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    • 5. 发明授权
    • Electrophotographic recording material containing photoconductive
porphyrin compounds
    • 含有光电性磷杂环化合物的电子记录材料
    • US5134048A
    • 1992-07-28
    • US611015
    • 1990-11-09
    • David R. TerrellStefaan K. De MeutterBernd Kaletta
    • David R. TerrellStefaan K. De MeutterBernd Kaletta
    • C09B47/00G03G5/06
    • G03G5/0696C09B47/00
    • An electrophotographic recording material comprising a conductive support and a photosensitive layer containing at least one photoconductive compound that has p-type charge generating capacity and is a tetrabenzoporphyrin type compound represented by the following general formula (I): ##STR1## wherein: each of X.sup.1, X.sup.2, X.sup.3, and X.sup.4 (same or different) represents a substituent selected from the group consisting of halogen, e.g. chlorine or bromine, nitro, cyano, (C.sub.1 -C.sub.2) alkyl and alkoxy, e.g. methoxy or ethoxy or 2 X.sup.1 's, 2 X.sup.2 's, 2 X.sup.3 's or 2 X.sup.4 's together represent the atoms necessary to form a substituted or unsubstituted carbocyclic or heterocyclic ring system;k, l, m, and n each and independently represent zero or an integer 1 to 4, R.sup.1 represents hydrogen, a (C.sub.1 -C.sub.2) alkyl, aralkyl or aryl group; each of the A's (same or different) represents nitrogen, or a CR.sup.2 group, wherein each of the R.sup.2 's (same or different) represents hydrogen, a (C.sub.1 -C.sub.2) alkyl, aralkyl or aryl group; and Z is hydrogen or two groups Z together stand for a metal atom which in the case of higher valency state than 2, will be linked to (an) additional valency compensating atom(s) or group.
    • 一种电子照相记录材料,其包含导电性支持体和含有至少一种具有p型电荷产生能力的光电导性化合物的感光层,并且是由以下通式(I)表示的四苯并卟啉型化合物:其中: X 1,X 2,X 3和X 4(相同或不同)表示选自卤素的取代基,例如, 氯或溴,硝基,氰基,(C1-C2)烷基和烷氧基。 甲氧基或乙氧基或2个X 1,2个X 2,2个X 3或2个X 4一起代表形成取代或未取代的碳环或杂环系所必需的原子; k,l,m和n各自独立地表示0或1〜4的整数,R1表示氢,(C1-C2)烷基,芳烷基或芳基; A(相同或不同)各自表示氮或CR 2基团,其中R2(相同或不同)表示氢,(C1-C2)烷基,芳烷基或芳基; 并且Z是氢或两个基团Z一起代表金属原子,在高于2的情况下,其将与(a)另外的化合价补偿原子或基团连接。
    • 6. 发明授权
    • Process for preparation of asymmetric isoindoline pigments
    • 不对称异吲哚啉颜料的制备方法
    • US5326872A
    • 1994-07-05
    • US843591
    • 1992-03-06
    • Barbara J. WagnerBernd Kaletta
    • Barbara J. WagnerBernd Kaletta
    • C09B57/04C07D403/04
    • C09B57/04
    • This invention relates to a process for preparing asymmetric isoindoline pigments of the formula ##STR1## in which R.sup.1 is an electron-withdrawing group, R.sup.2 and R.sup.3 are independently hydrogen, alkyl, or aryl, and R.sup.4 R.sup.5 R.sup.6 and R.sup.7 are independently hydrogen, halogen, alkyl, alkoxy, or aryloxy. The process employs an initial reaction of a 1,2-dicyanobenzene with an alcohol in an organic medium in the presence of a base. The resultant imino-isoindoline intermediate composition reacts without isolation with a cyanomethylene compound NC--CH.sub.2 -R.sup.1 to form a partly condensed product that is then condensed, optionally without isolation, in the presence of water with barbituric acid or a derivative thereof to form the asymmetric isoindoline pigment.
    • 本发明涉及一种制备式“IMAGE”的不对称异吲哚啉颜料的方法,其中R 1是吸电子基团,R 2和R 3独立地是氢,烷基或芳基,R 4 R 6和R 6独立地是氢,卤素, 烷基,烷氧基或芳氧基。 该方法在碱的存在下,在有机介质中使用1,2-二氰基苯与醇的初始反应。 得到的亚氨基 - 异二氢吲哚中间体组合物与氰基亚甲基化合物NC-CH2-R1分离反应以形成部分缩合的产物,然后在水与巴比妥酸或其衍生物存在下,任选不经分离而缩合,形成不对称的 异吲哚啉颜料。
    • 8. 发明授权
    • Process for preparation of asymmetric isoindoline pigments
    • 不对称异吲哚啉颜料的制备方法
    • US5177209A
    • 1993-01-05
    • US689398
    • 1991-04-22
    • Barbara J. WagnerBernd Kaletta
    • Barbara J. WagnerBernd Kaletta
    • C09B57/04
    • C09B57/04
    • This invention relates to a process for preparing asymmetric isoindoline pigments of the formula ##STR1## in which R.sup.1 is an electron-withdrawing group, R.sup.2 and R.sup.3 are independently hydrogen, alkyl, or aryl, and R.sup.4, R.sup.5, R.sup.6, and R.sup.7 are independently hydrogen, halogen, alkyl, alkoxy, or aryloxy. The process employs an initial reaction of a 1,2-dicyanobenzene with an alcohol in an organic medium in the presence of a base. The resultant imino-isoindoline intermediate composition reacts without isolation with a cyanomethylene compound NC--CH.sub.2 --R.sup.1 to form a partly condensed product that is then condensed without isolation in the presence of water with barbituric acid or a derivative thereof to form the asymmetric isoindoline pigment.
    • 本发明涉及制备式“IMAGE”的不对称异吲哚啉颜料的方法,其中R 1是吸电子基团,R 2和R 3独立地是氢,烷基或芳基,并且R 4,R 5,R 6和R 7独立地是 氢,卤素,烷基,烷氧基或芳氧基。 该方法在碱的存在下,在有机介质中使用1,2-二氰基苯与醇的初始反应。 得到的亚氨基 - 异二氢吲哚中间体组合物与氰基亚甲基化合物NC-CH2-R1分离反应以形成部分缩合的产物,然后在水与巴比妥酸或其衍生物存在下分离而冷凝,形成不对称异吲哚啉颜料。