doron Levin , Hans Georg Korsten , Vijay Swarup
发明人： Charles M Yarbrough , Brian William Roberts , Dennis Jay Davoren , Kenneth Joseph Buturla , Carl Stotz Katzenstein , Doron Levin , Hans Georg Korsten , Vijay Swarup
IPC分类号： C07C33/02
CPC分类号： B01J23/24 , B01J21/06 , B01J21/066 , B01J23/10 , C07C29/04 , C07C29/10 , C07C31/10 , C07C31/12
摘要： This invention relates to a process for the production of an alcohol, the process comprising (a) reacting an olefin and water in the presence of a catalyst under conditions sufficient to form a crude alcohol stream comprising alcohol, and a dialkyl ether; (b) separating at least a portion of the crude alcohol stream into an alcohol-containing stream and a dialkyl ether stream; (c) contacting at least a portion of the dialkyl ether stream with an ether decomposition catalyst, the ether decomposition catalyst comprising a mixed metal oxide having the following composition XmYnZpOq where X is at least one metal selected from Group 4 of the Periodic Table of Elements, Y is at least one metal selected from Group 3 (including the Lanthanides and Actinides) and Group 6 of the Periodic Table of Elements and Z is at least one metal selected from Groups 7, 8, and 11 of the Periodic Table of Elements; m, n, p, and q are the atomic ratios of their respective components and, when m is 1, n is from about 0.01 to about 0.75, p is from 0 to about 0.1, and q is the number of oxygen atoms necessary to satisfy the valence of the other components, to form a crude dialkyl ether decomposition stream comprising alcohol and olefin; (d) recovering at least a portion of the olefin from the crude dialkyl ether decomposition stream; and (e) recycling at least a portion of the olefin recovered in step (d) to step (a).
摘要翻译：本发明涉及一种生产醇的方法，该方法包括（a）在足以形成包含醇和二烷基醚的粗醇物流的条件下，在催化剂存在下使烯烃和水反应; （b）将至少一部分粗醇流分离成含醇流和二烷基醚流; （c）使至少一部分二烷基醚料流与醚分解催化剂接触，所述醚分解催化剂包含具有以下组成的混合金属氧化物：其中X是选自元素周期表第4族的至少一种金属，Y是选自第3族（包括镧系元素）中的至少一种金属和锕系元素）和元素周期表第6族，Z是选自元素周期表第7,8和11族中的至少一种金属; m，n，p和q是它们各自成分的原子比，当m为1时，n为约0.01至约0.75，p为0至约0.1，q为必需的氧原子数满足其他组分的化合价，形成包含醇和烯烃的粗二烷基醚分解物流; （d）从粗二烷基醚分解流中回收至少一部分烯烃; 和（e）将步骤（d）中回收的烯烃的至少一部分再循环到步骤（a）。

7. 发明授权

US08288595B2 Plasticiser alcohol and production improvement 有权
标题翻译：增塑酒精和生产改善
公开(公告)号：US08288595B2
公开(公告)日：2012-10-16
申请号：US13401257
申请日：2012-02-21
申请人： Eddy Van Driessche , Jean-Jacques G. Muls , Arie Van Vliet , Carl R. Beck , Charles M. Yarbrough
发明人： Eddy Van Driessche , Jean-Jacques G. Muls , Arie Van Vliet , Carl R. Beck , Charles M. Yarbrough
IPC分类号： C07C29/04 , C07C67/08
CPC分类号： C07C29/141 , C07C29/149 , C07C31/125
摘要： Embodiments of the invention disclosed herein relate to a process for the production of a C6-C15 alcohol mixture comprising the steps of: hydroformylating an olefin mixture comprising a branched C5-C14 olefin to form a hydroformylation product comprising aldehydes and formate esters, whereby the hydroformylation product has a net cold sap number from 15 to 38 mg KOH/g, and converting the aldehydes and formate esters to alcohols in a hydrogenation step comprising at least one first hydrogenation reactor comprising a fixed bed of a heterogeneous sulphided bimetallic catalyst.
摘要翻译：本文公开的本发明的实施方案涉及制备C 6 -C 15醇混合物的方法，其包括以下步骤：将包含支链C 5 -C 14烯烃的烯烃混合物加氢甲酰化以形成包含醛和甲酸酯的加氢甲酰化产物，由此加氢甲酰化产物具有15至38mg KOH / g的净冷液体数，并且在氢化步骤中将醛和甲酸酯转化为醇，所述氢化步骤包括至少一个包含异质硫化双金属催化剂的固定床的第一氢化反应器。

8. 发明授权

US07655826B2 Method for decomposition of ethers 有权
标题翻译：醚分解方法
公开(公告)号：US07655826B2
公开(公告)日：2010-02-02
申请号：US11104315
申请日：2005-04-12
申请人： Charles M. Yarbrough , Vijay Swarup , Patrick Joseph Maher , Albert Y Hu , Michael Walter Bedell
发明人： Charles M. Yarbrough , Vijay Swarup , Patrick Joseph Maher , Albert Y Hu , Michael Walter Bedell
IPC分类号： C07C4/02 , C07C1/00 , C10G9/00 , C10G11/00
CPC分类号： C07C1/24 , C07C1/213 , C10G3/40 , C10G3/49 , C10G3/57 , C10G3/62 , C10G2300/1037 , C10G2300/202 , C10G2300/4093 , C10G2400/20 , C10G2400/28
摘要： This invention relates to a method of making an olefin from a dialkyl ether comprising (a) introducing an ether having a formula CxH2x+1CyH2y+1 into a thermal or catalytic cracking unit processing a hydrocarbon feedstock; and (b) decomposing at least a portion of the ether to form an olefin having a formula CxH2x and/or CyH2y and an alcohol having a formula CxH2x+1 and/or CyH2y+1OH, wherein x and y independently range from about 1 to about 30. This invention also relates to a method of reducing coking in a thermal or catalytic cracking unit comprising (a) introducing an ether, having a formula CxH2x+1OCyH2y+1, into the cracking unit processing a hydrocarbon feedstock in an amount effective to reduce coke formation relative to processing the hydrocarbon feedstock in the absence of the ether, wherein x and y independently range from about 1 to about 30.
摘要翻译：本发明涉及一种由二烷基醚制备烯烃的方法，包括（a）将具有式CxH2x + 1CyH2y + 1的醚导入加工烃原料的热催化裂解装置; 和（b）分解至少一部分醚以形成具有式CxH2x和/或CyH2y的烯烃和具有式CxH2x + 1和/或CyH2y + 1OH的醇，其中x和y独立地为约1至本发明还涉及一种在热或催化裂化装置中减少焦化的方法，其包括（a）将具有式C x H 2 x + 1 O yy yy + 1的式C 4 H 8 O x + 1 O yy H y + 1的醚引入到裂化装置中，在不存在醚的情况下相对于处理烃原料减少焦炭形成，其中x和y独立地为约1至约30。

9. 发明授权

US07622621B2 Preparation of alkylaromatic hydrocarbons and alkylaryl sulfonates 失效
标题翻译：烷基芳烃和烷基芳基磺酸盐的制备
公开(公告)号：US07622621B2
公开(公告)日：2009-11-24
申请号：US10509508
申请日：2003-03-28
申请人： Carolyn B. Duncan , David Wayne Turner , Jane C. Cheng , Charles M. Yarbrough , Raphael Frans Caers , Ramzi Y. Saleh , James L. Propp
发明人： Carolyn B. Duncan , David Wayne Turner , Jane C. Cheng , Charles M. Yarbrough , Raphael Frans Caers , Ramzi Y. Saleh , James L. Propp
IPC分类号： C07C2/66 , C07C2/12
CPC分类号： C07C2/66 , C07C15/107 , C07C303/06 , C07C2527/1206 , C07C2527/126 , C07C2527/173 , C07C2529/70 , C07C309/31
摘要： In a process for preparing an alkylaromatic hydrocarbon composition an olefinic hydrocarbon mixture and an aromatic compound are contacted under alkylation conditions with an aromatic alkylation catalyst selected from a homogeneous acid catalyst and heterogeneous acid catalyst comprising a molecular sieve having an X-ray diffraction pattern including d-spacing maxima at 12.4±0.25, 6.9±0.15, 3.57±0.07 and 3.42±0.07 Angstroms. The olefinic hydrocarbon mixture comprises at least 5 wt % by weight of mono-olefin oligomers of the empirical formula: CnH2n wherein n is greater than or equal to 10, the mono-olefin oligomers comprising at least 20 percent by weight of olefins having at least 12 carbon atoms, and the olefins having at least 12 carbon atoms having an average of from 0.8 to 2.0 C1-C3 alkyl branches per carbon chain. Sulfonation of the alkylaromatic hydrocarbon product produces an alkylaryl sulfonate mixture that exhibits advantageous properties, such as biodegradability and hard and cold water performance.
摘要翻译：在制备烷基芳族烃组合物的方法中，烯烃混合物和芳族化合物在烷基化条件下与选自均相酸催化剂的芳族烷基化催化剂和包含具有包括d的X射线衍射图的分子筛的多相酸催化剂接触最大值为12.4±0.25,6.9±0.15,3.57±0.07和3.42±0.07埃。烯烃混合物包含至少5重量％的经验式为C n H 2n的单烯烃低聚物，其中n大于或等于10，单烯烃低聚物包含至少20重量％的至少具有至少20重量％ 12个碳原子，并且具有至少12个碳原子的烯烃在每个碳链上平均具有0.8至2.0个C 1 -C 3烷基支链。烷基芳族烃产物的磺化产生显示出有利性质的烷基芳基磺酸盐混合物，例如生物降解性和冷水和冷水性能。

10. 发明申请

US20100312005A1 Plasticiser Alcohol and Production Improvement 有权
标题翻译：增塑酒精和生产改进
公开(公告)号：US20100312005A1
公开(公告)日：2010-12-09
申请号：US12767343
申请日：2010-04-26
申请人： Eddy Van Driessche , Jean-Jacques G. Muls , Arie Van Vliet , Carl R. Beck , Charles M. Yarbrough
发明人： Eddy Van Driessche , Jean-Jacques G. Muls , Arie Van Vliet , Carl R. Beck , Charles M. Yarbrough
IPC分类号： C07C67/08 , C07C29/04
CPC分类号： C07C29/141 , C07C29/149 , C07C31/125
摘要： Oxo-alcohols in the plasticiser range typically contain small amounts of methyl esters having the same alkyl chain as the alcohol itself. These methyl esters are causing product quality problems and environmental problems because of transesterification in the esterification process where the plasticiser ester derivatives are produced. A process using controlled oxonation and hydrogenation conditions is disclosed for the production of alcohols containing low amounts of methyl esters. Plasticiser esters with low amounts of aliphatic di-alkyl esters are also disclosed.
摘要翻译：在增塑剂范围内的氧代醇通常含有少量与醇本身具有相同烷基链的甲基酯。这些甲酯在产生增塑剂酯衍生物的酯化过程中由于酯交换而引起产品质量问题和环境问题。公开了一种使用受控的氧化和氢化条件的方法，用于生产含有少量甲酯的醇。还公开了具有少量脂族二烷基酯的增塑剂酯。

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