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    • 2. 发明授权
    • Scatterometry with grating to observe resist removal rate during etch
    • 用光栅进行散射测量以观察蚀刻期间的抗蚀剂去除率
    • US06982043B1
    • 2006-01-03
    • US10382181
    • 2003-03-05
    • Ramkumar SubramanianBharath RangarajanCatherine B. LabelleBhanwar SinghChristopher F. Lyons
    • Ramkumar SubramanianBharath RangarajanCatherine B. LabelleBhanwar SinghChristopher F. Lyons
    • B44C1/22
    • H01L22/12H01L22/26
    • Disclosed are a system and method for monitoring a patterned photoresist clad-wafer structure undergoing an etch process. The system includes a semiconductor wafer structure comprising a substrate, one or more intermediate layers overlying the substrate, and a first patterned photoresist layer overlying the intermediate layers, the semiconductor wafer structure being etched through one or more openings in the photoresist layer; a wafer-etch photoresist monitoring system programmed to obtain data relating to the photoresist layer as the etch process progresses; a pattern-specific grating aligned with the wafer structure and employed in conjunction with the monitoring system, the grating having at least one of a pitch and a critical dimension identical to the first patterned photoresist layer; and a wafer processing controller operatively connected to the monitoring system and adapted to receive data from the monitoring system in order to determine adjustments to a subsequent wafer clean process.
    • 公开了用于监测经历蚀刻工艺的图案化光致抗蚀剂包覆晶片结构的系统和方法。 该系统包括半导体晶片结构,其包括衬底,覆盖衬底的一个或多个中间层和覆盖中间层的第一图案化光致抗蚀剂层,半导体晶片结构通过光致抗蚀剂层中的一个或多个开口进行蚀刻; 晶片蚀刻光刻胶监测系统被编程为随着蚀刻工艺的进行获得与光致抗蚀剂层有关的数据; 与晶片结构对准并与监视系统结合使用的图案特定光栅,光栅具有与第一图案化光致抗蚀剂层相同的间距和临界尺寸中的至少一个; 以及晶片处理控制器,可操作地连接到所述监控系统并且适于从所述监控系统接收数据,以便确定随后的晶片清洁过程的调整。
    • 4. 发明授权
    • Growing copper vias or lines within a patterned resist using a copper seed layer
    • 使用铜种子层在图案化抗蚀剂中生长铜通孔或线
    • US06905950B2
    • 2005-06-14
    • US09893198
    • 2001-06-27
    • Ramkumar SubramanianMichael K. TempletonBhanwar SinghBharath Rangarajan
    • Ramkumar SubramanianMichael K. TempletonBhanwar SinghBharath Rangarajan
    • H01L21/768H01L21/3205
    • H01L21/76885H01L21/76879
    • The present invention involves a method for fabricating interconnecting lines and vias. According to the invention, copper is grown within the openings in a patterned coating. The patterned coating can be a resist coating or a dielectric coating. Either type of coating can be formed over a copper seed layer, whereby the seed layer is exposed within the pattern gaps. The copper seed layer can also be provided within the pattern gaps after patterning. Copper features are grown within the pattern gaps by plating. Where the patterned coating is a resist, the resist is stripped leaving the copper features in the inverse pattern image. The copper features can be coated with a diffusion barrier layer and a dielectric. The dielectric is polished to leave the dielectric filling the spaces between copper features. The invention provides copper lines and vias without the need for a dielectric or metal etching step. Another benefit of the invention is that lines widths can be increased by trimming the patterned coating prior to growing the copper features.
    • 本发明涉及制造互连线和通孔的方法。 根据本发明,铜在图案化涂层的开口内生长。 图案化的涂层可以是抗蚀剂涂层或介电涂层。 任何一种类型的涂层可以在铜籽晶层上形成,从而种子层在图案间隙内露出。 图案化之后也可以在图案间隙内提供铜籽晶层。 铜特征通过电镀在图案间隙内生长。 在图案涂层是抗蚀剂的情况下,剥离抗蚀剂,留下逆向图案图案中的铜特征。 铜的特征可以涂覆有扩散阻挡层和电介质。 电介质被抛光以留下电介质填充铜特征之间的空间。 本发明提供铜线和通孔,而不需要电介质或金属蚀刻步骤。 本发明的另一个好处是通过在生长铜特征之前修整图案化涂层可以增加线宽。
    • 8. 发明授权
    • Vapor drying for cleaning photoresists
    • 用于清洁光致抗蚀剂的蒸气干燥
    • US06663723B1
    • 2003-12-16
    • US09974276
    • 2001-10-10
    • Michael K. TempletonRamkumar SubramanianKhoi A. PhanBharath Rangarajan
    • Michael K. TempletonRamkumar SubramanianKhoi A. PhanBharath Rangarajan
    • B08B500
    • G03F7/40B08B7/00
    • One aspect of the present invention relates to a method of cleaning a patterned photoresist clad structure involving the steps of contacting the patterned photoresist clad structure with an alcohol vapor comprising at least one compound having the Formula ROH, wherein R is a hydrocarbon group comprising from 4 to about 8 carbon atoms; condensing the alcohol vapor on the patterned photoresist clad structure; and removing the condensed alcohol vapor from the patterned photoresist clad structure. Another aspect of the present invention involves the use of an alcohol vapor having a boiling point from about 102° C. to about 175° C. Yet another aspect of the present invention involves the use of an alcohol vapor having a flash point from about 15° C. to about 80° C.
    • 本发明的一个方面涉及一种清洁图案化光致抗蚀剂包覆结构的方法,该方法包括以下步骤:使图案化的光致抗蚀剂包覆结构与包含至少一种具有式ROH的化合物的醇蒸气接触,其中R是包含4 至约8个碳原子; 在图案化的光致抗蚀剂包层结构上冷凝酒精蒸气; 并从图案化的光致抗蚀剂包覆结构去除冷凝的醇蒸气。 本发明的另一方面涉及使用沸点为约102℃至约175℃的醇蒸气。本发明的另一方面涉及使用闪点为约15℃的醇蒸汽 ℃至约80℃
    • 10. 发明授权
    • Treat resist surface to prevent pattern collapse
    • 处理抗蚀剂表面以防止图案塌陷
    • US06645702B1
    • 2003-11-11
    • US10050438
    • 2002-01-16
    • Bharath RangarajanMichael K. TempletonBhanwar Singh
    • Bharath RangarajanMichael K. TempletonBhanwar Singh
    • G03F700
    • G03F7/265H01L21/0273H01L21/31144H01L21/32139
    • The present invention relates to systems and methods for increasing the hydrophobicity of patterned resists. In one embodiment, the present invention relates to a method of processing an ultra-thin resist, involving depositing the ultra-thin photoresist over a semiconductor substrate; irradiating the ultra-thin resist with electromagnetic radiation; developing the ultra-thin resist with a developer to form a patterned resist, the patterned resist having a surface with a first hydrophobicity; contacting the patterned resist with a transition solvent to provide the surface of the patterned resist with a second hydrophobicity, wherein the second hydrophobicity is greater than the first hydrophobicity and contact of the patterned resist with the transition is conducted between developing the ultra-thin resist and rinsing patterned resist; and rinsing the patterned resist having the second hydrophobicity with an aqueous solution.
    • 本发明涉及增加图案化抗蚀剂疏水性的系统和方法。 在一个实施例中,本发明涉及一种处理超薄抗蚀剂的方法,包括在半导体衬底上沉积超薄光致抗蚀剂; 用电磁辐射照射超薄抗蚀剂; 用显影剂显影超薄抗蚀剂以形成图案化抗蚀剂,图案化抗蚀剂具有第一疏水性表面; 使图案化的抗蚀剂与过渡溶剂接触以提供具有第二疏水性的图案化抗蚀剂的表面,其中第二疏水性大于第一疏水性,并且图案化的抗蚀剂与转变的接触在显影超薄抗蚀剂和 冲洗图案抗蚀剂; 并用水溶液冲洗具有第二疏水性的图案化抗蚀剂。