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    • 3. 发明授权
    • Dimensionally stable polyester yarn for high tenacity treated cords
    • 适用于高强度处理帘线的尺寸稳定的聚酯纱线
    • US07108818B2
    • 2006-09-19
    • US10980546
    • 2004-11-03
    • Charles Jay NelsonJayendra Hiralal BhedaPeter Bryan RimJames Michael Turner
    • Charles Jay NelsonJayendra Hiralal BhedaPeter Bryan RimJames Michael Turner
    • D01D5/088
    • D01F6/62D01D5/12Y10T428/2913Y10T428/2969
    • A spun polyester fiber, a drawn polyester yarn, and methods for making them. Polyethylene terephthalate yarn is prepared by extruding a molten melt-spinnable polyethylene terephthalate having an intrinsic viscosity of at least about 0.8 through a shaped extrusion orifice having a plurality of openings to form a molten spun yarn; solidifying gradually said molten spun yarn by passing said molten spun yarn through a solidification zone which comprises (i) a retarded cooling zone and (ii) a cooling zone adjacent said retarded cooling zone where, in said cooling zone, said yarn is rapidly cooled and solidified in a gaseous atmosphere; withdrawing at sufficient speed said solidified yarn from said solidification zone to form a crystalline partially oriented yarn; and hot drawing said crystalline partially oriented yarn at a total draw ratio between about 1.5/1 and about 2.5/1 to produce a drawn yarn having an effective crosslink density (N) between about 10×1021 and about 20×1021 crosslinks per cubic centimeter. The yarns and fibers so prepared may be used to make treated tire cord having high tenacity in combination with improved dimensional stability.
    • 纺丝聚酯纤维,拉伸聚酯纱线及其制造方法。 聚对苯二甲酸乙二醇酯纱线通过具有多个开口的成型挤出孔挤出特性粘度至少为约0.8的熔融可纺丝聚对苯二甲酸乙二醇酯制成,以形成熔融纺丝纱线; 通过使所述熔融纺丝通过固化区,使熔融纺丝逐渐凝固,所述固化区包括(i)延迟冷却区和(ii)与所述延迟冷却区相邻的冷却区,在所述冷却区中所述纱快速冷却, 在气氛中固化; 以足够的速度从所述固化区抽出所述固化纱线以形成结晶部分取向的纱线; 并且以约1.5 / 1至约2.5 / 1的总拉伸比热拉伸所述结晶部分取向的纱线,以产生具有约10×10 21至约20×10 10的有效交联密度(N)的拉伸丝 每立方厘米交联。 如此制备的纱线和纤维可用于制造具有高强度的处理轮胎帘线,同时具有改进的尺寸稳定性。
    • 4. 发明授权
    • Dimensionally stable polyester yarn for high tenacity treated cords
    • 适用于高强度处理帘线的尺寸稳定的聚酯纱线
    • US06828021B2
    • 2004-12-07
    • US10440642
    • 2003-05-19
    • Charles Jay NelsonJayendra Hiralal BhedaPeter Bryan RimJames Michael Turner
    • Charles Jay NelsonJayendra Hiralal BhedaPeter Bryan RimJames Michael Turner
    • D01F600
    • D01F6/62D01D5/12Y10T428/2913Y10T428/2969
    • A spun polyester fiber, a drawn polyester yarn, and methods for making them. Polyethylene terephthalate yarn is prepared by extruding a molten melt-spinnable polyethylene terephthalate having an intrinsic viscosity of at least about 0.8 through a shaped extrusion orifice having a plurality of openings to form a molten spun yarn; solidifying gradually said molten spun yarn by passing said molten spun yarn through a solidification zone which comprises (i) a retarded cooling zone and (ii) a cooling zone adjacent said retarded cooling zone where, in said cooling zone, said yarn is rapidly cooled and solidified in a gaseous atmosphere; withdrawing at sufficient speed said solidified yarn from said solidification zone to form a crystalline partially oriented yarn; and hot drawing said crystalline partially oriented yarn at a total draw ratio between about 1.5/1 and about 2.5/1 to produce a drawn yarn having an effective crosslink density (N) between about 10×1021 and about 20×1021 crosslinks per cubic centimeter. The yarns and fibers so prepared may be used to make treated tire cord having high tenacity in combination with improved dimensional stability.
    • 纺丝聚酯纤维,拉伸聚酯纱线及其制造方法。 聚对苯二甲酸乙二醇酯纱线通过具有多个开口的成型挤出孔挤出特性粘度至少为约0.8的熔融可纺丝聚对苯二甲酸乙二醇酯制成,以形成熔融纺丝纱线; 通过使所述熔融纺丝通过固化区,使熔融纺丝逐渐凝固,所述固化区包括(i)延迟冷却区和(ii)与所述延迟冷却区相邻的冷却区,在所述冷却区中所述纱快速冷却, 在气氛中固化; 以足够的速度从所述固化区抽出所述固化纱线以形成结晶部分取向的纱线; 并且以约1.5 / 1至约2.5 / 1的总拉伸比热拉伸所述结晶部分取向的纱线,以产生具有约10×10 21至约20×10 21交联的有效交联密度(N)的拉伸丝 立方厘米。 如此制备的纱线和纤维可用于制造具有高强度的处理轮胎帘线,同时具有改进的尺寸稳定性。
    • 5. 发明授权
    • Polymeric additives and polymeric articles comprising said additive
    • 包含所述添加剂的聚合物添加剂和聚合物制品
    • US06777496B2
    • 2004-08-17
    • US09778333
    • 2001-02-07
    • Kundan M. PatelCharles Jay NelsonFrank MaresConor TwomeyYousef Mohajer
    • Kundan M. PatelCharles Jay NelsonFrank MaresConor TwomeyYousef Mohajer
    • C08L6702
    • B60C9/0042C08J3/005C08L23/02C08L67/02C08L77/00D01F6/92Y10T152/10Y10T428/249933C08L23/00
    • We have developed a process and product which provide thermoplastic articles featuring a permanent outer surface which has selectively varied chemical functionality while maintaining the inherent mechanical properties of the base fiber. The process comprises the steps of: (a) adding a substantially organic molten component with CSP value of at least 8 to a molten thermoplastic polymer and mixing to substantially uniformly disperse the molten component in the molten thermoplastic polymer and form a heterogeneous blend wherein (i) the melt viscosity of the molten component is substantially less than the melt viscosity of the molten thermoplastic polymer; and (ii) the amount of the molten component in the molten thermoplastic polymer is up to about ten percent by weight based on the heterogeneous blend; and (b) melt processing the heterogeneous blend wherein the molten component preferentially locates near the surface of the molten thermoplastic polymer and substantially no chemical reaction occurs between the molten component and the molten thermoplastic polymer.
    • 我们开发了一种工艺和产品,其提供具有永久性外表面的热塑性制品,其具有选择性变化的化学功能,同时保持基础纤维的固有机械性能。 该方法包括以下步骤:(a)将CSP值至少为8的基本上有机的熔融组分加入到熔融的热塑性聚合物中并混合以使熔融组分基本均匀地分散在熔融的热塑性聚合物中并形成非均相共混物,其中(i )熔融组分的熔体粘度基本上小于熔融热塑性聚合物的熔体粘度; 和(ii)熔融热塑性聚合物中的熔融组分的量基于异质混合物高达约10重量%; 和(b)熔融加工非均相共混物,其中熔融组分优选位于熔融热塑性聚合物的表面附近,并且在熔融组分和熔融热塑性聚合物之间基本上不发生化学反应。