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1. 发明授权

US09328191B2 Resin for use in a coating composition 有权
标题翻译：用于涂料组合物的树脂
公开(公告)号：US09328191B2
公开(公告)日：2016-05-03
申请号：US13577128
申请日：2011-02-04
申请人： Anthony J. Tye , Ali A. Rihan , Jeff Pierce
发明人： Anthony J. Tye , Ali A. Rihan , Jeff Pierce
IPC分类号： B32B27/30 , C09D123/26 , C09D133/06 , C09D151/00 , C08G81/00 , C08G81/02 , C08F299/00 , C08G18/62 , C08G18/10 , C08L23/08 , C08L23/26 , C08L33/00 , C08L33/06 , C08L67/00
CPC分类号： C08G18/6204 , C08F299/00 , C08G18/10 , C08G81/021 , C08L23/0846 , C08L23/0884 , C08L23/0892 , C08L23/26 , C08L33/00 , C08L33/062 , C08L67/00 , C08L2205/05 , C09D123/26 , C08G18/792 , C08L2666/02 , C08L2666/18 , C08L2666/20 , C08L2666/06 , C08L23/06
摘要： A coating system comprises a substrate and a cured film disposed on the substrate and formed from a coating composition. The coating composition comprises a solvent component and a resin. The resin comprises a reaction product of a polyolefin and an oligomer or polymer. The polyolefin, different from the oligomer or polymer, has a functional group that is reactive with the oligomer or polymer and the functional group is selected from acrylate, methacrylate, carboxyl, hydroxyl, epoxide, anhydride and isocyanate functional groups. The oligomer or polymer and the polyolefin are at least partially immiscible in solution at ambient temperature. The oligomer or polymer is grafted with the polyolefin to form the resin.
摘要翻译：涂料体系包括基材和设置在基材上并由涂料组合物形成的固化膜。涂料组合物包含溶剂组分和树脂。树脂包括聚烯烃和低聚物或聚合物的反应产物。与低聚物或聚合物不同的聚烯烃具有与低聚物或聚合物反应的官能团，官能团选自丙烯酸酯，甲基丙烯酸酯，羧基，羟基，环氧化物，酸酐和异氰酸酯官能团。低聚物或聚合物和聚烯烃在环境温度下至少部分地不溶于溶液。低聚物或聚合物与聚烯烃接枝以形成树脂。

2. 发明授权

US06369214B1 Method of dispersing a pigment 失效
标题翻译：分散颜料的方法
公开(公告)号：US06369214B1
公开(公告)日：2002-04-09
申请号：US09410912
申请日：1999-09-30
申请人： Anthony J. Tye , Gerald L. Bajc
发明人： Anthony J. Tye , Gerald L. Bajc
IPC分类号： C08B300
CPC分类号： C09D101/14 , B01F17/005 , C08B3/22 , C08K3/04 , C08K3/22 , C08K5/3462 , C08K5/357 , C09D7/61 , C09D7/63 , C09D17/004
摘要： Disclosed are a method of dispersing a pigment, a pigment dispersion, a coating composition comprising said pigment dispersion, an method of making a coating composition, and a method of improving the appearance of a coating composition. The pigment dispersion of the invention requires at least one pigment subjected to an action to decrease the average particle size of the pigment in the presence of an amine functional cellulose ester resin. The amine functional cellulose ester resins comprise at least one repeat unit of the structure: wherein R1, R2, and R3 are selected independently from the group consisting of hydrogen, R4C═O, and wherein at least one of R1, R2, and R3 is hydrogen, at least one of R1, R2, and R3 is R4C═O, and at least one of R1, R2, or R3 have the structure R4 is selected from the group consisting of C1-C20 alkyl groups, C1-C20 phenyl groups, C1-C20 napthyl groups, and C1-C20 alkenyl groups, L is a divalent linking group and R6 is selected from the group consisting of H and compounds having at least one secondary amine group, tertiary amine group, and mixtures thereof.
摘要翻译：公开了一种分散颜料，颜料分散体，包含所述颜料分散体的涂料组合物，制备涂料组合物的方法和改进涂料组合物外观的方法的方法。本发明的颜料分散体需要至少一种在胺官能纤维素酯树脂的存在下进行作用以降低颜料的平均粒度的颜料。胺官能纤维素酯树脂包含至少一个结构重复单元：其中R1，R2和R3独立地选自氢，R4C = O，其中R1，R2和R3中的至少一个是氢，R 1，R 2和R 3中的至少一个为R 4 C = O，R 1，R 2或R 3中的至少一个具有结构R 4选自C 1 -C 20烷基，C 1 -C 20苯基，C 1 -C 20萘基和C 1 -C 20链烯基，L是二价连接基团，R 6选自H和具有至少一个仲胺基团的化合物，叔胺基团及其混合物。

3. 发明授权

US06329491B1 Single stage carbodiimide containing coating compositions 失效
标题翻译：含单层碳化二亚胺的涂料组合物
公开(公告)号：US06329491B1
公开(公告)日：2001-12-11
申请号：US08928185
申请日：1997-09-12
申请人： Patrick J. Mormile , Anthony J. Tye , Stewart Shepler
发明人： Patrick J. Mormile , Anthony J. Tye , Stewart Shepler
IPC分类号： C08G1808
CPC分类号： C08G18/341 , C08G18/025 , C08G18/6229 , C08G18/797 , C09D175/04 , Y10S525/907
摘要： Non-isocyanate single stage coating compositions are disclosed. The composition is especially useful in air-dry systems and comprises a co-reactant having active hydrogen functionality, at least one anhydride functional co-reactant and a novel carbodiimide compound.
摘要翻译：公开了非异氰酸酯单级涂料组合物。该组合物在空气干燥系统中特别有用，并且包含具有活性氢官能团的共反应物，至少一种酸酐官能共反应物和新型碳二亚胺化合物。

4. 发明授权

US5578675A Non-isocyanate basecoat/clearcoat coating compositions which may be ambient cured 失效
标题翻译：可以环境固化的非异氰酸酯底漆/透明涂料涂料组合物
公开(公告)号：US5578675A
公开(公告)日：1996-11-26
申请号：US331313
申请日：1994-12-27
申请人： Patrick J. Mormile , Rajnikant P. Shah , Anthony J. Tye
发明人： Patrick J. Mormile , Rajnikant P. Shah , Anthony J. Tye
IPC分类号： C08G18/79 , C08G65/332 , C08G65/333 , C08G71/00 , C09D167/00 , C09D169/00 , C09D179/00 , C08G18/00 , C08L75/00
CPC分类号： C08G18/797 , C08G65/3324 , C08G65/33331 , C08G71/00 , C09D167/00 , C09D169/00 , C09D179/00
摘要： Improved basecoat--clearcoat paint coating compositions which may be ambient cured are disclosed. The coating compositions comprise:1) a hydroxyl functional coreactant,2) at least one anhydride functional coreactant and,3) a carbodiimide compound.The improved compositions cure at a rate especially useful as refinish paint compositions.
摘要翻译：公开了可以环境固化的改进的底漆 - 透明漆涂料组合物。涂料组合物包括：1）羟基官能共反应物，2）至少一种酸酐官能共反应物，和3）碳二亚胺化合物。改进的组合物以特别用作修补漆组合物的速率固化。

5. 发明授权

US06229007B1 Amine functional cellulose ester compounds and methods of making the same 失效
标题翻译：胺功能性纤维素酯化合物及其制备方法
公开(公告)号：US06229007B1
公开(公告)日：2001-05-08
申请号：US09410911
申请日：1999-09-30
申请人： Anthony J. Tye , Gerald L. Bajc
发明人： Anthony J. Tye , Gerald L. Bajc
IPC分类号： C08B300
CPC分类号： C08B3/22
摘要： Disclosed are amine functional cellulose ester resins and methods of making the same. The amine functional cellulose ester resins comprise at least one repeat unit of the structure: wherein R1, R2, and R3 are selected independently from the group consisting of hydrogen, R4C═O, and wherein at least one of R1, R2, and R3 is hydrogen, at least one of R1, R2, and R3 is R4C═O, and at least one of R1, R2, or R3 have the structure R4 is selected from the group consisting of C1-C20 alkyl groups, C1-C20 phenyl groups, C1-C20 napthyl groups, and C1-C20 alkenyl groups, L is a divalent linking group and R6 is selected from the group consisting of H and compounds having at least one secondary amine group, tertiary amine group, and mixtures thereof.
摘要翻译：公开了胺官能纤维素酯树脂及其制备方法。胺官能纤维素酯树脂包含至少一个结构重复单元：其中R1，R2和R3独立地选自氢，R4C = O，其中R1，R2和R3中的至少一个是氢，R 1，R 2和R 3中的至少一个为R 4 C = O，R 1，R 2或R 3中的至少一个具有结构R 4选自C 1 -C 20烷基，C 1 -C 20苯基，C 1 -C 20萘基和C 1 -C 20链烯基，L是二价连接基团，R 6选自H和具有至少一个仲胺基团的化合物，叔胺基团及其混合物。

6. 发明授权

US06610817B2 Coating composition containing alcoholic reactive diluents 有权
标题翻译：含醇反应性稀释剂的涂料组合物
公开(公告)号：US06610817B2
公开(公告)日：2003-08-26
申请号：US09740329
申请日：2000-12-18
申请人： William H. Plassmann , Anthony J. Tye , Patrick J. Mormile
发明人： William H. Plassmann , Anthony J. Tye , Patrick J. Mormile
IPC分类号： C08G5914
CPC分类号： C08G59/1444 , C08G59/1455 , C09D7/20
摘要： Reactive diluents are formed by reaction of a compound having at least two glycidyl ester groups and a compound having at least one hydroxyl and/or carboxyl group. The diluents are useful in coating compositions together with crosslinking agents and optional other vehicle components.
摘要翻译：反应性稀释剂通过具有至少两个缩水甘油酯基的化合物和具有至少一个羟基和/或羧基的化合物的反应形成。稀释剂可与涂料组合物一起用于交联剂和任选的其它载体组分。

7. 发明授权

US06384119B1 Coating compositions comprising volatile linear siloxane fluids 失效
标题翻译：包含挥发性线性硅氧烷流体的涂料组合物
公开(公告)号：US06384119B1
公开(公告)日：2002-05-07
申请号：US09612023
申请日：2000-07-07
申请人： Anthony J. Tye , Ali A. Rihan
发明人： Anthony J. Tye , Ali A. Rihan
IPC分类号： C08K55415
CPC分类号： C09D7/63 , C08K5/5415
摘要： The present invention provides a coating composition comprising no more than 2.00% by weight nonvolatile of Si-containing compounds, based on the total nonvolatile weight of the coating composition, and from 0.25 to no more than 5.0% by weight of a volatile linear siloxane of the formula: (R)3—Si—O—((R)2—Si—O)y—Si—(R)3 wherein R is H or an alkyl group of from 1 to 3 carbon atoms and y is a number from 0 to 6, based on the total nonvolatile weight of the coating composition. The invention also provides a method of providing a cured coating composition having an improved distinctness of image as well as a method of coating a substrate. The compositions of the invention have improved resistance to visual defects believed to be caused by surface contamination, such as “fisheyes” or “cratering” and “telegraphing”.
摘要翻译：本发明提供一种涂料组合物，其包含不超过2.00重量％的含Si化合物的不挥发性，基于涂料组合物的总不挥发重量，以及0.25至不超过5.0重量％的挥发性线性硅氧烷式中R为H或1至3个碳原子的烷基，y为0至6的数，基于涂料组合物的总非挥发重量。本发明还提供一种提供具有改进的图像清晰度的固化涂料组合物的方法以及涂布基材的方法。本发明的组合物具有改善的抗视觉缺陷，这些视觉缺陷被认为是由表面污染引起的，例如“鱼眼”或“火山口”和“电报”。

8. 发明授权

US5357021A Reactive carbodimide compositions 失效
标题翻译：活性碳二酰亚胺组合物
公开(公告)号：US5357021A
公开(公告)日：1994-10-18
申请号：US95076
申请日：1993-07-21
申请人： Anthony J. Tye , George G. Beck , Patrick J. Mormile
发明人： Anthony J. Tye , George G. Beck , Patrick J. Mormile
IPC分类号： C07C267/00 , C08G18/79 , C08G73/00 , C08G18/30
CPC分类号： C08G73/00 , C07C267/00 , C08G18/797 , C07C2101/14
摘要： Novel reactive carbodiimide compounds and their method of preparation are disclosed. These reactive carbodiimide compounds are especially useful in automotive paint compositions and more particularly in low volatile organic content (VOC) automotive paint compositions.
摘要翻译：公开了新型反应性碳二亚胺化合物及其制备方法。这些反应性碳二亚胺化合物特别适用于汽车涂料组合物，更特别是在低挥发性有机物（VOC）汽车涂料组合物中。

9. 发明授权

US09309434B2 Scratch resistant refinish clearcoat 有权
标题翻译：耐刮擦修补漆
公开(公告)号：US09309434B2
公开(公告)日：2016-04-12
申请号：US13878435
申请日：2011-10-19
申请人： Ali Rihan , Anthony J. Tye
发明人： Ali Rihan , Anthony J. Tye
IPC分类号： C09D133/14 , C09D133/08 , C08G18/36 , C08G18/62 , C08G18/65 , C09D175/04
CPC分类号： C09D133/14 , C08G18/36 , C08G18/6229 , C08G18/6254 , C08G18/6547 , C09D175/04 , Y10T428/31551
摘要： Scratch resistance and/or reflow of a refinish topcoat is improved by preparing the topcoat from a refinish topcoat coating composition comprising an unsaturated fatty acid ester polyol that does not undergo oxidative cure when the applied refinish topcoat coating composition is cured.
摘要翻译：通过从包含不饱和脂肪酸酯多元醇的修补面漆涂料组合物制备面漆可以改善涂层顶涂层的耐擦伤性和/或回流性能，所述不饱和脂肪酸酯多元醇在施用的修补面漆涂料组合物固化时不进行氧化固化。

10. 发明授权

US6063890A Polycarbodiimide polymers and their use as adhesive intermediate layers in automotive coatings 失效
标题翻译：聚碳化二亚胺聚合物及其作为汽车涂料中粘合剂中间层的用途
公开(公告)号：US6063890A
公开(公告)日：2000-05-16
申请号：US108497
申请日：1998-07-01
申请人： Anthony J. Tye
发明人： Anthony J. Tye
IPC分类号： C08G18/02 , C08G18/80 , C08G59/40 , C08G59/42 , C08G59/50 , C08G73/10 , C09D163/00 , C09D175/00 , C08G18/10 , C08G18/64 , C08G18/71 , C08G18/81
CPC分类号： C08G59/5006 , C08G59/4042 , C08G59/4207 , C09D163/00
摘要： The invention is directed to a block copolymer with the following representative structure:R.sub.1 --X--[[R.sub.2 --N.dbd.C.dbd.N--R.sub.2 --].sub.n [--X--R.sub.3 --X].sub.p --[R.sub.2 --N.dbd.C.dbd.N--R.sub.2 ].sub.r ].sub.m X--R.sub.1Where:m=1 to 20n=1 to 20p=0 or 1R.sub.1 =A monomeric or polymeric species containing only one functional group reactive with an isocyanate group. This species may also have another reactive functional group that is not reactive with a carbodiimide functionality such as an alkoxy silane.R.sub.2 =The radical from any available aliphatic, cycloaliphatic or shielded aromatic diiocyanate.R.sub.3 =Preformed polymer blocks such as a polyester, polyacrylate, polyurethane, polyether, polyethylene, polycarbonate, polyurea polysiloxane or similar hybrids.X=any combination of: ##STR1## The copolymer may be used in various automotive paint compositions. The resin may be prepared by first synthesizing the desired blocks, the polycarbodiimide blocks and the modifying blocks, then link them together. The resin may also be prepared by forming the polycarbodiimide directly onto the modifying blocks. The latter approach is the preferred one. The modifying blocks are prepared in the conventional manner for the chemistry and the choice of the modifying blocks depend on the application. For proper topcoat wetting, it is desired that some portion of the modifying blocks be highly polar.
摘要翻译：本发明涉及具有以下代表性结构的嵌段共聚物：R1-X - [[R2-N = C = N-R2-] n [-X-R3-X] p- [R2-N = C = N -R2] r] mX-R1其中：m = 1至20n = 1至20p = 0或1 R1 =仅含有一个与异氰酸酯基团反应的官能团的单体或聚合物质。该物质还可以具有不与碳二亚胺官能团反应的另一反应性官能团，例如烷氧基硅烷。 R2 =来自任何可用的脂族，脂环族或屏蔽芳族二异氰酸酯的基团。 R3 =预成型聚合物嵌段如聚酯，聚丙烯酸酯，聚氨酯，聚醚，聚乙烯，聚碳酸酯，聚脲聚硅氧烷或类似的混合物。 X =任何组合：共聚物可用于各种汽车涂料组合物中。树脂可以通过首先合成所需的嵌段，聚碳二亚胺嵌段和改性嵌段，然后将它们连接在一起来制备。也可以通过将聚碳化二亚胺直接形成到改性嵌段上来制备树脂。后一种方法是首选方法。修改块以常规的化学方式制备，并且修改块的选择取决于应用。为了适当的顶涂润湿，希望部分改性嵌段是极性极性的。

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