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    • 1. 发明申请
    • METHOD FOR PRODUCTION OF STABLE CERIUM OXIDE ORGANIC COLLOIDS
    • 生产稳定的氧化硅有机胶体的方法
    • US20130197107A1
    • 2013-08-01
    • US13753992
    • 2013-01-30
    • Cerion Technology, Inc.
    • Gary Robert ProkStephen Charles Williams
    • B01J13/00
    • B01J13/0047B01J13/003
    • An improved process for producing substantially non-polar doped or un-doped cerium oxide nanoparticle dispersions is disclosed. The cerium-containing oxide nanoparticles of an aqueous colloid are transferred to a substantially non-polar liquid comprising one or more amphiphilic materials, one or more low-polarity solvents, and one or more glycol ether promoter materials. The transfer is achieved by mixing the aqueous and substantially non-polar materials, forming an emulsion, followed by a phase separation into a remnant polar solution phase and a substantially non-polar organic colloid phase. The organic colloid phase is then collected. The promoter functions to speed the transfer of nanoparticles to the low-polarity phase. The promoter accelerates the phase separation, and also provides improved colloidal stability of the final substantially non-polar colloidal dispersion. Importantly, the glycol ether promoter reduces the temperature necessary to achieve the phase separation, while providing high extraction yield of nanoparticles into the low-polarity organic phase.
    • 公开了用于生产基本上非极性掺杂或未掺杂的氧化铈纳米颗粒分散体的改进方法。 将含水胶体的含铈氧化物纳米颗粒转移到包含一种或多种两亲物质,一种或多种低极性溶剂和一种或多种二醇醚促进剂材料的基本上非极性的液体中。 通过混合水性和基本上非极性材料,形成乳液,然后将相分离成剩余的极性溶液相和基本上非极性的有机胶体相来实现转移。 然后收集有机胶体相。 启动子用于加速纳米颗粒转移到低极性相。 促进剂加速相分离,并且还提供最终的基本上非极性的胶体分散体的改进的胶体稳定性。 重要的是,二醇醚促进剂降低了实现相分离所需的温度,同时提供了纳米颗粒到低极性有机相的高提取产率。
    • 3. 发明申请
    • RAPID METHOD FOR PRODUCTION OF CERIUM-CONTAINING OXIDE ORGANIC COLLOIDS
    • 用于生产含有氧化物有机胶体的快速方法
    • US20130192122A1
    • 2013-08-01
    • US13756971
    • 2013-02-01
    • Cerion Technology, Inc.
    • Gary Robert ProkStephen Charles Williams
    • C10L10/00
    • C10L1/1233C01G49/0054C01P2002/85C01P2004/04C01P2004/64C10L1/10C10L1/18C10L1/1826C10L1/1852C10L1/1881C10L10/00C10L10/02C10L2200/0245C10L2200/0254C10L2290/24C10M125/10C10M129/16C10M129/40
    • Improved methods for producing colloidal dispersions of cerium-containing oxide nanoparticles in substantially non-polar solvents is disclosed. The cerium-containing oxide nanoparticles of an aqueous colloid are transferred to a substantially non-polar liquid comprising one or more amphiphilic materials, one or more low-polarity solvents, and, optionally, one or more glycol ether promoter materials. The transfer is achieved by mixing the aqueous and substantially non-polar materials, forming an emulsion, followed by a phase separation into a remnant polar solution phase and a substantially non-polar organic colloid phase. The organic colloid phase is then collected. The promoter functions to speed the transfer of nanoparticles to the low-polarity phase. The promoter accelerates the phase separation, and also provides improved colloidal stability of the final substantially non-polar colloidal dispersion. The glycol ether promoter reduces the temperature necessary to achieve the phase separation, while providing high extraction yield of nanoparticles into the low-polarity organic phase. In addition, use of particular amphiphilic materials, such as heptanoic acid or octanoic acid, enable efficient extractions at ambient temperatures without the use of a glycol ether promoter.
    • 公开了用于在基本上非极性溶剂中生产含铈氧化物纳米粒子的胶体分散体的改进方法。 含水胶体的含铈氧化物纳米颗粒被转移到包含一种或多种两亲物质,一种或多种低极性溶剂和任选的一种或多种二醇醚促进剂材料的基本上非极性的液体中。 通过混合水性和基本上非极性材料,形成乳液,然后将相分离成剩余的极性溶液相和基本上非极性的有机胶体相来实现转移。 然后收集有机胶体相。 启动子用于加速纳米颗粒转移到低极性相。 促进剂加速相分离,并且还提供最终的基本上非极性的胶体分散体的改进的胶体稳定性。 二醇醚促进剂降低实现相分离所需的温度,同时提供纳米颗粒到低极性有机相的高提取产率。 此外,使用特定的两亲性物质,例如庚酸或辛酸,可以在环境温度下有效提取,而不使用二醇醚促进剂。